The Effects of Palm Oil MES Surfactant and Inorganic Salt Concentration on Interfacial Tension Values

2015 3rd International Conference on Adaptive
and Intelligent Agroindustry (ICAIA)

T A BLE OF CONTENT S

Innovative Agroindustriai and Business System Engineering
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Induslry From Spent Bleaching Earth
Fcbriani Purha. Ani Suryani and Sukardi
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An Antilysis of innovation Network Perfonnance on the Palm Oii industry
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Danang Krisna Yudha, Aji Hennawan and Machfud
Exploring the Internationalization Process ModeJ of an Indonesian Product
- Case study : Fruit Chips SME's
Dicki e Sulistya Apri liyanto, Hartrisari Hardjomidjojo, Titi C Sunarti
Innovation Management in Indonesian Palm Oi l Industry
Karim Abdullah, Aji Hennawan and Yandra Arkeman
Technology Innovation A.dopt'ion to Improve the Performance of Dairy
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Regency, West Java, Indones ia
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Managing Innovation through Knowledge Sharing in An Indonesia Coconut

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SM£
Muchammad Kodiyat P, Machfud, Nastiti S Indrasti
Increasing Added Value of Banana by Producing Synbiotic Banana " Sale"
Using Innovation & Technology Strategy Approach
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An AHP Appl ication for Selecting A Business lnnovation Stratef.,ry of
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Yani Kartika Pcrtiwi, M. Syamsul Maari f and Machfud
Understanding local food consumers and their motivations: A ease srudy in
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Spat ial Modcl Design for Competitive Improvcment of Small Medium
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System Analysis and Design for Seleciing Chitin and Chitosan Industry
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Tr:lnspon;uion

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Delmar Zakaria Firdaus and Endang Warsiki
Devc!opment of Downstream Cocoa Industry: Exploring the Role of T-95

Government and Small and Medium Industry in Partnership
Farda Eka Kusumawardana. Yandra Arkcman , Titi C Sunarti
1-101
The Rol e of Communi carion in the Technology Transfer Process
Anindita Dibyono. Sukardi. Machfud
The Center for Pulp and Paper Appraising its Productivity in Generating 1-10&
Industry-Applicable Research: A Good Practice Illustration
Ahmad Rudh Firdausi, Anas M Fauzi, Machfud

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Kurz) Leaf Extra
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The Comparison Of Media on the Microalgae Nannoch loropsis sp. Culture
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Gunam
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Endang Warsiki and Riris OClaviasari

The Effects of Palm Oil MES Surfactant and Inorganic Sail Concentration
on Interfacial Tension Values
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Pudji Pennadi. Bonar T.H Marbun and AT; Imam Sutamo
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through Tcnsile Test Analysis for Composite Reinforced Material
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Mclati Pratama. Endang Warsiki and Liesbetini Hartoto
Enhancing Ethanol Tolerant of Escherichia coli Recombinant by Glutamate
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Putra

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Ardhi Novrialdi Ginting. Liesbetini Haditjaroko and Iriani
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The Potential Applications of Modified Nagara Bean Fl our through
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Modelling Site-Specific Activities and Conditions

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Vita D Lclyana. Erwinsyah and Kiyotada Hayashi
Sequential PaHcm Mining on Hotspot Data using PrefixSpan Algorithm
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An Intelligent Optimization Model Analysis and Design ofSio-filtration in

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セ dゥュ・ョウッ。ャ@
Research Knowledge Model from
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ArifR. Hakim and Taufik Djalna
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セ n」オイッ@
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Joko Ratono, Kudang Boro Seminar, Yandra Arkeman and Arif Imam
Suroso

ivセRP@
jv

セ RT@

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セ SP@

セ SW@

tvセTQ@

AvセTW@

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セ UP@

イカ

セ US@

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セ UW@

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セ WT@

ICAIA 2015

ISBN: 978- 1-4673-7405-7

The Effects of Palm Oil MES Surfactant and Inorganic Salt
Concentration on Interfacial Tension Values
Risla Fitria. Eliza Hambali. Ani Suryani. Pudji Permadi. Mi ra Riva L Ari Imam

Laboratory o/SlIr/a ctGIIl a1/d Bioel/ergy Research Center
Faculty 0/ Agricultllral Technology. Hogor Agriculmral University
Program Study of Petroleum Engineering. Bandung Imililllte o/Technology
E-mail: risfit.92@gmail.com.erli=a.h@gmail.com.anisuryoni.sbrcipb@gmail.c:om.
pudji@tm.itb.ac.id. me_ raril'Oi@yahoo.com. art_imam@yallOo.c:um
Abstruct- Thc application of ュ」エィセ
G Q@
ester
sulfonic (MES) surfactant for enhanced oil
セ」ッカ・ャBIG@
(EOR) ""as 「セウ・、@
on its ability to reduce
interfacial tension in c rude oil-water- S\'s(cm that
reacbed 10'') dyne/cm. Performa nce of セ ・エ ィ ケ ャ@ este r
sulfonic (MES) surfactant from palm oil can be
identified with the spinning drop lIT method. T he
objectives of this research were to dt:lennine MES
surfactant perfonnance with the addition of
inorganic salt in differenr conditions. The
dispersing medi.a used ill this research were
demine rali7.cd w.ater and fonnation wate r. The
spinning dr-op 1FT method was conducted オ ウェョセ@
spinnillg drop te nsiometer TXSOOD tested in 40, 50
and 60"C. Results showed that reductio n of 1FT
values was affected by MES N セオイヲ。」エョ@
and
inorganic slI lr concentration In the 、」ュゥ
ョ セイ。ャコ・、@
water and fonnation watE'r :lS dis pcl"Sion medium.
Methyl [ster- Sulfonic surfacta nt could react better
at salinity nmgcs of 5000-25000 ppm.
!. fNTRODUCTIOl\
he application of surf.1clnnt for enhance oil
rccovcry (EOR) needs particular requirements
including ultralow interfacialtcnsion (:510.3 dyne/cm).
In
compatibility with formation water and セエ。「ゥャケ@
T

Manll>-("flpt rCCi "f nセci@
com:cnlr;ll;on Jnd ュcセw|ZiエャQ@
1CD1rott'.llllrCS on IFf valUe< orO, 3°;. MES
iOrm.11iQfl "''''leI' 、ゥセqヲャ@
medium
セオイヲcャ。u|@

in

It was found in this study that the addition of Nael
to dcminenllized water (1m,! formal ion waler resultcd in

increased 1FT values. In water fo rmation dispersion
medium samples, the lowcst 1FT v3luc was found in
fonnulation withoUi NaCi addition.
Thi!. was
supported by thc tindmg lhal formation waler rcacht:'a
its optimum salinity of 5795 ppm with MES surfactant
inclusion of 0.3%. Higher coneentnnion of NaCI
added resulted in higher [ FT values.
Results of this study also showed Ihal salt addition
in an optimun optimum concentration decreased 1FT
....alues. MES surfactant used in this study had an
optimum salt concentration of 5000-25000 ppm. If
),all concentroltion in the solution was abo.)\c 5000 ppm.
[Ff values of the solution would start to increase as
shown in Figure 2 and 4 . This could happen because
disodium c;lrboxy sulfonic was fonned when salt in the
solutiull W;lS over the 0pLi.llum セSQエ@
lilllit of the
surfactant itself. Salt ・クゥセエ
・ ョ」 ・@ in a solution containing

11 - 22

IC'AIA 2015

ISBN: 97R-I-4673-7405-7

MES would mako: MES lose its lost its f.1cial active
property as MES would gel involved in a rcactlon to
carboxy sulfonate (di-salt). Anionic
form 、ゥNセオュ@
surfactant (1-.1£5) which was origul,LUy bonded to .:I Na
molecule would bind to more N;J ions from salt (NaCl)
so th:!t there would be one molecule containing two
Na ions [15.16]. This reliuhcd in a dl:creascd surfactant
performance and lugher IFf values. Tbe rc;Jction
mechanism of disodium carboxy sulfonate fonnation is
depicted in Figure 5..

loOlubility in water making the performancc of MES
surfaelanl in lowering interfacial tension reduced.
TABLE I
P!-!YS!("OC!lEMICAL PROPERTIES OF FLUID TAKEN FRO\1
SANDSTO'lE FIELD WATER USED N TIltS SruDY

P:lr.lmeter

InjCClIOll

Un:!

Wat.:r

Anion

soi'

« ....

mg>l.
m.L
mg>l.

tKO,

C,
Killion

510$

""
jsiセ@

1939

,

mgll

29J3

2lu

K

20

13.9

^M

m.,t.
mWJ-

250. 7
QセN@

SQセbNPjoe@

Mg'·

mgt!.

9.08

Ba"

mgfl.
mg/l.

"WL
mwL

12.9
0.73
3.71
0.26
RJ

31BRJ030E
3124R.3030E
312SB3030E
31 26 B. 3030 E
4500-H-·8

mwL

11417

""

'::5208

mgll.

'"

67.9

セjTP@

mg>l.
mg>l.

Jl
l.

5.59

.5.74

45()()..O.G

Sr"
rei'
pll
Salim!>

"'

nセci@

T",,'
Hardness

.,

ClICD,

With similar sail concentration and ivIES surfactant
concentration (0.3%) . 1FT values of samples of
demineralized water dispersion medium were lower
than those of fonnation water. The lowest IFf value
was obtained at salt coneentr.ltion of 0.5% or 5000
ppm which was closed to .snIt concentration in
formation water. Results of the test done at three
lemper-Hures with salt addition of 5000-7500 ppm in
dcmineralized water dil:persiom medium showed that
the II-I values were 2.64 x 10"" 1.3 X 10.3 dyne/cm.
These values were lower than those obtained from
formation water (1.10 x lO,j - 4.40 ,.; 10.1 d}11dcm).
This might be caused by less amount of electrolytcs, in
addition to NaC"1. in dcmmeralizt.'ti water than in
fonmtion water. The existence of other electrolytes
originating from other molecules was suspt:cted to
inhibit the rcaction to reduce IFf v31ues by surfactant
Hard water, like formation water u!-dodecyl-jl-d-m.allos,de
|BZャイゥエIHNセ@
Journal of Nuclear
micelles stnlCtUrcs by a セゥIHiエ@
[n