The study of pulsation flow
14TH REGIONAL SYMPOSIUM ON CHEMICAL ENGINEERING 2007
ISBN 978-979-16978-0-4
LIST OF ORAL PRESENTATION
RSCE 2007
PROCESS ENGINEERING GROUP
PE
Authors
Title
1
Abdurahman H. Nour, R. Mohd
Yunus, A. Hisyam
Water-in-Crude
Demulsification
2
Aditya Putranto, Judy Retti Witono,
Arlina Purwanti, and Dian Natalia
Osmotic dehydration of Mangifera indica with Zugarramurdi and
Lupin method
3
Agung Nugroho, Kiki Yustendi, and
Tjandra Setiadi
4
Aning Ayucitra, Chris Colby
Gelatinisation and Retrogradation Properties of Acetylated Corn
Starches with Various Degrees of Substitution
5
Aswati Mindaryani,
Febrian
Kinetics of Air Drying of Cassava starch
6
Bahruddin,
Sumarno,
Wibawa, Nonot Soewarno
7
Dewi Tristantini Øyvind Borg,Börje
Gevert, Anders Holmen
Effect Of Water Addition On Direct Use Of H2-Poor Bio-Syngas
Model In Fischer-Tropsch Synthesis Over Co/Al2O3 Catalyst
8
Dyah Setia Novianti , Yolanda P.
Brondial, Servillano Olano Jr.,
Junjiro Kawasaki
Vapor-Liquid-Liquid Equilibria Of Acetone-Toluene-Water With
And Without Salt Effect
9
Eden Mariquit , Chris Salim and
Hirofumi Hinode
Effect of Ionic Strength on the Adsorption and Photocatalytic
Oxidation of Humic Acid at neutral Ph
10
Eka Prasetia Merdika, Joseph
Auresenia, Raymond G.R. Tan,
Masaaki Suzuki
Control System Design and Modeling on CNT Production using
Modified Microwave Oven
11
Enjarlis, Setijo
Roekmijati
Kinetics Degradation of Carbofuran By Ozonation in presence of
Activated carbon
12
Hayder A. Abdul Bari
Drag Reduction Improvement In Two Phase Flow System Using
Traces Of Sles Surfactant
13
Heri Hermansyah,Masaki Kubob,
Naomi
Shibasaki-Kitakawab,
Toshikuni Yonemotob
Rigorous Kinetic Model for Triglyceride Hydrolysis Using Porcine
Pancreatic Lipase
14
Ideris A., Zulkali M.M.D., Ahmad
A.L.
Production of Simple Reducing Sugars from Oil Palm Empty Fruit
Bunch Using Acid Hydrolysis: Optimization Using Response
Muhammad
Bismo,
Gede
Slamet,
Oil
Emulsions:
Its
Stabilization
and
The Effect Of Cod Concentration On Organic Acids
Production From Cassava Ethanol Stillage
The effect of Maleated Polypropylene on the Morphology and
Mechanical Properties of Dynamically Vulcanized Natural
Rubber/Polypropylene Blends
Yogyakarta-Indonesia, 4-5th December 2007
Chemical Engineering Department , Gadjah Mada University
14TH REGIONAL SYMPOSIUM ON CHEMICAL ENGINEERING 2007
ISBN 978-979-16978-0-4
8
Risdianto, H., Setiadi, T., Suhardi,
S.H., Niloperbowo, W.
Laccase Production From Marasmius Sp. Using A Modified
Temporary Immersion Bioreactor
9
Rozaimah, S. A. S., Anuar, N. &
Salwa, A. A.
Bacteria Identification Based On Bergey s Manual Via A Neural
Network System
10
Shahin Ghafari, Masitah Hasan,
and Mohamed Kheireddine Aroua
Development Of Autotrophic Denitrifying Bacteria In Activated
Sludge Using CO2 As Inorganic Carbon Source
11
Voltaire
Acosta,
Analiza
Palenzuela-Rollon, Le Thi Hong
Tran and Kiyohiko Nakasaki
Anaerobic Digestion Of Alkali-Pretreated Kitchen Waste
Extractusing Upflow Anaerobic Sludge Blanket (Uasb) Reactor
12
Reasmey Tan, Florinda Bacani,
Susan Roces, Nguyen Xuam Sam,
Yasunori Tanji, Hajime Unno
The Bioremediation Of Pentachlorophenol (PCP) In Soil Matrix
Using PCP Degrader Isolated From PCP Acclimated Sludge
13
Lindawati
Combined Approaches For Microbial Community Analysis Of An
Activated Sludge System
15
15
16
17
18
Mohd Noor Ahmad Wei Yen Kwan,
A.K.M. Shafiqul Islam, Zhari Ismail,
Misni Surif
Biosensor for antioxidant determination
Orthosiphon stamineus benth
in
herbal
tea,
Tri Widjaja, Ali Altway and Sri
Rahmania Yuliastuti
Addition Of Chemical Substances With Different
Adsorption/Desorption And Biodegradation Properties On
Performance Of Pact Process
Samsuri, M., Gozan, M., Wijanarko,
A., Hermansyah, H. , Wulan,
P.P.D.K. , Dianursanti, Nasikin, M. ,
Prasetya, B.
I. HYDROLYSIS OF BAGASSE BY CELLULASE AND XYLANASE FOR
BIOETHANOL PRODUCTION IN SIMULTANEOUS SACCHARIFICATION
AND FERMENTATION
Soeprijanto, Budi Setiawam, Fambudi
Eko Prasetyo, and Satriyo Utomo
Retno Gumilang Dewi
II. ISOLATION OF CHITOSAN FROM SHRIMP SHELL WASTES USING
CHITIN DEACETYLASE FROM MUCOR ROUXII
Bio-Fixation of CO2 Emissions and Fuel Production From Microalgae
Botriococcus Braunii
III.
19
20
H.Y. Saw, J. Janaun, S. Kumaresan
Sri Haryati, Erfina Oktariani
Sri Haryati, Erfina Oktariani
21
Studies On The Swelling Characteristics Of Palm Kernel Cake For Its
Application As A Bioreactor Substrate In Solid State Fermentation
The Study of The Pulsation Flow s Effect on D-Glucose
TautomerizationTo Be D-Fructose in Basic Condition
Study of Kinetic s Effects as The Balancing Factor on α Cellulose
Conversion To Be D-Glucose in Hydrolises Process of PT. Tanjung
Enim Lestari s Solid Waste by Using Oscillation Current
ENERGY GROUP
Yogyakarta-Indonesia, 4-5th December 2007
Chemical Engineering Department , Gadjah Mada University
14TH REGIONAL SYMPOSIUM ON CHEMICAL ENGINEERING 2007
ISBN 978-979-16978-0-4
The Study of The Pulsation Flow’s Effect on D-Glucose Tautomerization
To Be D-Fructose in Basic Condition
A. SRI HARYATI a. B. ERFINA OKTARIANI
a
Departement of Chemical Engineering University of Sriwijaya, Indonesia
a
Graduate School University of Sriwijaya
a
Jalan Padang Selasa N0.524, Bukit Besar, Palembang 30139, Indonesia
a
Telp: (0711)352132 – 354222 Fax : (0711) 317202 – 320310
a
E-mail : [email protected]
ABSTRACT
There are two processes in this research to transform D-glucose becomes D-fructose. Both are
transformation process of D-glucose to be D fructose in the reaction zone and separation process of Dfructose in adsorption column. This research is also using technology of pulsation flow. D-fructose
conversion is high enough about 94% for sugar feed.
Keywords : D-Fructose, Pulsation, Tautomerization, Glucose.
I. INTRODUCTION
The technology process of sucrose’s synthesis becomes fructose has been researched since 1847. This
process can be done by biochemical and chemical processes. The biochemical process is used more generally
than the chemical process, because the chemical process tends to produce complex sugar compounds and
fructose that is produced in the chemical process tends changing to be glucose again. Besides the technology to
change D-glucose becomes D-fructose has been evolved, some researchers also develop the technology of Dglucose and D-fructose separation.
In 1969, Frederick W. Parrish et. al. [1] found the method of D-fructose’s formation from D-glucose in
basic condition by using alumine as the catalyst. In 1987, Sidney A. Barker and Peter J. Somer [2] introduced
the effectiveness process to change aldose become ketose in acid condition by using halide metal as the catalyst.
Richard W Neusoil et. al. in 1984 [3] found a method to separate glucose from mixture of glucose and
fructose by using synthetic zeolite that consists of zeolite A with Na cation, zeolite Y with Na cation, and
SiO2/Al2O3 ratio is about 3–6 and zeolite X with Na cation and SiO2/Al2O3 ratio is about 0.5–2.5. In the same
year, Akimitsu Miyahara Tokio et.al.[4] also found a separation’s method of glucose-fructose mixture to be
glucose and fructose by using strong acid resin from alkaline metal.
To increase the colour and fructose’s conversion, pulsation technology is chosen. Because it has
advantage in mass and heat transfer rising, and energy process can be minimized than agitator technology. And
the flow path of pulsation flow is axial component from rotation move becomes translation move, where the
translation move will produce glucose-fructose with acceleration and deacceleration. So degree of turbulency
can be bigger and dispertion of sollution is more homogenous.
The purpose of this research is to study the pulsation flow’s effect to D-glucose transformation becomes
D-fructose.
II. RESEARCH METHODS
This research [5] tries to separate D-glucose and D-fructose sollution by using natural zeolite. The natural
zeolite is from PT.Minatama Mineral Perdana. The research methods is divided in two process. They are
reaction process and adsorbtion column process. In the reaction process, is also divided in two step, first to find
the optimum condition by using non-pulsation and pulsation flow with pure a D-glucosepyronise feed. And the
second step is using the optimum operation condition from first step by using non-pulsation and pulsation
process with sugar feed.
Yogyakarta-Indonesia, 4-5th December 2007
Chemical Engineering Department , Gadjah Mada University
14TH REGIONAL SYMPOSIUM ON CHEMICAL ENGINEERING 2007
ISBN 978-979-16978-0-4
H2 O
a D-glucopyronise
NaOH
NaBr.2H2O
MIXING
TAUTOMERIZATION
Recycle
76%
Recycle
MIXING
Backwash
H2 O
Product
ADSORPTION
Fig. 1.1 Diagram Block of D-Glucose Transformation to be D-Fructose
III. ANALYSES AND DISCUSSION
Konversi D-Glukosa (%)
Pulsation flow process can give higher conversion than non-pilsation process. Highest conversion is
85.35% for pure a.D-glucopyronise with motor’s frequency 8 Hz. Whereas highest conversion by using sugar
feed is 94.05% and motor’s frequency 8Hz.
100
90
80
70
60
50
40
30
20
10
0
A = 4 cm
A = 6 cm
A = 8 cm
A = 10 cm
0
20
40
60
Waktu, t (menit)
80
Fig 1.2 Graphic between XA vs t at T=500C and Frequency 8 Hz
IV. CONCLUSION
From the last analysis and discussion can conclude that the highest D-fructose conversion on 8 Hz
frequency and 6 cm amplitude with pure α.D-glucopyranose feed at 600C, with catalyst ratio NaBr.2H2O and
feed 10 in basic condition is 85%.
REFERENCES
[1] Frederick W.P., and Natick., “Fructose Formation From Glucose”, 1969, US.Patent 3.431.253.
Yogyakarta-Indonesia, 4-5th December 2007
Chemical Engineering Department , Gadjah Mada University
14TH REGIONAL SYMPOSIUM ON CHEMICAL ENGINEERING 2007
ISBN 978-979-16978-0-4
[2] Sidney A.B., and Peter J.S., “Process For Effecting Aldose To Ketose Conversion”, 1987, US.Patent
4.663.449.
[3] Neusil.et.al., “Process For Separating Glucose From Fructose By Selective Adsorption”, 1984,
US.Patent.4,442,285.
[4] Miyahara.et.al., “Method For The Separation Of Glocose And Fructose”, 1984, US.Patent 4.472.203.
[5] Porawati. H., and Haryati. S., "Thesis: The study of the Pulsation Flow's Effect on D-Glucose
Tautomerization to be D-Fructose in Basic Condition", 2002, Palembang: University of Sriwijaya.
Yogyakarta-Indonesia, 4-5th December 2007
Chemical Engineering Department , Gadjah Mada University
ISBN 978-979-16978-0-4
LIST OF ORAL PRESENTATION
RSCE 2007
PROCESS ENGINEERING GROUP
PE
Authors
Title
1
Abdurahman H. Nour, R. Mohd
Yunus, A. Hisyam
Water-in-Crude
Demulsification
2
Aditya Putranto, Judy Retti Witono,
Arlina Purwanti, and Dian Natalia
Osmotic dehydration of Mangifera indica with Zugarramurdi and
Lupin method
3
Agung Nugroho, Kiki Yustendi, and
Tjandra Setiadi
4
Aning Ayucitra, Chris Colby
Gelatinisation and Retrogradation Properties of Acetylated Corn
Starches with Various Degrees of Substitution
5
Aswati Mindaryani,
Febrian
Kinetics of Air Drying of Cassava starch
6
Bahruddin,
Sumarno,
Wibawa, Nonot Soewarno
7
Dewi Tristantini Øyvind Borg,Börje
Gevert, Anders Holmen
Effect Of Water Addition On Direct Use Of H2-Poor Bio-Syngas
Model In Fischer-Tropsch Synthesis Over Co/Al2O3 Catalyst
8
Dyah Setia Novianti , Yolanda P.
Brondial, Servillano Olano Jr.,
Junjiro Kawasaki
Vapor-Liquid-Liquid Equilibria Of Acetone-Toluene-Water With
And Without Salt Effect
9
Eden Mariquit , Chris Salim and
Hirofumi Hinode
Effect of Ionic Strength on the Adsorption and Photocatalytic
Oxidation of Humic Acid at neutral Ph
10
Eka Prasetia Merdika, Joseph
Auresenia, Raymond G.R. Tan,
Masaaki Suzuki
Control System Design and Modeling on CNT Production using
Modified Microwave Oven
11
Enjarlis, Setijo
Roekmijati
Kinetics Degradation of Carbofuran By Ozonation in presence of
Activated carbon
12
Hayder A. Abdul Bari
Drag Reduction Improvement In Two Phase Flow System Using
Traces Of Sles Surfactant
13
Heri Hermansyah,Masaki Kubob,
Naomi
Shibasaki-Kitakawab,
Toshikuni Yonemotob
Rigorous Kinetic Model for Triglyceride Hydrolysis Using Porcine
Pancreatic Lipase
14
Ideris A., Zulkali M.M.D., Ahmad
A.L.
Production of Simple Reducing Sugars from Oil Palm Empty Fruit
Bunch Using Acid Hydrolysis: Optimization Using Response
Muhammad
Bismo,
Gede
Slamet,
Oil
Emulsions:
Its
Stabilization
and
The Effect Of Cod Concentration On Organic Acids
Production From Cassava Ethanol Stillage
The effect of Maleated Polypropylene on the Morphology and
Mechanical Properties of Dynamically Vulcanized Natural
Rubber/Polypropylene Blends
Yogyakarta-Indonesia, 4-5th December 2007
Chemical Engineering Department , Gadjah Mada University
14TH REGIONAL SYMPOSIUM ON CHEMICAL ENGINEERING 2007
ISBN 978-979-16978-0-4
8
Risdianto, H., Setiadi, T., Suhardi,
S.H., Niloperbowo, W.
Laccase Production From Marasmius Sp. Using A Modified
Temporary Immersion Bioreactor
9
Rozaimah, S. A. S., Anuar, N. &
Salwa, A. A.
Bacteria Identification Based On Bergey s Manual Via A Neural
Network System
10
Shahin Ghafari, Masitah Hasan,
and Mohamed Kheireddine Aroua
Development Of Autotrophic Denitrifying Bacteria In Activated
Sludge Using CO2 As Inorganic Carbon Source
11
Voltaire
Acosta,
Analiza
Palenzuela-Rollon, Le Thi Hong
Tran and Kiyohiko Nakasaki
Anaerobic Digestion Of Alkali-Pretreated Kitchen Waste
Extractusing Upflow Anaerobic Sludge Blanket (Uasb) Reactor
12
Reasmey Tan, Florinda Bacani,
Susan Roces, Nguyen Xuam Sam,
Yasunori Tanji, Hajime Unno
The Bioremediation Of Pentachlorophenol (PCP) In Soil Matrix
Using PCP Degrader Isolated From PCP Acclimated Sludge
13
Lindawati
Combined Approaches For Microbial Community Analysis Of An
Activated Sludge System
15
15
16
17
18
Mohd Noor Ahmad Wei Yen Kwan,
A.K.M. Shafiqul Islam, Zhari Ismail,
Misni Surif
Biosensor for antioxidant determination
Orthosiphon stamineus benth
in
herbal
tea,
Tri Widjaja, Ali Altway and Sri
Rahmania Yuliastuti
Addition Of Chemical Substances With Different
Adsorption/Desorption And Biodegradation Properties On
Performance Of Pact Process
Samsuri, M., Gozan, M., Wijanarko,
A., Hermansyah, H. , Wulan,
P.P.D.K. , Dianursanti, Nasikin, M. ,
Prasetya, B.
I. HYDROLYSIS OF BAGASSE BY CELLULASE AND XYLANASE FOR
BIOETHANOL PRODUCTION IN SIMULTANEOUS SACCHARIFICATION
AND FERMENTATION
Soeprijanto, Budi Setiawam, Fambudi
Eko Prasetyo, and Satriyo Utomo
Retno Gumilang Dewi
II. ISOLATION OF CHITOSAN FROM SHRIMP SHELL WASTES USING
CHITIN DEACETYLASE FROM MUCOR ROUXII
Bio-Fixation of CO2 Emissions and Fuel Production From Microalgae
Botriococcus Braunii
III.
19
20
H.Y. Saw, J. Janaun, S. Kumaresan
Sri Haryati, Erfina Oktariani
Sri Haryati, Erfina Oktariani
21
Studies On The Swelling Characteristics Of Palm Kernel Cake For Its
Application As A Bioreactor Substrate In Solid State Fermentation
The Study of The Pulsation Flow s Effect on D-Glucose
TautomerizationTo Be D-Fructose in Basic Condition
Study of Kinetic s Effects as The Balancing Factor on α Cellulose
Conversion To Be D-Glucose in Hydrolises Process of PT. Tanjung
Enim Lestari s Solid Waste by Using Oscillation Current
ENERGY GROUP
Yogyakarta-Indonesia, 4-5th December 2007
Chemical Engineering Department , Gadjah Mada University
14TH REGIONAL SYMPOSIUM ON CHEMICAL ENGINEERING 2007
ISBN 978-979-16978-0-4
The Study of The Pulsation Flow’s Effect on D-Glucose Tautomerization
To Be D-Fructose in Basic Condition
A. SRI HARYATI a. B. ERFINA OKTARIANI
a
Departement of Chemical Engineering University of Sriwijaya, Indonesia
a
Graduate School University of Sriwijaya
a
Jalan Padang Selasa N0.524, Bukit Besar, Palembang 30139, Indonesia
a
Telp: (0711)352132 – 354222 Fax : (0711) 317202 – 320310
a
E-mail : [email protected]
ABSTRACT
There are two processes in this research to transform D-glucose becomes D-fructose. Both are
transformation process of D-glucose to be D fructose in the reaction zone and separation process of Dfructose in adsorption column. This research is also using technology of pulsation flow. D-fructose
conversion is high enough about 94% for sugar feed.
Keywords : D-Fructose, Pulsation, Tautomerization, Glucose.
I. INTRODUCTION
The technology process of sucrose’s synthesis becomes fructose has been researched since 1847. This
process can be done by biochemical and chemical processes. The biochemical process is used more generally
than the chemical process, because the chemical process tends to produce complex sugar compounds and
fructose that is produced in the chemical process tends changing to be glucose again. Besides the technology to
change D-glucose becomes D-fructose has been evolved, some researchers also develop the technology of Dglucose and D-fructose separation.
In 1969, Frederick W. Parrish et. al. [1] found the method of D-fructose’s formation from D-glucose in
basic condition by using alumine as the catalyst. In 1987, Sidney A. Barker and Peter J. Somer [2] introduced
the effectiveness process to change aldose become ketose in acid condition by using halide metal as the catalyst.
Richard W Neusoil et. al. in 1984 [3] found a method to separate glucose from mixture of glucose and
fructose by using synthetic zeolite that consists of zeolite A with Na cation, zeolite Y with Na cation, and
SiO2/Al2O3 ratio is about 3–6 and zeolite X with Na cation and SiO2/Al2O3 ratio is about 0.5–2.5. In the same
year, Akimitsu Miyahara Tokio et.al.[4] also found a separation’s method of glucose-fructose mixture to be
glucose and fructose by using strong acid resin from alkaline metal.
To increase the colour and fructose’s conversion, pulsation technology is chosen. Because it has
advantage in mass and heat transfer rising, and energy process can be minimized than agitator technology. And
the flow path of pulsation flow is axial component from rotation move becomes translation move, where the
translation move will produce glucose-fructose with acceleration and deacceleration. So degree of turbulency
can be bigger and dispertion of sollution is more homogenous.
The purpose of this research is to study the pulsation flow’s effect to D-glucose transformation becomes
D-fructose.
II. RESEARCH METHODS
This research [5] tries to separate D-glucose and D-fructose sollution by using natural zeolite. The natural
zeolite is from PT.Minatama Mineral Perdana. The research methods is divided in two process. They are
reaction process and adsorbtion column process. In the reaction process, is also divided in two step, first to find
the optimum condition by using non-pulsation and pulsation flow with pure a D-glucosepyronise feed. And the
second step is using the optimum operation condition from first step by using non-pulsation and pulsation
process with sugar feed.
Yogyakarta-Indonesia, 4-5th December 2007
Chemical Engineering Department , Gadjah Mada University
14TH REGIONAL SYMPOSIUM ON CHEMICAL ENGINEERING 2007
ISBN 978-979-16978-0-4
H2 O
a D-glucopyronise
NaOH
NaBr.2H2O
MIXING
TAUTOMERIZATION
Recycle
76%
Recycle
MIXING
Backwash
H2 O
Product
ADSORPTION
Fig. 1.1 Diagram Block of D-Glucose Transformation to be D-Fructose
III. ANALYSES AND DISCUSSION
Konversi D-Glukosa (%)
Pulsation flow process can give higher conversion than non-pilsation process. Highest conversion is
85.35% for pure a.D-glucopyronise with motor’s frequency 8 Hz. Whereas highest conversion by using sugar
feed is 94.05% and motor’s frequency 8Hz.
100
90
80
70
60
50
40
30
20
10
0
A = 4 cm
A = 6 cm
A = 8 cm
A = 10 cm
0
20
40
60
Waktu, t (menit)
80
Fig 1.2 Graphic between XA vs t at T=500C and Frequency 8 Hz
IV. CONCLUSION
From the last analysis and discussion can conclude that the highest D-fructose conversion on 8 Hz
frequency and 6 cm amplitude with pure α.D-glucopyranose feed at 600C, with catalyst ratio NaBr.2H2O and
feed 10 in basic condition is 85%.
REFERENCES
[1] Frederick W.P., and Natick., “Fructose Formation From Glucose”, 1969, US.Patent 3.431.253.
Yogyakarta-Indonesia, 4-5th December 2007
Chemical Engineering Department , Gadjah Mada University
14TH REGIONAL SYMPOSIUM ON CHEMICAL ENGINEERING 2007
ISBN 978-979-16978-0-4
[2] Sidney A.B., and Peter J.S., “Process For Effecting Aldose To Ketose Conversion”, 1987, US.Patent
4.663.449.
[3] Neusil.et.al., “Process For Separating Glucose From Fructose By Selective Adsorption”, 1984,
US.Patent.4,442,285.
[4] Miyahara.et.al., “Method For The Separation Of Glocose And Fructose”, 1984, US.Patent 4.472.203.
[5] Porawati. H., and Haryati. S., "Thesis: The study of the Pulsation Flow's Effect on D-Glucose
Tautomerization to be D-Fructose in Basic Condition", 2002, Palembang: University of Sriwijaya.
Yogyakarta-Indonesia, 4-5th December 2007
Chemical Engineering Department , Gadjah Mada University