PRELIMINARY PLANT DESIGN OF CHLOROFORM FROM ACETONE AND BLEACHING POWDER Preliminary Plant Design Of Chloroform From Acetone And Bleaching Powder Capacity 40,000 Tonnes Per Year.

PRELIMINARY PLANT DESIGN OF CHLOROFORM
FROM ACETONE AND BLEACHING POWDER
CAPACITY 40,000 TONNES PER YEAR

By :
MUHAMMAD FAHMI HAKIM
D 500 112 007

Supervisor :
1. Muhammad Mujiburrohman, S.T., M.T., Ph.D
2. Emi Erawati, S.T., M.Eng

DEPARTMENT OF CHEMICAL ENGINEERING
FACULTY OF ENGINEERING
UNIVERSITAS MUHAMMADIYAH SURAKARTA
2015

MOTTO

LIFE IS STRUGGLE


v
DEDICATION

I dedicate this work to :
My beloved mother and father. Thank you for your prayers, support, love, sacrifice and
education you’ve given.(Abdi Roat,S.Pd and Sri Mulyani)
My beloved brother, Muhammad Fiqri Dzikrullah,S.P.and my beloved sister Arsya Fadhila
Putri Ananda . who always gives support, advices, and support me to hang on.

My Future

,Anisah Anggraini Putri who always gives support,inspiration and spirit .

All of my friends are ready for help me, Student of PESMA KH.MAS Mansyur

All of my students who brought color into my life.

All of my classmates in the International class 2011 who gave me comfort when learning.

All of my friends from 2009, 2010, 2011, 2012, 2013 and all of people, who give me support

until my final project are completed.

Thank’s you for All…

PREFACE

All praises due to Allah SWT, because of his mercy and blessing this
final project been completed. This report is one of requirements to pass the
bachelor in chemical engineering.
The author realizes this report is not perfect due to our limited knowledge
and experience, therefore advice and suggestion are welcome.
In this occasion, the authors would like to thank to every one who has
helped and guided in completing this report,
1. Allah SWT who has given the opportunity to complete this final project
2. Prophet Muhammad S.A.W. who has given exemplary to do the best
3. Both Parents who always provide support in completing the final project
4. Muhammad Mujiburrohman, S.T., M.T., Ph.D. as first supervisor of final
project
5. Emi Erawati, S.T.,M.Eng. as second supervisor of final project
6. Rois Fatoni, S.T., M.Sc. Ph.D. head of Chemical Engineering Department

of UMS
7. Qomaroh, For good discussion.
8. Everyone who has supported the author to carry out this final project very
well.
Authors wish this report to be benefical to those may concern.
Surakarta, March 2015

Muhammad Fahmi Hakim

THE TABLE OF CONTENT
COVER ........................................................................................................... i
VALIDATION ................................................................................................ ii
STATEMENT OF AUTHENTICITY ............................................................. iii
MOTTO ........................................................................................................... iv
DEDICATION ................................................................................................. v
PREFACE ....................................................................................................... vi
TABLE OF CONTENTS ................................................................................. vii
LIST OF TABLE ............................................................................................. viii
LIST OF FIGURES ......................................................................................... ix
ABSTRACT .................................................................................................... x

CHAPTER I INTRODUCTION ..................................................................... 1
1.1. Background............................................................................... 1
1.2. The Designed Production Capacity .......................................... 1
1.3. Site Selection for the Manufacturer .......................................... 4
1.4. Literature Reviews.................................................................... 8
1.4.1

Types of the Processes ............................................. 8

1.4.2

The Use of the Product ............................................ 10

1.4.3

Physical and Chemical Properties ........................... 11

1.4.4

General Process Overview ....................................... 17


CHAPTER II PROCESS DESCRIPTION .................................................... 19
2.1

2.2

Specification Raw Materials and Products ............................... 19
2.1.1

Spesification of Raw Materials................................ 19

2.1.2

Spesification Product ............................................... 19

Concept of Process ……….…………………………………...20
2.2.1

Basic of Reaction ..................................................... 20


2.2.2

Operation Condition ................................................ 20

2.2.3

Reaction Mechanism ............................................... 20

2.2.4

Thermodynamics Review ........................................ 21

2.2.5

Review Kinetics ....................................................... 25

2.3 Process Flow diagram .............................................................. 28
2.3.1

Process Flow Diagram ............................................. 28


2.3.2

Production Process .................................................. 28

2.4 Mass Balance and Heat Balance .............................................. 33
2.4.1

Mass Balance ........................................................... 33

2.4.2

Heat Balance ............................................................ 38

2.5 Factory and Process Equipment Lay Out ................................. 43
2.5.1

Factory Layout ......................................................... 43

2.5.2


Equipment Lay Out ................................................. 48

CHAPTER III EQUIPMENT SPECIFICATION ............................................ 52
3.1

Acetone Storage Tank ............................................................. 52

3.2

Chloroform Storage Tank ........................................................ 52

3.3

Reaktor .................................................................................... 53

3.4

Mixer 01 ................................................................................... 53


3.5

Distillation Column .................................................................. 54

3.6

Filter ......................................................................................... 55

3.7

Decanter .................................................................................. 56

3.8

Heat Exchanger 01 ................................................................... 56

3.9

Heat Exchanger 02 ................................................................... 57


3.10 Heat Exchanger 03 ................................................................... 58
3.11 Heat Exchanger 04 ................................................................... 59
3.12 Heat Exchanger 05 ................................................................... 60
3.13 Heat Exchanger 06 ................................................................... 61
3.14 Condenser 01 ............................................................................ 63
3.15 Reboiler 01 ............................................................................... 64
3.16 Pump 01 .................................................................................... 65
3.17 Pump 02 ................................................................................... 65
3.18 Pump 03 ................................................................................... 66
3.19 Pump 04 ................................................................................... 66
3.20 Pump 05 ................................................................................... 67
3.21 Pump 06 ................................................................................... 67

3.22 Pump 07 ................................................................................... 68
3.23 Pump 08 ................................................................................... 68
3.24 Pump 09 .................................................................................... 69
3.25 Bin Bleaching powder .............................................................. 69
3.26 Belt Conveyor 01 ...................................................................... 70
3.27 Screw Conveyor Feeder 01 ...................................................... 70
CHAPTER IV UTILITIES .............................................................................. 71

4.1

The Process Supporting ........................................................... 71
4.1.1

Water Procurement Unit .......................................... 72

4.1.2

Procurement Unit Steam .......................................... 86

4.1.3

Power Supply Unit................................................... 89

4.1.4

Procurement Fuel Unit............................................. 93

4.1.5

Compressed Air Supply Unit ................................... 94

4.1.6

Waste Processing Unit ............................................. 94

4.2 Laboratory ................................................................................ 95
4.2.1

Laboratory Work Program....................................... 96

4.2.2

Analysis Method ...................................................... 96

4.2.3

The Main Equipment of the Laboratory .................. 97

4.3 Health and Safety at Work ....................................................... 97
CHAPTER V MANAGEMENT ..................................................................... 100
5.1

Format of The Company .......................................................... 100

5.2

Organizational Structure ........................................................... 102

5.3

Tasks and Authorities ............................................................... 104

5.4

Working Hours Allocation ....................................................... 107

5.5

Employee’s Status and Wages System ..................................... 109

5.6

Classification of Position.......................................................... 110

5.7

Employee’s Social Welfare ...................................................... 114

5.8

Production Management ........................................................... 114

5.9

Production Planning ................................................................. 115

5.10 Production Control ................................................................... 116

CHAPTER V1 ECONOMIC ANALYSIS....................................................... 118
6.1

Equipment Prices Approximation ........................................... 121

6.2

Basic Calculation ..................................................................... 123

6.3

Total Capital Investment (TCI) Determination ........................ 124

6.4

Result Calculation .................................................................... 125

6.5

Feasibility Analysis .................................................................. 131

CHAPTER VII DISCUSSION AND CONCLUSION .................................... 133
7.1

Discussion ................................................................................ 133

7.2

Conclusion ............................................................................... 133

REFERENCES ................................................................................................ xi
Attachments

LIST OF TABLE
Table 1.1 Import of Chloroform in Indonesia from 2006 until 2010 ............... 2
Table 1.2 The demand of Chloroform overseas at 2006 until 2010................. 3
Table 1.3 Data of the capacity of the plants established abroad ...................... 4
o

Table 2.1 Data of ∆H f every component at 298 K ......................................... 22
Table 2.2 Data of Gibb’s free energy every component at 298K ................... 24
Table 2.3 Mass balance Mixer01 (M-110)....................................................... 33
Table 2.4 Mass balance Reactor (R-110) ......................................................... 34
Table 2.5 Mass balance Filter (H-110) ............................................................ 34
Table 2.6 Mass balance Decanter (H-210) ....................................................... 35
Table 2.7 Mass balance Distillaation Column (D-110) ................................... 35
Table 2.7 Total mass balance ........................................................................... 36
Table 2.8 Heat balance Reactor (R-110) ......................................................... 38
Table 2.9 Heat balance Filter (H-110) ............................................................. 38
Table 2.10 Heat balance Decanter (H-001)...................................................... 39
Table 2.11 Heat balance Distillaation Column (D-110) ................................. 39
Table 2.12 Heat balance Heat Exchanger 01 (E-110) ..................................... 39
Table 2.13 Heat balance Heat Exchanger 02 (E-111) ..................................... 40
Table 2.14 Heat balance Heat Exchanger 03 (E-210) ..................................... 40
Table 2.15 Heat balance Heat Exchanger 04 (E-112) ..................................... 41
Table 2.16 Heat balance Heat Exchanger 05 (E-211) ..................................... 41
Table 2.17 Heat balance Heat Exchanger 06 (E-212) ..................................... 41
Table 2.18 Total heat balance .......................................................................... 46
Table 2.19 Land area as manufacture plant .................................................... 45
Table 4.1 Totals of water need ......................................................................... 86
Table 4.2 Procurement needs steam ................................................................. 86
Table 4.3 Power consumption for process and utillity..................................... 90
Table 4.4 Power consumption for lighting ....................................................... 91
Table 4.5 Waste sources ................................................................................... 95
Table 5.1 The work schedules of each team .................................................... 109

Table 5.2 Position classification, number of employees and salaries .............. 111
Table 6.1 Price of equipment is done by using a price index data 1991-2002 122
Table 6.2 Indeks equipment price 2005-2012 .................................................. 122
Table 6.3 Fixed Capital Invesment .................................................................. 125
Table 6.4 Working Capital Investment ............................................................ 125
Table 6.5 Direct Manufacturing Cost .............................................................. 126
Table 6.6 Indirect Manufacturing Cost ............................................................ 126
Table 6.7 Fixed Manufacturing Cost ............................................................... 127
Table 6.8 General Expense .............................................................................. 127
Table 6.9 Feasibility Analysis .......................................................................... 131

LIST OF FIGURES

Figure 1.1 Graph need of chloroform in Indonesia .......................................... 2
Figure 1.2 Location to manufacture the plant .................................................. 7
Figure 2.1 Schematic mechanism reaction modele of chloroform .................. 21
Figure 2.2 Flow diagram qualitative flow ........................................................ 30
Figure 2.3 Flow diagram quantitave ................................................................ 31
Figure 2.4 Flow mass balance .......................................................................... 33
Figure 2.5 Flow heat balance ........................................................................... 37
Figure 2.6 Plant lay out ................................................................................... 47
Figure 2.7 Lay out of equipment ...................................................................... 50
Figure 4.1 Water treatment plant ..................................................................... 76
Figure 5.1 Structure Organization in the Chloroform Plant ............................. 104
Figure 6.1 Chemical Engineering Cost Index .................................................. 123
Figure 6.2 Graph of Feasibility Analysis ......................................................... 132

ABSTRACT

Chloroform is one of industries have been good prospect. For need
chloroform, Indonesia still importing from the other countries.
Chloroform used as an anesthetic and a non-polar solvent in laboratories
or by industries. From many factors as the availbillity of raw materials,
transportation, need of chloroform in Indonesia and overseas, can determine
optimum capacity to produce chloroform is 40,000 tonnes/year. With reacted
between bleaching powder and aceton in ratio 27,522 kg of acetone and 2,752 kg
of bleaching powder in batch reactor (T=50℃ and P=1 atm) during 2 hours, will
produce chloroform and byproducts like as calcium acetate Ca(CH3COO)2,
calcium hydroxide (Ca(OH)2), calcium chloride (CaCl2). Plant will be build at
2017 in Cilegon,Banten with area is 52,332 m2. total of water needs is 278
m3/hours, steam required is 2,693.886 kg/h,for electricity is 542 KW,fuel
requirement is 82.79 L/h.
The economic analysis concludes that fixed manufacturing cost (Fa) is
1,845,139,452,209. Variable cost (Va) is 16,510,294,893,475. Regulated cost (Ra)
is 16,822,580,694,015. Selling product (Sa) is 41,325,887,664,951. ROI (Return
on Investment) before and after tax are 99.95% and 69.97%. POT (Pay OutTime)
before and after tax are 0.91 years and 1.25 years. BEP is 52.58 % and. So if this
plant will be build so many advantages and very profitably.

Keywords

: chloroform, acetone, bleaching powder.