Chandra Asri Petrochemical SDS GHS 05 Py Gas
SAFETY DATA SHEET
Safety Data Sheet in accordance with UN GHS Purple Book
CAP – SDS – 05 – Pyrolysis Gasoline (Rev.00)
ISSUED DATE : 09 Jan 2015
SECTION-1. IDENTIFICATION
Product/Material
Recommended Use
Manufacturer
Head Office
Plant
Emergency contact (24 hrs)
Additional Information
:
:
:
:
:
:
:
Pyrolysis Gasoline (Py gas)
Raw material use in industrial applications for chemical synthesis etc.
PT. CHANDRA ASRI PETROCHEMICAL Tbk (CAP)
Wisma Barito Pacific, Tower A, 7th floor, Jl. Letjend S. Parman, Kav.62-63. Jakarta
11410, Indonesia.
Jl Raya Anyer Km.123, Ciwandan, Cilegon 42447, Indonesia. Ph: 62-254-601501
GROUPSHEDIVISION@capcx.com, Phone: 62-254-601829, 601501 Ext 1232
GROUPRND@capcx.com, Phone: +62-254-601501 Ext 1869, 1616
SECTION-2. HAZARD IDENTIFICATION
GHS Classification
:
Hazard Statements
:
Pictogram (Hazard Symbols)
:
Signal Word
Target Organ
Physical Hazards
Environmental Hazards
Health Hazards
:
:
:
:
:
Precautionary Hazard
Prevention
:
:
Safety Data Sheet – 05 – Py Gas
Flammable liquid: Category 2│Acute aquatic toxicant: Category 2│Chronic aquatic
toxicant: Category 2 │ Aspiration toxicant: Category 1 │ Carcinogen: Category 1A │
Target organ toxicant (repeated exposure): Category 1 │ Eye irritation: Category 2A
│ Germ Cell Mutagen: Category 1B │ Reproductive toxicant: Category 1B │ Skin
irritation: Category 2 │ Target organ toxicant (central nervous system): Category 3 │
Target organ toxicant: Category 3 │ Acute oral toxicant: Category 4.
Highly flammable liquid and vapor│May be fatal if swallowed and enters
airways│May be harmful in contact with skin│Causes skin irritation│May cause
respiratory irritation, and drowsiness or dizziness│May cause genetic defects│May
cause cancer│Suspected of damaging fertility or the unborn child│Causes damage
to organs (Blood, Eyes, Auditory organs, Nervous system) through prolonged or
repeated exposure│May cause damage to organs (Auditory organs) through
prolonged or repeated exposure if inhaled│Toxic to aquatic life with long lasting
effects.
DANGER
Causes damage to organs through prolonged or repeated exposure.
Extremely flammable liquid and vapor.
Toxic to aquatic life. Toxic to aquatic life with long lasting effects.
May be fatal if swallowed and enters airways. Harmful if swallowed. May cause
cancer. May cause genetic defects. May damage fertility or the unborn child.
Causes serious eye irritation. Causes skin irritation. May cause drowsiness or
dizziness. May cause respiratory irritation.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Keep
Page 1 of 9
Precautionary Hazard Response
:
Precautionary Hazard-Storage
Precautionary Hazard-Disposal
:
:
away from heat/sparks/open flames/hot surfaces. – No smoking.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical advice/attention. IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Take
off contaminated clothing and wash before reuse. IF SWALLOWED: Immediately
call a POISON CENTER or doctor/physician Wash with plenty of soap and water.
Rinse mouth. Do NOT induce vomiting. IF exposed or concerned: Get medical
advice/attention. Specific treatment (see Notes to Physician on this label). In case of
fire: Use manufacturer/supplier or the competent authority to specify appropriate
media for extinction. Collect spillage.
Store in a well-ventilated place. Keep cool. Store locked up.
Dispose of contents/container in accordance with applicable local/ regional/ national/
international regulations.
SECTION-3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Identity
Common Name
:
:
Pyrolysis Gasoline
Py Gas
Component
C5’s and lighter
Contains: Styrene
Total BTX
Non Aromatic (C6 & heavier)
:
:
:
:
CAS No
Mixture
100-42-5
Mixture
Mixture
CAS No : 68606-10-0
Concentration (ppm wt.)
< 1.5 % wt
60 % weight
< 40% weight
SECTION-4. FIRST-AID MEASURES
Skin
:
Inhalation
:
Eyes
:
Ingestion
:
Note to Physician
:
To remove the material from skin, use soap and water. Discard contaminated
clothing and shoes or thoroughly clean before reuse. Get medical attention if any
symptoms develop.
Move the exposed person to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention if breathing difficulties
continue.
Flush eyes with running water immediately while holding the eyelids open. Remove
contact lenses, if worn, after initial flushing, and continue flushing for at least 15
minutes. Get immediate medical attention.
If swallowed, do not induce vomiting. Give the person a glass of water or milk to
drink and get immediate medical attention. Never give anything by mouth to an
unconscious person.
Ingestion of this product or subsequent vomiting may result in aspiration of light
hydrocarbon liquid, which may cause pneumonitis.
SECTION-5. FIRE-FIGHTING MEASURES
Flammable Properties
Extinguishing Media
:
Clear fire area of all non-emergency personnel.
Suitable Extinguishing Media
:
Unsuitable Extinguishing Media
:
Foam, water spray or fog. Dry chemical powder, carbon dioxide, san or earth may
be used for small fires only.
Do not use water jet.
Specific Hazards in Case of Fire
Hazardous Combustion Products :
Safety Data Sheet – 05 – Py Gas
The vapor is heavier than air, spreads along the ground and distant ignition is
possible. Will float and can be reignited on surface water. Carbon monoxide may be
Page 2 of 9
evolved in incomplete combustion occurs.
Special Protective Equipment and Precaution for Fire Fighter
Special Protective Equipment
Precautions for Fire- Fighter
:
:
Wear full protective clothing and self-contained breathing apparatus
Do not spray on an open flame or any other incandescent material. Take necessary
action to avoid static electricity discharge (which might cause ignition of organic
vapors). Use only explosion proof equipment. Keep away from open flames, hot
surfaces and sources of ignition.
SECTION-6. ACCIDENTAL RELEASE MEASURES
Protective Measures
:
Spill Management
:
Eliminate all sources of ignition in the vicinity of the spill or released vapor. If this
material is released into the work area, evacuate the area immediately. Monitor area
with combustible gas indicator. Wear appropriate personal protective equipment
when cleaning up spills.
Stop the source of the release if you can do it without risk. Contain release to
prevent further contamination of soil, surface water or groundwater. Clean up spill as
soon as possible, observing precautions in Exposure Controls/Personal Protection.
Use appropriate techniques such as applying non-combustible sorbent materials or
pumping. All equipment used when handling the product must be grounded. A vapor
suppressing foam may be used to reduce vapors. Use clean non-sparking tools to
collect absorbed material. Where feasible and appropriate, remove contaminated
soil. Place contaminated materials in disposable containers and dispose of in a
manner consistent with applicable regulations.
SECTION-7. HANDLING AND STORAGE
Precautions for Safe Handling
:
This material presents a fire hazard. Liquid quickly evaporates and forms vapor
(fumes) which can catch fire and burn with explosive violence. Invisible vapor
spreads easily and can be set on fire by many sources such as pilot lights, welding
equipment, and electrical motors and switches. Fire hazard is greater as liquid
temperature rises above 15°F. Do not breathe vapor or fumes.
Unusual Handling Hazards
:
General Handling Information
:
Static Hazard
:
Inspect tank vents periodically. Styrene vapors may polymerize in vents or flame
arrestors of storage tanks. Check temperature, inhibitor and polymer content at least
once a week during warm weather. Increase monitoring frequency if stored at
greater than 70 F for longer than 30 days. Minimize storage time
Avoid work practices that may release volatile components in the atmosphere. Local
air pollution regulations should be consulted to determine if the release of volatile
components is regulated or restricted in the area in which this material is used.
Avoid contaminating soil or releasing this material into sewage and drainage
systems and bodies of water.
Electrostatic charge may accumulate and create a hazardous condition when
handling this material. To minimize this hazard, bonding and grounding may be
necessary but may not, by themselves, be sufficient. Review all operations, which
have the potential of generating an accumulation of electrostatic charge and/or a
flammable atmosphere (including tank and container filling, splash filling, tank
cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum
truck operations) and use appropriate mitigating procedures. For more information,
refer to OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids,
National Fire Protection Association (NFPA 77), Recommended Practice on Static
Electricity' (liquids, powders and dusts), and/or the American Petroleum Institute
(API) Recommended Practice 2003, 'Protection Against Ignitions Arising Out of
Safety Data Sheet – 05 – Py Gas
Page 3 of 9
General Storage Information
:
Static, Lightning, and Stray Currents' (liquids).
Container is not designed to contain pressure. Does not use pressure to empty
container or it may rupture with explosive force. Empty containers retain product
residue (solid, liquid, and/or vapor) and can be dangerous. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks,
static electricity, or other sources of ignition. They may explode and cause injury or
death. Empty containers should be completely drained, properly closed, and
promptly returned to a drum reconditioner, or disposed of properly. DO NOT USE
OR STORE near heat, sparks or open flames. USE AND STORE ONLY IN WELL
VENTILATED AREA. Keep container closed when not in use.
SECTION-8. EXPOSURE CONTROLS / PERSONAL PROTECTION
General Considerations:
Consider the potential hazards of this material, applicable exposure limits, job activities, and other substances in the work
place when designing engineering controls and selecting personal protective equipment. If engineering controls or work
practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed
below is recommended. The user should read and understand all instructions and limitations supplied with the equipment
since protection is usually provided for a limited timer or under certain circumstances.
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below the
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT:
Eye/Face Protection: Wear eye protection such as safety glasses, chemical goggles, or face-shields if engineering controls
or work practices are not adequate to prevent eye contact.
Skin Protection: Wear impervious protective clothing to prevent skin contact. Selection of protective clothing may include
gloves, apron, boots, and complete facial protection depending on operations conducted. Users should determine acceptable
performance characteristics of protective clothing. Consider physical requirements and other substances present when
selecting protective clothing. Suggested materials for protective gloves include: Silver Shield, or 4H (PE/EVAL), or Teflon, or
Viton.
Respiratory Protection: If exposure is anticipated to be greater than applicable exposure limits, wear a NIOSH approved
respirator that provides adequate protection from measured concentrations of this material, such as: Supplied-Air Respirator,
or Air-Purifying Respirator for Organic Vapors, or Self-contained breathing apparatus (SCBA) for use in environments with
unknown concentrations or emergency situations. Use a positive pressure, air-supplying respirator if there is potential for
uncontrolled release, exposure levels are not known, or other circumstances where air-purifying respirators may not provide
adequate protection.
Occupational Exposure Limits:
Component Name
Contains: Benzene
Contains: Benzene
Contains: Benzene
Contains: Benzene
Contains: Ethyl Benzene
Contains: Ethyl Benzene
Contains: Ethyl Benzene
Contains: Hexane
Contains: Hexane
Contains: Hexane
Contains: Styrene
Safety Data Sheet – 05 – Py Gas
Limit
ACGIH
CPCHEM
German MAK
OSHA PEL
ACGIH
German MAK
OSHA PEL
ACGIH
German MAK
OSHA PEL
ACGIH
TWA
0.5 ppm
0.5 ppm
1 ppm
1 ppm
100 ppm
440 mg/m3
100 ppm
50 ppm
3
180 mg/m
500 ppm
20 ppm
STEL
2.5 ppm
2.5 ppm
NA
5 ppm
125 ppm
NA
NA
NA
NA
NA
40 ppm
Ceiling/Peak
NA
NA
3
NA
NA
1
NA
NA
4
NA
NA
Notation
Skin (BEI) A1
Skin
Skin, 1
NA
BEI A3
Skin
NA
Skin
NA
NA
BEI
Page 4 of 9
Contains: Styrene
Contains: Styrene
Contains: Toluene
Contains: Toluene
Contains: Toluene
Contains: Xylene
German MAK
OSHA PEL
ACGIH
German MAK
OSHA PEL
ACGIH
3
89 mg/m
100 ppm
10 ppm
50ppm
200 ppm
100 ppm
NA
NA
NA
NA
NA
150 ppm
4
200 ppm
NA
4
300 ppm
NA
NA
NA
Skin (BEI) A4
Skin, C
NA
BEI A3
SECTION-9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State and
Appearance
Color
Odor
Odor Threshold
pH
Boiling Point/Boiling
Range
70 C to 160 C (158 F to
320OF) IBP-EP
Auto-ignition
400-500OC (752-932OF)
Lower Flammable
(explosion) Limit
Upper Flammable
(explosion) Limit
Amber liquid with olefinic
odor
Pale yellow
Aromatic
NA
Not Applicable
O
O
O
1.3 %
7.5 %
Solubility (water)
Evaporation Rate
Vapor Pressure
Evaporation Rate
Viscosity
Partition Coefficient
Octanol/Water Log Pow)
Relative Vapor Density
(air=1)
Additional Physical and
Chemical properties
Melting Point
Flash Point
Soluble in HC solvents;
insoluble in water
NA
O
O
3.5 psia at 38 C (100 F)
NA
0.9 cSt at 40OC (104OF)
NA
2.8
No additional information
available
O
O
- 95 C (-139 F)
O
O
- 7 C (19.4 F)
SECTION-10. STABILITY AND REACTIVITY
Chemical Stability
:
Incompatibility With Other
Materials
Conditions to Avoid
:
Substances to Avoid
Hazardous Decomposition
Products
:
:
:
Unstable at elevated temperatures. Stable when inhibited with greater than 10 ppm
TBC. This material is considered stable under normal ambient and anticipated
storage and handling conditions of temperature and pressure.
May react with oxygen and strong oxidizing agents, such as chlorates, nitrates,
peroxides, etc. Corrosive to copper and copper bearing alloys
Avoid heat, sparks, open flames and other ignition sources. Prevent vapor
accumulation.
Strong oxidizing agents.
No Data
SECTION-11. TOXICOLOGICAL INFORMATION
IMMEDIATE HEALTH EFFECTS:
Acute Oral Toxicity
Acute Dermal Toxicity
Acute Inhalation Toxicity
Eye irritation
Skin Irritation
Respiratory Tract Irritation
Sensitization
: LD50 Oral: > 5,000 mg/kg Species: rat
: LD50 Dermal: > 2,000 mg/kg, Information refers to the main ingredient.
: LC50: > 12400 ppm, Exposure time: 4 Hrs, Species: rat
: This material is irritating to the eyes
: This material is irritating to the skin
: This material maybe irritating to the respiratory tract.
: Dermal/not expected to be a sensitizer
ADDITIONAL TOXICOLOGY INFORMATION:
This product contains BENZENE:
Repeated Dose Toxicity: 13 wks/inhalation/rat/Doses: 0, 10, 30, or 300 ppm/6h/d; 5d/wk/NOAEL=10 ppm, LOAEL=30 ppm
(increase in mean thyroid weight); 103 wks/gavage/rat/Doses: 0, 25, 50, or 100 mg/kg for females, 0, 50, 100, or 200 mg/kg
for males; 5d/wk/NOAEL300 mg/kg Target Organs: 13 weeks/inhalation/rat/Doses: 0, 50, 200, or 800ppm/6h/d,
7d/w/NOAEL=200ppm, LOAEL=800ppm (auditory dysfunction at mid and high frequencies) Genetic Toxicity: Ames testnegative, Cytogenetic assay-positive; E. coli reverse mutation assay-negative; Mouse Lymphoma assay–negative; Sister
Chromatid Exchange assay-positive; Mammalian cell gene mutation assay–negative; Micronucleus test–positive
Carcinogenicity: 2 years/in drinking water/rat/Doses: 0, 125 or 250 ppm/daily/no evidence of carcinogenicity
This product contains TOLUENE:
Repeated Dose Toxicity: 15 wks/inhalation/rat/Doses: 0, 100, 625, 1250, 2500 or 3000 ppm/6h/d, 5d/wk/NOAEL=625 ppm
(changes in liver and kidney weights, decreased leukocyte count), 14 wks/inhalation/mice/Doses: 0, 100, 625, 1250, 2500
or 3000 ppm/6h/d, 5d/wk/NOAEL = 100 ppm (increased organ weights, decreased body weights)
Reproductive And Developmental Toxicity: 2-generation/95 days/inhalation/rats/Doses; 0, 100, 500 or 2000 ppm/
NOAEL=2000 ppm (max dose)–no effect on fertility, repro or lactation parameters; NOAEL for developmental effects=400 –
750 ppm (skeletal malformations) Genetic Toxicity: Ames test-negative; Sister Chromatid Exchange assay-negative; Mouse
lymphoma assay–negative; Cytogenetic assay in vivo/in vitro–negative; Micronucleus test–negative.
Carcinogenicity: 2 years/inhalation/rat & mouse/Doses: 0, 600 or 1200 ppm/6.5h/day, 5 d/week/no evidence of
carcinogenicity.
This product contains N-HEXANE:
Repeated Dose Toxicity: 13 wks/inhalation/rat/Doses: 0, 3000, 6500, or 10,000 ppm/6h/d, 5d/wk/LOAEL=6500 ppm
(depression of body weight gain, lower brain weight and axonopathy in male rats)
Reproductive And Developmental Toxicity: 61days/inhalation/rats/Doses; 0, 1000 ppm/permanent testicular damage
characterized by loss of germ-cell line Genetic Toxicity: Ames test-negative; Sister Chromatid Exchange assay-negative;
Mouse lymphoma assay–positive
Carcinogenicity: 24 wks/inhalation/rat/Doses: 0, 3000 ppm/8h/day, 6days/wk/rats developed papillary proliferation of nonciliated bronchiolar cells.
This product contains ETHYLBENZENE:
BIRTH DEFECTS AND REPRODUCTION: Not expected to be a teratogen or reproductive toxicant based on rats and
rabbits studies. NOAEL is 500 ppm in a rat 2-generation reproductive neurotoxicity study.
IMMUNOTOXICITY: NOAEL is 500 ppm in a rat splenic antibody formation study. There is no evidence that ethyl benzene
is immunotoxic.
HEARING: 200 ppm or higher concentration of vapor exposures was associated with structural and electrophysiological
alterations in the auditory system of laboratory animals.
Safety Data Sheet – 05 – Py Gas
Page 6 of 9
Genetic toxicity: Negative in the bacterial mutation test, Chinese Hamster Ovary (CHO) cell in vitro assay, sister chromatid
exchange assay and an unscheduled DNA synthesis assay. Conflicting results for the mouse lymphoma cell assay.
Increased micronuclei were reported in an in vitro Syrian hamster embryo cell assay; however, two in vivo micronuclei
studies in mice were negative. In Syrian hamster embryo cells in vitro, cell transformation was observed at 7 days of
incubation but not at 24 hours.
Carcinogenicity: 103 wks/inhalation/rats and mice/6h/d for 5d/wk/Doses: 75, 250, or 750 ppm/in rats exposed to 750 ppm,
the incidence of kidney tubule hyperplasia and tumors was increased. In mice, the incidences of lung tumors in males and
liver tumors in females exposed to 750 ppm increased as compared to control mice but were within the range of incidences
observed historically in control mice. Ethyl benzene is classified in group 2B (possibly carcinogenic to humans) by IARC.
This product contains MIXED XYLENES:
Repeated Dose Toxicity: 13 wks/gavage/rat/Doses: 0, 62.5, 125, 250, 500, or 1000mg/kg/daily, 5d/w/NOAEL = 1000mg/kg
(for systemic effects including CNS effects) and NOAEL = 500mg/kg (reduced weight gain); 13 wks/inhalation/rat/Doses: 0,
180, 460, or 810ppm/6h/d, 5d/w/NOAEL > 810ppm.
Reproductive and Developmental Toxicity: GD 7-16/inhalation/rat/Doses: 0, 805, or 1610ppm/6h/d/NOAEL = 1610ppm;
GD 6-15/oral (gavage)/mouse/Doses: 0, 780, 1960, or 2619mg/kg/3 times/day/LOAEL = 1960mg/kg (maternal toxicity and
increased incidences of resorptions and cleft palate),
Other test substance – paraxylene Target Organs: 13 wks/inhalation/rat/Doses: 0, 450, 900 or 1800ppm/6h/d,
6d/wk/LOAEL = 900ppm (moderate to severe ototoxicity).
Other test substance – paraxylene Genetic toxicity: Ames-negative; Mouse lymphoma assay-negative; Micronucleus
assay–negative Carcinogenicity: 103 wes/gavage/rat/ 0, 250, 500 mg/kg/5d/w/NOAEL=250 mg/kg/LOAEL=500mg/kg
(decreased body weight and decreased survival); 103 wks/gavage/mouse/0, 500, 100mg/kg/5d/w/NOAEL=1000mg/kg
SECTION-12. ECOLOGICAL INFORMATION
Eco toxicity
:
Environmental Fate
:
This material is expected to be toxic to aquatic organisms.
Contains: Benzene-8 days/EC50/green algae (Selenastrum capricornutum)/41 mg/l
Contains: Benzene-96 hrs/LC50/striped bass (Marone saxatilis)/5.3 mg/l
Contains: Benzene-96 hrs/LC50/rainbow trout (Oncorhynchus mykiss)/5.3-9.1mg/l
Contains: Benzene-24 hrs/EC50/water flea (Daphnia magna)/240 mg/l
This material is volatile and is expected to partition to air. This material is expected
to biodegrade under certain environmental conditions. More than 99% of xylene
released to the environment is volatilized to the atmosphere. Xylene is readily
biodegradable; the rate of biodegradation varies with the source of microbial culture
and whether acclimation to the substrate has been accomplished by pre-exposure to
xylene. Toluene is volatile and when released into water will be volatilized to the
atmosphere where it is degraded with a half-life of 10 to 104 hours. Toluene is
readily biodegradable in tests using sewage or sludge inocula. The biodegradation
half-life for toluene in surface waters and soils is expected to range from 4 to 22
days. Toluene that does not evaporate following release to soil is expected to be
highly mobile and may leach to groundwater. In groundwater, toluene has been
reported to be degraded in 7 to 28 days. N-Hexane has low water solubility and is
highly volatile. Data on the toxicity of n-Hexane to aquatic organisms are few,
variable, conducted under inappropriate conditions and inadequate to make an
assessment of the environmental risk
SECTION-13. DISPOSAL CONSIDERATIONS
Waste Disposal
Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a
hazardous waste as defined by US EPA under RCRA (40 CFR 261) or local regulations. Measurement of certain physical
properties and analysis for regulated component may be necessary to make a correct determination. If this material is
Safety Data Sheet – 05 – Py Gas
Page 7 of 9
classified as a hazardous waste, Kementrian Lingkungan Hidup Republic Indonesia requires disposal at a licensed
hazardous waste disposal.
Product: The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds,
waterways or ditches with chemical or used container. Sent to a licensed waste management company. Contaminated
packaging: Empty remaining contents. Dispose as unused product. Do not re-use empty containers. Do not burn, or use a
cutting torch on, the empty drum.
SECTION-14. TRANSPORT INFORMATION
UN Number
UN Proper Shipping name
1268
Py Gas
Transport Hazard Class
Road (ADR)/Rail (RID)/Water (ADNR)
IMDG class (Marine Transport)
ICAO/IATA class (Air Transport)
Packing Group
Marine Pollutant
UN 1268, PETROLEUM
DISTILLATES, N.O.S., 3, I, ADR
UN 1268, PETROLEUM
DISTILLATES, N.O.S., 3, I, (>-11°C),
RQ (Benzene, Ethylbenzene
UN 1268, PETROLEUM
DISTILLATES, N.O.S., 3, I
Yes
SECTION-15. REGULATORY INFORMATION
Regulatory Information
:
KEPMENAKER 187/Men/1999 Pengendalian Bahan Kimia Berbahaya
PERMENLH RI No. 3 Year 2008: Tata Cara Pemberian Simbol dan Label Bahan
Berbahaya dan Beracun.
PERMENPERIN RI No. 87/M-IND/PER/9/2009: Sistem Harmonisasi Global
Klasifikasi dan Label pada Bahan kimia.
SECTION-16. OTHER INFORMATION
Training Advice
:
Personnel handling the product need to be demonstrably with its hazardous
properties, with health and environmental protection principles related to the product
and first aid principles
Recommended Uses
Safety Data Sheet – 05 – Py Gas
:
THE PRODUCT IS RESTRICTED TO PROFESSIONAL USAGE. Ensure all
national/local regulations are observed. Ensure operators understand the
flammability hazard. The hazard of asphyxiation is often overlooked and must be
stressed during operator training. This Safety Data Sheet has been established in
accordance with the applicable European. Directives and applies to all countries that
have translated the Directives in their national laws. Details given in this document
are believed to be correct at the time of going to press. Whilst proper care has been
taken in the preparation of this document, no liability for injury or damage resulting
from its use can be accepted. Although reasonable care has been taken in the
preparation of this document, we extend no warranties and make no representations
as to the accuracy or completeness of the information contained herein, and assume
no responsibility regarding the suitability of this information for the user’s intended
purposes or for the consequences of its use. Each individual should make a
determination as to the suitability of the information for their particular purpose.
Page 8 of 9
NFPA Hazard Rating for Py Gas
NFPA Code
Health-2
Intense or continued but not chronic exposure could cause temporary
incapacitation or possible residual injury
Flammability-3
Liquids and solids (including finely divided suspended solids) that can be
ignited under almost all ambient temperature conditions
Reactivity-0
Normally stable, even under fire exposure conditions, and is not reactive with
water
Abbreviations that may have been used in this document:
NOAEL :
No Observed Adverse Effect Level
LOAEL :
Lower Observed Adverse Effect Level
ACGIH :
American Conference of Governmental Industrial Hygienist
ADNR :
European Agreement concerning the Int’l Carriage of Dangerous Goods by inland Waterways
ADR :
European Agreement concerning the Int’l Carriage of Dangerous Goods by Road
CAS :
Chemical Abstract Service
EPA :
Environmental Protection Agency
EU :
European Union
IATA :
International Air Transport Association
ICAO :
International Civil Aviation Organization
IMDG :
International Maritime Dangerous Goods
IMO :
International Maritime Organization
LC50 :
Lethal Concentration, concentration of chemical which kills 50% of a sample population
LD50 :
Lethal Dose, dose of a chemical which kills 50% of a sample population
NFPA :
National Fire Protection Association
NTP :
National Toxicology Program
PSHA :
Occupational Safety and Health Administration
RID :
International Rule for Transportation of Dangerous Substance by Railway
TLV :
Threshold Limit Value
TWA :
Time Weighted Averages
THE INFORMATION EXPRESSED HEREIN IS THOSE OF QUALIFIED CURRENT KNOWLEDGE AND EXPERIENCE ANT THAT
THE INFORMATION IS SUFFICIENT OF ALL CASES. USERS SHOULD CONSIDER THE DATA AS A SUPPLEMENT TO OTHER
INFORMATION AND SHOULD MAKE INDEPENDENT DETERMINATION OF ITS SUITABILITY, THEIR EMPLOYEES AND
CUSTOMERS AND OF THE ENVIRONMENTAL PROTECTION TO ASSURE PROPER USE AND DISPOSAL OF THE MATERIAL.
RESPONSIBILITY FOR USAGE, STORAGE, HANDLING AND DISPOSAL OF THE PRODUCTS DESCRIBED HEREIN, WHETHER
ALONE, OR IN COMBINATION WITH ANY OTHER SUBSTANCE, IS THAT OF THE PURCHASER AND/OR END-USER. CAP
MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULT TO BE
OBTAINED FROM THE USE THEREOF. CAP ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT
DESCRIBED HEREIN.
Safety Data Sheet – 05 – Py Gas
Page 9 of 9
Safety Data Sheet in accordance with UN GHS Purple Book
CAP – SDS – 05 – Pyrolysis Gasoline (Rev.00)
ISSUED DATE : 09 Jan 2015
SECTION-1. IDENTIFICATION
Product/Material
Recommended Use
Manufacturer
Head Office
Plant
Emergency contact (24 hrs)
Additional Information
:
:
:
:
:
:
:
Pyrolysis Gasoline (Py gas)
Raw material use in industrial applications for chemical synthesis etc.
PT. CHANDRA ASRI PETROCHEMICAL Tbk (CAP)
Wisma Barito Pacific, Tower A, 7th floor, Jl. Letjend S. Parman, Kav.62-63. Jakarta
11410, Indonesia.
Jl Raya Anyer Km.123, Ciwandan, Cilegon 42447, Indonesia. Ph: 62-254-601501
GROUPSHEDIVISION@capcx.com, Phone: 62-254-601829, 601501 Ext 1232
GROUPRND@capcx.com, Phone: +62-254-601501 Ext 1869, 1616
SECTION-2. HAZARD IDENTIFICATION
GHS Classification
:
Hazard Statements
:
Pictogram (Hazard Symbols)
:
Signal Word
Target Organ
Physical Hazards
Environmental Hazards
Health Hazards
:
:
:
:
:
Precautionary Hazard
Prevention
:
:
Safety Data Sheet – 05 – Py Gas
Flammable liquid: Category 2│Acute aquatic toxicant: Category 2│Chronic aquatic
toxicant: Category 2 │ Aspiration toxicant: Category 1 │ Carcinogen: Category 1A │
Target organ toxicant (repeated exposure): Category 1 │ Eye irritation: Category 2A
│ Germ Cell Mutagen: Category 1B │ Reproductive toxicant: Category 1B │ Skin
irritation: Category 2 │ Target organ toxicant (central nervous system): Category 3 │
Target organ toxicant: Category 3 │ Acute oral toxicant: Category 4.
Highly flammable liquid and vapor│May be fatal if swallowed and enters
airways│May be harmful in contact with skin│Causes skin irritation│May cause
respiratory irritation, and drowsiness or dizziness│May cause genetic defects│May
cause cancer│Suspected of damaging fertility or the unborn child│Causes damage
to organs (Blood, Eyes, Auditory organs, Nervous system) through prolonged or
repeated exposure│May cause damage to organs (Auditory organs) through
prolonged or repeated exposure if inhaled│Toxic to aquatic life with long lasting
effects.
DANGER
Causes damage to organs through prolonged or repeated exposure.
Extremely flammable liquid and vapor.
Toxic to aquatic life. Toxic to aquatic life with long lasting effects.
May be fatal if swallowed and enters airways. Harmful if swallowed. May cause
cancer. May cause genetic defects. May damage fertility or the unborn child.
Causes serious eye irritation. Causes skin irritation. May cause drowsiness or
dizziness. May cause respiratory irritation.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Keep
Page 1 of 9
Precautionary Hazard Response
:
Precautionary Hazard-Storage
Precautionary Hazard-Disposal
:
:
away from heat/sparks/open flames/hot surfaces. – No smoking.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical advice/attention. IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Take
off contaminated clothing and wash before reuse. IF SWALLOWED: Immediately
call a POISON CENTER or doctor/physician Wash with plenty of soap and water.
Rinse mouth. Do NOT induce vomiting. IF exposed or concerned: Get medical
advice/attention. Specific treatment (see Notes to Physician on this label). In case of
fire: Use manufacturer/supplier or the competent authority to specify appropriate
media for extinction. Collect spillage.
Store in a well-ventilated place. Keep cool. Store locked up.
Dispose of contents/container in accordance with applicable local/ regional/ national/
international regulations.
SECTION-3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Identity
Common Name
:
:
Pyrolysis Gasoline
Py Gas
Component
C5’s and lighter
Contains: Styrene
Total BTX
Non Aromatic (C6 & heavier)
:
:
:
:
CAS No
Mixture
100-42-5
Mixture
Mixture
CAS No : 68606-10-0
Concentration (ppm wt.)
< 1.5 % wt
60 % weight
< 40% weight
SECTION-4. FIRST-AID MEASURES
Skin
:
Inhalation
:
Eyes
:
Ingestion
:
Note to Physician
:
To remove the material from skin, use soap and water. Discard contaminated
clothing and shoes or thoroughly clean before reuse. Get medical attention if any
symptoms develop.
Move the exposed person to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention if breathing difficulties
continue.
Flush eyes with running water immediately while holding the eyelids open. Remove
contact lenses, if worn, after initial flushing, and continue flushing for at least 15
minutes. Get immediate medical attention.
If swallowed, do not induce vomiting. Give the person a glass of water or milk to
drink and get immediate medical attention. Never give anything by mouth to an
unconscious person.
Ingestion of this product or subsequent vomiting may result in aspiration of light
hydrocarbon liquid, which may cause pneumonitis.
SECTION-5. FIRE-FIGHTING MEASURES
Flammable Properties
Extinguishing Media
:
Clear fire area of all non-emergency personnel.
Suitable Extinguishing Media
:
Unsuitable Extinguishing Media
:
Foam, water spray or fog. Dry chemical powder, carbon dioxide, san or earth may
be used for small fires only.
Do not use water jet.
Specific Hazards in Case of Fire
Hazardous Combustion Products :
Safety Data Sheet – 05 – Py Gas
The vapor is heavier than air, spreads along the ground and distant ignition is
possible. Will float and can be reignited on surface water. Carbon monoxide may be
Page 2 of 9
evolved in incomplete combustion occurs.
Special Protective Equipment and Precaution for Fire Fighter
Special Protective Equipment
Precautions for Fire- Fighter
:
:
Wear full protective clothing and self-contained breathing apparatus
Do not spray on an open flame or any other incandescent material. Take necessary
action to avoid static electricity discharge (which might cause ignition of organic
vapors). Use only explosion proof equipment. Keep away from open flames, hot
surfaces and sources of ignition.
SECTION-6. ACCIDENTAL RELEASE MEASURES
Protective Measures
:
Spill Management
:
Eliminate all sources of ignition in the vicinity of the spill or released vapor. If this
material is released into the work area, evacuate the area immediately. Monitor area
with combustible gas indicator. Wear appropriate personal protective equipment
when cleaning up spills.
Stop the source of the release if you can do it without risk. Contain release to
prevent further contamination of soil, surface water or groundwater. Clean up spill as
soon as possible, observing precautions in Exposure Controls/Personal Protection.
Use appropriate techniques such as applying non-combustible sorbent materials or
pumping. All equipment used when handling the product must be grounded. A vapor
suppressing foam may be used to reduce vapors. Use clean non-sparking tools to
collect absorbed material. Where feasible and appropriate, remove contaminated
soil. Place contaminated materials in disposable containers and dispose of in a
manner consistent with applicable regulations.
SECTION-7. HANDLING AND STORAGE
Precautions for Safe Handling
:
This material presents a fire hazard. Liquid quickly evaporates and forms vapor
(fumes) which can catch fire and burn with explosive violence. Invisible vapor
spreads easily and can be set on fire by many sources such as pilot lights, welding
equipment, and electrical motors and switches. Fire hazard is greater as liquid
temperature rises above 15°F. Do not breathe vapor or fumes.
Unusual Handling Hazards
:
General Handling Information
:
Static Hazard
:
Inspect tank vents periodically. Styrene vapors may polymerize in vents or flame
arrestors of storage tanks. Check temperature, inhibitor and polymer content at least
once a week during warm weather. Increase monitoring frequency if stored at
greater than 70 F for longer than 30 days. Minimize storage time
Avoid work practices that may release volatile components in the atmosphere. Local
air pollution regulations should be consulted to determine if the release of volatile
components is regulated or restricted in the area in which this material is used.
Avoid contaminating soil or releasing this material into sewage and drainage
systems and bodies of water.
Electrostatic charge may accumulate and create a hazardous condition when
handling this material. To minimize this hazard, bonding and grounding may be
necessary but may not, by themselves, be sufficient. Review all operations, which
have the potential of generating an accumulation of electrostatic charge and/or a
flammable atmosphere (including tank and container filling, splash filling, tank
cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum
truck operations) and use appropriate mitigating procedures. For more information,
refer to OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids,
National Fire Protection Association (NFPA 77), Recommended Practice on Static
Electricity' (liquids, powders and dusts), and/or the American Petroleum Institute
(API) Recommended Practice 2003, 'Protection Against Ignitions Arising Out of
Safety Data Sheet – 05 – Py Gas
Page 3 of 9
General Storage Information
:
Static, Lightning, and Stray Currents' (liquids).
Container is not designed to contain pressure. Does not use pressure to empty
container or it may rupture with explosive force. Empty containers retain product
residue (solid, liquid, and/or vapor) and can be dangerous. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks,
static electricity, or other sources of ignition. They may explode and cause injury or
death. Empty containers should be completely drained, properly closed, and
promptly returned to a drum reconditioner, or disposed of properly. DO NOT USE
OR STORE near heat, sparks or open flames. USE AND STORE ONLY IN WELL
VENTILATED AREA. Keep container closed when not in use.
SECTION-8. EXPOSURE CONTROLS / PERSONAL PROTECTION
General Considerations:
Consider the potential hazards of this material, applicable exposure limits, job activities, and other substances in the work
place when designing engineering controls and selecting personal protective equipment. If engineering controls or work
practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed
below is recommended. The user should read and understand all instructions and limitations supplied with the equipment
since protection is usually provided for a limited timer or under certain circumstances.
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below the
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT:
Eye/Face Protection: Wear eye protection such as safety glasses, chemical goggles, or face-shields if engineering controls
or work practices are not adequate to prevent eye contact.
Skin Protection: Wear impervious protective clothing to prevent skin contact. Selection of protective clothing may include
gloves, apron, boots, and complete facial protection depending on operations conducted. Users should determine acceptable
performance characteristics of protective clothing. Consider physical requirements and other substances present when
selecting protective clothing. Suggested materials for protective gloves include: Silver Shield, or 4H (PE/EVAL), or Teflon, or
Viton.
Respiratory Protection: If exposure is anticipated to be greater than applicable exposure limits, wear a NIOSH approved
respirator that provides adequate protection from measured concentrations of this material, such as: Supplied-Air Respirator,
or Air-Purifying Respirator for Organic Vapors, or Self-contained breathing apparatus (SCBA) for use in environments with
unknown concentrations or emergency situations. Use a positive pressure, air-supplying respirator if there is potential for
uncontrolled release, exposure levels are not known, or other circumstances where air-purifying respirators may not provide
adequate protection.
Occupational Exposure Limits:
Component Name
Contains: Benzene
Contains: Benzene
Contains: Benzene
Contains: Benzene
Contains: Ethyl Benzene
Contains: Ethyl Benzene
Contains: Ethyl Benzene
Contains: Hexane
Contains: Hexane
Contains: Hexane
Contains: Styrene
Safety Data Sheet – 05 – Py Gas
Limit
ACGIH
CPCHEM
German MAK
OSHA PEL
ACGIH
German MAK
OSHA PEL
ACGIH
German MAK
OSHA PEL
ACGIH
TWA
0.5 ppm
0.5 ppm
1 ppm
1 ppm
100 ppm
440 mg/m3
100 ppm
50 ppm
3
180 mg/m
500 ppm
20 ppm
STEL
2.5 ppm
2.5 ppm
NA
5 ppm
125 ppm
NA
NA
NA
NA
NA
40 ppm
Ceiling/Peak
NA
NA
3
NA
NA
1
NA
NA
4
NA
NA
Notation
Skin (BEI) A1
Skin
Skin, 1
NA
BEI A3
Skin
NA
Skin
NA
NA
BEI
Page 4 of 9
Contains: Styrene
Contains: Styrene
Contains: Toluene
Contains: Toluene
Contains: Toluene
Contains: Xylene
German MAK
OSHA PEL
ACGIH
German MAK
OSHA PEL
ACGIH
3
89 mg/m
100 ppm
10 ppm
50ppm
200 ppm
100 ppm
NA
NA
NA
NA
NA
150 ppm
4
200 ppm
NA
4
300 ppm
NA
NA
NA
Skin (BEI) A4
Skin, C
NA
BEI A3
SECTION-9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State and
Appearance
Color
Odor
Odor Threshold
pH
Boiling Point/Boiling
Range
70 C to 160 C (158 F to
320OF) IBP-EP
Auto-ignition
400-500OC (752-932OF)
Lower Flammable
(explosion) Limit
Upper Flammable
(explosion) Limit
Amber liquid with olefinic
odor
Pale yellow
Aromatic
NA
Not Applicable
O
O
O
1.3 %
7.5 %
Solubility (water)
Evaporation Rate
Vapor Pressure
Evaporation Rate
Viscosity
Partition Coefficient
Octanol/Water Log Pow)
Relative Vapor Density
(air=1)
Additional Physical and
Chemical properties
Melting Point
Flash Point
Soluble in HC solvents;
insoluble in water
NA
O
O
3.5 psia at 38 C (100 F)
NA
0.9 cSt at 40OC (104OF)
NA
2.8
No additional information
available
O
O
- 95 C (-139 F)
O
O
- 7 C (19.4 F)
SECTION-10. STABILITY AND REACTIVITY
Chemical Stability
:
Incompatibility With Other
Materials
Conditions to Avoid
:
Substances to Avoid
Hazardous Decomposition
Products
:
:
:
Unstable at elevated temperatures. Stable when inhibited with greater than 10 ppm
TBC. This material is considered stable under normal ambient and anticipated
storage and handling conditions of temperature and pressure.
May react with oxygen and strong oxidizing agents, such as chlorates, nitrates,
peroxides, etc. Corrosive to copper and copper bearing alloys
Avoid heat, sparks, open flames and other ignition sources. Prevent vapor
accumulation.
Strong oxidizing agents.
No Data
SECTION-11. TOXICOLOGICAL INFORMATION
IMMEDIATE HEALTH EFFECTS:
Acute Oral Toxicity
Acute Dermal Toxicity
Acute Inhalation Toxicity
Eye irritation
Skin Irritation
Respiratory Tract Irritation
Sensitization
: LD50 Oral: > 5,000 mg/kg Species: rat
: LD50 Dermal: > 2,000 mg/kg, Information refers to the main ingredient.
: LC50: > 12400 ppm, Exposure time: 4 Hrs, Species: rat
: This material is irritating to the eyes
: This material is irritating to the skin
: This material maybe irritating to the respiratory tract.
: Dermal/not expected to be a sensitizer
ADDITIONAL TOXICOLOGY INFORMATION:
This product contains BENZENE:
Repeated Dose Toxicity: 13 wks/inhalation/rat/Doses: 0, 10, 30, or 300 ppm/6h/d; 5d/wk/NOAEL=10 ppm, LOAEL=30 ppm
(increase in mean thyroid weight); 103 wks/gavage/rat/Doses: 0, 25, 50, or 100 mg/kg for females, 0, 50, 100, or 200 mg/kg
for males; 5d/wk/NOAEL300 mg/kg Target Organs: 13 weeks/inhalation/rat/Doses: 0, 50, 200, or 800ppm/6h/d,
7d/w/NOAEL=200ppm, LOAEL=800ppm (auditory dysfunction at mid and high frequencies) Genetic Toxicity: Ames testnegative, Cytogenetic assay-positive; E. coli reverse mutation assay-negative; Mouse Lymphoma assay–negative; Sister
Chromatid Exchange assay-positive; Mammalian cell gene mutation assay–negative; Micronucleus test–positive
Carcinogenicity: 2 years/in drinking water/rat/Doses: 0, 125 or 250 ppm/daily/no evidence of carcinogenicity
This product contains TOLUENE:
Repeated Dose Toxicity: 15 wks/inhalation/rat/Doses: 0, 100, 625, 1250, 2500 or 3000 ppm/6h/d, 5d/wk/NOAEL=625 ppm
(changes in liver and kidney weights, decreased leukocyte count), 14 wks/inhalation/mice/Doses: 0, 100, 625, 1250, 2500
or 3000 ppm/6h/d, 5d/wk/NOAEL = 100 ppm (increased organ weights, decreased body weights)
Reproductive And Developmental Toxicity: 2-generation/95 days/inhalation/rats/Doses; 0, 100, 500 or 2000 ppm/
NOAEL=2000 ppm (max dose)–no effect on fertility, repro or lactation parameters; NOAEL for developmental effects=400 –
750 ppm (skeletal malformations) Genetic Toxicity: Ames test-negative; Sister Chromatid Exchange assay-negative; Mouse
lymphoma assay–negative; Cytogenetic assay in vivo/in vitro–negative; Micronucleus test–negative.
Carcinogenicity: 2 years/inhalation/rat & mouse/Doses: 0, 600 or 1200 ppm/6.5h/day, 5 d/week/no evidence of
carcinogenicity.
This product contains N-HEXANE:
Repeated Dose Toxicity: 13 wks/inhalation/rat/Doses: 0, 3000, 6500, or 10,000 ppm/6h/d, 5d/wk/LOAEL=6500 ppm
(depression of body weight gain, lower brain weight and axonopathy in male rats)
Reproductive And Developmental Toxicity: 61days/inhalation/rats/Doses; 0, 1000 ppm/permanent testicular damage
characterized by loss of germ-cell line Genetic Toxicity: Ames test-negative; Sister Chromatid Exchange assay-negative;
Mouse lymphoma assay–positive
Carcinogenicity: 24 wks/inhalation/rat/Doses: 0, 3000 ppm/8h/day, 6days/wk/rats developed papillary proliferation of nonciliated bronchiolar cells.
This product contains ETHYLBENZENE:
BIRTH DEFECTS AND REPRODUCTION: Not expected to be a teratogen or reproductive toxicant based on rats and
rabbits studies. NOAEL is 500 ppm in a rat 2-generation reproductive neurotoxicity study.
IMMUNOTOXICITY: NOAEL is 500 ppm in a rat splenic antibody formation study. There is no evidence that ethyl benzene
is immunotoxic.
HEARING: 200 ppm or higher concentration of vapor exposures was associated with structural and electrophysiological
alterations in the auditory system of laboratory animals.
Safety Data Sheet – 05 – Py Gas
Page 6 of 9
Genetic toxicity: Negative in the bacterial mutation test, Chinese Hamster Ovary (CHO) cell in vitro assay, sister chromatid
exchange assay and an unscheduled DNA synthesis assay. Conflicting results for the mouse lymphoma cell assay.
Increased micronuclei were reported in an in vitro Syrian hamster embryo cell assay; however, two in vivo micronuclei
studies in mice were negative. In Syrian hamster embryo cells in vitro, cell transformation was observed at 7 days of
incubation but not at 24 hours.
Carcinogenicity: 103 wks/inhalation/rats and mice/6h/d for 5d/wk/Doses: 75, 250, or 750 ppm/in rats exposed to 750 ppm,
the incidence of kidney tubule hyperplasia and tumors was increased. In mice, the incidences of lung tumors in males and
liver tumors in females exposed to 750 ppm increased as compared to control mice but were within the range of incidences
observed historically in control mice. Ethyl benzene is classified in group 2B (possibly carcinogenic to humans) by IARC.
This product contains MIXED XYLENES:
Repeated Dose Toxicity: 13 wks/gavage/rat/Doses: 0, 62.5, 125, 250, 500, or 1000mg/kg/daily, 5d/w/NOAEL = 1000mg/kg
(for systemic effects including CNS effects) and NOAEL = 500mg/kg (reduced weight gain); 13 wks/inhalation/rat/Doses: 0,
180, 460, or 810ppm/6h/d, 5d/w/NOAEL > 810ppm.
Reproductive and Developmental Toxicity: GD 7-16/inhalation/rat/Doses: 0, 805, or 1610ppm/6h/d/NOAEL = 1610ppm;
GD 6-15/oral (gavage)/mouse/Doses: 0, 780, 1960, or 2619mg/kg/3 times/day/LOAEL = 1960mg/kg (maternal toxicity and
increased incidences of resorptions and cleft palate),
Other test substance – paraxylene Target Organs: 13 wks/inhalation/rat/Doses: 0, 450, 900 or 1800ppm/6h/d,
6d/wk/LOAEL = 900ppm (moderate to severe ototoxicity).
Other test substance – paraxylene Genetic toxicity: Ames-negative; Mouse lymphoma assay-negative; Micronucleus
assay–negative Carcinogenicity: 103 wes/gavage/rat/ 0, 250, 500 mg/kg/5d/w/NOAEL=250 mg/kg/LOAEL=500mg/kg
(decreased body weight and decreased survival); 103 wks/gavage/mouse/0, 500, 100mg/kg/5d/w/NOAEL=1000mg/kg
SECTION-12. ECOLOGICAL INFORMATION
Eco toxicity
:
Environmental Fate
:
This material is expected to be toxic to aquatic organisms.
Contains: Benzene-8 days/EC50/green algae (Selenastrum capricornutum)/41 mg/l
Contains: Benzene-96 hrs/LC50/striped bass (Marone saxatilis)/5.3 mg/l
Contains: Benzene-96 hrs/LC50/rainbow trout (Oncorhynchus mykiss)/5.3-9.1mg/l
Contains: Benzene-24 hrs/EC50/water flea (Daphnia magna)/240 mg/l
This material is volatile and is expected to partition to air. This material is expected
to biodegrade under certain environmental conditions. More than 99% of xylene
released to the environment is volatilized to the atmosphere. Xylene is readily
biodegradable; the rate of biodegradation varies with the source of microbial culture
and whether acclimation to the substrate has been accomplished by pre-exposure to
xylene. Toluene is volatile and when released into water will be volatilized to the
atmosphere where it is degraded with a half-life of 10 to 104 hours. Toluene is
readily biodegradable in tests using sewage or sludge inocula. The biodegradation
half-life for toluene in surface waters and soils is expected to range from 4 to 22
days. Toluene that does not evaporate following release to soil is expected to be
highly mobile and may leach to groundwater. In groundwater, toluene has been
reported to be degraded in 7 to 28 days. N-Hexane has low water solubility and is
highly volatile. Data on the toxicity of n-Hexane to aquatic organisms are few,
variable, conducted under inappropriate conditions and inadequate to make an
assessment of the environmental risk
SECTION-13. DISPOSAL CONSIDERATIONS
Waste Disposal
Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a
hazardous waste as defined by US EPA under RCRA (40 CFR 261) or local regulations. Measurement of certain physical
properties and analysis for regulated component may be necessary to make a correct determination. If this material is
Safety Data Sheet – 05 – Py Gas
Page 7 of 9
classified as a hazardous waste, Kementrian Lingkungan Hidup Republic Indonesia requires disposal at a licensed
hazardous waste disposal.
Product: The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds,
waterways or ditches with chemical or used container. Sent to a licensed waste management company. Contaminated
packaging: Empty remaining contents. Dispose as unused product. Do not re-use empty containers. Do not burn, or use a
cutting torch on, the empty drum.
SECTION-14. TRANSPORT INFORMATION
UN Number
UN Proper Shipping name
1268
Py Gas
Transport Hazard Class
Road (ADR)/Rail (RID)/Water (ADNR)
IMDG class (Marine Transport)
ICAO/IATA class (Air Transport)
Packing Group
Marine Pollutant
UN 1268, PETROLEUM
DISTILLATES, N.O.S., 3, I, ADR
UN 1268, PETROLEUM
DISTILLATES, N.O.S., 3, I, (>-11°C),
RQ (Benzene, Ethylbenzene
UN 1268, PETROLEUM
DISTILLATES, N.O.S., 3, I
Yes
SECTION-15. REGULATORY INFORMATION
Regulatory Information
:
KEPMENAKER 187/Men/1999 Pengendalian Bahan Kimia Berbahaya
PERMENLH RI No. 3 Year 2008: Tata Cara Pemberian Simbol dan Label Bahan
Berbahaya dan Beracun.
PERMENPERIN RI No. 87/M-IND/PER/9/2009: Sistem Harmonisasi Global
Klasifikasi dan Label pada Bahan kimia.
SECTION-16. OTHER INFORMATION
Training Advice
:
Personnel handling the product need to be demonstrably with its hazardous
properties, with health and environmental protection principles related to the product
and first aid principles
Recommended Uses
Safety Data Sheet – 05 – Py Gas
:
THE PRODUCT IS RESTRICTED TO PROFESSIONAL USAGE. Ensure all
national/local regulations are observed. Ensure operators understand the
flammability hazard. The hazard of asphyxiation is often overlooked and must be
stressed during operator training. This Safety Data Sheet has been established in
accordance with the applicable European. Directives and applies to all countries that
have translated the Directives in their national laws. Details given in this document
are believed to be correct at the time of going to press. Whilst proper care has been
taken in the preparation of this document, no liability for injury or damage resulting
from its use can be accepted. Although reasonable care has been taken in the
preparation of this document, we extend no warranties and make no representations
as to the accuracy or completeness of the information contained herein, and assume
no responsibility regarding the suitability of this information for the user’s intended
purposes or for the consequences of its use. Each individual should make a
determination as to the suitability of the information for their particular purpose.
Page 8 of 9
NFPA Hazard Rating for Py Gas
NFPA Code
Health-2
Intense or continued but not chronic exposure could cause temporary
incapacitation or possible residual injury
Flammability-3
Liquids and solids (including finely divided suspended solids) that can be
ignited under almost all ambient temperature conditions
Reactivity-0
Normally stable, even under fire exposure conditions, and is not reactive with
water
Abbreviations that may have been used in this document:
NOAEL :
No Observed Adverse Effect Level
LOAEL :
Lower Observed Adverse Effect Level
ACGIH :
American Conference of Governmental Industrial Hygienist
ADNR :
European Agreement concerning the Int’l Carriage of Dangerous Goods by inland Waterways
ADR :
European Agreement concerning the Int’l Carriage of Dangerous Goods by Road
CAS :
Chemical Abstract Service
EPA :
Environmental Protection Agency
EU :
European Union
IATA :
International Air Transport Association
ICAO :
International Civil Aviation Organization
IMDG :
International Maritime Dangerous Goods
IMO :
International Maritime Organization
LC50 :
Lethal Concentration, concentration of chemical which kills 50% of a sample population
LD50 :
Lethal Dose, dose of a chemical which kills 50% of a sample population
NFPA :
National Fire Protection Association
NTP :
National Toxicology Program
PSHA :
Occupational Safety and Health Administration
RID :
International Rule for Transportation of Dangerous Substance by Railway
TLV :
Threshold Limit Value
TWA :
Time Weighted Averages
THE INFORMATION EXPRESSED HEREIN IS THOSE OF QUALIFIED CURRENT KNOWLEDGE AND EXPERIENCE ANT THAT
THE INFORMATION IS SUFFICIENT OF ALL CASES. USERS SHOULD CONSIDER THE DATA AS A SUPPLEMENT TO OTHER
INFORMATION AND SHOULD MAKE INDEPENDENT DETERMINATION OF ITS SUITABILITY, THEIR EMPLOYEES AND
CUSTOMERS AND OF THE ENVIRONMENTAL PROTECTION TO ASSURE PROPER USE AND DISPOSAL OF THE MATERIAL.
RESPONSIBILITY FOR USAGE, STORAGE, HANDLING AND DISPOSAL OF THE PRODUCTS DESCRIBED HEREIN, WHETHER
ALONE, OR IN COMBINATION WITH ANY OTHER SUBSTANCE, IS THAT OF THE PURCHASER AND/OR END-USER. CAP
MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULT TO BE
OBTAINED FROM THE USE THEREOF. CAP ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT
DESCRIBED HEREIN.
Safety Data Sheet – 05 – Py Gas
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