O2 downstream Measurement with Urea Spray and 4 SCR bricks.

83 Three columns on the right side of table 4.1.5 give reference to the actual data log in appendix 4, provide a guide on how to read the table and refer to related appendix for the data in respective rows.

4.1.6 Measurement with Urea Spray and 4 SCR bricks.

The test results with urea spray and 4 SCR bricks are summarized in the table 4.1.6. The same methodology used for Urea Spray with 1 SCR was utilised in this test. The main differences from the 1 SCR case is the NOx reading downstream of the SCR. Clearly in this test, excess ammonia from urea spray have reduced all of NOx but posses another problem in the system. The undesired NH 3 slippages have been detected and further analysis in the section 4.1.6 will discuss this in depth. Table 4.1.6 Summary of Result: Urea Spray with 4 SCR. all measurements in ppm Results for urea spray 4 SCRs Temp upstream 592 K Temp downstream 582 K O2 upstream

9.30 O2 downstream

7.90 4 SCRs Spray pulse length ms -- 24 26 28 30 32 34 36 Refn Guide Apdx Potential up 4SCR Pot NH3 552 614 696 818 888 960 1042 calc A 3.6.2 Potential up 4SCR Pot SUM 510 1062 1124 1206 1328 1398 1470 1552 nh3+nox B MEXA up 4SCR SUM 544 797 813 837 858 878 904 908 avg sum C 4.1.6B MEXA, Spray off up 4SCR NO 200 200 200 200 200 200 200 200 240708b D 4.1.6 MEXA, Spray off up 4SCR NOx 510 510 510 510 510 510 510 510 240708b E 4.1.6 Calculated up 4SCR NO2 310 310 310 310 310 310 310 310 calc F MEXA Reading up 4SCR NH3 38 318 346 381 405 434 466 240708b G 4.1.6 Deduced ammonia up 4SCR SUM-NOx 34 287 303 327 348 368 394 398 240708b C-E=H 4.1.6 MEXA dw 4SCR SUM 539 78 128 181 242 304 367 424 avg sum I 4.1.6 MEXA dw 4SCR NO 205 30 5 1 1 1 2 20708c J 4.1.6 Measured dw 4SCR NH3 79 136 167 225 310 375 230708b K 4.1.6 NH3 + NO2 dw 4SCR SUM-NO 334 48 123 180 241 303 365 424 calc I-J=L Total consumed across 4 SCrs Pot SUM- SUM -29 984 996 1025 1086 1094 1103 1128 calc B-I=M Note: Plotted against potential ammonia supplied 4 SCR spray Pot NH3 up 552 614 696 818 888 960 1042 A up - down, 4SCR Pot SUM-SUM 4 SCR -29 984 996 1025 1086 1094 1103 1128 M 4SCR spray NOx or NH3consumed -15 492 498 512.5 543 547 551.5 564 M2=N 4SCR spray NO consumed -5 170 195 199 199 199 198 200 D-J=O 4SCR spray NO2 consumed -9.5 322 303 313.5 344 348 353.5 364 N-O =P concentration table pot NH3 up 552 614 696 818 888 960 1042 A Deduced ammonia ups 4SCR SUM-NOx 34 287 303 327 348 368 394 398 H NH3 14.5 60 116 183.5 275 341 408.5 478 A-N NOx 525 18 12 -2.5 -33 -37 -41.5 -54 E-N NO 205 30 5 1 1 1 2 D-O NO2 320 -12 7 -3.5 -34 -38 -43.5 -54 F-P Downstream 84 At the bottom of table 4.1.6 some of the NOx and NO 2 reading were showing negative values due to experimental error in this study using the methodology described earlier in the range of around +- 55 ppm. The NO 2 measurements were not measured directly but derived using the methodology described in section 4.1. It is believed that the negative values reflect the magnitude of the errors resulting from these assumptions, but do not affect the general conclusions discussed later.

4.2 Ammonia gas studies: General Overview