5. May Twe Aye.pdf

  

Majalah Geologi Indonesia, Vol. 26 No. 3 Desember 2011: 191-198

Copper-Gold Bearing Skarn Mineralization at the Batu Hijau

Deposit, Sumbawa Island, Indonesia

  

Mineralisasi Skarn Pembawa Tembaga dan Emas pada Cebakan Batu

_1,2

Hijau, Pulau Sumbawa, Indonesia

_{1 1 2 2} May Thwe Aye , Akira Imai , Naoto Araki , Subagyo Pramumijoyo , Arifudin Idrus , Lucas Donny _{2 3 1} Setijadji , dan Johan Arif ₂ Department of Earth Resources Engineering, Kyushu University, Japan

Department of Geological Engineering, Gadjah Mada University, Indonesia

₃ Mine Geology Department, PT Newmont Nusa Tenggara, Indonesia ABSTRACT

The Batu Hijau copper-gold skarn is located in the south western part of Sumbawa Island, Indonesia.

  

An interaction of hydrothermal fluids associated with Early to Middle Miocene andesitic volcaniclastic

rocks and Early to Middle Pliocene intermediate tonalite porphyry intrusion, formed a well-developed

exo-skarn. No limestone is known in the Batu Hijau deposit. The skarn is typified by the presence

of abundant garnet of andradite type, clinopyroxene (diopside-hedenbergite), opaque minerals as

hematite and magnetite, and sulfides comprising chalcopyrite and pyrite. Typically, they are charac-

terized by two main alteration stages based on a separate precipitation of calc-silicate minerals: (1)

early prograde, followed by (2) later retrograde. During the prograde stage, metasomatism led to the

formation of calcic-exoskarn consisting mainly of garnet (andradite-grossular) and pyroxene (diop-

side-hedenbergite). On the other hand, the retrograde alteration is characterized by presence of

epidote, calcite, quartz, and chlorite. Skarn mineralization is mostly concentrated along the brecciated

magnetite zone during the retrograde stage. Prograde metasomatism commenced with segregation and

evolution of a fluid phase in the pluton and its invasion into fractures and microfractures of the host

rocks. It is structurally and lithologically controlled. According to texture and mineralogy, during the

retrograde stage, the previously formed skarn zones were affected by intense multiple hydro-fracturing.

Consequently, considerable amounts of hydrous calc-silicate mineral (epidote), sulfides (pyrite, chal-

copyrite, galena, sphalerite, ±bornite), oxides (magnetite, hematite), and carbonates (calcite) replaced

the anhydrous calc- silicates. Contemporaneous with the invasion of the early-formed skarn minerals

then were partially altered to a series of very fine-grained aggregates of chlorite, magnetite, and calcite.

  Keywords: Cu-Au skarn, Batu Hijau, calcic-exoskarn, Sumbawa, Indonesia SARI

Skarn pembawa tembaga dan emas Batu Hijau terletak di bagian barat daya Pulau Sumbawa, In-

donesia. Interaksi fluida hidrotermal yang berasosiasi dengan batuan andesitik vulkaniklastika be-

rumur Miosen Awal - Tengah dan intrusi porfiri tonalit intermedier berumur Pliosen Awal - Tengah,

membentuk eksoskarn yang berkembang dengan baik. Tak ditemukan batugamping pada endapan

Batu Hijau. Skarn tersebut dicirikan oleh kehadiran garnet yang melimpah berjenis andradit, kli-

nopiroksen (diopsida-hedenbergit), mineral opak seperti hematit dan magnetit, serta sulfida seperti

kalkopirit dan pirit. Menurut jenisnya, mineral-mineral tersebut dicirikan oleh dua tahapan alterasi

utama berdasarkan pengendapan terpisah mineral-mineral kalk-silikat: (1) prograde awal, dan diikuti

oleh (2) retrograde belakangan. Selama tahapan prograde, metasomatisme diikuti oleh pembentukan

kalsik-eksoskarn yang terutama mengandung garnet (andradit-grosular) dan piroksen (diopsid-

hedenbergit). Sebaliknya, alterasi retrograde dicirikan oleh kehadiran epidot, kalsit, kuarsa, dan

_{Naskah diterima: 03 Januari 2011, revisi terakhir: 20 Desember 2011}

klorit. Mineralisasi skarn terutama terkonsentrasi di sepanjang zona magnetit terbreksikan selama

  

Majalah Geologi Indonesia, Vol. 26 No. 3 Desember 2011: 191-198

tahapan retrograde. Metasomatisme prograde dimulai dengan segregasi dan evolusi fase fluida di

dalam pluton dan invasinya ke dalam rekahan dan rekahan mikro batuan induk tersebut. Peristiwa

tersebut dikontrol oleh struktur dan litologi. Berdasarkan tekstur dan mineralogi, selama tahapan

retrograde, zona skarn yang terbentuk sebelumnya dipengaruhi oleh retakan hidro berulang yang

intensif. Akibat nya, sejumlah besar mineral kalk-silikat hidrat (epidot), sulfida (pirit, kalkopirit,

galena, sfalerit, ± bornit), oksida (magnetit, hematit), dan karbonat (kalsit) menggantikan kalk-sili-

kat anhidrat. Bersamaan dengan invasi mineral skarn yang terbentuk lebih awal, sebagian batuan

terubah menjadi serangkaian agregat yang berbutir sangat halus seperti klorit, magnetit, dan kalsit.

  Kata kunci: skarn Cu-Au, Batu Hijau, kalsik-eksoskarn, Sumbawa, Indonesia

  

INTRODUCTION petrological, geochemical condition of

  skarn and skarn mineralization, and the Batu Hijau, a world class porphyry Cu-Au genetically relationship between the skarn deposit, is located at the southwestern part mineralization and porphyry Cu-Au sys- of Sumbawa Island, Province of West Nusa tem. The authors therefore tend to conduct Tenggara, Indonesia (Figure 1). The deposit a microscopic study and geochemical contains 914Mt of ore at an average grade analysis as X-Ray Diffraction (XRD), X- of 0.53% Cu and 0.40g/t Au. Deep drilling Ray Fluorescence (XRF), Sacnning Elec- in 2003 indicates the presence of skarn and tron Microscopy (SEM/EDX), Actomic gold-copper bearing skarn mineralization Absorption Spectro-photometry (AAS), which interbedded with andesitic volcanic fluid inclusion studies (FI), and Stable unit (Setyandhaka et al., 2008; Idrus et al., Isotopic studies. This study was focused on 2009). The proposed research will attempt microscopic study (thin section and black to constrain the geological, mineralogical, polished section). _{116 00 E o o 117 00 E}

  N

Flores Sea

o Lombok Island _{8 30 S} ^o _{8 30 S o 9 00 S}

  Sumbawa Island _{o 9 00 S} Batu Hijau Deposit Indian Ocean

  15

  30

  30 Town _{116 00 E 117 00 E o o} Kilometers Figure 1. Map showing the location of Batu Hijau deposit.

  

Copper-Gold Bearing Skarn Mineralization at the Batu Hijau Deposit,

Sumbawa Island, Indonesia (M. T. Aye et al.)

BACKGROUND GEOLOGY

  The Batu Hijau deposit encompasses Early to Middle Miocene andesitic volcaniclastic units which are the most extensive rock unit in the deposit and they are gently dipping westward with locally contain thin interca- lations of limestone. The premineralization porphyritic andesitic intrusion and porphy- ritic stock and related dikes of porphyritic quartz diorite were continuously intruded by equigranular quartz diorite and multiple phases of tonalite intrusion (Clode et al., 1996; Garwin, 2002). Figure 2 illustrates the geological map of the Batu Hijau de- posit. These andesitic volcaniclastic units are cross-cut by the earliest phase porphyritic andesite. The tonalite porphyry intrusions occupy the central part of the Batu Hijau deposit and form a steeply dipping cluster of upward tapering, north-northeasterly- elongate, conical stocks. Along the contact between the andesitic volcanic unit and the equigranular quartz diorite, the tonalite porphyries were emplaced. The Batu Hiaju porphyry copper-gold mineralization system is centred on, and spatially and temporally related with this tonalite porphyry intrusion complex. (Clode et al., 1996; Garwin, 2002).

CHARACTERISTICS OF SKARN AND SKARN MINERALIZATION

  The skarn mineralization occurs at the deep level of the Batu Hijau porphyry copper- gold deposit. Skarn-type metasomatic al- teration and mineralization occur along the contact between the andesitic volcaniclastic unit and the tonalite porphyry intrusion and it can be found at the elevation of -450 to >-1000 m relative to sea level.

  The typical characteristics of skarn in Batu Hijau deposit is green, reddish brown,

Figure 2. Geological map of Batu Hijau deposit. Circles show the bore hole location of skarn mineralization.

  Legend Young Tonalite Intermediate Tonalite Equi Qtz Diorite Porp Qtz Diorite

  Porp Andesite Intrusion Volcanic Lithic Breccia Fine-grainedVolcaniclastic Fault

  Bore Hole location 484800 485200 485600 486000 486400 ^{9010000 9009600 9009200 9008800 9008400} 484800

  485200 485600 486000 486400 _9010000 9009600 9009200

  9008800 9008400 0,4 0,8

  0,2 Kilometers

  

Majalah Geologi Indonesia, Vol. 26 No. 3 Desember 2011: 191-198

  locally black in colour and fine-grained showing layers of colour banding, brec- ciated nature, and massive in some. The green layers predominantly consist of fine-to medium-grained clinopyroxene (diopside and hedenbergite) and the reddish-brown layers are mainly composed of garnet (an- dradite-grossularite), whereas white layers are chiefly composed of calcite and quartz. Ca-rich plagioclase (anorthite), quartz, epi- dote, and chlorite can also be recognized.

  The type of skarn can be classified as exoskarn because of the abundances of pyroxene-garnet minerals. The process of skarn formation occurrs in two stages: (1) prograde and (2) retrograde. The pro- grade skarn is typically characterized by the reddish-brown coloured, fine-grained garnet (andradite) which shows banded nature with others and greenish coloured clinopyroxene (diopside-hedenbergite) at high temperature of 340 ->400 ^o C by high salinity fluid of 35-45 NaCl wt% eq based on fluid inclusion thermometry. On the other hand, calcite, epidote, chlorite, and quartz represent the retrograde stage which is formed at low temperature of 280 - 300 ^o C by low salinity fluid of 1-10 NaCl wt% eq

  (Idrus et al., 2009). Prograde metasomatism commenced by segregation and evolution of a fluid phase in the pluton and its inva- sion into fractures and micro-fractures of the host rocks. According to texture and mineralogy, during the retrograde stage, the previously formed skarn zones were affected by intense multiple hydro-fracturing. Con- sequently, considerable amounts of hydrous calc-silicate mineral (epidote), sulfides (pyrite, chalcopyrite, galena, sphalerite, ± bornite), oxides (magnetite, hematite), and carbonates (calcite) replaced the anhydrous skarn minerals. Contemporaneous with the invasion of the early-formed skarn miner- als, they were partially altered to a series of very fine-grained aggregates of chlorite, hematite, and calcite.

  Skarn ore mineralizations are generated in the retrograde stage. Photographs of representa- tive drill core samples showing the typical texture of skarn and nature of occurrences of skarn ore mineralization are shown in Fig- ures 3 and 4. Various types of anhydrous and hydrous calc-silicates (garnet, diopside, am- phibole, epidote), silicates (chlorite, quartz, clay minerals), sulfides (pyrite, chalcopyrite, sphalerite, galena, bornite), oxides (magne- tite, hematite), and carbonates (calcite) were developed during sequential stages of skarni- fication processes in the skarn zones along the contact between andesitic volcanic unit and the tonalite porphyry intrusion. Garnet occurs ubiquitously in the skarn zone as fine-to coarse-grained, anhedral to euhedral crystals. Quartz/calcite veins and veinslets are cutting across the garnet- pyroxene skarn (Figures 5b and 5c). Most garnet crystals display concentric zoning (Figure 5d) occuring as patchy aggregates with conspicuous growth zoning, and are isotropic. Furthermore, it was recognized as one of representative minerals which corresponds to prograde stage. Most of the garnets partially, to entirely alter to epidote, calcite, quartz, chlorite, and clay minerals mainly along fractures and microfractures.

  Pyroxene occurs as fine-grained, anhedral to subhedral crystals showing decussate texture (Figure 6d). It seems partially to entirely alter to amphibole (tremolite-actin- olite) (Figure 6c). The alteration is more pronounced along calcite micro-veinlets, although compositional variations of the host rocks and intrusion exert a strong control on the mineralogy of the skarn zones (Meinert, 2000; Ray et al., 1990). Pyroxene occurs as vein and veinslets along the fracture in some. Furthermore, skarn mineralization in this deposit is mainly controlled by structure as most mineral- izations are highly generated in broken magnetite zones.

  

Copper-Gold Bearing Skarn Mineralization at the Batu Hijau Deposit,

Sumbawa Island, Indonesia (M. T. Aye et al.)

SBD-263/670 a

  SBD-260/572 b

  SBD-271/650 SBD-252/873 c d f e

SBD-240/741 SBD-260/930

  

Figure 3. Photograph showing the typical features of skarn: (a) banded nature of pyroxene and garnet, (b)

quartz vein across cutting the pyroxene abundance skarn, (c) quartz calcite vein which includes ore mineraliza-

tion cross cutting the garnet abundance skarn with some epidote, (d) quartz/calcite and magnetite veinlets cut

across the coarse-grained garnet and pyroxene skarn, (e) the contact nature of intermediate tonalite and skarn,

and (f) massive nature of garnet cross cut by quartz vein near brecciated zone.

  SBD-225/629 SBD-226/736 a b

SBD-240/912 SBD-226/930

  c d

SBD-286/931 SBD-252/786

  e f

Figure 4. Photograph showing the occurrences of skarn ore mineralization (a,b,d, and f) showing the vein type

skarn mineralization, (c) massive nature of pyrite along the contact of intermediate tonalite and skarn, and (e)

disseminated nature of skarn mineralization at the broken magnetite zone.

  

Majalah Geologi Indonesia, Vol. 26 No. 3 Desember 2011: 191-198

  As it was reported that an assemblage of bornite and chalcopyrite is common in prin- cipal ores in porphyry copper-gold deposits in western Pacific island arcs (Imai, 2001, 2005), bornite and chalcopyrite have also been recognized in the porphyry copper- gold deposit, Batu Hijau (Arif and Baker, 2004; Imai and Ohno, Imai and Nagai, 2009). However, the presence of bornite in the 19 drill hole samples collected from the skarn mineralization zone was not identified.

  It implies that bornite was not stable under the condition, and only chalcopyrite that could occur. Magnetite is the most abundant in the brecciated zone occuring as broken ore minerals and massive aggregates, and as veinlets within the skarn. Magnetite replaces pyrite (Figure 7b) and in turns is replaced partially by chalcopyrite and sphalerite. Magnetite coexists with ore minerals and is predominant over the others. In addition, the average of Cu concentration is relatively high among the chosen boreholes. This may

  Figure 5. Photomicrograph of (a) pyroxene vein cut across the pyroxene-garnet skarn, (b) quartz vein cutting the pyroxene abundance skarn, (c) quartz/ calcite veinlets cutting across the garnet abundance skarn, and (d) concentric zonning in coarse-grained garnet (cross polarized light).

  Figure 6. Photomicrograph of (a) sheet texture of pyroxene, (b) plagioclase show twinning nature (c) partial alteration of clinopyroxene by amphibole, and (d) pyroxene showing decussate texture (cross polarized light) Figure 7. Photomicrograph of opaque bearing skarn ore minerals (Polarized reflected light)

  suggest that the mineralization here is related to magnetite. Proffett (2003) and Setyandhaka

  et al. (2008) also stated that the highest grade

  of copper and gold occur in the broken mag- netite zone, which is commonly defined as skarn mineralization interval. In other words, it is likely that magnetite formed at first, pyrite then formed surrounding magnetite, and finally chalcopyrite filled the interstices. Imai and Nagai’s research (2009) differs from this result in that blebs of chalcopyrite (and bornite) inclusions and in magnetite grains in their drill hole samples. Blebs of native gold were recognized in chalcopyrite (Figure 7d). Pyrite is relatively abundant minerals and is present mainly within calc-silicates as massive and dispersed patchy aggregates and/ or as veinlets and microveinlets.

  a b c d ^{qtz qtz py py} _{py qtz} ^{mt cp cp cp 500 mm 500 mm} _{cp sph} 500 ^{mm 100 mm Au Au cp} a b c d ^{Px vein px} _{Qtz/cal veinletz} ^{grt Px vein} _{grt Zoned grt} ^{px 200 mm 200 mm 200 mm 200 mm}

  200 mm 200 mm a b c d ^{px px ch px plg plg} _{px epl grt} ^{200 mm 200 mm}

  200 mm 200 ^mm

  

Copper-Gold Bearing Skarn Mineralization at the Batu Hijau Deposit,

Sumbawa Island, Indonesia (M. T. Aye et al.)

DISCUSSION AND CONCLUSION

  Skarn zones were developed along the contact of the andesitic volcaniclastic unit with intermediate tonalite porphyry intru- sion. Field evidence, analytical data, and mineralogical and textural criteria show that in the studied area genetically skarnification processes and their evolutionary trend can be categorized into two discrete stages: (1) prograde and (2) retrograde. The alteration progressed isochemically by the effect of heat flowing from the pluton into the sur- rounding andesitic volcaniclastic rocks. In general, some anhydrous calc-silicates are in proximity to the contact (higher tem- perature), and some hydrous minerals at distances were developed by metasomatic processes from clay-rich carbonate inter- layers during this stage. In general, the de- velopment of calc-silicates is accompanied by decarbonation reactions which cause a slight volume decrease and the subsequently formation of fractures and microfractures in the host rock. Almost no opaque minerals (oxides and sulfides) were formed during the prograde stage.

  Prograde metasomatic alteration com- menced with the beginning of crystallization and consolidation and concurrent separation of high temperature fluids. The invasion and infiltration of such fluids into secondary fractures, resulted from both decarbonation reactions and hydro-fracturing processes, transferred noticeable amounts of Fe, Si, and Mg to the skarn zones. The introduc- tion of these elements caused the further progression of the decarbonation processes and the formation of a series of medium- to coarse-grained anhydrous calc-silicates within a fine-grained matrix. Garnets and pyroxenes formed during prograde stage are mainly andraditic and hedenbergitic in com- position, respectively, which may be due to the introduction of considerable amounts of Fe into the skarn system by the invading fluids. Textural relationships indicate that opaque minerals were not formed during the prograde stage.

  During the retrograde stage, in addition to Fe, Si, and Mg, considerable amounts of Cu as sulfides along with volatile constituents were also added to the skarn system, moti- vating a series of hydrolysis, sulfidation, and carbonation reactions within the anhydrous calc-silicates. As a result of these reactions, considerable amounts of hydrous calc-sili- cates (epidote), sulfides (pyrite, chacopyrite, and sphalerite), oxides (magnetite, hematite), and carbonates (calcite) replaced the early formed anhydrous calc-silicates. The early formed mineral assemblages were altered to a series of fine-grained aggregates of chlorite, hematite, calcite, and clay chiefly along frac- tures and micro- fractures by a relatively low temperature during the retrograde alteration.

  ACKNOWLEDGEMENTS This research is partially supported by JICA (Japan International Cooperation Agency). Thanks are also due to the management of PT. Newmont Nusa Teng- gara for the permission to conduct the field investi- gation and for the helps during the field work at the Batu Hijau mine in carrying out this research work.

  REFERENCES Clode, C.,Proffett, J.,Mitchell, P., and Munajat, I., 1996. Relationships of intrusion, wall-rock alteration and mineralization in the Batu Hijau copper-gold porphyry deposit, in 1999 Pacrim Congress, Bali, Indonesia.

  Australian Institute of Mining and Met- allurgy, Proceedings, Publication Series No 4/99, p.485-498. Garwin, S. L., 2001. The geologic setting of intru- sion-related hydrothermal systems near the Batu

  

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hijau porphyry copper-gold deposit, Sumbawa, Meinert, L.D., 2000. Gold in skarns related to epizo-

Indonesia. nal intrusions. In: Hagemann, S.G., and Brown, P.E.

  Society of Economic Geologist, Special Publication 9. p. 333-366. (Eds.), Gold in 2000. Reviews in Economic Geology, 13, p. 347-375.

  Idrus, A., Kolb, J., Meyer, F. M., Arif, J., Setyand-

haka, D., and Keply, S., 2009. A preliminary study Proffett, J.M., 2003. Review of deep drilling results

on skarn-related calcsilicate rocks associated with the at Batu Hijau.

  Unpublished Newmont Nusa Tenggara

Batu hijau porphry copper-gold deposit, Sumbawa Company Report. PT. Newmont Nusa Tenggra, Batu

Island, Indonesia. Hijau project, Sumbawa, Indonesia. 6pp.

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  295-306.

  Setyandhaka, D., Proffett, J.M., Kepli, S., and Arif, J., 2008. Skarn mineralization in Batu Hijau Cu-Au porphyry system. Proceeding of 37th Annual Meeting of Association of Indonesian Geologist, Bandung, p. 664-671.