Pengaruh Penambahan Selulosa Nanokristal Dari Kulit Rotan Dengan Plasticizer Gliserol dan Co-Plasticizer Asam Sitrat Dalam Pembuatan Biokomposit Berbahan Dasar Pati Sagu (Metroxylon Sp)

DAFTAR PUSTAKA
[1] Zareena B. I. 2010. “Plastics and Environment”. Dissemination Paper – 12.
Centre of Excellence in Environmental Economics. India : Madras School of
Economics.
[2] Kipngetich T. E dan Hillary M. 2012. “A blend of Green Algae and Sweet Potato
Starch as a Potential Source of Bioplastic Production and Its Significance to the
Polymer Industry”. International Journal of Green and Herbal Chemistry. 2 (1)
: hal. 5-14.
[3] United Nation Enviroment Programme. 2009. “Converting Waste Plastic Into A
Resource”. Division Of Technology, Industry and Economics. Osaka :
International Enviromental Technology Centre.
[4] Jones A., Zeler M.A., dan Sharma S. 2013. “Thermal, Mechanical, and Moisture
Absorption Properties of Egg White Protein Bioplastics with Natural Rubber and
Glycerol”. Progress in Biomaterials, 2 (1).
[5] Radecka I.K. 2013. “Biodegradeble Plastics In UK – Past, Present and Future”.
3rd International Plastice Conference. Faculty Of Science & Engineering. UK :
University Of Wolverhampton.
[6] Reddy R.L., Reddy V.S. dan Gupta G.A. 2013 “Study of Bioplastics As Green &
Sustainable Alternative To Plastics” International Journal of Engeenering
Technology and Advanced Enginering. 3 (5) : hal. 82-89.
[7] Yuli D., Sri Ismiyati D., Tigor M. 2010. “Influence Concentration of Plasticizer

and Formulation of Banana Starch – Chitosan to Mechanical Property and Water
Uptake of Bioplastic”, International Journal of Engineering and Science, 1 (4) :
hal. 97-104.
[8] Wattanakornsiri A., Pachana K., Kaewpiron S., Sawangwong P. dan Migliaresi C.
2011. “Green Composites of Thermoplastics Corn Starchand Recycled Paper
Cellulose Fibers”, Journal of Science and Technology. 33 (4) : hal. 461-467.
[9] Zuraida A., Yusliza Y, Amar H. dan Mohd Khairul M.R. 2012. “The Effect Of
Water and Citric Acid on Sago Starch Bio-plastics”, International Food Research
Journal, 19 (2) : hal. 715-719.
[10] Fessenden R.J. dan Fessenden J.S. 1995. “Kimia Organik” , Edisi Ketiga, Jakarta:
Penerbit Erlangga, hal. 125-127.
[11] Yuniarti, L.I., Gatot S.H. dan Abdul R. 2014. “Synthesis and Characterization of
Bioplastic Based on Sago Starch (Metroxylon sp)”, e-J Agrotekbis, 2 (1) : hal. 3846.

62
Universitas Sumatera Utara

[12] Udin S. 2006. “Rekayasa Proses Tepung Sahu (Metroxylon sp) dan Beberapa
Karakternya”. Skripsi. Fakultas Teknologi Pertanian. Bogor : Institut Pertanian
Bogor.

[13] Shi R., Zhang Z., Liu Q., Han Y., Zhang L., Chen D., dan Tian W. 2007.
“Characterization of Citric Acid/Glycerol Co-Plasticized Thermoplastic Starch
Prepared by Melt Blending” Carbohydrate Polymers, 69 : hal. 748-755.
[14] Erfan A. 2014. “Sintesis Bioplastik dari Pati Ubi Jalar Menggunakan Penguat
Logam ZnO dan Penguat Alami Kitosan”. Skripsi. Program Studi Teknik Kimia.
Depok : Universitas Indonesia.
[15] Handayani P.A, dan Wijayanti H. 2015. “Pembuatan Film Plastik
Biodegradeable dari Limbah Biji Durian (Durio zibethius murr)”, Jurnal Bahan
Alam Terbarukan, 4 (1).
[16] Epriyanti N.M.H, Harsojuwono B.A., dan Arnata I.W. 2016. “Pengaruh Suhu
dan Lama Pengeringan terhadap Karakteristik Komposit Plasti Biodegradeable
dari Pati Kulit Singkong dan Kitosan”. Jurusan Teknologi Industri Pertanian.
Denpasar : Universitas Udayana.
[17] Mardiyati C. dan Suratman R. 2014. “Pembuatan Mikrokristalin Selulosa Rotan
Manau (Calamus manan sp.) serta Karakterisasinya”, Jurnal Selulosa, 4 (2) : hal
89-96.
[18] Nikmatin S., Sudirman, Idwan L., dan Kurniati M. 2014. “Pengembangan
Teknologi Proses Produksi Bionanokomposit Filler Biomassa Rotan”, Jurnal Ilmu
Pertanian Indonesia (JIPI), 19 (3) : hal. 163-168.
[19] Nikmatin S., Purwanto S., Maddu A., Mandang T., dan Aris P. 2012. “Analisis

Struktur Selulosa Kulit Rotan Sebagai Filler Bionanokomposit dengan Difraksi
Sinar X”, Jurnal Sains Materi Indonesia, 13 (2) : hal. 97-102.
[20] Peng B.L, Dhar N., Liu H.L. dan Tam K.C. 2011. “Biocomposite Rainforced
with Cellulose and Its Derivates : A Nanotechnology Perspective”, Canadian
Journal Of Chemical Engineering, 9999 : hal 1-16.
[21] Maddahy N.K., Ramezani O., dan Kermanian H. 2012. “Production
Nanocrystalline Cellulose from Sugarcane Bagasse”, Iran : Shahid Bahesti
University.
[22] Lagaron J.M. dan Rubio A.l. 2011. “Nanotechnology for Bioplastics:
Oportunities, Challenges and Strategies”, Novel Material and Nanotechnology
Group. Trends in Food Science and Technology, 22 : hal. 611-617.

63
Universitas Sumatera Utara

[23] Lazuardi G.P. dan Cahyaningrum S.E. 2013. “Preparation and Characterization
Based Bioplastic Chitosan and Cassava Starch with Glycerol Plasticizer”, Journal
Of Chemistry, 2 (3) : hal. 161-166.
[24] Delvia V. 2006. “Kajian Pengaruh Penambahan Dietilen Glikol sebagai Pemlastis
pada Karakteristik Bioplastik dari Poli-β-Hidroksilat (PHA) yang dihasilkan

Ralstronia Eutropha pada Substrat Hidrolisa Pati Sagu”, Bogor : Institut Pertanian
Bogor.
[25] Nuryetti, Hermansyah H. dan Nasikin M. 2012. “Bionanokomposit: Peluang
Polimer Alami sebagai Material Baru Semikonduktor”, Jurnal Riset Industri, 6
(1) : hal 75-85.
[26] Aulia F, Marpongahtun, dan Gea S. 2013. “Studi Penyediaan Nanokristal
Selulosa dari Tandan Kosong Sawit (TKS)”. Jurnal Saintia Kimia, 1 (2).
[27] Setiawan H., Lutfi M., dan Masruroh. 2014. “Optimasi Plastik Biodegradable
Berbahan Jelarut (Marantha arundinacea L) dengan Variasi LLDPE untuk
Meningkatkan Karakteristik Mekanik”. Jurnal Keteknikan Pertanian Tropis dan
Biosistem, 2 (2) : hal. 124-130.
[28] Thermo Nicolet. 2001. “Introduction Fourier Transform InfraRed Spectrometry”,
Madison.
[29] ASTM D792-91. “Standard Test Method for Density and Specific Gravity
(Relative Density) of Plastics by Displacement”. The American Society for Testing
and Materials. 1991.
[30] ASTM D 638-00. 2005.”Standard Test Method for Tensile Properties of
Plastics’’. An American National Standard.
[31] ASTM 570-98. 2005. “Standard Test Method for Water Absorption of Plastics”.
The American Society for Testing and Materials.

[32] Ningwulan M.P.S. 2012. “Pembuatan Biokomposit Edible Film dari Gelatin /
Bacterical Cellulose Microcrystal (BCMC) : Variasi Konsentrasi Matriks, Filler,
dan Waktu Sonikasi”. Skripsi. Departemen Teknik Kimia. Depok : Universitas
Indonesia.
[33] Anggraeni A.A. 2013. “Sintesis dan Karakterisasi Sifat Mekanik Biokomposit
Filler Short Fiber Kulit Rotan Hasil Fermentasi dan Hasil Milling”. Skripsi.
Departemen Fisika. Bogor : Institut Pertanian Bogor.
[34] Tumpal O.R. dan Hanses A.M.S. 2015. “Analisis Fraksi Volume Serat Pelepah
Pisang Bermatriks Unsaturated Resin Polyester (UPR) Terhadap Kekuatan Tarik
dan SEM”, Jurnal Mechanical, 6 (1).

64
Universitas Sumatera Utara

[35] Laisina V.G. 2014. “Lamanya Waktu Penyinaran dapat Meningkatkan Kekerasan
Permukaan Resin Komposit”. Skripsi. Fakultas Kedokteran Gigi. Denpasar :
Universitas Udayana.
[36] Kurniawan D., Nikmatin S. dan Maddu A. 2012. “Sintesis Nanopartikel Serat
Rami dengan Metode Ultrasonivikasi Untuk Aplikasi Filler Bionanokomposit”,
Jurnal Biofisika, 8 (2), hal : 34-41.

[37] Mostafa H.M.S. 2010. “Studies On Bioplastic For Developing and Evaluating of
Drip Irrigation”, Disertation, Faculty Of Agrikultural Sciences, Nutritional
Science and Enviromental Management, Justus Liebig University Giessen. hal.
57.
[38] Mukerjee T.K.N. 2013. “Pla Based Biopolymer Reinforced With Natural Fibre:
A Review, Di Dalam : Alexander Jones, Mark Ashton Zeller, Suraj Sharma,
Thermal, Mechanical, and Moisture Absorbtion Properties of Egg White Protein
Bioplastics With Natural Rubber and Glycerol”, Progress In Biomaterials, 2 (12)
: hal. 1.
[39] Averous L. 2004. “Biodegradeable Multiphase System Based on Olasticized
Starch : Review”, Journal of Macromolecular Science, 44 (3) : hal. 231-274.
[40] Lu D.R., Xiao C.M., dan
Xu S.J. 2009. “Starch-based Completely
Biodegradeable Polymer Materials”, 3 (6) : hal. 366-375.
[41] Detzel A., Kauertz B., dan Greeven C.D. 2013 “Study of the Environmental
Impacts of Packagigs Made of Biodegradeable Plastics”, Institut Fur Energie. hal.
4.
[42] Valentina S., Pietro R., Santina R., dan Marco D.R. 2008. “Biodegradeable
Polymers foR Food Packageing: A review”, Trends in Food Science and
Technology. 19 : hal. 634-643.

[43] Jacobs H. dan Delucour J.A. 1998. “Hydrothermal Modification of Granular
Starch with Rention of the Granular Structure: Riview”, Journal of Agricultural
and Food Chemical, 46 (8) : hal. 2895-2905.
[44] Robyt J.F. dan Ackerman R.J. 1971. “Isolation, Purification, and Characterization
of a Malthose-Producing Amylase from Psedomonas stuzeri”, Arch. Biochem.
Biophys. 145 (1) : hal. 05-14.
[45] Marc J.E.C., Veen B., Uitdehaag, J.C.M., Hans L., dan Dijkhuizen, L. 2002.
“Properties and Applications of Starch-Converting Enzymes of The α-Amylase
Family”. Journal of Biotechnology 94 : hal. 137–155.
[46] Dyah P. dan Yoshiyuki O. 2000. “Some Enzyme Properties of Raw Starch
Digesting Amylase from Steptomyces sp.”, 52 (4) : hal. 28-32.
65
Universitas Sumatera Utara

[47] Eui-Jum C., Chang-Hyeon K., dan Jung-Ki P. 1999. “Systesys and
Characterization of Starch-g-Polycaprolactone Copolymer”, 32 : hal. 7402-7408.
[48] Chen D. 2013. “Biocomposites Reinforced with Cellulose Nanocrystals Derived
From Potato Peel Waste”, Mc Master University.
[49] Sumaiyah. 2014. “Pembuatan dan Karakterisasi Selulosa Mikrokristal dan
Nanokristal Tandan Aren (Arenga pinnata (Wurmb) Merr.) dan Penggunaannya

Sebagai Eksipien dalam Tablet Natrium Diklofenak”, Medan : Universitas
Sumatera Utara.
[50] Namikaze L. 2014. “Struktur dan Metabolisme Karbohidrat”, Jakarta :
Universitas Negeri Jakarta.
[51] Klemm D., Philipp B., Heinze T., Heinze U., dan Wagenknecht W. 1998.
“Fundamentals and Analytical Methods”. Comprehensive Cellulose Chemistry, :
hal. 1, 14, 18.
[52] Gea S. 2010. “Innovative Bio-Nanocomposites Based on Bacterial Cellulose”. A
Thesis Submitted to The University of London for The Degree of Doctor of
Philosophy, 14 : hal. 36-37.
[53] Arioen R. 2011. “Kajian Perlakuan Awal Secara Basa dan Enzimatis untuk
Menghidrolisis Ampas Tebu Menjadi Gula Reduksi”, Lampung : Universitas
Lampung.
[54] Habibi Y., Lucia L.A., dan Rojas. 2010. “Cellulose Nanocrystals: Chemistry,
Self-Assembly, and Applications”. Chemical Reviews, 110 : hal. 3479– 3500.
[55] Aulia F., Marpongahtun, dan Gea S. 2013. “Studi Penyediaan Nanokristal
Selulosa dari Tandan Kosong Sawit (TKS)”. Jurnal Saintia Kimia, 1 (2).
[56] Wilense R.C., de Boer A.P., Van Dan J., dan Gotsis A.D. 1998. “Co-continious
Morphologies in Polymer Blends: A New Model. Polymer”, 39 (24) : hal. 58795887.
[57] Marbun E.S. 2012. “Sintesis Bioplastik dari Pati Ubi Jalar Menggunakan Penguat

Logan ZnO dan Penguat Alami Selulosa”, Skripsi, Program Studi Teknik Kimia,
Fakultas Teknik, Depok : Universitas Indonesia.
[58] Utomo A.W., Argo B.D., dan Hermanto M.B. 2013. “Pengaruh Suhu dan Lama
Pengeringan Terhadap Karakteristik Fisikokimiawi Plastik Biodegradable Dari
Komposit Pati Lidah Buaya (Aloe Vera)-Kitosan”. Jurnal Bioproses Komoditas
Tropis, 1 (1).

66
Universitas Sumatera Utara

[59] Sanjaya I.G. dan Puspita T. 2011. “Pengaruh Penambahan Khitosan dan
Plastisizer Gliserol Pada Karakteristik Plastik Biodegradable dari Pati Limbah
Kulit Singkong”. Jurusan Teknik Kimia. Surabaya : Institut Teknologi Surabaya.
[60] Paulo da Silva G., Matthias M., dan Jonas C. 2009. “Glycerol : A Promising and
Abundant Carbon Source for Industrial Microbiology”, Biotechnology advances,
27 : hal. 30-39.
[61] Rossi M. 2008. “Glycerol : Properties and Production”, Future Of Glycerol, ISBN
: 978-0-85404-124-4.
[62] Hermawati Y., Rofieq A., dan Wahyono P. 2015. “Pengaruh Konsentrasi Asam
Sitrat Terhadap Karakteristik Ektrak Antioksidan Daun Jati serta Uji Stabilitasnya

dalam Es Krim”, Program studi Biologi, Malang : Universitas Muhammadiyah
Malang.
[63] SIDS Initian Assessment Report. 2001. “Citric Acid”, 77 (92).
[64] John M.J dan Thomas S. 2008. ‘’Biofibres and Biocomposites’’. Carbohydrate
Polymers, 71: hal. 343–364.
[65] Hanisyah S.S, Chi H.C, Chin H.C, Sarani Z. dan Shafirah N.S.J. 2015. “Isolation
of Cellulose Nanocrystals from Kenaf Core”. Sains Malaysiana, 44 (11) : hal
1635-1542.
[66] Wichang L., Rui G., Yong L., Yi Z., Wei X. dan Yuanming Z. 2013. “Preparation
and Properties of Cellulose Nanocrystals Reinforced Collagen Composite Films”.
Journal of Biomedical Materials Research, 102 (4) : hal 1131-1139.
[67] Bilbao-Sainz C, Bras J, Williams T, Sénechal T dan Orts W. 2011. ‘’HPMC
Reinforced With Different Cellulose Nano-Particles’’. Carbohydrate Polymers,
86 : hal. 1549-1557.
[68] Hongjia L, Yu G, Longhui Z dan Xiong L. 2013. ‘’Morphological, Crystalline,
Thermal and Physicochemical Properties of Cellulose Nanocrystals Obtained
from Sweet Potato Residue’’. Food Research International, 50 : hal. 121–128.
[69] You W.C., Thean H.T., Hwei V.L. dan Sharifah B.A.H. 2017. “Easy Fabrication
of Highly Thermal-Stable Cellulose Nanocrystals Using Cr(NO3)3 Catalytic
Hysdrolysis System: A Feasibility Study from Macro- to Nano Dimensions”.

Materials, 10 (42).
[70] Segal L.J.J., Creely A.E., Martin Jr. dan Conrad C.M. 1959. “An Empirical
Method for Estimaging the Degree of Crystallinity of Native Cellulose Using the
X-Ray Diffractometer”. Textile Research Journal, 26 : hal 786-796.

67
Universitas Sumatera Utara

[71] Xiao Y.T., Sharifah B.A.H. dan Chin W.L. 2015. “Preparation of High
Crystallinity Cellulose Nanocrystals (CNCs) by ionic liquid Solvolysis”. Biomass
and Bioenergy, 81 : hal 584-591.
[72] Shaoping Q., Huanhuan Z. dan Kuichuan S. 2017. “Cellulose Nanowhiskers from
Moso Bamboo Residues: Extraction and Charactirization”. Bioresources, 12 (1) :
hal 419-433.
[73] Wie L., Rui W. dan Shouxin L. 2011. “Nanocrystalline Cellulose Prepared From
Softwood Kraft Pulp Via Ultrasonic-Assisted Acid Hydrolysis”. Bioresources, 6
(4) hal : 4271-4281.
[74] Juan I.M, Vera A.A, Viviana P dan Cyras A.V. 2008. ‘’Extraction of cellulose and
preparation of nanocellulose from sisal fibers’’. Cellulose, 15 : hal. 144-159.
[75] Guangping H, Siqi H, jingquan H, Zhen Z dan Qinglin W. 2013. ‘’Effect of Acid
Hydrolysis
Conditions
of
Cellulose
Nanoparticle
Reinforced
Polymethylmethacrylate Composites’’. Materials, 7 : hal 16-29.
[76] Anupama K dan Ramanpreet K. 2016. ‘’ Thermoplastic Starch Nanocomposites
Reinforced With Cellulose Nanocrystals: Effect of Plasticizer on Properties’’.
Composite Interfaces, ISSN : 0927-6440.
[77] Rumpoko W, Khaswar S, Indah Y dan Muhamad N. 2013. ‘’Cellulose Nanofibers
from Cassava Bagasse: Characterization and Application on Tapioca-Film’’.
Chemistry and Materials Research, 3 (13) : hal. 79-87.
[78] Fui K.L, Sinin H, Rezaur R, Mohamad R, Josephine C.H.L, Faruk H dan M
Rahman. 2015. ‘’Synthesis and Characterization of Cellulose from Green Bamboo
by Chemical Treatment with Mechanical Process’’. Journal of Chemistry, March.
(Hindawi Publishing Corporation).
[79] Karim Z.Z, Chowdhury, Bee S, Hamid A dan Ali E. 2014. “Statistical
Optimization for Acid Hydrolysis of Microcrystalline Cellulose and Its
Physiochemical Characterization by Using Metal Ion Catalyst,” Materials, 7 : hal.
6982–6999.
[80] Feng H., Xiao J.W., Yan Y. dan Yan H.L. 2015. “Preparation and Properties of
Cellulose Laurate (CL)/ Starch Nanocrystals Acetat (SNS) Bio-Nanocomposites”.
Polymers, 7 : hal 1331-1345.
[81] Cao X., Chen Y., Chang P.R., Stumborg M. dan Huncault M.A. 2008. “Green
Composites reinforced with Hemp Nanocrystals in Plasticized Starch. Polymers,
109 : hal (3804-3810).
[82] Majdzadeh-Ardakani K. dan Nazari B. 2010. “Improving the Mechanical
Properties of Thermoplastics Starch/ Poly(vinyl alcohol)/ Clac Nanocomposite”.
Carbohydrate Polymers, 75 : hal 712-718.

68
Universitas Sumatera Utara

[83] Nurain J. dan Ishak A. 2012. “Morphological, Thermal, and Mechanical
Properties of Starch Biocomposite Film Reinforced by Cellulose Nanocrystals
From Rice Husks”. Bioresources, 7 (4) : hal 5488-5577.
[84] Xiaofei, Jiugao M. Y., John and Kennedy. 2005. “Studies on the Properties of
Natural Fibers-Reinforced Thermoplastics Starch Comosites. Carbohydrate
Polymers, 62 : hal 19-24.
[85] Babak G, Hadi A dan Ali A.E. 2010. ‘’Improving The Barrier And Mechanical
Properties of Cornstarch Based Edible Films: Effect of Citric Acid And Carboxy
Methyl Cellulose’’.
[86] Zimmermann T, Bordeanu N dan Strub E. 2010. ‘’Properties of Nanofibrillated
Cellulose from Different Raw Materials and Its Reinforcement Potential’’.
Carbohydrate Polymers, 79 : hal. 1086-1093.
[87] Rodriuez E.S., Giacomelli F. dan Vazquez A. 2010. “Study of Saturated and
Unsaturated Permeability in Natural Fiber Fabrics”. Composites, 59 (9) : hal 22572267.
[88] Melissa B A, Bashir A, Shanna Marie M.A. dan Famille M.P. 2014. ‘’Bioplastic
Based on Starch and Cellulose Nanocrystals from Rice Straw’’. Journal of
Reinforced Plastics and Composites, 24 : hal. 2205–2213.
[89] Ning L. 2014. “Cellulose Nanocrystals: Surface Modification and Advanced
Materials”. Sigillum Universitatis Gratianopollitane, France.
[90] Rodrigo O.T. 2015. “Development and Characterization of Corn Starch Film by
Blending with More Hydrophobic Compounds”. Doctoral Thesis. Universitat
Politenvia De Valencia. Program de Doctorado, Valencia.
[91] Halimatuddahliana N., Yurnaliza, Veronicha dan Irmadani. 2017. “Preparation
and Characterization of Cellulose Microcrystalline (MCC) from Fiber of Empty
Fruit Bunch Palm Oil”. Materials Science and Engineering, hal. 180.
[92] Devi B.E, Nurul H.R, Asep B.D.N dan Ahmad M. 2015. ‘’Sintesis Nanoselulosa’’.
Jurnal Integrasi Proses, 5 : hal. 61-74.
[93] Fasihuddin B. A., Peter A. Williams A., Jean-Louis D., Sylvie D. dan Alain B.
1999. “Physico-chemical characterisation of sago starch”. Carbohydrate Polymer,
38 : hal 361-370.
[94] Gomand S.V, Lamberts L, Derde L.J, Goesaert H, Vandeputte G.E, Goderis B,
Visser R.G.F, Delcour J.A. 2010.‘’ Structural properties and gelatinisation
characteristics of potato and cassava starches and mutants thereof’’. Food
Hydrocolloids, 24 : hal. 307–317.

69
Universitas Sumatera Utara