Properties of Leaves Particleboard for Sheathing Application

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  Properties of Leaves Particleboard for Sheathing Application Arif Nuryawan1, Rahmawaty2

  1Department of Forest Products Technology, Faculty of Forestry, University of Sumatera Utara, Jl. Tri Dharma Ujung No.1 Kampus USU, Medan, Indonesia

  2Department of Forest Management, Faculty of Forestry, University of Sumatera Utara, Jl. Tri Dharma Ujung No.1 Kampus USU, Medan, Indonesia

  • Email: arif5@usu.ac.id or arifnury@yahoo.com Abstract. Manufacturing particleboard (PB) made of leaves
  • 1 2 was carried out in order to make non-structural building components, such as insulation, partition, wall, and 1 sheathing. Raw materials used dry leaves originated from

      [ → ] 2 in order to to

      plantation (palm oil leaves) and forest plantation 3 Possibly confused word (magahony leaves). The adhesive used was interior type thermosetting commercial resins, namely 10% urea- formaldehyde (UF) based on oven dry leaves. Hardener 3 used for UF resin was 1% and 3% ammonium chloride

      [ magahony Mahony ]

      (NH4Cl) 20% (w/w), respectively. Technically, the target density of PB was 0.8 g/cm3 with the dimension’s size of (250 x 250 x 10) mm3. The pressure, temperature, and 4 time of pressing of the hot press were 25 kgf /cm2,

      120°C, and 10 minutes, respectively. After conditioning 5 for 1 week, the PB then was evaluated their physical and mechanical properties according to Japanese Industrial Standard (JIS) A 5908 (2003). Results of this work 7 8 4 showed: 1) Both type of PB (palm oil and mahagony 5 [ kgf kg ] leaves) were feasible to be produced for non-structural

      [ 1 one ]

      applications; 2) Addition of hardener enhanced the physical and mechanical properties of PB; 3) It was recommended to enhance the performance of the PB by 9 6 6 manipulation on the raw materials and the design.

      Wordiness

      8

      mechanical properties, non-structural component [ [ → → ] ]

      mahagony type types mahogany

      Introduction 11 In tropical country particularly Indonesia, plantation 12 9 forest’s model such as industrial plantation forest, man- 13

      [ manipulation on manipulation of ]

      made forest, and community forest yields large 10 quantities of waste which predominantly thinning and

      Possibly confused word

      pruning volumes comprising small diameter wood of branch and twig, bark, and leaves. 16 15 17 14 Some efforts have been done in order to utilize 18 11 these residues as substitution of wood products, 12 [ a tropical or the tropical ] particularly for producing particleboard. For instances, 19 13 Possibly confused word

      Nuryawan et al. [1] used sawdust of acacia (Acacia 20 Possible gender-biased language mangium ) wood from industrial plantation forest in Riau province as the raw material of particleboard. They applied 21 urea-formaldehyde (UF) resin mixed with isocyanate as 22 the adhesive for producing interior type of particleboard. 23 Similar work has also been conducted by Muhdi et al. 14

      [2]. They employed logging waste as the raw material of

      Unoriginal text: 8 words

      particleboard. Either part of thinning or pruning was also www.ncbi.nlm.nih.gov/pmc/articles/… 15 24 Passive voice an object of research on particleboard with three species 16 do make 17 Possibly confused and of wood have been utilized, namely acacia, eucalyptus

      [ → ] 25 26 18 in order to to

      (Eucalyptus deglupta ), and sengon (Paraserianthes wood 19 Repetitive word: 27

      [ → ] Nuryawan Narayanan

      falcataria ) [3]. Recently, Ruhendi & Putra [4] exploited 20

      [ → ] 28 mangium magnesium

      part of trunk and branch of jabon wood (Anthocephalus 29 21 cadamba Miq) as the main component of particleboard.

      [ ] 22 an isocyanate or the isocyanate [ the interior or an interior ]

      Success story on utilization of waste from forest and plantation for making panel products have been published 23

      [ → ] 30 Muhdi Mehdi

      by our group research , for example: volume of thinning and pruning of acacia and eucalyptus wood [5]; small diameter and inferior logs [6]; residue of forest harvesting 24 32 31 Possibly confused word [7]; and waste of oil palm (Elaeis guinensis ) trunk [8]. 33 34 It was concluded that the particleboard could be 35

      26

      wood residue and lignocelluloses materials such as [ [ → → ] ] 27 sengon deglupta second delta

      [ → ] falcataria falcata ria vascular bundles of oil palm trunk. 28

      [ → ] 29 jabon jambon [ → ] cadamba caramba

      On the other hand, waste of plantation and forest comprise of not only lignocelluloses but also leaves. In this work, 30 we attempted to make panel products particularly 36 37 31 Passive voice particleboard made of leaves of mahagony and oil Wordiness palm. Because of the abundance of waste leaves originated 38 from plantation and forest as well as the eagerness to utilize these residues, this research is dedicated to 39 develop panel products made of non-wood. Furthermore, 32 application of these products is for sheathing applications 33 [ guinensis Sinensis ] such as wall and ceiling panels, office dividers, bulletin 34 Passive voice boards, cabinets, furniture, insulator, coater, counter tops 40 35 Possibly confused word and desk tops [9] . 41 [ manufactured in manufactured on ]

      The objective of this study was to evaluate the quality of 42 the panel products made of leaves of mahagony 43 (Swietenia macrophylla ) and oil palm (E.guinensis). In 44 addition , the discussions for improving the physical and 45 mechanical properties have been presented . 36 37 Possibly confused word [ → ]

      mahagony mahogany

      Materials and Methods 38

      1.1. Primary Materials

      [ and forest and forest ] In this contribution, dry-leaves of mahagony (S. 39 macrophylla) (Fig.1) was collected from mahagony forest [ → ] develop developing plantation at the university campus (Hutan Tri Dharma).

      So, the dry-leaves residue of oil palm plantation was compiled along the street of Jalan Tri Dharma which oil palm tree grows (Fig.2). In fact, both of these materials were dried naturally by sunlight. In order to make uniform, 40

      [ the addition or an addition ]

      these materials were then oven-dried under temperature of 103฀C for 24 hours. Further, these materials have also 41 Unoriginal text: 9 words been sieved under size of 4 mesh. www.ncbi.nlm.nih.gov/pubmed/2037…

      43 [ [ → → ] ] 44 mahagony macrophylla mahogany macrophilia

      [ In addition Also ]

      Figure 1. Dry-leaves residue of mahagony forest as the 45 materials in this study. Figure 2. Dry-leaves residue of

      Passive voice oil palm plantation as the materials in this study.

      1.2. Methods In this research, the procedure of particleboard production was as follows:

      1. Raw materials preparation The raw materials were consisted of leaves particle as explained in the primary materials with containing 5% moisture content, UF resins as adhesive, and ammonium chloride (NH4Cl) as the hardener.

      2. Blending process The amount of leaves particle needed for one board will be weighed after screening and drying. The particle will be put into a rotary blender and mixed with resin by means called a spray gun. The target of board thickness will be 1 cm and the density 0.80 g/cm3. UF resin’s solid content was 60%, and the level of resin was 10% based on oven dry particle weight. Both 1% and 3% hardener of NH4Cl were added in the form of aqueous with concentration 20%wt.

      3. Mat forming and hot pressing After the blending process, the furnish (the mixture of leaves particle, adhesive, and hardener) will be hand formed into a mat. Both top and bottom surfaces of the furnish mat will be covered with aluminium foil sheets.

      Pressure value was 25 kg/cm2, pressing time was 10 minutes, and pressing temperature was 120฀C. During boards pressing, the day light will be inserted steel bar stop to meet the particleboard target thickness.

      4. Conditioning After hot pressing, the particleboard samples will be conditioned in an ambient room for 2 weeks.

      After conditioning for 2 weeks, the particleboard will be cut into specimen and tested for physical and mechanical properties according to Japanese Industrial Standard (JIS) A 5908 (2003) [10] with three replications for each condition. The data were analyzed with simple statistics with standard deviation.

      1.3. Physical properties Investigation of physical properties was carried out in ambient temperature at Forest Products Laboratory, Faculty of Forestry, University of Sumatera Utara (Medan, Indonesia) with at least three replications, consisted of determination of density, moisture content (MC), water absorption, and thickness swelling. Both density and MC specimen’s size were 10 cm x 10 cm. The dimension of test piece of water absoption and thickness swelling was 5 cm x 5 cm. Weight and dimension were measured using electronic balance and callipers. Moisture content was 46 determined by grav imetric analysis. All of the testing was according to Japanese Industrial Standard (JIS) A 5908 (2003) [10].

      1.4. Mechanical properties Mechanical test was conducted using the Tensilon UTM (Universal Testing Machine) in ambient temperature for at least three replications. The mechanical test consisted of bending strength and internal bond strength. Bending strength was determined through measurement of MOE/ modulus of elasticity and MOR/ modulus of rupture, respectively.All of the mechanical properties tests were also conducted at Forest Products Laboratory, Faculty of Forestry, University of Sumatera Utara (Medan, Indonesia).

      1.5. Data analysis Mean value from at least three data measurements both on physical and mechanical properties testing were presented

      Results and Discussions

      1.1. Physical properties Results of physical test were presented in Table 1. Air-dry density values of the specimens ranged between 0.53-0.62 g/cm3. They fulfilled the Japanese Industrial Standard (JIS A 5908-2003). Unfortunately, the values were below on the target density. This phenomenon may be related to the spring back effect and the voluminous (bulky) leaves 46 particles, therefore compression ratio was difficult to

      [ the test or a test ] calculate.

      Moisture content showed that all of the values met the standard. Leaves belong to lignocelluloses material, they have hygroscopic characteristic. They can bond or release water from the environment, and inherently they have hydrogen bonding. Both thickness swelling and water absorption showed very high percentage after immersing in the water. This situation was reasonable since the used adhesive was interior type (UF resins) Table 1. Physical properties of leaves particleboard with 1% and 3% hardener Property Mahagony leaves particleboard with NH4Cl Oil palm leaves particleboard with NH4Cl 1% 3% 1% 3% Density (g/cm3) 0.62 + 0.04 0.60 + 0.03 0.53 + 0.04 0.56 + 0.03

    • 0.75 8.75 + 2.03 Thickness swelling-2h (%) 9.82 + 0.59 7.11 + 2.44 53.71 + 8.82 43.61+22.08 Thickness swelling-24h (%) 29.34 + 2.01 20.86 + 1.81 69.23 + 18.12 77.31 + 7.20 Water absoption-2h (%) 21.43 + 2.69 22.52 + 3.82

      53.71 + 8.82 49.44 + 10.80 Water absoption-24h (%) 93.01 + 8.32 84.01+ 31.71 149.23 +16.88 134.75+11.25

      1.2. Mechanical properties Table 2 shows values of mechanical properties of leaves particleboard with different hardener content.

      Table 2. Mechanical properties of leaves particleboard with 1% and 3% hardener Property Mahagony leaves particleboard with NH4Cl Oil palm leaves particleboard with NH4Cl 1% 3% 1% 3% MOE (kgf/cm2) 146+47 117+ 35 2283+ 385 2310+ 146 MOR (kgf/cm2) 9.79 + 6.46 6.55 + 1.61 22.15 + 3.00 24.45+ 10.28

      IB (kgf/cm2) 0.02 + 0.01 0.07 + 0.01 0.27 + 0.03 0.27 + 0.03 All the mechanical properties were failed to satisfy the standard (JIS A 5908-2003). The failure of both MOE and MOR have to enhance by strengthen the raw material of leaves. The failure of internal bond have to be repaired using manipulation of the adhesive used

      In order to get better properties of the leaves particleboard, we attempted to mix the leaves with wood (sawdust) in various ratio [11], for instance ratio of mahagony leaves and sawdust 100:0; 75:25; 50:50; and 25:75. But the results showed statistically were not significant. Therefore this work has been stopped. In addition, we also tried to add the level of adhesives used [11]. The level adhesive used was increased up to 12%. The results showed statistically were significant. Therefore, this treatment then becomes a future work.

      1.4. On going and future work to improve the quality of the leaves particleboard properties

      1.4.1.Addition more hardener (NH4Cl) In this study, we applied 1% and 3% hardener for the particleboard however the properties were still not satisfied. Addition of hardener up to 5%; 7%; and 9% hopefully could improve the properties of the leaves particleboard as shown in temporary results of this experiment (Figure 3). NH4Cl created acidic condition hence UF resin (with increased level of adhesive up to 12%) will be more cured as shown in Figure 4.

      Furthermore, addition of hardener will make the UF resin more aqueous thus the distribution of the UF resin into particleboard is more extend.

      Figure 3. Leaves particleboard of oil palm and mahagony with various hardener level (5%;7%;9%)

      Resulted in pH 7 Resulted in pH 5 Resulted in pH 3 47 Figure 4. Result of measurement of pH of the furnish.

      Higher hardener level showed lower pH which indicated more acidic.

      1.4.2.Addition layers on both surfaces using veneer 48 For sheathing application, both surface of leaves 49 50 particleboard should be layered as shown in Figure 5.

      Addition veneer layers on both surfaces of leaves 51 particleboard will improve the MOE and MOR values including its dimension stability. The thickness of the 52 veneer also must be considered

      53 Figure 5. Construction of leaves particleboard with

      layers on both surface (face and back)

      1.4.3.Replacement UF resin with exterior type adhesive 54 UF resin is one of types interior adhesives thus it is 55 prone to water or high moisture.In addition , because of formaldehyde based, UF resin will release formaldehyde 56 emission during service used. Therefore, good choice if we replace UF resin with exterior type adhesive such as 57 58 isocyanate. Isocyanate can be used without addition 59 60 of hardener , can be applied using sprayer , and non- formalin based.

      Conclusions 61 The leaves particleboard has been successfully produced 62 unfortunately their physical and mechanical properties 63 were not satisfy . Therefore, some future works should be carried out, for instances: 1) addition more hardener into of the leaves particleboard; 3) application of exterior adhesive such as isocyanate Acknowledgment This study was supported by Penelitian Talenta from University of Sumatera Utara in the year of 2017. Thanks also for Jan Heri Setiawan Damanik, Dame Lasmaria Siahaan, Iwan Risnasari, Irawati Azhar, Aidul Adha Sagala, and Hendra Joseph Saota for their laboratory working helps. 64 65 47

      [ ]

      48 [ surface surfaces

      ] → 49 Possibly confused word 50 Passive voice 51 Possibly confused word 52 Repetitive word: veneer

      53 Possibly confused word

      54 [ the types ] 55 [ ]

      Result The result In addition Also

      56 [ a good or the good ] 57 [

      Isocyanate The isocyanate ] → 58 Passive voice 59 [ the hardener

      ] 60 [ a sprayer or the sprayer

      ] 61 Possibly confused word 62 Squinting modifier 63 [ were not satisfy were not satisfied ]

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      Rahmawaty PhD <rahmawaty1974@gmail.com> Fw: Friendly City4 2017 Medan : Final Information 1 message

      Sat, Dec 1, 2018 at 10:45 AM Arif Nuryawan <arifnury@yahoo.com> To: Rahmawaty Hamsuddin <rahmawaty1974@gmail.com> Arif Nuryawan, S.Hut., M.Si., Ph.D.

      Teaching staff at University of Sumatera Utara (USU) Department of Forestry, Faculty of Agriculture Jl.Tri Dharma Ujung No.1 Kampus USU Medan-Indonesia 20155 Phone +62-877-6918-7088 Email

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      Sat, Dec 1, 2018 at 10:46 AM To: Rahmawaty Hamsuddin <rahmawaty1974@gmail.com> Arif Nuryawan, S.Hut., M.Si., Ph.D. Teaching staff at University of Sumatera Utara (USU) Department of Forestry, Faculty of Agriculture Jl.Tri Dharma Ujung No.1 Kampus USU Medan-Indonesia 20155 Phone +62-877-6918-7088 Email

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