the effect of the calcinations temperature Abstract 2015
EditorialBoard
Executive Editor
Dr.V K Sharma(Chemical
Sciences)
Dr. C S Chauhan(Pharmaceutical
Sciences)
Associate Editor
Zainul
Dr. Rahadian
Dr. P S Naruka
Dr. H P Singh
Dr. C S Sharma
Editorial Board
Aliero,Nigeria
Dr.A U Itodo,KebbiStateUniversityof ScienceandTechnology,
Zarrouk,Laboratoryof AppliedChemistry& Environment
Department
of Chemistry,Facultyof Science,
Dr. Abdelkader
University
lYohammed
Premier,Oujda,l4orocco
KohatUniversity
Dr.AbdulWahab,Departmentof Pharmacy,
of ScienceandTechnology,KhaiberPakhtoonKhwa,Pakistan
Dr.AbhijiGhosh,BrighamYoungUniversity,
UT,USA
Dr. MaobiEzike,
Universityof Nigeria,Nsukka,Enugu,Nigeria
Dr.AdedijiJohnsonF, FederalUniversityof AgricultureAbeokuta,Abeokuta,Ogun,Nigeria
Facultyof Science,
Universityof Tabuk,Tabuk,KSA
Dr.AdelKameMadbouly,
BiologyDepartment,
Taif university,KSA
Dr.AhmadF. ELShahaby,Biotechnology
Unit,Collegeof N'ledicine,
and GeneticEngineering
Dr. AhmedO Alnajjar,KingFaisalUniversity,
SaudiArabia
Dr. AkmalShawkyGaballa,FacultyoFSpecificEducation,
ZagazigUniversity,
Zagazig,Egypt
Egypt
Damanhour,
Dr, AlaaE, Ali, Headof chemistryDepartment,Facultyof Science,Damanhour
University,
N Pavlovic,
Dr.Aleksandra
Universityof Ni5,Visegradska,
Ni5,Serbia
Dr. Ali H. AFMowali,
Unive6ityof Basrah,Basrah,Iraq
Tabriz,Iran
Dr. Alirezacarjani,
TabrizUniversityof [4edicalSciences,
Dr. Amanoekebo,AdamaScienceand TechnologyUniversity,ldanrd
Egypt
Dr. AmerE A, CairoUniversity,
- BandungSchoolof Pharmacy/SekolahTinggiFarmasiBandung(STFB),
Dr. AriYuniarto,Divisionof Pharmacology
Bandung,Indonesia
Faculty,LampungUniversity,
Indonesia
Dr. AsepSukohar,Nledical
Dr. Atul KumarSingh,CRNTs,IIT Bombay,Bombay,India
Dr. AytaeGuder,GiresunUniversity,
Turkey
Algdrie
Dr. B Boumoud,
Constantine,
UniversitdMentouride Constantine,
Dr. B M Rao,Johnson& JohnsonLtd, Mumbai,India
India
Dr. B S Bhoop,UIPS,PunjabUniversity,
Chandigarh,
of Biology,University
Algeria
Dr. BachirB€narba,Department
of Mascara,
II, France
Dr. BernardGuyot,UMRQualisud(CIMD), Universit6Montpellier
Dr. BrianHenriks€na,
Omaha,NE
CreightonUniversity,
Irupati, India
Dr,C VenkataRao,SriVenkateswara
University,
A. C. Technolog,AnnaUniversity,Chennai,India
Dr, C,Jayakumar,
Deparfnentof ChemicalEngineering,
of Zululand,SouthAfrica
of Chemistry,KwaDlangezwa,
Kwazulu-Natal,
University
Dr. C. Sampath,Department
Cairo,Egypt
Dr. CamiliaG Michel,CairoUniversity,
Phoenix,AZ, USA
ichilampalli,InsysTherapeutics
Dr.Chandeshwar
Xi' an, Shaanxi,P. R China
ShaanxiUniversityof Science& Technology,
Dr. Chengyuan
Liang,Departmentof Pharmacy,
of Lagos,Lagos,Nigeria
P
C
Azubuike,
University
Nigeria
Dr. Chukwuemeka
Okwelogu,Uniyersityof Lagos,
Dr. Chinyere
Dr. Chukwuma
O Agubata,Universityof Nigeria,Nsukka
Dr. ClementJackson,Universityof Uyo,Uyo,Akwalbom,Nigeria
Ile-ife,Osun,Nigeria
Dr. CraigA Obafemi,ObafemiAwolowoUniversity,
l4ehsana,
India
Pharmacy
College,HN GujaratUniversity,
Dr, D J Sen,ShriSarvajanik
Dr. D S Ashilenje,Moitjniversity,Eldoret,Kenya,
LaCOPS,
Cotonou,Benin
Universityof Abomey-Calavi,
Or.D S SalomdKpoviessi,
KampusLimauManis,Padang,WestSumatra,Indonesia
Facultyof Pharmacl,AndalasUniversity,
Dr. Dachriyanus,
StateUniversity,Washington
School
of Pharmacl,Washington
Sciences,
Dr. DafengChu,Department
of Pharmaceutical
Cairo,Egypt
NationalOrganization
for Dr.ugControland Research,
Dr. DemianaI Nesseem,
Dhaka,Bangladesh
Dr. DewanTaslimaAkhter,StamfordUniversityBangladesh,
pal,Bilashpurlnstituteof Pharmaceutical
Koni,Bilashpur
Viswavidyalaya,
GuruGhasidas
Sciences,
Dr. Dilipkumar
Dr. E J Koranteng-Addo,
Universityof CapeCoast,CapeCoast,Ghana
Island,Nigeria
Wilberforce
Dr. EdebiN Vaikosen,NigerDeltaUniversity,
University,Egypt
T. Helmy,ChemistryDepartment,Facultyof Science,Mansoura
Dr. Elsayed
Dr. F 14Al-labri, BasrahUniversity,Basrah,Iraq
Dr.G Aranovich,
lohns HopkinsUniversity,Baltimore,Maryland,USA
Ile-ife,OsunState,Nigeria
obafemiAwolowoUniversity,
Dr. Gabrielo Egharevba,
University,Egypt
Dr.GalalH Said,Ain-Shams
Dr. H M Hassan,
Al-AzharUniversity,NasrCity,Cairo,Egypt
llaret,
LSCT,TiaretUniversity,
Laboratory
and Catalysis
Departmentof Chemistry,Synthesis
Dr. HaddadBoumediene,
Algeria
Centre,Egypt
Division,NationalResearch
l4edicalResearch
Dr. HanaaH, Ahmed,Headof HormonesDepartment,
Riyadh,SaudiArabia
Dr. HananM Al-YoussetKingSaudUniversity,
University
of Sharjah,UAE
of Pharmacology,
Collegeof Pharmacy,
Dr. HanyA. Omar,Department
CA
Inc,, 630 GatewayBlvd.,SouthSanFrancisco,
Dr. HaoWu, NGl4Biopharmaceuticals
l4edicalCenter,Dallas,Texas,
Universityof TexasSouthwestern
Dr. HariKishoreAnnavarapu,
KhoramAbad,
of MedicalSciences,
Schoolof Medicine,LorestanUniversity
Ahmadvand,
Dept.of Biochemistry,
Dr. Hassan
Iran
Dr. HassanAli Zamani,QuchanBranch,IslamicAzadUniversity,
Quchan,Iran
BBN,PutraNilai,Nilai,Negeri
PersiaranPerdana
University,
INTI International
Dr. Ho SoonMin,Facultyof AppliedSciences,
Malaysia
Sembilan,
Sidi
FESUniversity
and Techniques,
Facultyof Sciences
Dr. HoudaBouchafra,
Laboratoryof OrganicChemistryApplication,
N,lohammed
Ibn Abdillah,FES,Morocco
Science,ChinaThreeGorgesUnive6ity,Yichang,Hubeiprovince,
and Pharmaceutical
Dr, Hua-JunLuo,Collegeof Biological
P,R,China
Dr. IkotunAdebomiAyodeji,BowenUniversity,lwo, OsunState,Nigeria
Russia
KurskStatel4edicalUniversity,
of Pharmacy,
of l4anagement
and Economics
Department
Dr. Inna Razdorskaya,
of CapeCoast,Ghana
Dr, I K Koka,University
of CapeCoast,CapeCoast,Ghana
Dr.J K Tufuor,University
Dt. I P K, Adotey,Universjtyof CapeCoast,Ghana
Erazil
Petrolina,Pernambuco,
Federaldo Valedo SeoFrancisco,
Dr. lacksonRobertoGuedesda SilvaAlmeida,Universidade
Singapore
and Nanotechnology,
Dr.Jin QuanWan9,Instituteof Bioengineering
universityof washington,seattle,wA, usA
schoolof Pharmacy,
Dr. linghuaDuan,Departmentof Pharmaceutics,
Nagpur,India
S14lvlc,
of Physics,
Dr.JitendraRamteke,Department
Brazil
Petrolina,Pernambuco,
Federaldo Valedo SaoFrancisco,
Tolentinode Lima,Universidade
Dr,Julianeli
BurkinaFaso
ouagadougou,
Dr, KaboreAdama,lnstitutde ltnvironnementetde RecherchesAgricoles,
Dr. KawkabAli Hussain.Universityof Basrah,Iraq
Federalda Paraiba,JoSoPessoa,Paraiba,Brazil
Dr. KellySamarade Liralvlota,Universidade
Collegeof science,Surat,India
Dr. KetanC. Parmar,Sir P T Sarvaianik
and Drug
Department,Pharmaceutical
centre(NRc),Pharmacognosy
Dr. KhaledNabihzaki Rashed,NationalResearch
Division,Dokki,Giza,Egypt
IndustriesResearch
Inc., Chandler,AZ, USA
InsysTherapeutics.
Dr. Kiranvangara,
Road,Bardoli,surat
university,Bardoli-Mahuva
R. Desai,Departmentof chemistry,ukaTarsadia
Dr. Kishorbhai
Controland Phytopharmaq'
of Pesticides
Institute,Department
t']. Kasiotis,BenakiPhytopathological
Dr. Konstantinos
Kifissia,
Athens
Iran
PayameNoorUniversity,
Dr. LotfAli Saghatforoush,
Ouargla,Algeria
Dr. LotfiBaameur,KasdiMerbahUniversity,
Dr. LucasV B Hoelz,CidadeUniversitiria,Ilha do Fundao,Riode Janeiro,Rl, Brazil
Rabat- Instituts,N4aroc
Dr. 14A Faouzi,Facult6de MddecineetPharmacie,
and AppliedBiologyGroupLeader,KingFahdMedicalResealchcenter,KingAbdulaziz
Dr. M A Kamal,Fundamental
SaudiArabia
University,
Aliero,Nigena
of ScienceandTechnology,
Dr. lvlK 6afar,KebbiStateUniversity
Dr, M O Aqwara,Universityof Yaound6I, Yaound6,Cameroon
ISTlYKinshasa,RDCongo
chimiemddicaleetpharmacologie,
UERdebiochimie,
Dr.M P Kanyonga,
Artsand Sciencecollege,Khammam'A P ' India
B.
G.
N
R.
Government
R
&
Physics,
s.
of
Dr. 14.V, Ramana,Department
Keffi
StateUniYersity,
Dr. MaduP C, Nasarawa
USA
Labs,
Kentucky,
Bhide,Coldstream
Dr. lvlahesh
Iran
Khorramabad,
of MedicalSciences,
Center,LorestanUniversity
Research
Bahmani,RaziHerbatMedicines
Dr. Mahmoud
Yemen
sana'aUniversity,
MahyoobAlburyhi,Facultyof Pharmacy,
Dr. Nlahmoud
Tait Kingdomof SaudiArabia
Dr. llahmoudSalman,Taif University,
UniversitylbnTofail,Kenitra,Morocco
Process
Laboratory,Facultyof Science,
Larit Separation
Dr. Majdouline
Pahang,Kuantan,Pahang,Malaysia
Dr. MakkyE A, Universitylvlalaysia
of
ShahidBeheshtiUniversity
& llycology,Schoolof Medicine,
t4edicalparasitology
Department
of
Dr, MaryamNiyyati,
Tehran,Iran
MedicalSciences,
Turkey
Department
of Chemistry,UludagUniversity,
Dr, Mellahllyas,
Van,Turkey
Kovuncu,YuzuncuYrlUniversity,
Dr. Menderes
lava'
surabaya-East
Airlanggaunive6ity,Kampusc UNAIR,14ulyorejo
Df. t4irnilamid,Facultyof veterinaryf4edicine,
lndonesia
of Carthage,
IPEST,University
Laboratory,
MaterialsandApplications
The tYolecular
Abderrabba,
Abdelmanef
Dr. l4ohamed
La flarsa,Tunisia
l4ara),CampusPuncak,Alam,selangor,l4alaysia
UiTM(Universitlfeknologi
Salama,Facultyof Pharmacy
Dr. t4ohamed
B€nisuef
organicchemistry,Facultyof Pharmacy,
of Pharmaceutical
Department
Abdelgawad,
Abdelwahab
Dr. Mohammed
EgYPt
BeniSuef,
University,
Dr.MohammedRahmatu||ah,Facu|tyofLifesciences,UniversityofDeve|opmentA|ternative,Dhanmondi,Dhaka,
BangladeshOr. YoussefRamli,Facultyof Medicineand Pharmacy,MohammedV University-Rabat,Morocco
Egypt
Y S Abary,CairoUniversity,
Dr. l4ohammed
(NSR)lnc, Stamford,CT,USA
Sarker,NaturalStateResearch
Dr, f4oinuddin
Banani,Dhaka,Bangladesh
University,
Dr, MoynulHasan,DhakaInternational
Dr. !lubo A Sonibare,Universityof Ibadan,IbadanNigeria
Basra,Iraq
BasraUniversity,
lvlohammed-Ali,
Abdul-Jaleel
Dr. l'4unther
Amravati'India
Dr. l4urlidharP,Wadekar,Departmentof Chemistry,Govt VidarbhaInstituteof Science& Humanities'
University,India
Annamalai
and Biotechnology,
of Biochemistry
Department
Dr, N. Vijayakumar,
Dr. NajiA Abood,BasrahUniversity,Basrah,Iraq
Egypt
AleDr'xandria,
AlexandriaUniversity,
Dr, NasrH EFHammamy,
Dr.NeetaRajSharma,FacultyofBiotechnology&Biosciences,LovelyProfessionalUniversity(LPU),Phagwara,Punjab,
India
BasraUniversity,Basra,lraq
Dr, NesreenNadhumlvlajeed,
Riyadh,SaudiArabia
NoraBintAbdulRahmanUniversity,
Princess
Dr, NoraH At-Shaalan,
PulauPinang,l4alaysia
Dr. NurulAil izakaria,UniversitiSainsMalaysia,
Island,Nigeria
Wilberforce
Delta
University,
Niger
Dr.O R Omobuwajo,
ziraat FakijltesiBaheeBitkileriBiilumii,BalcalrAdana
Dr. Okanozkaya,qukurovauniversitesi,
Assiut,Egypt
AssiutUniversity,
Facultyof Pharmacy,
Dr.OlaI. A. Salem,pharmOrganicChemistryDepartment,
Taif, Kingdomof SaudiArabia
Dr. OmarB lbrahim,Taif University,
OkparaUniversityof Agriculture,Umudike,Abia
l'4ichael
of Biochemistry,
Dave,Department
Olorunshola
Dr. Omodamiro
State,Nigeria
India
Kurukshetra,
University,
Dr. P c sharma.Kurukshetra
lbnBattouta,Rabat-l'laroc
Facult6dessciences-Agdal,
Polede comp6tencesPharmacochimie,
Dr. P M Kanyonga,
Thailand
Princeof SongklaUniversity,Songkhla,
Dr. P Sumanatrakul,
l-iruchendur'Tamilnadu
of
Aditanarcollege Artsand Science,
Departmentof Physics,
Dr. P.Selvarajan,
Dr. PatriciaA onocha,Universityof lbadan,Nigeria
Owerri,Imo State,Nigeria
Imo StateUniversity,
Departmentof Biochemistry,
Dr. PaulC.Chikezie.
Yaound€'cameroun
pour le Ddvelopement,
Institutde RechercheAgricole
Dr. PaulineMounjouenpou,
of Nigeria,Nsukka,EnuguState,Nigeria
Dr. PFUzor,University
Varanasi,India
Solanki,BanarasHinduUniversity,
Dr. PremPrakash
Dr. PremRai,LucknowUniversity,Lucknow,India
Iran
Sabzevar,
Tarbiatl4oallemUniversity,
Dr. RezaTavebee.Sabzevar
of Damam,SaudiaArabia
Dr. S A Abubshait,University
Arqentina
de InvestigacionescientificasyTecnologicas,
ConsejoNacional
Dr. S Lucangioli,
Ooty,India
J S S Collegeof Pharmacy,
Dr. S N l4eyyanathan,
.launpur,India
University,
Dr. S PTripathi,Poorvanchal
Udaipur,India
Dr. S ssisodia,B N Collegeof Pharmacy,
Collegeof science,Jordan
ChemistryDepartment,
Dr. safwanFraihat,Allouf Universify,
Dr. SalemAshoor,Universityof I'lisurata,Libya
Dr. Seyedl4ehdiTalebi,ShahidBeheshtiUniversity,Iran
UK
l'4anchester,
LJniversity,
l4etropolitan
Dr. ShaabanK Mohamed,Manchester
Ohio,USA
Columbus,
Oottikkal,OhioStateUniversity,
Dr. Shameema
Inc, NJ,USA
Puthli,TrisPharma
Dr.Shivanand
ouroPreto,l4G'Brazil
Federalde OuroPreto,
Dr. SidneyAuqustoVieiraFilho,Universidade
MD,USA
Rockville,
uS Pharmacopeia,
Dr, SitaramBhavaraiu,
Dr. SoadA Yehia,CairoUniversity,Cairo,Egypt
TX
TexasA & M University,
of Chemistry,
Dr. SoumikBiswas,Department
center,Dallas,TX
l'4edical
The universityof southwestern
or Radiology,
Dr. Srinivaschiguru,Department
Dr. SrinivasNammi,Universityof Canberra,Australia
NewDelhi
JamiaHamdard,
Facultyof Pharmacy,
Departmentof Pharmaceutics,
Talegaonkar,
Dr, Sushama
Ames,IA, USA
NewLinkGenetics,
Dr.TanayKesharwani,
Tlemcen,Algeria
Dr,Tarikchaouche,TlemcenUniversity,
Tripoli,Libya
Dr.TariqK. Almog,TripoliUniversity,
Dr, UhoodJ AL-Hamdani,Universityof Basrah,Basrah,Iraq
Medical
Hospital/Harvard
and l4olecularImaging,BostonChildren's
Akurathi,Divisionof Nuclearl4edicine
Dr. Vamsidhar
School,Boston,l4A,USA
Center,Covington,LA,USA
TulaneNationalPrimateResearch
Divisionof Microbiology,
Dr. VibhaYadav,
Eckert& ZieglerEurotopeGMBH,Hopkinton,l4A,USA
Dr.ViiayGottumukkala,
Facultyof science,
lvledicinal
chemistryand Pharmacognosy,
of Pharmaceuticnl
Dr. WaelAhmadAbu Dayyih,Department
Amman,Jordan
PetraUniversity,
M
Dr. waleed Sweileh,An-NajahNationalUniversity,Nablus,Palestine
of Connedicut,storrs,CT,USA
Dr. Wenjiecai,University
of Alabamain Huntsville,Huntslille,USA
University
N
Setzer,
Dr. William
Cairo,Eqypt
Dr. Y A El-gadry,Ain ShamsUniversity,
v university-Rabat,
l4ohammed
and Pharmacy,
youssef
Facultyof Medicine
Laboratory,
chemistry
l4edicinal
Ramli,
Dr.
l4orocco
Branch,lran
Dr. Z Bayat,IslamicAzadUniversity-Quchan
Yinchuan,Ningxia,P R China
Dr. Zhi-zhongWan9,NingxialledicalUniversity,
CONTENT
Biosorption of cadmium (II) ions from aqueous solutionby cassava (Nanihotutilissima) leaves
Adrian, Edy Fachrial, Almahdy, Syaifullah, Edison Munaf and Rahmiana Zein
Page No:l-8
Immunohistochemical detection of P53 protein as a prognostic indicator in prostate carcir.oma
Bungaran Sihombing, Jamaludin, Djong Hon Cong, Sanusi Ibrahim and Sumaryati Syukur
Page No:9-13
A catalytic test of Mn(II) and Ni(II) grafted on modified mesoporous silica in transesterificationof vegetable
oil
Admi, Vanella Indah Pratiwi, Fitria Ramadhani, Sry Wahyuni, Jervita Sari, Meri Asnita, Wiza Ladya, Syukri Arief, Emdeniz,
Mai Efdi, Zulhadjri and Syukri
Page No:14-16
Synthesis of biodiesel from waste cooking oil by two steps process transesterificationandozonation
Lieke Riadi,Aioysius Yuli Widianto, Edy Purwanto,Akso Pone and Ruth Theresia
Page No:l?-21
Adsorption profile of Cu (II) using Soursop (Annona muricata L) leaves powder as biosorbent
Buter Samin, Edy Fachrial, Almahdy, Edison Munaf, Refilda, Zulkarnain Chaidir and Rahmiana Zein
Page No:22-27
Biosorption ofzinc (II) ions from aqueous solution by Androgaphispaniculataleaves powder on batch method
Deli, Zulkarnain Chaidir, Almahdy, Rahmiana Zein and Edison Munaf
Page No:28-38
Adsorption of Cu(II) using sauropusandrogynus(L.) Ne".from aqueous solution
Chrismis Novalinda Ginting, Edison Munaf, A!mahdy, Eti Yerizel and Rahmtana Zein
Page No:39-45
The optimization of biopolyol synthesis from liquefaction of rice strawusing response sutface method
Edy Putwanto, Joko Sutrisno, Rakhel Apriliana and Kevin Monthiego Horax
Page No:46-53
The effect of increasing blood glucose level on severalatherogenic factors with biomolecularin diabetes
mellitus type II patients
Eti rerize/ and Asman Manaf
Page No:54-58
The purification of waste cooking oil based on lipid profiles measurements by using skin of Salaccazalacca
Ermi Girsang, Agung A Kiswandono, Refilkhtiari, Hermansyah Aziz, Zulkamain Chaidir and Rahmiana Zein
Page No:59-65
Endophytic fungi isolated from Sambiloto (AndrographispaniculataNees) as a source offungallipid
production
Elfita, Muharni and Munawar
Page No:66-69
The effect of the calcinations temperature during synthesis of 7102-Fe304-bentonite as photocatalyst
material
Emma 5avitri,Restu Kartiko Widi and Arief Budhyantoro
Page No:70-75
Separation of inorganic anion from biomaterial using methacrylate-based column in ion chromatography
capillary system
ｈｩ､｡ｹｾ＠
Rahmiana Zein, Edison Munaf, Lee Wah Lim and Toyohide Takeuchi
Page No:76-80
The removal of Cr{VI) with Dimocarpuslongan as a low cost biosorbent
Florenty,Re khtiari, HermansyahAziz, Syafizayantiand RahmianaZein
PageNo:81-88
absorbent of metel
characbrtzanon and utilitation of kepok banana bark Powder (trlusa balbisianacolta) as
solation
in
agueoas
ions Pb(II) & Cd(U)
HenniNengsih,Zilfa and RefildaSuhail
PageNo:89-93
wasb (Gliycinemax)
RiBorptionof cadmiam ion from aqaeotg solutions btatow!9st.?ybean
and Rahmianazein
Desmiafti
Munat
Reni
Harniiati,salnariza, DesiKumiawatLintan LesaL Edison
PageNo:94-100
The effect of banana starch concentration on the proryrti$ of chitosan'starch hioplasti6
SamuelPadmawiaya,OkkySrayanti and Petruslaya Wardhana
LannySapei,Karsono
PageNo:1A1-lAs
gutwP(Annonamurkata)
Extraction tshnique to separaE kaempferot from
IrmanidaBatubar4suminarSetiatiAchnadi and WennyNurwendari
PageNo:106-110
leaves
an (Duiozibethinus)
Equilibfium and kineti9 ,nodeting biosorptionof zn(Ir) in aqaeous solution using du
sed as low-@st biosorbent
Zein and HermansyahAziz
Iitan Lestari,salnarizaSy, Hamiwati DesyKurniawatLAdnin Alit EdisonMunat Rahmiana
PageNo:111-122
Modet of po ution impact for policy design in conttolling dioxin/funn
arrd nonfefious industrY in Cilegon)
Lina Waruna
PageNo:123-134
emission(case stady: Metal fenous
(Mtte balbianacolla)
Riosorption meal ion of Pb (II) an(f Ccl (fi) using kepok banana weevi! Powder
MelatiSuryaHafni,Zlfa and RefildaSuhaili
Pagetlo:135-138
Prcpafation,characterizationofzno/coFe2o4magneticnanocompositesanda.tivityevaluationundersolaf
Iight irradiation
ninr"ymi DeviA., YeniStiadi NovesarJamarun,Emiadi and SyukriArief
PageNo:139-146
Em|aationacu?fuxicityandantibacteriatadivityofPeniciltiumspendophiticfungusextadofkunyit
putih(Carcuma zederi4 in mice (Mus masculas L')
Muhami,Heni YohandinLFitrya and Roni
PageNo:147-151
drainage synthetic
Bentonite and Bentonite-Fego4 @mPosits as adsorbent for treaanent acid mine
fbedji LoekitowatiHariani,salni and Fahna Riyanti
PageNo:152-158
Deyetopment and ualidation of TLc densi pmew
atd gtibenctamide in tableE dosage form
ReginaAndayani,Fifi Pitasai and Rusdi
PageNo:159-164
method lor simuttaneous determlnation of m&formin Hct
production, pufifrcation, and charac9ization of inatina*from
gtyonq ChainultiffahA. M., AunaArdhiand Nova WahyuPratiwi
PageNo:165-176
dahtia rizhosphere-isotatedAspctgillusclauatus
compost mixture
O4mizatlon spetmphotometric determination of phosphor in soit and
Yefrida
and
Cetildasuhaiti,luneili zoni Sudarnisa
PageNo:177-182
hsic blue
tke of TiO2-FegO4pittaa(t bentonite as Photocabtystin photodegradationof
Emma
Savitri
and
Restufaftiko WidLArief Budhyanwo
PageNo:183-188
Hydrothermat synth8ized Ag nanoparticlesusing bioredsctor of gambier leaf extract (UncariagambierRoxb)
SyukriAriet ViuiGustia,Diana VandaWe ia, Zulhadjri. Takayukiaan and YutakaOhya
PageNo:189-192
Removat of Mn (II) iot s from agueoas solution by adsorption asing Terminaliacatappa fruit powdef
Sofian Wijay4 Edy Fachriat,Djong Hon Tjong Ety Yerizel,EdisonMunafand RahmianaZein
PageNo:193-200
Antimicrobiat activity and molecular chancterization of endophytic fungi strain itolated ftom dahlia (Dahlia
variabilis)
Saryonq SefniHendrit Dina Fitriyah, Chn$ine lose, nbnia T. Nugrohoand Aulia Ardhi
PageNo:201-208
BiBorption of copper (Ir) rotg frcm aqueous solution by ttothopanax scatellarium leaves powdef on bEh
mcthod
Si WahyuniNasution,Edy FachriaLEti Yerizel,Refrldaand RahmianaZein
PageNo:209-214
Effect of tumeric powder (Carcama domsticaUal)
TertiaDeliaNovaand YuIa Yeuita
PageNo;215-221
in fed, on the blood of local duck
fsobtion and chancterization of microalgae ielated from palm oil mi efluent (PoME) for biotlisel
stocb with P-@roteoe as co-product
WidiyantiSektresna, Abdi Dharna, Rahmianazein and ZulkarnainChaidi
PageNo:222-231
Antioxidant abltw of pepino fruib (tutanum muricatum aiton) in apoptotic mdalation
(Saffiaromyc8 cerevisiae FNCC3072)
DeviRatnawatiand Eni Widiyati
PageNo: 232-238
The media vanbnce of prodaction for anti mkrobe homogeny from the endopMe
(Dahlia uariab is)
Dewi YudianaShina. Yusmarini,Herix SonataM5 Hilwan YudaTerunaand Saryono
PageNo: 239-245
feed
of yeast cells
fangi of dahlia plant seed
Available online www.jocpr.com
Journal of Chemical and Pharmaceutical Research, 2015, 7(9S):70-75
Research Article
ISSN : 0975-7384
CODEN(USA) : JCPRC5
The effect of the calcinations temperature during synthesis of
TiO2-Fe3O4-bentonite as photocatalyst material
Emma Savitri*, Restu Kartiko Widi and Arief Budhyantoro
Department of Chemical Engineering, University of Surabaya, TG building 5th floor, Raya Kalirungkut, Surabaya,
Indonesia
_____________________________________________________________________________________________
ABSTRACT
The TiO2-Fe3O4 supported bentonite has been synthesized. The syntheses of the TiO2-Fe3O4 based photocatalyst
have been carried out by sol-gel method. The bentonite used for porous support was obtained from Pacitan,
Indonesia. The mol ratio of Ti and Fe in this experiment was 1:1. The syntheses of the photocatalyst material were
followed by calcinations. This experiment was focused on the effect of temperature calcinations toward Ti and Fe
crystal phase, which was affected to the capability of the materials in photocatalysis of phenol degradation. The
variation of the calcinations temperature was 500, 600 and 700oC. The physicochemical properties of TiO2-Fe3O4
bentonite samples were characterized by X-ray diffraction. Photocatalytic activity of the materials was evaluated by
phenol photodegradation using UV light. The calcinations temperature was significantly influenced in the forming
of anatase phase of TiO2 which was affected in the catalytic activity.
Keywords: bentonite; calcination; TiO2-Fe3O4; phenol degradation; photocatalyst
_____________________________________________________________________________________________
INTRODUCTION
Photocatalytic technology has various applications in degradation of organic and inorganic pollutants. Some of
photocatalysts that have been used were TiO2, Fe2O3 and other substances. TiO2 has been widely used as
photocatalysts because of its relatively high photocatalytic activity, biological and chemical stability, low cost, nontoxicity, and long term stability against photocorrosion and chemical corrosion [1,2]. However, TiO2 has limitation
on the aspect of the photocatalytic activity in the UV region and also the difficulty to be separated from the system.
Some methods has been developed by the researchers to solve this limitations, such as doping transition metals
[3,4,5,6], doping non-metallic elements [7,8,9,10,11], etc. Its purposes to enhance the photocatalytic activity of TiO2
and also to improve the utilization of visible light. The researches resulted that the composite photocatalysts had
higher photocatalytic activity than single ones. Therefore, iron oxide / iron ore (Fe2O3) can be added to TiO2 as a
stabilizer in the application of TiO2. The existence of magnetite (Fe3O4) as a doping oxide in this composite also
serves as a crystal formation controller of anatase phase. Anatase phase of TiO2 photocatalyst give greater
photocatalytic ability than the rutile phase of it [12]. In this study, it also used bentonite as a support catalyst.
Bentonite generally is used as adsorbents and catalysts because of the pore number. The utilization of bentonite as
solid support will facilitate and accelerate the mass transfer of adsorbate into the bentonite so that the contact
between metal oxide of photocatalyst with organic compounds will more easily occur and react.
70
Executive Editor
Dr.V K Sharma(Chemical
Sciences)
Dr. C S Chauhan(Pharmaceutical
Sciences)
Associate Editor
Zainul
Dr. Rahadian
Dr. P S Naruka
Dr. H P Singh
Dr. C S Sharma
Editorial Board
Aliero,Nigeria
Dr.A U Itodo,KebbiStateUniversityof ScienceandTechnology,
Zarrouk,Laboratoryof AppliedChemistry& Environment
Department
of Chemistry,Facultyof Science,
Dr. Abdelkader
University
lYohammed
Premier,Oujda,l4orocco
KohatUniversity
Dr.AbdulWahab,Departmentof Pharmacy,
of ScienceandTechnology,KhaiberPakhtoonKhwa,Pakistan
Dr.AbhijiGhosh,BrighamYoungUniversity,
UT,USA
Dr. MaobiEzike,
Universityof Nigeria,Nsukka,Enugu,Nigeria
Dr.AdedijiJohnsonF, FederalUniversityof AgricultureAbeokuta,Abeokuta,Ogun,Nigeria
Facultyof Science,
Universityof Tabuk,Tabuk,KSA
Dr.AdelKameMadbouly,
BiologyDepartment,
Taif university,KSA
Dr.AhmadF. ELShahaby,Biotechnology
Unit,Collegeof N'ledicine,
and GeneticEngineering
Dr. AhmedO Alnajjar,KingFaisalUniversity,
SaudiArabia
Dr. AkmalShawkyGaballa,FacultyoFSpecificEducation,
ZagazigUniversity,
Zagazig,Egypt
Egypt
Damanhour,
Dr, AlaaE, Ali, Headof chemistryDepartment,Facultyof Science,Damanhour
University,
N Pavlovic,
Dr.Aleksandra
Universityof Ni5,Visegradska,
Ni5,Serbia
Dr. Ali H. AFMowali,
Unive6ityof Basrah,Basrah,Iraq
Tabriz,Iran
Dr. Alirezacarjani,
TabrizUniversityof [4edicalSciences,
Dr. Amanoekebo,AdamaScienceand TechnologyUniversity,ldanrd
Egypt
Dr. AmerE A, CairoUniversity,
- BandungSchoolof Pharmacy/SekolahTinggiFarmasiBandung(STFB),
Dr. AriYuniarto,Divisionof Pharmacology
Bandung,Indonesia
Faculty,LampungUniversity,
Indonesia
Dr. AsepSukohar,Nledical
Dr. Atul KumarSingh,CRNTs,IIT Bombay,Bombay,India
Dr. AytaeGuder,GiresunUniversity,
Turkey
Algdrie
Dr. B Boumoud,
Constantine,
UniversitdMentouride Constantine,
Dr. B M Rao,Johnson& JohnsonLtd, Mumbai,India
India
Dr. B S Bhoop,UIPS,PunjabUniversity,
Chandigarh,
of Biology,University
Algeria
Dr. BachirB€narba,Department
of Mascara,
II, France
Dr. BernardGuyot,UMRQualisud(CIMD), Universit6Montpellier
Dr. BrianHenriks€na,
Omaha,NE
CreightonUniversity,
Irupati, India
Dr,C VenkataRao,SriVenkateswara
University,
A. C. Technolog,AnnaUniversity,Chennai,India
Dr, C,Jayakumar,
Deparfnentof ChemicalEngineering,
of Zululand,SouthAfrica
of Chemistry,KwaDlangezwa,
Kwazulu-Natal,
University
Dr. C. Sampath,Department
Cairo,Egypt
Dr. CamiliaG Michel,CairoUniversity,
Phoenix,AZ, USA
ichilampalli,InsysTherapeutics
Dr.Chandeshwar
Xi' an, Shaanxi,P. R China
ShaanxiUniversityof Science& Technology,
Dr. Chengyuan
Liang,Departmentof Pharmacy,
of Lagos,Lagos,Nigeria
P
C
Azubuike,
University
Nigeria
Dr. Chukwuemeka
Okwelogu,Uniyersityof Lagos,
Dr. Chinyere
Dr. Chukwuma
O Agubata,Universityof Nigeria,Nsukka
Dr. ClementJackson,Universityof Uyo,Uyo,Akwalbom,Nigeria
Ile-ife,Osun,Nigeria
Dr. CraigA Obafemi,ObafemiAwolowoUniversity,
l4ehsana,
India
Pharmacy
College,HN GujaratUniversity,
Dr, D J Sen,ShriSarvajanik
Dr. D S Ashilenje,Moitjniversity,Eldoret,Kenya,
LaCOPS,
Cotonou,Benin
Universityof Abomey-Calavi,
Or.D S SalomdKpoviessi,
KampusLimauManis,Padang,WestSumatra,Indonesia
Facultyof Pharmacl,AndalasUniversity,
Dr. Dachriyanus,
StateUniversity,Washington
School
of Pharmacl,Washington
Sciences,
Dr. DafengChu,Department
of Pharmaceutical
Cairo,Egypt
NationalOrganization
for Dr.ugControland Research,
Dr. DemianaI Nesseem,
Dhaka,Bangladesh
Dr. DewanTaslimaAkhter,StamfordUniversityBangladesh,
pal,Bilashpurlnstituteof Pharmaceutical
Koni,Bilashpur
Viswavidyalaya,
GuruGhasidas
Sciences,
Dr. Dilipkumar
Dr. E J Koranteng-Addo,
Universityof CapeCoast,CapeCoast,Ghana
Island,Nigeria
Wilberforce
Dr. EdebiN Vaikosen,NigerDeltaUniversity,
University,Egypt
T. Helmy,ChemistryDepartment,Facultyof Science,Mansoura
Dr. Elsayed
Dr. F 14Al-labri, BasrahUniversity,Basrah,Iraq
Dr.G Aranovich,
lohns HopkinsUniversity,Baltimore,Maryland,USA
Ile-ife,OsunState,Nigeria
obafemiAwolowoUniversity,
Dr. Gabrielo Egharevba,
University,Egypt
Dr.GalalH Said,Ain-Shams
Dr. H M Hassan,
Al-AzharUniversity,NasrCity,Cairo,Egypt
llaret,
LSCT,TiaretUniversity,
Laboratory
and Catalysis
Departmentof Chemistry,Synthesis
Dr. HaddadBoumediene,
Algeria
Centre,Egypt
Division,NationalResearch
l4edicalResearch
Dr. HanaaH, Ahmed,Headof HormonesDepartment,
Riyadh,SaudiArabia
Dr. HananM Al-YoussetKingSaudUniversity,
University
of Sharjah,UAE
of Pharmacology,
Collegeof Pharmacy,
Dr. HanyA. Omar,Department
CA
Inc,, 630 GatewayBlvd.,SouthSanFrancisco,
Dr. HaoWu, NGl4Biopharmaceuticals
l4edicalCenter,Dallas,Texas,
Universityof TexasSouthwestern
Dr. HariKishoreAnnavarapu,
KhoramAbad,
of MedicalSciences,
Schoolof Medicine,LorestanUniversity
Ahmadvand,
Dept.of Biochemistry,
Dr. Hassan
Iran
Dr. HassanAli Zamani,QuchanBranch,IslamicAzadUniversity,
Quchan,Iran
BBN,PutraNilai,Nilai,Negeri
PersiaranPerdana
University,
INTI International
Dr. Ho SoonMin,Facultyof AppliedSciences,
Malaysia
Sembilan,
Sidi
FESUniversity
and Techniques,
Facultyof Sciences
Dr. HoudaBouchafra,
Laboratoryof OrganicChemistryApplication,
N,lohammed
Ibn Abdillah,FES,Morocco
Science,ChinaThreeGorgesUnive6ity,Yichang,Hubeiprovince,
and Pharmaceutical
Dr, Hua-JunLuo,Collegeof Biological
P,R,China
Dr. IkotunAdebomiAyodeji,BowenUniversity,lwo, OsunState,Nigeria
Russia
KurskStatel4edicalUniversity,
of Pharmacy,
of l4anagement
and Economics
Department
Dr. Inna Razdorskaya,
of CapeCoast,Ghana
Dr, I K Koka,University
of CapeCoast,CapeCoast,Ghana
Dr.J K Tufuor,University
Dt. I P K, Adotey,Universjtyof CapeCoast,Ghana
Erazil
Petrolina,Pernambuco,
Federaldo Valedo SeoFrancisco,
Dr. lacksonRobertoGuedesda SilvaAlmeida,Universidade
Singapore
and Nanotechnology,
Dr.Jin QuanWan9,Instituteof Bioengineering
universityof washington,seattle,wA, usA
schoolof Pharmacy,
Dr. linghuaDuan,Departmentof Pharmaceutics,
Nagpur,India
S14lvlc,
of Physics,
Dr.JitendraRamteke,Department
Brazil
Petrolina,Pernambuco,
Federaldo Valedo SaoFrancisco,
Tolentinode Lima,Universidade
Dr,Julianeli
BurkinaFaso
ouagadougou,
Dr, KaboreAdama,lnstitutde ltnvironnementetde RecherchesAgricoles,
Dr. KawkabAli Hussain.Universityof Basrah,Iraq
Federalda Paraiba,JoSoPessoa,Paraiba,Brazil
Dr. KellySamarade Liralvlota,Universidade
Collegeof science,Surat,India
Dr. KetanC. Parmar,Sir P T Sarvaianik
and Drug
Department,Pharmaceutical
centre(NRc),Pharmacognosy
Dr. KhaledNabihzaki Rashed,NationalResearch
Division,Dokki,Giza,Egypt
IndustriesResearch
Inc., Chandler,AZ, USA
InsysTherapeutics.
Dr. Kiranvangara,
Road,Bardoli,surat
university,Bardoli-Mahuva
R. Desai,Departmentof chemistry,ukaTarsadia
Dr. Kishorbhai
Controland Phytopharmaq'
of Pesticides
Institute,Department
t']. Kasiotis,BenakiPhytopathological
Dr. Konstantinos
Kifissia,
Athens
Iran
PayameNoorUniversity,
Dr. LotfAli Saghatforoush,
Ouargla,Algeria
Dr. LotfiBaameur,KasdiMerbahUniversity,
Dr. LucasV B Hoelz,CidadeUniversitiria,Ilha do Fundao,Riode Janeiro,Rl, Brazil
Rabat- Instituts,N4aroc
Dr. 14A Faouzi,Facult6de MddecineetPharmacie,
and AppliedBiologyGroupLeader,KingFahdMedicalResealchcenter,KingAbdulaziz
Dr. M A Kamal,Fundamental
SaudiArabia
University,
Aliero,Nigena
of ScienceandTechnology,
Dr. lvlK 6afar,KebbiStateUniversity
Dr, M O Aqwara,Universityof Yaound6I, Yaound6,Cameroon
ISTlYKinshasa,RDCongo
chimiemddicaleetpharmacologie,
UERdebiochimie,
Dr.M P Kanyonga,
Artsand Sciencecollege,Khammam'A P ' India
B.
G.
N
R.
Government
R
&
Physics,
s.
of
Dr. 14.V, Ramana,Department
Keffi
StateUniYersity,
Dr. MaduP C, Nasarawa
USA
Labs,
Kentucky,
Bhide,Coldstream
Dr. lvlahesh
Iran
Khorramabad,
of MedicalSciences,
Center,LorestanUniversity
Research
Bahmani,RaziHerbatMedicines
Dr. Mahmoud
Yemen
sana'aUniversity,
MahyoobAlburyhi,Facultyof Pharmacy,
Dr. Nlahmoud
Tait Kingdomof SaudiArabia
Dr. llahmoudSalman,Taif University,
UniversitylbnTofail,Kenitra,Morocco
Process
Laboratory,Facultyof Science,
Larit Separation
Dr. Majdouline
Pahang,Kuantan,Pahang,Malaysia
Dr. MakkyE A, Universitylvlalaysia
of
ShahidBeheshtiUniversity
& llycology,Schoolof Medicine,
t4edicalparasitology
Department
of
Dr, MaryamNiyyati,
Tehran,Iran
MedicalSciences,
Turkey
Department
of Chemistry,UludagUniversity,
Dr, Mellahllyas,
Van,Turkey
Kovuncu,YuzuncuYrlUniversity,
Dr. Menderes
lava'
surabaya-East
Airlanggaunive6ity,Kampusc UNAIR,14ulyorejo
Df. t4irnilamid,Facultyof veterinaryf4edicine,
lndonesia
of Carthage,
IPEST,University
Laboratory,
MaterialsandApplications
The tYolecular
Abderrabba,
Abdelmanef
Dr. l4ohamed
La flarsa,Tunisia
l4ara),CampusPuncak,Alam,selangor,l4alaysia
UiTM(Universitlfeknologi
Salama,Facultyof Pharmacy
Dr. t4ohamed
B€nisuef
organicchemistry,Facultyof Pharmacy,
of Pharmaceutical
Department
Abdelgawad,
Abdelwahab
Dr. Mohammed
EgYPt
BeniSuef,
University,
Dr.MohammedRahmatu||ah,Facu|tyofLifesciences,UniversityofDeve|opmentA|ternative,Dhanmondi,Dhaka,
BangladeshOr. YoussefRamli,Facultyof Medicineand Pharmacy,MohammedV University-Rabat,Morocco
Egypt
Y S Abary,CairoUniversity,
Dr. l4ohammed
(NSR)lnc, Stamford,CT,USA
Sarker,NaturalStateResearch
Dr, f4oinuddin
Banani,Dhaka,Bangladesh
University,
Dr, MoynulHasan,DhakaInternational
Dr. !lubo A Sonibare,Universityof Ibadan,IbadanNigeria
Basra,Iraq
BasraUniversity,
lvlohammed-Ali,
Abdul-Jaleel
Dr. l'4unther
Amravati'India
Dr. l4urlidharP,Wadekar,Departmentof Chemistry,Govt VidarbhaInstituteof Science& Humanities'
University,India
Annamalai
and Biotechnology,
of Biochemistry
Department
Dr, N. Vijayakumar,
Dr. NajiA Abood,BasrahUniversity,Basrah,Iraq
Egypt
AleDr'xandria,
AlexandriaUniversity,
Dr, NasrH EFHammamy,
Dr.NeetaRajSharma,FacultyofBiotechnology&Biosciences,LovelyProfessionalUniversity(LPU),Phagwara,Punjab,
India
BasraUniversity,Basra,lraq
Dr, NesreenNadhumlvlajeed,
Riyadh,SaudiArabia
NoraBintAbdulRahmanUniversity,
Princess
Dr, NoraH At-Shaalan,
PulauPinang,l4alaysia
Dr. NurulAil izakaria,UniversitiSainsMalaysia,
Island,Nigeria
Wilberforce
Delta
University,
Niger
Dr.O R Omobuwajo,
ziraat FakijltesiBaheeBitkileriBiilumii,BalcalrAdana
Dr. Okanozkaya,qukurovauniversitesi,
Assiut,Egypt
AssiutUniversity,
Facultyof Pharmacy,
Dr.OlaI. A. Salem,pharmOrganicChemistryDepartment,
Taif, Kingdomof SaudiArabia
Dr. OmarB lbrahim,Taif University,
OkparaUniversityof Agriculture,Umudike,Abia
l'4ichael
of Biochemistry,
Dave,Department
Olorunshola
Dr. Omodamiro
State,Nigeria
India
Kurukshetra,
University,
Dr. P c sharma.Kurukshetra
lbnBattouta,Rabat-l'laroc
Facult6dessciences-Agdal,
Polede comp6tencesPharmacochimie,
Dr. P M Kanyonga,
Thailand
Princeof SongklaUniversity,Songkhla,
Dr. P Sumanatrakul,
l-iruchendur'Tamilnadu
of
Aditanarcollege Artsand Science,
Departmentof Physics,
Dr. P.Selvarajan,
Dr. PatriciaA onocha,Universityof lbadan,Nigeria
Owerri,Imo State,Nigeria
Imo StateUniversity,
Departmentof Biochemistry,
Dr. PaulC.Chikezie.
Yaound€'cameroun
pour le Ddvelopement,
Institutde RechercheAgricole
Dr. PaulineMounjouenpou,
of Nigeria,Nsukka,EnuguState,Nigeria
Dr. PFUzor,University
Varanasi,India
Solanki,BanarasHinduUniversity,
Dr. PremPrakash
Dr. PremRai,LucknowUniversity,Lucknow,India
Iran
Sabzevar,
Tarbiatl4oallemUniversity,
Dr. RezaTavebee.Sabzevar
of Damam,SaudiaArabia
Dr. S A Abubshait,University
Arqentina
de InvestigacionescientificasyTecnologicas,
ConsejoNacional
Dr. S Lucangioli,
Ooty,India
J S S Collegeof Pharmacy,
Dr. S N l4eyyanathan,
.launpur,India
University,
Dr. S PTripathi,Poorvanchal
Udaipur,India
Dr. S ssisodia,B N Collegeof Pharmacy,
Collegeof science,Jordan
ChemistryDepartment,
Dr. safwanFraihat,Allouf Universify,
Dr. SalemAshoor,Universityof I'lisurata,Libya
Dr. Seyedl4ehdiTalebi,ShahidBeheshtiUniversity,Iran
UK
l'4anchester,
LJniversity,
l4etropolitan
Dr. ShaabanK Mohamed,Manchester
Ohio,USA
Columbus,
Oottikkal,OhioStateUniversity,
Dr. Shameema
Inc, NJ,USA
Puthli,TrisPharma
Dr.Shivanand
ouroPreto,l4G'Brazil
Federalde OuroPreto,
Dr. SidneyAuqustoVieiraFilho,Universidade
MD,USA
Rockville,
uS Pharmacopeia,
Dr, SitaramBhavaraiu,
Dr. SoadA Yehia,CairoUniversity,Cairo,Egypt
TX
TexasA & M University,
of Chemistry,
Dr. SoumikBiswas,Department
center,Dallas,TX
l'4edical
The universityof southwestern
or Radiology,
Dr. Srinivaschiguru,Department
Dr. SrinivasNammi,Universityof Canberra,Australia
NewDelhi
JamiaHamdard,
Facultyof Pharmacy,
Departmentof Pharmaceutics,
Talegaonkar,
Dr, Sushama
Ames,IA, USA
NewLinkGenetics,
Dr.TanayKesharwani,
Tlemcen,Algeria
Dr,Tarikchaouche,TlemcenUniversity,
Tripoli,Libya
Dr.TariqK. Almog,TripoliUniversity,
Dr, UhoodJ AL-Hamdani,Universityof Basrah,Basrah,Iraq
Medical
Hospital/Harvard
and l4olecularImaging,BostonChildren's
Akurathi,Divisionof Nuclearl4edicine
Dr. Vamsidhar
School,Boston,l4A,USA
Center,Covington,LA,USA
TulaneNationalPrimateResearch
Divisionof Microbiology,
Dr. VibhaYadav,
Eckert& ZieglerEurotopeGMBH,Hopkinton,l4A,USA
Dr.ViiayGottumukkala,
Facultyof science,
lvledicinal
chemistryand Pharmacognosy,
of Pharmaceuticnl
Dr. WaelAhmadAbu Dayyih,Department
Amman,Jordan
PetraUniversity,
M
Dr. waleed Sweileh,An-NajahNationalUniversity,Nablus,Palestine
of Connedicut,storrs,CT,USA
Dr. Wenjiecai,University
of Alabamain Huntsville,Huntslille,USA
University
N
Setzer,
Dr. William
Cairo,Eqypt
Dr. Y A El-gadry,Ain ShamsUniversity,
v university-Rabat,
l4ohammed
and Pharmacy,
youssef
Facultyof Medicine
Laboratory,
chemistry
l4edicinal
Ramli,
Dr.
l4orocco
Branch,lran
Dr. Z Bayat,IslamicAzadUniversity-Quchan
Yinchuan,Ningxia,P R China
Dr. Zhi-zhongWan9,NingxialledicalUniversity,
CONTENT
Biosorption of cadmium (II) ions from aqueous solutionby cassava (Nanihotutilissima) leaves
Adrian, Edy Fachrial, Almahdy, Syaifullah, Edison Munaf and Rahmiana Zein
Page No:l-8
Immunohistochemical detection of P53 protein as a prognostic indicator in prostate carcir.oma
Bungaran Sihombing, Jamaludin, Djong Hon Cong, Sanusi Ibrahim and Sumaryati Syukur
Page No:9-13
A catalytic test of Mn(II) and Ni(II) grafted on modified mesoporous silica in transesterificationof vegetable
oil
Admi, Vanella Indah Pratiwi, Fitria Ramadhani, Sry Wahyuni, Jervita Sari, Meri Asnita, Wiza Ladya, Syukri Arief, Emdeniz,
Mai Efdi, Zulhadjri and Syukri
Page No:14-16
Synthesis of biodiesel from waste cooking oil by two steps process transesterificationandozonation
Lieke Riadi,Aioysius Yuli Widianto, Edy Purwanto,Akso Pone and Ruth Theresia
Page No:l?-21
Adsorption profile of Cu (II) using Soursop (Annona muricata L) leaves powder as biosorbent
Buter Samin, Edy Fachrial, Almahdy, Edison Munaf, Refilda, Zulkarnain Chaidir and Rahmiana Zein
Page No:22-27
Biosorption ofzinc (II) ions from aqueous solution by Androgaphispaniculataleaves powder on batch method
Deli, Zulkarnain Chaidir, Almahdy, Rahmiana Zein and Edison Munaf
Page No:28-38
Adsorption of Cu(II) using sauropusandrogynus(L.) Ne".from aqueous solution
Chrismis Novalinda Ginting, Edison Munaf, A!mahdy, Eti Yerizel and Rahmtana Zein
Page No:39-45
The optimization of biopolyol synthesis from liquefaction of rice strawusing response sutface method
Edy Putwanto, Joko Sutrisno, Rakhel Apriliana and Kevin Monthiego Horax
Page No:46-53
The effect of increasing blood glucose level on severalatherogenic factors with biomolecularin diabetes
mellitus type II patients
Eti rerize/ and Asman Manaf
Page No:54-58
The purification of waste cooking oil based on lipid profiles measurements by using skin of Salaccazalacca
Ermi Girsang, Agung A Kiswandono, Refilkhtiari, Hermansyah Aziz, Zulkamain Chaidir and Rahmiana Zein
Page No:59-65
Endophytic fungi isolated from Sambiloto (AndrographispaniculataNees) as a source offungallipid
production
Elfita, Muharni and Munawar
Page No:66-69
The effect of the calcinations temperature during synthesis of 7102-Fe304-bentonite as photocatalyst
material
Emma 5avitri,Restu Kartiko Widi and Arief Budhyantoro
Page No:70-75
Separation of inorganic anion from biomaterial using methacrylate-based column in ion chromatography
capillary system
ｈｩ､｡ｹｾ＠
Rahmiana Zein, Edison Munaf, Lee Wah Lim and Toyohide Takeuchi
Page No:76-80
The removal of Cr{VI) with Dimocarpuslongan as a low cost biosorbent
Florenty,Re khtiari, HermansyahAziz, Syafizayantiand RahmianaZein
PageNo:81-88
absorbent of metel
characbrtzanon and utilitation of kepok banana bark Powder (trlusa balbisianacolta) as
solation
in
agueoas
ions Pb(II) & Cd(U)
HenniNengsih,Zilfa and RefildaSuhail
PageNo:89-93
wasb (Gliycinemax)
RiBorptionof cadmiam ion from aqaeotg solutions btatow!9st.?ybean
and Rahmianazein
Desmiafti
Munat
Reni
Harniiati,salnariza, DesiKumiawatLintan LesaL Edison
PageNo:94-100
The effect of banana starch concentration on the proryrti$ of chitosan'starch hioplasti6
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an (Duiozibethinus)
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atd gtibenctamide in tableE dosage form
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production, pufifrcation, and charac9ization of inatina*from
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dahtia rizhosphere-isotatedAspctgillusclauatus
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hsic blue
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in fed, on the blood of local duck
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Available online www.jocpr.com
Journal of Chemical and Pharmaceutical Research, 2015, 7(9S):70-75
Research Article
ISSN : 0975-7384
CODEN(USA) : JCPRC5
The effect of the calcinations temperature during synthesis of
TiO2-Fe3O4-bentonite as photocatalyst material
Emma Savitri*, Restu Kartiko Widi and Arief Budhyantoro
Department of Chemical Engineering, University of Surabaya, TG building 5th floor, Raya Kalirungkut, Surabaya,
Indonesia
_____________________________________________________________________________________________
ABSTRACT
The TiO2-Fe3O4 supported bentonite has been synthesized. The syntheses of the TiO2-Fe3O4 based photocatalyst
have been carried out by sol-gel method. The bentonite used for porous support was obtained from Pacitan,
Indonesia. The mol ratio of Ti and Fe in this experiment was 1:1. The syntheses of the photocatalyst material were
followed by calcinations. This experiment was focused on the effect of temperature calcinations toward Ti and Fe
crystal phase, which was affected to the capability of the materials in photocatalysis of phenol degradation. The
variation of the calcinations temperature was 500, 600 and 700oC. The physicochemical properties of TiO2-Fe3O4
bentonite samples were characterized by X-ray diffraction. Photocatalytic activity of the materials was evaluated by
phenol photodegradation using UV light. The calcinations temperature was significantly influenced in the forming
of anatase phase of TiO2 which was affected in the catalytic activity.
Keywords: bentonite; calcination; TiO2-Fe3O4; phenol degradation; photocatalyst
_____________________________________________________________________________________________
INTRODUCTION
Photocatalytic technology has various applications in degradation of organic and inorganic pollutants. Some of
photocatalysts that have been used were TiO2, Fe2O3 and other substances. TiO2 has been widely used as
photocatalysts because of its relatively high photocatalytic activity, biological and chemical stability, low cost, nontoxicity, and long term stability against photocorrosion and chemical corrosion [1,2]. However, TiO2 has limitation
on the aspect of the photocatalytic activity in the UV region and also the difficulty to be separated from the system.
Some methods has been developed by the researchers to solve this limitations, such as doping transition metals
[3,4,5,6], doping non-metallic elements [7,8,9,10,11], etc. Its purposes to enhance the photocatalytic activity of TiO2
and also to improve the utilization of visible light. The researches resulted that the composite photocatalysts had
higher photocatalytic activity than single ones. Therefore, iron oxide / iron ore (Fe2O3) can be added to TiO2 as a
stabilizer in the application of TiO2. The existence of magnetite (Fe3O4) as a doping oxide in this composite also
serves as a crystal formation controller of anatase phase. Anatase phase of TiO2 photocatalyst give greater
photocatalytic ability than the rutile phase of it [12]. In this study, it also used bentonite as a support catalyst.
Bentonite generally is used as adsorbents and catalysts because of the pore number. The utilization of bentonite as
solid support will facilitate and accelerate the mass transfer of adsorbate into the bentonite so that the contact
between metal oxide of photocatalyst with organic compounds will more easily occur and react.
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