Thermodynamics System The First Law of Thermodynamics

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A. Thermodynamics System

In thermodynamics, an amount of matters that we observe is called system . And everything arround it is called environtment. If there is no heat transfer into or out of the system, the system said to be thermally isolated system. When you learn about heat and temperature, you find that heat is generated by a change of temperature. Heat transfers from higher temperature to the lower temperature. So, heat is a form of energy transfer.

B. The First Law of Thermodynamics

If a gas with constant volume is heated, the temperature will increase. So the molecules of gas move faster than before. It cause more collution between molecules and wall. The collutions cause the pressure of gas increase, also the kinetic energy. It means the internal energy also incrrease. In order to raise gas temperature, an amount of heat Q is needed. If an amount of heat is added to the system, the heat will be used to do work. But there is some of heat is used to raise internal energy of the system. If an amount of heat is given to the system, the internal energy of the system will increase. The heat given to the system is expressed by equation Q = ∆U + W Q : heat transferred to or from the system J ∆U : change of internal energy J W : work done by system J Real power does not hit hard , but straight to the point 9 The equation above is the formulation of first law of thermodynamics. We have to follow some rules to apply first law of thermodynaics. The rules are 1. If heat transferred to the system, value of Q is positive +Q. If heat transferred from the system, value of Q is negative -Q. 2. If the system do work , value of W is positive +W. If the system accept work , value of W is negative -W. You can also find work done by system using curve. Work done is equal to under the process curve on a P-V diagram. P V V 1 V 2 Now let’s go to al o a d take a look at application of first law of thermodynamics. Balcony A worker with weight 65 kg shovels coal for 3 hours. During the shoveling, the worker did work at average rate of 20 W and loss heat to the environtment at average rate of 480 W. How much fat will the worker lose? Energy value of fat E f is 9.3 kcalg. Solution Listing the given value, then converting power to owrk and heat. Given: W = Pt = 20 W3h3600s = 2.16 x 10 5 J Q = - 480 W3 h3600 s = -5.18 x 10 6 J Q is negative because heat is lost E f = 9.3 kcalg = 9.3 x 10 3 kcalkg = 9.3 x 10 3 kcalkg4186 Jkcal 10 = 3.89 x 10 7 Jkg Find: mass of fat burned Answer from the first law of thermodynamics, Q = ∆U + W, we have ∆U = Q – W = - 5.18 x 10 6 J – 2.16 x 10 6 J = - 5.4 x 10 6 J The mass of fat loss is m = = = 0.14 kg follow up exercise How much fat will be lost if the worker were playing basketball, doing work at rate of 120 W and generating heat at rate of 600 W? Hint : the answer is 0.2 Kg Living Room Lapindo and First Law of Thermodynamics The example of The first Law of Thermodynamics is mud spray in sidoarjo. The mud inside the earth blows out because it was at a higher pressure than the atmosphere. So it did positive work on its surroundings. So its internal energy decreased negative. ∆U = Q – W. Because the work is positive, and ∆U is negative, so the Q is zero. The reduction in internal e e g ill ause ud’s s oke. Reading Room

C. Thermodynamics Processes for an Ideal Gas