Catalytic Hydrocracking Of Palm Oil To Gasoline Willi Copper-Galium Mixed Metals Onzeolite
CATALYTIC HYDROCRACKING OF PALM OIL TO GASOLINE WIlli COPPER-GALIUM MIXED METALS
ON ZEOLITE
Master Research Proposal
BY
TIRENA BAHNUR SIREGAR MK023001
ｾｾＱｮｬＢｾｬｦｭ 07002609 SUPERVISOR
P.M. Dr. NOR AISHAR SAIDINA AMIN
Faculty of Chemical and Natural Resources Engineering University Teknologi Malaysia
DECEMBER, 2002
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
ABSTRACT
1
The cracking oflong chain hydrocarbons can be carried out either thermally or catalytically; for this purpose, zeolite Y catalyst is commonly used for petroleum cracking. The catalytic crackings oflong chain hydrocarbons are closely related to the acidity and the reactivity of metal content in catalyst. Hydrocracking is a combination of catalytic cracking and hydrogenation. In this research, refined-bleached-deodorized-
palm oil ( RBDPO) will be subjected to catalytic hydrocracking over lSM-5 or 13 zeolite
by impregnating a mixture of copper and gallium metals in different weigh percent ratios. The performance of the catalysts is tested in micro fixed bed reactor. Palm oil will be injected to the system with a syringe pump, then the oil will be preheated and evaporated. The palm oil vapor and hydrogen gas will be allowed into the reactor and the reaction product will be condensed to complete gas and liquid products. The evaporation temperature of palm oil and reactor temperature will be set at temperature range between 1500 C and 3500 C, and from 3400 C to 3800 C, respectively. The weight hourly space velocity (WHSV) of palm oil will be varied between 1.0 h-I and 3.0 h-I. The pressure of hydrogen gas will be varied between 0 and 8 bars, while the weight percent of each metal copper and gallium in zeolite will be varied between 0 and 8 wt 'Yo. The main objective is to study the effect of all independent variables on gasoline rich product using design of experiment (DOE). Screening of these variables will be performed using Plackett-Burman Design (PBD), while optimization is to be canied out using central composite design (CCD). The gas and liquid products will be analyzed by gas chromatograph with HP- I capillary column and the catalyst before and after reaction will be characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR), temperature programmed desorption (TPD) and nitrogen adsorption (NA) methods.
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
ON ZEOLITE
Master Research Proposal
BY
TIRENA BAHNUR SIREGAR MK023001
ｾｾＱｮｬＢｾｬｦｭ 07002609 SUPERVISOR
P.M. Dr. NOR AISHAR SAIDINA AMIN
Faculty of Chemical and Natural Resources Engineering University Teknologi Malaysia
DECEMBER, 2002
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
ABSTRACT
1
The cracking oflong chain hydrocarbons can be carried out either thermally or catalytically; for this purpose, zeolite Y catalyst is commonly used for petroleum cracking. The catalytic crackings oflong chain hydrocarbons are closely related to the acidity and the reactivity of metal content in catalyst. Hydrocracking is a combination of catalytic cracking and hydrogenation. In this research, refined-bleached-deodorized-
palm oil ( RBDPO) will be subjected to catalytic hydrocracking over lSM-5 or 13 zeolite
by impregnating a mixture of copper and gallium metals in different weigh percent ratios. The performance of the catalysts is tested in micro fixed bed reactor. Palm oil will be injected to the system with a syringe pump, then the oil will be preheated and evaporated. The palm oil vapor and hydrogen gas will be allowed into the reactor and the reaction product will be condensed to complete gas and liquid products. The evaporation temperature of palm oil and reactor temperature will be set at temperature range between 1500 C and 3500 C, and from 3400 C to 3800 C, respectively. The weight hourly space velocity (WHSV) of palm oil will be varied between 1.0 h-I and 3.0 h-I. The pressure of hydrogen gas will be varied between 0 and 8 bars, while the weight percent of each metal copper and gallium in zeolite will be varied between 0 and 8 wt 'Yo. The main objective is to study the effect of all independent variables on gasoline rich product using design of experiment (DOE). Screening of these variables will be performed using Plackett-Burman Design (PBD), while optimization is to be canied out using central composite design (CCD). The gas and liquid products will be analyzed by gas chromatograph with HP- I capillary column and the catalyst before and after reaction will be characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR), temperature programmed desorption (TPD) and nitrogen adsorption (NA) methods.
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008
Tirena Bahnur Siregar :Catalytic hydrocracking of palm oil to gasoline willi ..., 2002. USU e-Repository © 2008