And for the data of gibbs free energy use : No.
Component G
o 298
kJmol 1
CH
3
COCH
3
- 153,304 2
CaOCl
2
.H
2
O 3
CHCl
3
70,405 4
CaCH
3
COO
2
5 CaOH
2
- 899,040 6
CaCl
2
- 748,608 7
H
2
O - 237,304
And get this value :
G
o
= - R.T.lnK
o
lnK
o
= - T
R
o
G
lnK
o
=
298 .
314 ,
8 310
. 020
. 5
lnK
o
= 2.026,302
3.2 Review Kinetics
Can get from the value :
t =
X
A
= 0,91 a
= 2 b
= 6 k
= 1,81.10
-8
Lkmol.detik t=
t=
1.831 hours ≈ 2 hours
1
ln .
. 1
A X
M A
X a
b M
A
a b
M C
k
91
, 1
561 ,
91 ,
2 6
561 ,
8
ln 2
6 561
, 013
, 10
. 81
, 1
1
x x
x x
3.3 Main Equipment Process
a Reactor Batch
Code : R-110
Function : Reaction between chlorine and acetone,
will produce chloroform for 2 hours.
Type : Batch reactors are equipped stirrer and
heating coil
Volume : 70.979 m
3
Total : 4 buah parallel
Dimension : Height
= 8.312 m
Diameter = 5.791 m
Thick head = 0.00635 m
Thick shell = 0.00793 m
Agitator : Turbin
Diameter : 1.524 m
Height : 0.305 m
Width agitator : 0.381 m
Width baffle : 0.457 m
rpm : 45 rpm
motor power : 22 HP
Material Construction : Stainless stell SA 167 type 304
b Mixer 01
Code : M-110
Function : Mix between chlorine and water
Type : Vertical cylinder with head and bottom
shaped torispherical Amount
: one Tank
: Diameter D : 4.110 m
Height H : 4.918 m
Thick : 0,00794 m
Agitator : Type marine propeller with 3 blades and 4 baffle
Diameter : 1.370 m
Rpm : 53.705 rpm
Tenaga motor : 6 HP
Materials : Carbon steel grade CSA-285
c Coloumn Destillation
Code :D-110
Function :Make a pure chloroform.
Type : plate coloumn with sieve tray
Temperature : Feed = 62.2
o
C Top = 60.4
o
C Bottom= 94.0
o
C Shell Diameter
:Top = 0.941 m Bottom= 0.941 m
Thick :Top = 0,0048 m
Bottom= 0,0048 m Material
:Stainless stell SA 167 type 304 Height Shell
: 20.56 m Column Height
: 17.515 m Top section
: 12.419 m Bottom section
: 5.096 m Support
: 3,048 m Head Type
: Torispherical dishedhead Thick head
: Top =0,0048 m
Bottom = 0,0048 m
Height head : Top
= 0,2068 m Bottom
= 0,8683 m Plate Type
: Sieve tray Amount plate
: 25 Feed plate ke
: 7
