Kesehatan Masyarakat: Soal UAS Toksikologi Industri.
^ ^
ly
L Berdoalahterlebih dahulu sebelumandamengerjakan!
2' Bacalahseluruhsoal untuk memahamimaksudsoal,sebelumdijawab !
lupa tuliskan nim, nama, dan tanda tangan anda, sebelummenjawab soal!
1. fung.u.n
4. Jawablahpertanyaandengansingkatdanjelas ! (untuk soal essay/ isian)
Pilihlah.jawaban
yang paling tepat
5. Kerjakanlahsoal yang anda anggaplebih mudahdahulu,dan tuliskan iawabandilembariawaban
yangtelahdisediakan
!
6. Jawabanharusditulis dengantulisan yangjelas dan mudah dibaca,dan tidak diperbolehkan
kerja sama !
7. Koreksilah jawaban sebelumdikumpulkan !
JAWAPLAH DENGAN CERMAT. JELAS & TEPAT!
1. Jelaskanhal-halapasajayang harusadadalamsebuahMSDS? Dan siapasajapenggunaMSDS?
2. Jelaskanmekanismetoksisitaspestisidadiazinon?
3. Jelaskan
diazinon?
i
peran masyarakat awam dalam penanganankasus keracunan pestisida
4. Jelaskandampa(pestisdiadiazinonbagi lingkungan?
r3
DIAZINONAG6OOWBC
TERIAL SAFETYDATA SHEET
NIGHT1-800'424-9300
EXPOSIJREOR ACCIDENT'CALL CHEMTREC DAY OR
FORCHEMICAL EMERGENCY,SPILL,LEAK, FIRE,
F O R M U L A T E DF O R :
-800-424-9300
24-Hour Emergency Phone: 1
MedicalEmergencies: 1-800-301-7976
U.S. Coast Guard National Response Center: 1-800-424-8802
L O V E L A N DP R O D U C T S 'I N C
P O B o x 1 2 8 6 ' G r e e l e YC, O 8 0 6 3 2 - 1 2 8 6
P R o D U C T N A M E : D | A Z I N o N A G 6 0 0 W A T E R - B A S E D C O N C E N T R A T E I N S Ep
ChToIsCp|hDoEr o t h i o a t e )
o , u o n o n ' ( o - o . d i e t h y |o - ( 2 - i s o p r o p y l - 6 - r r e t h - r 1 - 4 . p y r i m i d i n y l )
C H E M | C A LN A M E :
Organophosphatelnsecticide
CHgVrfCAlFAMILY:
66222-103-34704
EPA REG.NO.:
'3
MSDSRevisions: Sec:icM S D SN u m b e r "6 6 2 2 2013 - 0 7 ' t P l
D a t e O f l s s u e : 1 0 / 15 / 0 7
Superqgdes:09/03/04
suMMARY
ffiRDS rDENTlFtcATloN
A v o i d c o n l a o tw l t n
- H a r r n f u il f s r " a l l o " ' e o i n h a l e dc r a b s o r b e dt h r o u q hs K r n C a u s e s e y c i r r i t a t i o n
a n d m e a s u r l n gc u p s
KEEP OUT OF REACH OF cHILDREN CAUTION
t
a
b
l
e
s
p
o
o
n
s
a
s
s
u
c
h
utenstts
Food
feed
and
food
mrst Avord contarrinationof
skin, eyes or clothing.Avold breathingvapor or spray
anlmals D o n o t u s e o n h u m a n s 'h o u s e h o l dp e t s o r
in measurtngpesticides Keep out of reach of domestic
should not be used for food purposes after use
livestock.Do not contaminateornamentalfishponds
odor
T h i s o r o d u c ti s a n o f f - w h r t el i q u i dw i t h s l i g h ts u l f u r - l i k e
3. COMPOSlrloN,INFORMfiTIONOXIIgIEDIENTS
Percentaqe bv Weiqht:
C h e m i c a lI n o r e d i e n t s :
56 00
44 00
Diazinon
lnerl Ingredients
CAS No.
TLV (Unitsl
3 3 3 - 4 1- 5
O O 1 m g / m : (' S k i n )
c o m m u n i c a t i o ns t a n d a r d( 2 9 C F R 1 9 1 0 1 2 0 0 )
T h i s p r o d u c ti s h a z a r d o u sa c c o r d i n gt o t h e o S H A H a z a r d
TIRSTAIDMEASURES
+
lf swallowed:
lf in eyes:
lf inhaled:
lf on skin or clothing:
to swallow
troatrncntadvice.Havc pcrsorrsip a glass of water tf able
call a poison controlccntor or doctor irnrnodiatclyfor
g i v e a n y t h i n gb y m o u t ht o a n
n
o
t
D
o
o
r
d
o
o
t
o
r
'
c
c
n
t
c
r
p
o
i
s
o
n
c
o
n
t
r
o
l
b
y
a
s
o
t
o
d
o
D o n o t i n d u c ev o m i t i n gu n l e s si o l d
nutes Removc contact lenses' if present' after the first 5
' or doctor for treatmcntadvlce
an ambulance,then give artificialrespiration,preferably
er treatmentadvice
p l e n t yo f w a t e r f o r 1 5 - 2 0 m i n u t e s C a l l a p o i s o nc o n t r o lc e n t e r
o r d o c t o r f o r t r e a t m e n ta o v l c e
p r o d u c tc o n t a i n e ro r l a b e l w i t h y o u w h e n c a l l i n ga p o i s o nc o n t r o l
T H I S P R O D U C TC A L L : 1 - 8 0 0 . 3 0 1 - 7 9 7 6 . H A V C t h e
INVOLVING
F o R A M E D I C A LE M E R G E N C Y
t
r
e
a
t
m
e
n
t
g
o
i
n
g
f
o
r
o
r
center or 2 , 5 m g / L ( 4 h r )
C a r c i n o g e n i c P o t e n t i a l : N o n e l i s t e di n O S H A , N T P , I A R C o r A C G I H
Acute Dermal LDm (rabbit): > 2020 mg/kg
Skin lrritation (rabbit): Non-irritating
S k i n S e n s i t i z a t i o n( G u i n e a P i g ) : N o t a s e n s i t i z e r
ponds, tidal
Summarv of Effects: Drazinonis highly toxic to birds, lish, and other wildlife Avoid exposure to waterfowl Keep out of lakes' streams'
water mark
a"d est,.laries.Do not apply direcfly to water, to areas where surface water is present, or to intertidalareas below the mean high
rates on the product label.
",*ches,
Drift and runoff may be hazardous to aquatii organisms in neighboringareas. Shrimp and crab may be killed at application
of equipment or
Do not apply this pioduct where fish, shrimp, crJb, and other aquatic life are important resources.Do not contaminate water by cleaning
not apply this
disposal of lquipment wash waters. Highly toxic to bees exposed to direct treatment or to residues on blooming crops or weeds Do
product or allow it to drift to blooming crops or weeds if bees are visitingthe trealment area
PAGEzOF 3
TERIALSAFETYDATASHEET
DIAZINONAG6OOWBC
E c o - A c u t eT o x i c i t y
96 HR LC5!
Rainbow Trout
Bluegill Sunfish
48 HR LCso
18mgAl/L
0 2 1m g A l / L
D a p h n i aM a g n a
B o b w h i t e O r a l L D 5 s :5 2 m g / k g
M a l l a r d O r a l L D 5 e :1 4 4 m g / k g
B o b w h i t e 8 - d a y D i e t a r y L C 5 s :2 3 5 p p m
M a l l a r d 8 - d a y D i e t a r y L C 5 e :3 3 p p m A I
0O011mgAl/L
Eco-ChronicToxicity
D i a z i n o n : F i s h ( F a t h e a dm i n n o w )E a r l y L i f e S t a g e M A T C > 0 0 9 2 a n d < 0 1 7 m g / L
( D a p h n i aM a g n a ) L i f e C y c l e M A T C > 0 0 0 0 1 7 a n d < 0 0 0 0 3 2 m g / L
Invertebrate
M a l l a r dR e p r o d u c t i o nN O E C 1 0 p p m ( C h E i n h i b i t i o n. 5 p p m )
B o b w h i t eR e p r o d u c t i o N
n O E C 4 0 p p m ( C h E i n h i b i t i o n< 1 0 p p m )
13. DISPOSALCONSIDERATIONS
Do not reuse product container Plastic: Triple rinse (or equivalent),then offer for recycling at an ACRC site (go to bltp_llrywweercey_S!,C
!,!d for
l o c a t i o n so
) r b y r e c o n d i t i o n i n go,r p u n c t u r ea n d d i s p o s eo f i n a s a n i t a r yl a n d f i l l o, r , i n c i n e r a t i o no, r , i f a l l o w e db y s t a t e a n d l o c a l a u t h o r i t i e sb, y b u r n i n g l f
b u r n e d ,s t a y o u t o f s m o k e P e s t i c i d ew a s t e s a r e t o x r c l m p r o p e rd i s p o s a lo f e x c e s s p e s t i c i d e s, p r a y m i x t u r e ,o r r i n s a t ei s a v i o l a t i o no f F e d e r a ll a w D o
not contaminatewater, food or feed by storage or disposa.
14. TRANSPORT
INFORMATION
D O T S h i p p i n g D e s c r i p t i o n : R Q E N V I R O N M E N T A L L YH A Z A R D O U SS U B S T A N C E ,L | Q U l D ,N O S , 9 U N 3 0 8 2 . i l t ( D | A Z I N O N )I V A R | N E
P O L L U T A N TE R G G U I D E 1 7 1
U . S S u r f a c e F r e i g h t C l a s s i f i o a t i o nI:N S E C T I C I D E S
I N, S E C T R E P E L L E N T N
S O I O T H E R T H A N P O I S O N ( N M F C 1 0 2 1 2 0 , C L A S6S0:)
C o n s u l t a p p r o p r i a t e I C A O / I A T Aa n d I M D G r e g u l a t i o n s f o r s h i p m e n t r e q u i r e m e n t s i n t h e A i r a n d M a r i t i m e s h i p p i n g m o d e s .
15. REGULATORY
INFORMATION
N F P A & H M I SH a z a r dR a t i n g s :
' ,
NFPA
1
1
0
SARA Hazard Notification/Reporting
SARA Title lll Hazard Category:
HI\4IS
Health
Flammability
Instability
lmmediate
Delayed
Y
Y
0
1
2
3
4
Least
Shght
Moderate
Htgh
Severe
Frre
Reactive
1
1
0
H
N
N
Health
Flammability
Reactivity
PPE
S u d d o nR e l e a s eo f P r e s s u r e
N
Reportable Quantity (RQ) under U.S. CERCLA:Diazinon
(CAS:333a1-5)'l pound
S A R A , T i t l e l l l , S e c t i o n 3 1 3 : D i a z i n o n(CAS:333-41-5)
56 0%
RCRA Waste Code: Not listed
CA Proposition 65: Not listed
16. OTHERINFORMATION
MSOS STATUS: Section 16 revised
PREPARED BY: Registrationsand RegulatoryAffairs
R E V I E W E DB Y : E n v i r o n m e n t aR
li equlatorvServices
Th6 product is a RESTRICTED USE PESTICIDE due to Avian and Aquatic Toxicity
Disclaimer and Limitation of Liability: This data sheet was developed from informationon the constituent materials ic1entified
herein and does nor
relate to the use of such materials in combination with any other material or process No warranty is expressed or implied with respect to the
c o m p l e t e n e s s o r o n g o l n g a c c u r a ct yhoefi n f o r m a t i o n c o n t a i n e d i n t h i s d a t a s h e e t , a n d L O V E L A N D P R O D Ul nCcTdSi s, c l a i m s a ll il a b i l i t y f o r r e l i a n c e o n
such information This data sheet is not a guarantee of safety Users are responsiblefor ensuring that they have all current informationnecessaryro
safely use the productdescribedby this data sheet for their specificpurpose
PAGE3 OF 3
ly
L Berdoalahterlebih dahulu sebelumandamengerjakan!
2' Bacalahseluruhsoal untuk memahamimaksudsoal,sebelumdijawab !
lupa tuliskan nim, nama, dan tanda tangan anda, sebelummenjawab soal!
1. fung.u.n
4. Jawablahpertanyaandengansingkatdanjelas ! (untuk soal essay/ isian)
Pilihlah.jawaban
yang paling tepat
5. Kerjakanlahsoal yang anda anggaplebih mudahdahulu,dan tuliskan iawabandilembariawaban
yangtelahdisediakan
!
6. Jawabanharusditulis dengantulisan yangjelas dan mudah dibaca,dan tidak diperbolehkan
kerja sama !
7. Koreksilah jawaban sebelumdikumpulkan !
JAWAPLAH DENGAN CERMAT. JELAS & TEPAT!
1. Jelaskanhal-halapasajayang harusadadalamsebuahMSDS? Dan siapasajapenggunaMSDS?
2. Jelaskanmekanismetoksisitaspestisidadiazinon?
3. Jelaskan
diazinon?
i
peran masyarakat awam dalam penanganankasus keracunan pestisida
4. Jelaskandampa(pestisdiadiazinonbagi lingkungan?
r3
DIAZINONAG6OOWBC
TERIAL SAFETYDATA SHEET
NIGHT1-800'424-9300
EXPOSIJREOR ACCIDENT'CALL CHEMTREC DAY OR
FORCHEMICAL EMERGENCY,SPILL,LEAK, FIRE,
F O R M U L A T E DF O R :
-800-424-9300
24-Hour Emergency Phone: 1
MedicalEmergencies: 1-800-301-7976
U.S. Coast Guard National Response Center: 1-800-424-8802
L O V E L A N DP R O D U C T S 'I N C
P O B o x 1 2 8 6 ' G r e e l e YC, O 8 0 6 3 2 - 1 2 8 6
P R o D U C T N A M E : D | A Z I N o N A G 6 0 0 W A T E R - B A S E D C O N C E N T R A T E I N S Ep
ChToIsCp|hDoEr o t h i o a t e )
o , u o n o n ' ( o - o . d i e t h y |o - ( 2 - i s o p r o p y l - 6 - r r e t h - r 1 - 4 . p y r i m i d i n y l )
C H E M | C A LN A M E :
Organophosphatelnsecticide
CHgVrfCAlFAMILY:
66222-103-34704
EPA REG.NO.:
'3
MSDSRevisions: Sec:icM S D SN u m b e r "6 6 2 2 2013 - 0 7 ' t P l
D a t e O f l s s u e : 1 0 / 15 / 0 7
Superqgdes:09/03/04
suMMARY
ffiRDS rDENTlFtcATloN
A v o i d c o n l a o tw l t n
- H a r r n f u il f s r " a l l o " ' e o i n h a l e dc r a b s o r b e dt h r o u q hs K r n C a u s e s e y c i r r i t a t i o n
a n d m e a s u r l n gc u p s
KEEP OUT OF REACH OF cHILDREN CAUTION
t
a
b
l
e
s
p
o
o
n
s
a
s
s
u
c
h
utenstts
Food
feed
and
food
mrst Avord contarrinationof
skin, eyes or clothing.Avold breathingvapor or spray
anlmals D o n o t u s e o n h u m a n s 'h o u s e h o l dp e t s o r
in measurtngpesticides Keep out of reach of domestic
should not be used for food purposes after use
livestock.Do not contaminateornamentalfishponds
odor
T h i s o r o d u c ti s a n o f f - w h r t el i q u i dw i t h s l i g h ts u l f u r - l i k e
3. COMPOSlrloN,INFORMfiTIONOXIIgIEDIENTS
Percentaqe bv Weiqht:
C h e m i c a lI n o r e d i e n t s :
56 00
44 00
Diazinon
lnerl Ingredients
CAS No.
TLV (Unitsl
3 3 3 - 4 1- 5
O O 1 m g / m : (' S k i n )
c o m m u n i c a t i o ns t a n d a r d( 2 9 C F R 1 9 1 0 1 2 0 0 )
T h i s p r o d u c ti s h a z a r d o u sa c c o r d i n gt o t h e o S H A H a z a r d
TIRSTAIDMEASURES
+
lf swallowed:
lf in eyes:
lf inhaled:
lf on skin or clothing:
to swallow
troatrncntadvice.Havc pcrsorrsip a glass of water tf able
call a poison controlccntor or doctor irnrnodiatclyfor
g i v e a n y t h i n gb y m o u t ht o a n
n
o
t
D
o
o
r
d
o
o
t
o
r
'
c
c
n
t
c
r
p
o
i
s
o
n
c
o
n
t
r
o
l
b
y
a
s
o
t
o
d
o
D o n o t i n d u c ev o m i t i n gu n l e s si o l d
nutes Removc contact lenses' if present' after the first 5
' or doctor for treatmcntadvlce
an ambulance,then give artificialrespiration,preferably
er treatmentadvice
p l e n t yo f w a t e r f o r 1 5 - 2 0 m i n u t e s C a l l a p o i s o nc o n t r o lc e n t e r
o r d o c t o r f o r t r e a t m e n ta o v l c e
p r o d u c tc o n t a i n e ro r l a b e l w i t h y o u w h e n c a l l i n ga p o i s o nc o n t r o l
T H I S P R O D U C TC A L L : 1 - 8 0 0 . 3 0 1 - 7 9 7 6 . H A V C t h e
INVOLVING
F o R A M E D I C A LE M E R G E N C Y
t
r
e
a
t
m
e
n
t
g
o
i
n
g
f
o
r
o
r
center or 2 , 5 m g / L ( 4 h r )
C a r c i n o g e n i c P o t e n t i a l : N o n e l i s t e di n O S H A , N T P , I A R C o r A C G I H
Acute Dermal LDm (rabbit): > 2020 mg/kg
Skin lrritation (rabbit): Non-irritating
S k i n S e n s i t i z a t i o n( G u i n e a P i g ) : N o t a s e n s i t i z e r
ponds, tidal
Summarv of Effects: Drazinonis highly toxic to birds, lish, and other wildlife Avoid exposure to waterfowl Keep out of lakes' streams'
water mark
a"d est,.laries.Do not apply direcfly to water, to areas where surface water is present, or to intertidalareas below the mean high
rates on the product label.
",*ches,
Drift and runoff may be hazardous to aquatii organisms in neighboringareas. Shrimp and crab may be killed at application
of equipment or
Do not apply this pioduct where fish, shrimp, crJb, and other aquatic life are important resources.Do not contaminate water by cleaning
not apply this
disposal of lquipment wash waters. Highly toxic to bees exposed to direct treatment or to residues on blooming crops or weeds Do
product or allow it to drift to blooming crops or weeds if bees are visitingthe trealment area
PAGEzOF 3
TERIALSAFETYDATASHEET
DIAZINONAG6OOWBC
E c o - A c u t eT o x i c i t y
96 HR LC5!
Rainbow Trout
Bluegill Sunfish
48 HR LCso
18mgAl/L
0 2 1m g A l / L
D a p h n i aM a g n a
B o b w h i t e O r a l L D 5 s :5 2 m g / k g
M a l l a r d O r a l L D 5 e :1 4 4 m g / k g
B o b w h i t e 8 - d a y D i e t a r y L C 5 s :2 3 5 p p m
M a l l a r d 8 - d a y D i e t a r y L C 5 e :3 3 p p m A I
0O011mgAl/L
Eco-ChronicToxicity
D i a z i n o n : F i s h ( F a t h e a dm i n n o w )E a r l y L i f e S t a g e M A T C > 0 0 9 2 a n d < 0 1 7 m g / L
( D a p h n i aM a g n a ) L i f e C y c l e M A T C > 0 0 0 0 1 7 a n d < 0 0 0 0 3 2 m g / L
Invertebrate
M a l l a r dR e p r o d u c t i o nN O E C 1 0 p p m ( C h E i n h i b i t i o n. 5 p p m )
B o b w h i t eR e p r o d u c t i o N
n O E C 4 0 p p m ( C h E i n h i b i t i o n< 1 0 p p m )
13. DISPOSALCONSIDERATIONS
Do not reuse product container Plastic: Triple rinse (or equivalent),then offer for recycling at an ACRC site (go to bltp_llrywweercey_S!,C
!,!d for
l o c a t i o n so
) r b y r e c o n d i t i o n i n go,r p u n c t u r ea n d d i s p o s eo f i n a s a n i t a r yl a n d f i l l o, r , i n c i n e r a t i o no, r , i f a l l o w e db y s t a t e a n d l o c a l a u t h o r i t i e sb, y b u r n i n g l f
b u r n e d ,s t a y o u t o f s m o k e P e s t i c i d ew a s t e s a r e t o x r c l m p r o p e rd i s p o s a lo f e x c e s s p e s t i c i d e s, p r a y m i x t u r e ,o r r i n s a t ei s a v i o l a t i o no f F e d e r a ll a w D o
not contaminatewater, food or feed by storage or disposa.
14. TRANSPORT
INFORMATION
D O T S h i p p i n g D e s c r i p t i o n : R Q E N V I R O N M E N T A L L YH A Z A R D O U SS U B S T A N C E ,L | Q U l D ,N O S , 9 U N 3 0 8 2 . i l t ( D | A Z I N O N )I V A R | N E
P O L L U T A N TE R G G U I D E 1 7 1
U . S S u r f a c e F r e i g h t C l a s s i f i o a t i o nI:N S E C T I C I D E S
I N, S E C T R E P E L L E N T N
S O I O T H E R T H A N P O I S O N ( N M F C 1 0 2 1 2 0 , C L A S6S0:)
C o n s u l t a p p r o p r i a t e I C A O / I A T Aa n d I M D G r e g u l a t i o n s f o r s h i p m e n t r e q u i r e m e n t s i n t h e A i r a n d M a r i t i m e s h i p p i n g m o d e s .
15. REGULATORY
INFORMATION
N F P A & H M I SH a z a r dR a t i n g s :
' ,
NFPA
1
1
0
SARA Hazard Notification/Reporting
SARA Title lll Hazard Category:
HI\4IS
Health
Flammability
Instability
lmmediate
Delayed
Y
Y
0
1
2
3
4
Least
Shght
Moderate
Htgh
Severe
Frre
Reactive
1
1
0
H
N
N
Health
Flammability
Reactivity
PPE
S u d d o nR e l e a s eo f P r e s s u r e
N
Reportable Quantity (RQ) under U.S. CERCLA:Diazinon
(CAS:333a1-5)'l pound
S A R A , T i t l e l l l , S e c t i o n 3 1 3 : D i a z i n o n(CAS:333-41-5)
56 0%
RCRA Waste Code: Not listed
CA Proposition 65: Not listed
16. OTHERINFORMATION
MSOS STATUS: Section 16 revised
PREPARED BY: Registrationsand RegulatoryAffairs
R E V I E W E DB Y : E n v i r o n m e n t aR
li equlatorvServices
Th6 product is a RESTRICTED USE PESTICIDE due to Avian and Aquatic Toxicity
Disclaimer and Limitation of Liability: This data sheet was developed from informationon the constituent materials ic1entified
herein and does nor
relate to the use of such materials in combination with any other material or process No warranty is expressed or implied with respect to the
c o m p l e t e n e s s o r o n g o l n g a c c u r a ct yhoefi n f o r m a t i o n c o n t a i n e d i n t h i s d a t a s h e e t , a n d L O V E L A N D P R O D Ul nCcTdSi s, c l a i m s a ll il a b i l i t y f o r r e l i a n c e o n
such information This data sheet is not a guarantee of safety Users are responsiblefor ensuring that they have all current informationnecessaryro
safely use the productdescribedby this data sheet for their specificpurpose
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