Perbandingan Penggunaan Isopropil Alkohol (IPA) dan Toluena Sebagai Kolektor Karotenoida Dari Minyak Kelapa Sawit Mutu Rendah Memakai Adsorben Polar pada Sokletasi
LAMPIRAN
Universitas Sumatera Utara
LAMPIRAN 1. DATA BET ADSORBEN CaSiO3
Sample: CASIO3 A USU
Operator: Hari S
Submitter:
File: C:\2020\DATA\CASIO3A.SMP
Started: 05/05/2015 8:25:50
Completed: 05/05/2015 13:54:29
Report Time: 06/05/2015 9:29:42
Sample Mass: 0.2750 g
Measured
Cold Free Space: 81.0825 cm³
Ambient Temperature: 22.00 °C
Automatic Degas: Yes
Analysis Adsorptive: N2
Analysis Bath Temp.: 77.350 K
Thermal Correction: No
Warm Free Space:
25.6311 cm³
Equilibration Interval: 10 s
Low Pressure Dose: None
Summary Report
Surface Area
Single point surface area at p/p° = 0.300054396:
BET Surface Area:
13.3196 m²/g
2.7197 m²/g
t-Plot External Surface Area:
30.0947 m²/g
BJH Adsorption cumulative surface area of pores
between 1.7000 nm and 300.0000 nm width:
17.940 m²/g
BJH Desorption cumulative surface area of pores
between 1.7000 nm and 300.0000 nm width:
18.7151 m²/g
Pore Volume
Single point adsorption total pore volume of pore less than 376.7317 nm width at p/p°
= 0.994858283: 0.027577 cm³/g
t-Plot micropore volume:
-0.008449 cm³/g
BJH Adsorption cumulative volume of pores
between 1.7000 nm and 300.0000 nm width:
0.025051 cm³/g
BJH Desorption cumulative volume of pores
Universitas Sumatera Utara
between 1.7000 nm and 300.0000 nm width:
0.025258 cm³/g
Pore Size
Adsorption average pore width (4V/A by BET):
40.55952 nm
BJH Adsorption average pore width (4V/A):
5.5855 nm
BJH Desorption average pore width (4V/A):
5.3984 nm
Isotherm Linear Plot
CASIO3 A USU - Adsorption
Relative Pressure (p/p°)
Quantity Adsorbed (cm³/g STP)
0.0104716
0.425262
0.0335989
0.778723
0.0676961
1.26095
0.0796655
1.42073
0.0999388
1.69829
0.119856
1.96849
0.139926
2.23023
0.159775
2.49648
0.17971
2.76513
0.199789
3.02724
0.249579
3.70004
0.300054
4.37138
0.35012
5.05648
0.400296
5.73036
0.450137
6.42435
0.500267
7.12245
0.550153
7.82045
0.600182
8.54472
0.650239
9.28229
0.700194
10.0406
0.750201
10.8179
0.800197
11.6393
0.820193
11.9856
0.850181
12.5346
0.875197
13.0148
0.900123
13.5442
0.925122
14.1488
0.949993
14.8988
0.974673
15.9941
0.980579
16.3706
Universitas Sumatera Utara
0.990251
0.994858
17.147
17.8285
CASIO3 A USU - Desorption
Relative Pressure (p/p°)
Quantity Adsorbed (cm³/g STP)
0.994858
17.8285
0.974225
16.4936
0.934644
14.9863
0.907692
14.2546
0.882295
13.6846
0.8754
13.5344
0.850165
13.0195
0.825214
12.5402
0.800208
12.0775
0.75056
11.2248
0.700313
10.3759
0.65009
9.57824
0.600303
8.81623
0.549832
8.05623
0.499893
7.30722
0.450105
6.41908
0.399017
5.71024
0.350415
5.05546
0.299984
4.38163
0.250052
3.70804
0.199964
3.05676
0.140027
2.26766
0.0800698
1.47288
Universitas Sumatera Utara
Sample: CASIO3 A USU
Operator: Hari S
Submitter:
File: C:\2020\DATA\CASIO3A.SMP
Started: 05/05/2015 8:25:50
Completed: 05/05/2015 13:54:29
Report Time: 06/05/2015 9:29:42
Sample Mass: 0.2750 g
Measured
Cold Free Space: 81.0825 cm³
Ambient Temperature: 22.00 °C
Automatic Degas: Yes
Analysis Adsorptive: N2
Analysis Bath Temp.: 77.350 K
Thermal Correction: No
Warm Free Space:
25.6311 cm³
Equilibration Interval: 10 s
Low Pressure Dose: None
BJH Adsorption dV/dlog(w) Pore Volume
CASIO3 A USU
Pore Width (nm)
199.489
100.959
77.6893
39.701
26.6151
19.9688
15.959
13.2542
10.984
9.83975
7.75837
6.34807
5.32449
4.54112
3.92004
3.41339
2.98625
2.62195
2.3009
2.01493
1.75214
Pore Volume (cm³/g)
0.00109934
0.00236774
0.00298664
0.00483799
0.00612027
0.00716922
0.00810144
0.00895748
0.00995187
0.0105839
0.0121075
0.013565
0.0150004
0.0163997
0.0177724
0.019081
0.0203768
0.0216436
0.0228261
0.0239913
0.0250509
Universitas Sumatera Utara
CASIO3 A USU
Pore Width (nm)
237.821
120.684
86.2811
47.335
30.5914
22.3255
17.502
14.3462
11.8975
10.3458
8.54333
6.90602
5.74243
4.86783
4.18309
3.63042
3.17045
2.77993
2.44027
2.13902
1.86557
dV/dlog(w) Pore Volume (cm³/g)
0.00399325
0.00428845
0.00543914
0.00634982
0.0073833
0.00840674
0.0095763
0.0106138
0.0121872
0.0132297
0.0147614
0.0167278
0.0187969
0.0202466
0.0214912
0.021772
0.0223172
0.0224218
0.0208456
0.0202153
0.0174585
Universitas Sumatera Utara
BJH Desorption Pore Distribution Report
Width Range
: 1.7000 nm to 300.0000 nm
Adsorbate Property Factor: 0.95300 nm
Density Conversion Factor: 0.0015468
Fraction of Pores Open at Both Ends: 0.00
Pore Width
Range (nm)
-----376.0 - 76.4
76.4 - 30.5
30.5 - 21.6
21.6 - 16.9
16.9 - 16.0
16.0 - 13.3
13.3 - 11.3
11.3 - 9.8
9.8 - 7.8
7.8 - 6.4
6.4 - 5.3
5.3 - 4.6
4.6 - 3.9
3.9 - 3.4
3.4 - 3.0
3.0 - 2.6
2.6 - 2.3
2.3 - 2.0
Incremental Cumulative
Cumulative
Average
Pore
Pore
Incremental
Pore
Width
Volume Volume
Pore Area
Area
(nm)
(cm³/g)
(cm³/g)
(m²/g)
(m²/g)
87.7
36.5
24.5
18.7
16.4
14.4
12.1
10.5
8.6
6.9
5.8
4.9
4.2
3.6
3.2
2.8
2.4
2.1
0.002233
0.002589
0.001262
0.000996
0.000265
0.000919
0.000866
0.000846
0.001582
0.001602
0.001510
0.001446
0.001442
0.001417
0.001735
0.001261
0.001123
0.001110
0.002233
0.004823
0.006084
0.007081
0.007346
0.008264
0.009130
0.009976
0.011558
0.013160
0.014670
0.016116
0.017559
0.018976
0.020711
0.021972
0.023095
0.024205
0.102
0.284
0.206
0.213
0.065
0.256
0.286
0.323
0.739
0.926
1.051
1.186
1.377
1.559
2.184
1.812
1.836
2.067
0.102
0.386
0.592
0.805
0.869
1.125
1.411
1.734
2.473
3.398
4.449
5.635
7.012
8.571
10.755
12.567
14.404
16.470
Universitas Sumatera Utara
Universitas Sumatera Utara
LAMPIRAN 1. DATA BET ADSORBEN CaSiO3
Sample: CASIO3 A USU
Operator: Hari S
Submitter:
File: C:\2020\DATA\CASIO3A.SMP
Started: 05/05/2015 8:25:50
Completed: 05/05/2015 13:54:29
Report Time: 06/05/2015 9:29:42
Sample Mass: 0.2750 g
Measured
Cold Free Space: 81.0825 cm³
Ambient Temperature: 22.00 °C
Automatic Degas: Yes
Analysis Adsorptive: N2
Analysis Bath Temp.: 77.350 K
Thermal Correction: No
Warm Free Space:
25.6311 cm³
Equilibration Interval: 10 s
Low Pressure Dose: None
Summary Report
Surface Area
Single point surface area at p/p° = 0.300054396:
BET Surface Area:
13.3196 m²/g
2.7197 m²/g
t-Plot External Surface Area:
30.0947 m²/g
BJH Adsorption cumulative surface area of pores
between 1.7000 nm and 300.0000 nm width:
17.940 m²/g
BJH Desorption cumulative surface area of pores
between 1.7000 nm and 300.0000 nm width:
18.7151 m²/g
Pore Volume
Single point adsorption total pore volume of pore less than 376.7317 nm width at p/p°
= 0.994858283: 0.027577 cm³/g
t-Plot micropore volume:
-0.008449 cm³/g
BJH Adsorption cumulative volume of pores
between 1.7000 nm and 300.0000 nm width:
0.025051 cm³/g
BJH Desorption cumulative volume of pores
Universitas Sumatera Utara
between 1.7000 nm and 300.0000 nm width:
0.025258 cm³/g
Pore Size
Adsorption average pore width (4V/A by BET):
40.55952 nm
BJH Adsorption average pore width (4V/A):
5.5855 nm
BJH Desorption average pore width (4V/A):
5.3984 nm
Isotherm Linear Plot
CASIO3 A USU - Adsorption
Relative Pressure (p/p°)
Quantity Adsorbed (cm³/g STP)
0.0104716
0.425262
0.0335989
0.778723
0.0676961
1.26095
0.0796655
1.42073
0.0999388
1.69829
0.119856
1.96849
0.139926
2.23023
0.159775
2.49648
0.17971
2.76513
0.199789
3.02724
0.249579
3.70004
0.300054
4.37138
0.35012
5.05648
0.400296
5.73036
0.450137
6.42435
0.500267
7.12245
0.550153
7.82045
0.600182
8.54472
0.650239
9.28229
0.700194
10.0406
0.750201
10.8179
0.800197
11.6393
0.820193
11.9856
0.850181
12.5346
0.875197
13.0148
0.900123
13.5442
0.925122
14.1488
0.949993
14.8988
0.974673
15.9941
0.980579
16.3706
Universitas Sumatera Utara
0.990251
0.994858
17.147
17.8285
CASIO3 A USU - Desorption
Relative Pressure (p/p°)
Quantity Adsorbed (cm³/g STP)
0.994858
17.8285
0.974225
16.4936
0.934644
14.9863
0.907692
14.2546
0.882295
13.6846
0.8754
13.5344
0.850165
13.0195
0.825214
12.5402
0.800208
12.0775
0.75056
11.2248
0.700313
10.3759
0.65009
9.57824
0.600303
8.81623
0.549832
8.05623
0.499893
7.30722
0.450105
6.41908
0.399017
5.71024
0.350415
5.05546
0.299984
4.38163
0.250052
3.70804
0.199964
3.05676
0.140027
2.26766
0.0800698
1.47288
Universitas Sumatera Utara
Sample: CASIO3 A USU
Operator: Hari S
Submitter:
File: C:\2020\DATA\CASIO3A.SMP
Started: 05/05/2015 8:25:50
Completed: 05/05/2015 13:54:29
Report Time: 06/05/2015 9:29:42
Sample Mass: 0.2750 g
Measured
Cold Free Space: 81.0825 cm³
Ambient Temperature: 22.00 °C
Automatic Degas: Yes
Analysis Adsorptive: N2
Analysis Bath Temp.: 77.350 K
Thermal Correction: No
Warm Free Space:
25.6311 cm³
Equilibration Interval: 10 s
Low Pressure Dose: None
BJH Adsorption dV/dlog(w) Pore Volume
CASIO3 A USU
Pore Width (nm)
199.489
100.959
77.6893
39.701
26.6151
19.9688
15.959
13.2542
10.984
9.83975
7.75837
6.34807
5.32449
4.54112
3.92004
3.41339
2.98625
2.62195
2.3009
2.01493
1.75214
Pore Volume (cm³/g)
0.00109934
0.00236774
0.00298664
0.00483799
0.00612027
0.00716922
0.00810144
0.00895748
0.00995187
0.0105839
0.0121075
0.013565
0.0150004
0.0163997
0.0177724
0.019081
0.0203768
0.0216436
0.0228261
0.0239913
0.0250509
Universitas Sumatera Utara
CASIO3 A USU
Pore Width (nm)
237.821
120.684
86.2811
47.335
30.5914
22.3255
17.502
14.3462
11.8975
10.3458
8.54333
6.90602
5.74243
4.86783
4.18309
3.63042
3.17045
2.77993
2.44027
2.13902
1.86557
dV/dlog(w) Pore Volume (cm³/g)
0.00399325
0.00428845
0.00543914
0.00634982
0.0073833
0.00840674
0.0095763
0.0106138
0.0121872
0.0132297
0.0147614
0.0167278
0.0187969
0.0202466
0.0214912
0.021772
0.0223172
0.0224218
0.0208456
0.0202153
0.0174585
Universitas Sumatera Utara
BJH Desorption Pore Distribution Report
Width Range
: 1.7000 nm to 300.0000 nm
Adsorbate Property Factor: 0.95300 nm
Density Conversion Factor: 0.0015468
Fraction of Pores Open at Both Ends: 0.00
Pore Width
Range (nm)
-----376.0 - 76.4
76.4 - 30.5
30.5 - 21.6
21.6 - 16.9
16.9 - 16.0
16.0 - 13.3
13.3 - 11.3
11.3 - 9.8
9.8 - 7.8
7.8 - 6.4
6.4 - 5.3
5.3 - 4.6
4.6 - 3.9
3.9 - 3.4
3.4 - 3.0
3.0 - 2.6
2.6 - 2.3
2.3 - 2.0
Incremental Cumulative
Cumulative
Average
Pore
Pore
Incremental
Pore
Width
Volume Volume
Pore Area
Area
(nm)
(cm³/g)
(cm³/g)
(m²/g)
(m²/g)
87.7
36.5
24.5
18.7
16.4
14.4
12.1
10.5
8.6
6.9
5.8
4.9
4.2
3.6
3.2
2.8
2.4
2.1
0.002233
0.002589
0.001262
0.000996
0.000265
0.000919
0.000866
0.000846
0.001582
0.001602
0.001510
0.001446
0.001442
0.001417
0.001735
0.001261
0.001123
0.001110
0.002233
0.004823
0.006084
0.007081
0.007346
0.008264
0.009130
0.009976
0.011558
0.013160
0.014670
0.016116
0.017559
0.018976
0.020711
0.021972
0.023095
0.024205
0.102
0.284
0.206
0.213
0.065
0.256
0.286
0.323
0.739
0.926
1.051
1.186
1.377
1.559
2.184
1.812
1.836
2.067
0.102
0.386
0.592
0.805
0.869
1.125
1.411
1.734
2.473
3.398
4.449
5.635
7.012
8.571
10.755
12.567
14.404
16.470
Universitas Sumatera Utara