Reaksi Transesterifikasi DPO (Degummed Palm Oil) untuk Menghasilkan Biodiesel Sawit Menggunakan Lipozyme dalam Pelarut Ionic Liquid1-Butyl-3- Methylimidazolium Hexafluorophosphate ([Bmim][Pf6]

4. Disarankan dilakukan pemurnian terlebih dahulu terhadap biodiesel sebelum dilakukan analisa viskositas, densitas dan kandungan metil ester.

DAFTAR PUSTAKA

  [1] Xu Y, Du, W. & Liu, D. “Study on the kinetics of enzymatic interesterification of triglycerides for biodiesel production with methyl acetate as the acyl acceptor”.

  Vol. 32, No. 5-6, 2005 : Hal 241-245.

  Journal of Molecular Catalysis B: Enzymatic,

  [2] Hermansyah, Heri., Marno, S., Arbianti, R., Utami, T.S.,& Wijanarko, A, “Interesterifikasi Minyak Kelapa Sawit dengan Metil Asetat untuk Sintesis Biodiesel menggunakan Candida Rugosa Lipase Terimobilisasi,” JTKI Aptekindo, 8(1) 2009 : hal. 24 – 32.

  

[3] Ruzich NI and Bassi AS.“Proposed kinetic mechanism of biodieselproduction

through lipase catalysed interesterification with amethyl acetate acyl acceptor

and ionic liquid [BMIM][PF6] cosolvent”.Canadian J Chem Eng Vol. 89, 2011 :

Hal. 3]166–170.

  

[4] Ha SH, Lan MN and Koo Y-M.“Continuous production and in situseparation of

fatty acid ester in ionic liquids”.Enzyme MicrobiolTechnol Vol. 47, 2007 : Hal.6-10.

[5] Sunitha S, Kanjilal S, Reddy PS and Prasad RBN.“Ionic liquids as a reaction

medium for lipase-catalyzed methanolysis of sunfloweroil”.Biotechnol LettVol. 29,

2007 : Hal. 1881–1885.

[6] Yang Z, Zhang K-P, Huang Y and Wang Z. “Both hydrolytic and

transesterification activities of Penicillium expansum lipase aresignificantly

enhanced in ionic liquid [BMIm][PF6]”. J Mol Catal B:Enzyme Vol. 63, 2010 : Hal

:23–30. [7] Zhao H, Baker GA and Holmes S.“New eutectic ionic liquids for lipaseactivation and enzymatic preparation of biodiesel”. Org BiomolChem Vol. 9, Hal. 1908–1916, 2012.

  [8] Marchetti, J. M., Miguel, V. U., Errazu, A. F. “Possible methods for biodiesel production”.Renewable & Sustainable Energy Reviews, Vol. 11,No. 6, Hal: 1300-1311, 2007.

  [9] Lozano P, Bernal JM, Piamtongkam R, Fetzer D and Vaultier M. “Onephaseionic liquid reaction medium for biocatalytic production ofbiodiesel”.

  ChemSusChem Vol. 3, Hal :1359–1363, 2010.

  [10] Maulana, Mirza Akbar, “Pemanfaatan Whole Cell Candida Rugosa sebagai Biokatalis untuk Sintesis Biodiesel Melalui Rute Non Alkohol”. Skripsi.Universitas Indonesia.Depok. 2012.

  [11] Muchtadi, “ Karakterisasi Komponen Intrinsik Utama Buah Sawit

  (Elais guineensis ) dalam Rangka Optimalisasi Proses Ekstraksi Minyak dan Pemanfaatan Provitamin A”. Sekolah Pascasarjana Institut Pertanian Bogor, 1992.

  [12] Kurniasih, Eka, “Produksi Biodiesel dari Crude Palm Oil melalui Reaksi Dua Tahap”. Jurusan Teknik Kimia Politeknik Negeri Lhokseumawe, 2012.

  [13] Basiron, Y, “Baileys Industrial Oil and Fat Products”. Hoboken John Wiley & Sons, Inc . Edisi ke-6, Vol. 2, 2005.

  [14] Ayustaningwarno, Fitriyono, “Proses Pengolahan dan Aplikasi Minyak Sawit Merah pada Industri Pangan”. Program Studi Ilmu Gizi, Fakultas Kedokteran, [15] Suhara, Pengantar tentang Enzim, Jurusan Pendidikan Biologi, Universitas Pendidikan Indonesia, Bandung, 2010.

  [16] Dupont, J., Suarez, P. A. Z., Meneghetti, M. R.,Meneghetti, S. M. P., “Catalytic production ofbiodiesel and diesel-like hydrocarbons fromtriglycerides”. Energy &

  Environmental Science , No. 2, Hal: 1258-1265, 2009.

  [17] Liang, X., Gong, G., Wu, H., Yang, J. “Highlyefficient procedure for the synthesis of biodieselfrom soybean oil using chloroaluminate ionic liquid as catalyst”. Fuel, Vol. 88, No. 4, Hal: 613-616, 2009. [18] Gamba, M., Lapis, A. A. M., Dupont, J. “Supportedionic liquid enzymatic catalysis for theproduction of biodiesel”. Advanced Synthesis & Catalysis , Vol. 350, No. 1, Hal: 160-164,2008 [19] Al-Juhair, Sulaiman., Fan, Wei, Ling., Lim Song Jun, “Proposed Kinetic Mechanism of the Production of Biodiesel from Palm Oil Using Lipase”. Process Biochemistry , Vol. 42, Hal: 951-960, 2007.

  [20] Kumar, Santhosh. “Enzymatic Transesterification of Waste Animal Fats for Production of Biodiesel”, Dalhousie University Halifax, Nova Scotia July, Hal: 128- 130, 2013.

  [21] Andreani, L., Rocha, J.D, “Use of Ionic Liquids in Biodiesel Production”.

  Brazilian Journal of Chemical Engineering , Vol. 29, No. 01, Hal: 1-13, 2012.

  

[22] Tavares, Ana P.M. Oscar, Rodriguez and Eugenia A. Macedo. “New

  Generations of Ionic Liquids Applied to EnzymaticBiocatalysis”. INTECH Chapter 20 , Hal: 538-556, 2013. [23] Nordwald, , Erik M., Joel L. Kaar. “Stabilization of Enzymes in Ionic Liquids Via Modification of Enzyme Charge”. Biotechnology and Bioengineering, Vol 30. No 30, 2013.

  [24] Parthu, Republik Daudi, “Sintesis Biodiesel Rute Non Alkohol dari Minyak Goreng dengan Biokatalis Terimobilisasi Entrapment pada Reaktor Batch dan Reaktor Packed Bed”. Skripsi.Universitas Indonesia.Depok. 2012.

  [25] McCormick, Robert L., Teresa Alleman, Aaron Williams, Yoshio Coy, Andrew Hudgins, and Wendy Dafoe. “Status and Issues for Biodiesel in the United States”.National Renewable Energy Laboratory. 2009.

  [26] News. “UA Researchers Create Biodiesel Fuel from Chicken Fat”. University of Arkansas .2005. [27] Ma, F. and Hanna, M. A.“Biodiesel production: areview”. Bioresource [28] Du, W., Xu, Y., Liu D., & Zeng, J (2004). “Comparative Study on Lipase- Catalyzed Transformation of Soybean Oil for Biodiesel Production with Different Acyl Acceptors”.Journal of Molecular Catalysis B: Enzymatic, Vol. 30, No. 3-4, Hal: 125-129. [29] Diego Teresa et al. “A Recyclable Enzymatic Biodiesel Production Process in Ionic Liquids”. Journal Bioresource Technology. No 102. 2011 Hal 6336-6339. [30] Muhammad Nawshad et al. “An Overview of the Role of Ionic Liquids in Biodiesel Reactions. Journal of Industrial and Engineering Chemistry. No 10. 2012. [31] Baidawi, A., Latif, I., Rachmania, O, “Transesterifikasi Dengan Co-Solvent Sebagai Salah Satu Alternatif Peningkatan Yield Metil Ester Pada Pembuatan Biodiesel Dari Crude Palm Oil (CPO),”Jurnal Institut Teknologi Sepuluh November. Surabaya.2009.

  

[32] Charlie Van Doorslaer, A Joos Wahlen, Pascal Martens, Koen Binnemansb and

Dirk De Vos, “Immobilization of Moleculer Catalysts in Supported Ionic Liquid

Phases”. The Royal Society of Chemistry, Vol. 39, Hal: 8377-8390, 2010.

  

[33] Wheler, Christy, “Ionic Liquids as Catalytic Green Solvents for Nucleophilic

Displacement Reactions”. School of Chemical Engineering, Georgia Institute of

Technology Atlanta, The Royal Society of Chemistry , Hal: 887-888, 2001.

  [34] “Analisa Sederhana Program Biodiesel dari CPO”, Kompas, 1 Juli 2014. [35] Satriana dan Muhammad D. Supardan, Kinetic Study of Esterification of Free

Acid in Low Grade Crude Palm Oil Using Sulfuric Acid , AJChe, 8(1), 2008: hal. 1-8.

  [36] Prateepchaikul, G., Allen, M.L., Leevijit, T. dan Thaveesinsopha, K., Methyl

  

Ester Production from High Free Fatty Acid Mixed Crude Palm Oil, Songklanakarin

J. Sci. Technol., 29(6), 2007: hal 1551-1561.

  [37] Alkabbashi, A.N., Alam, Md. Z., Mirghani, M.E.S., Al-Fusaiel, A.M.A.,

  

Biodiesel Production from Crude Palm Oil by Transesterification Process, Journal of

Applied Science 9 (17), 2009: hal 3166-3170.

  [38] Minovska,Vilma., Eleonora Winkelhausen, Slobodanka Kuzmanova. “Lipase Immobilized by Different Techniques on Various Support Materials Applied in Oil Hydrolysis”.Journal Serb Chemical Soc (JSCS), Vol. 70 (4), 2005.Hal : 609-624.

  [39] Haryono, Muhammad Ali, Wahyuni, “Proses Pemucatan Minyak Sawit Mentah dengan Arang Aktif”, Berkala Ilmiah Teknik Kimia, Vol. 1, No. 1, 2012. [40] Manurung, Renita., Ricky Afrianto, Melina Widyawati, “Synthesis Biodiesel Catalyst The Effect of Amount of Biocatalyst, Mole Ratio of Reactan, Temperature to Yield ”.International Journal of Science and Engineering, Vol. 7 (2), 2014. [41] Arita, Susila., Meta Berlian Dara, Jaya Irawan, “Pembuatan Metil Ester Asam Lemak dari CPO off Grade dengan Metode Esterifikasi-Transesterifikasi”, Jurnal Teknik Kimia Universitas Sriwijaya, Vol. 15, No. 2, 2008. [42] Meng Liu & Jailani Salihon, “Conversion of Palm Oil to Methyl and Ethyl Ester using Crude Enzymes”, Biotechnology and Biomaterials, Vol. 1, 2011. [43] Vasudevan, P. T. & M. Briggs, “Biodiesel production-current state of the art and and challenges”, Journal of Industry Microbiology and Biotechnology, No. 35, 2008 : Hal 421-430. [44] Fukuda, H., A. Kondo & H. Noda, “Biodiesel fuel Production by Transesterification of Oils”. Journal of Bioscience and Bioengineering, No. 2001 : Hal 405-416. [45] Chen, J. W & W. T. Wu, “Regeneration of immobilized Candida antarctica lipase for transesterification”. Journal of Bioscience and Bioengineering No. 95, 2003 : Hal 466-469. [46] Royon, D., M. Daz, G. Ellenrieder and S. Locatelli, “Enzymatic production of Biodiesel from cotton seed oil using t-butanol as a solvent”, Bioresource of Technology , No. 98, 2007 : Hal 648-653. [47] Ranganathan, S. V., S. L. Narasimhan and K. Muthukumar, “An overview of enzymatic production of biodiesel”, Bioresource of Technology, No. 99, 2008 : Hal 3975-3981. [48] Raharja, Sapta.,Prayoga Suryadarma, Melina Widyawati, “Hidrolisis Enzimatik Minyak Ikan untuk Produksi Asam Lemak Omega-3 Menggunakan Lipase dari Aspergillus Niger ”.Jurnal Teknologi dan Industri Pangan, Vol. 22 (1), 2011.

  [49] Yilmaz, E., & Sezgin, M., “Immobilization of Candida rugosa Lipase on Glass Beads for Enantioselective Hydrolysis of Racemic Naproxen Methyl Ester”, Bioresource Technology, Vol. 102, No, 2, Hal 499-506. 2011.

  

[50]Badan Standarisasi Nasional, Standar Nasional Indonesia,

www.bsn.com, SNI : 7182:2012, 2012, diakses pada 28 Juli 2012.

  [51] Dube´ M.A., Tremblay A.Y., dan Cao P, “A Novel Membrane Reactor for the Continuous Production ofBiodiesel”, Departement of Chemical Engineering, University of Ottawa, Canada, 2006.

  [52] Cao P., Dube´ M.A., dan Tremblay A.Y, “Methanol recycling in the production of biodiesel in a membranereactor”, Fuel, 87, 2008, hal. 825–833. [53] Sari, Ariza Budi Tanjung. “Proses Pembuatan Biodiesel Minyak Jarak Pagar dengan Transesterifikasi Satu dan Dua Tahap”, Departemen Teknologi Industri Pertanian, Institut Pertanian Bogor, Skripsi 2007. [54] Sukarno, “Aplikasi Adsorben dalam Proses Pemurnian Biodiesel Jarak Menggunakan Metode Kolom”. Institut Pertanian Bogor, Skripsi 2012.