Pengaruh Annealing dan Komposisi Aditif Ferro Boron (FeB) Terhadap Sifat Fisis dan Magnet Dari Barium Heksaferit (BaFe12O19)
LAMPIRAN 1
GAMBAR ALAT DAN BAHAN
Bahan Barium Heksaferit
Mortar dan Alu
Ayakan 200 Mesh
Bahan FeB
Spatula
Cawan Perahu
Universitas Sumatera Utara
Planetary Ball Mill
High Energy Milling
Bola-bola keramik
Jar mill
Beaker glass
Neraca digital 2 digit
Piknometer
Oven
Universitas Sumatera Utara
Optical Microscope
Fiber Glass Vacuum Desicator
Aquades
Vakum
Toluene
Alat XRD
Universitas Sumatera Utara
LAMPIRAN 2
PENGUKURAN TRUE DENSITY
Perhitugan True Density serbuk sampel uji
Dimana: m1 = massa piknometer kosong
m2 = massa piknometer + aquades
m3 = massa piknometer + serbuk
m4 = massa piknometer + serbuk + aquades
1. TRUE DENSITY BaFe12O19
m1
14.09
14.1
14.1
m2
23.79
23.83
23.82
m1
14.1
14.09
14.09
m2
23.83
23.79
23.78
m1
14.09
14.09
14.1
m2
23.79
23.79
23.82
T Milling = 12 jam
m3
m4
ρ (g/cm3)
15.09
24.59
4.98
15.09
24.61
4.70
15.1
24.61
4.74
3
Rata-rata = 4,81 g/cm
T Milling = 24 jam
m3
m4
ρ (g/cm3)
15.09
24.61
4.70
15.09
24.59
4.98
15.09
24.59
5.24
3
Rata-rata = 4,97 g/cm
T Milling = 36 jam
m3
m4
ρ (g/cm3)
15.09
24.59
4.98
15.09
24.58
4.74
15.1
24.61
4.74
3
Rata-rata = 4,82 g/cm
2. TRUE DENSITY BaFe12O19 – FeB sebelum Annealing
m1
28.756
28.756
28.756
m2
78.415
78.415
78.415
m3
29.757
29.756
29.757
m4
79.218
79.22
79.223
ρ (g/cm3)
5.04
5.11
5.17
Universitas Sumatera Utara
3. TRUE DENSITY BaFe12O19 – FeB setelah Annealing
Aditif FeB
3
6
9
Aditif FeB
3
6
9
Aditif FeB
3
6
9
m1
28.756
28.756
28.756
28.756
28.756
28.756
28.756
28.756
28.756
T annealing = 1000 oC
m2
m3
m4
(g/cm3)
78.415 29.757 79.226
5.25
78.415 29.757 79.225
5.23
78.415 29.757 79.227
5.28
78.415 29.757 79.224
5.20
78.415 29.757 79.225
5.23
78.415 29.757 79.225
5.23
78.415 29.757 79.214
4.94
78.415 29.756 79.212
4.91
78.415 29.757 79.215
4.97
m1
28.756
28.756
28.756
28.756
28.756
28.756
28.756
28.756
28.756
T annealing = 1100 oC
m2
m3
m4
(g/cm3)
78.415 29.757 79.229
5.34
78.415 29.757 79.225
5.23
78.415 29.757 79.233
5.45
78.415 29.757 79.227
5.28
78.415 29.757 79.229
5.34
78.415 29.757 79.23
5.37
78.415 29.757 79.226
5.25
78.415 29.756 79.225
5.25
78.415 29.757 79.226
5.25
m1
28.756
28.756
28.756
28.756
28.756
28.756
28.756
28.756
28.756
T annealing = 1200 oC
m2
m3
m4
(g/cm3)
78.415 29.757 79.234
5.48
78.415 29.757 79.236
5.54
78.415 29.757 79.238
5.61
78.415 29.757 79.226
5.25
78.415 29.757 79.229
5.34
78.415 29.757 79.232
5.42
78.415 29.757 79.226
5.25
78.415 29.756 79.227
5.30
78.415 29.757 79.226
5.25
Rata-rata
5.25 g/cm
3
5.22 g/cm3
4.94 g/cm3
Rata-rata
5.34 g/cm3
5.33 g/cm3
5.25 g/cm3
Rata-rata
5.54 g/cm3
5.34 g/cm3
5.27 g/cm3
Universitas Sumatera Utara
LAMPIRAN 3
HASIL Analisis X-RAY DIFFRACTION
a) Barium Heksaferit
b) FeB
Universitas Sumatera Utara
Hasil XRD 97 % BaFe12O19 – 3 % FeB setelah Annealing 1200 oC
T-Cal 1200_Theta_2-Theta.rawFeB 3%
Sample name : T-Cal 1200
Comment :
IS=RS1=2;RS2=1
Date : 2016/04/27
13:18:02
Operator :
X-Ray : 40 kV , 30 mA
Wavelength :CuKa /
1.541862 A
Goniometer :
Base att. config. :
Attachment :
Detector : SC-70
Memo :
Optics attribute :
Scan mode :
CONTINUOUS
Scan speed / Duration
time : 4.0000 deg./min.
Step width : 0.0200 deg.
Scan axis : 2Theta/Theta
Scan range : 10.0000 90.0000 deg.
2-Theta :
Omega :
Chi :
Phi :
2-ThetaChi :
CBO selection slit :
Incident parallel slit :
Incident slit : 2.000deg
Length limiting slit :
Receiving slit # 1 :
2.000deg
Filter :Cu_K-beta
Receiving optical device :
Receiving parallel slit :
Receiving slit # 2 :
1.000mm
Attenuator :
Diffrected beam mono. :
None Monochromatorslit :
Universitas Sumatera Utara
Hasil XRD 91 % BaFe12O19 – 9 % FeB setelah Annealing 1200 oC
T-Cal 1200_Theta_2-Theta.raw FeB 9%
Sample name : T-Cal 1200
Comment :
IS=RS1=2;RS2=1
Date : 2016/04/27
13:18:02
Operator :
X-Ray : 40 kV , 30 mA
Wavelength :CuKa /
1.541862 A
Goniometer :
Base att. config. :
Attachment :
Detector : SC-70
Memo :
Optics attribute :
Scan mode :
CONTINUOUS
Scan speed / Duration
time : 4.0000 deg./min.
Step width : 0.0200 deg.
Scan axis : 2Theta/Theta
Scan range : 10.0000 90.0000 deg.
2-Theta :
Omega :
Chi :
Phi :
2-ThetaChi :
CBO selection slit :
Incident parallel slit :
Incident slit : 2.000deg
Length limiting slit :
Receiving slit # 1 :
2.000deg
Filter :Cu_K-beta
Receiving optical device :
Receiving parallel slit :
Receiving slit # 2 :
1.000mm
Attenuator :
Diffrected beam mono. :
None
Universitas Sumatera Utara
LAMPIRAN 4
SKEMA ANNEALING
Pada temperatur annealing 1000 oC, t hold = 2 jam
Temperatur
Waktu
(menit)
Annealing
(⁰C)
0
25
57
600
117
600
157
1000
277
1000
374
25
Skema Annealing
120 Menit
1000
Suhu (⁰C)
800
600
400
200
0
0
100
200
Waktu (menit)
300
400
Universitas Sumatera Utara
Pada temperatur annealing 1100 oC, t hold = 2 jam
Temperatur
Waktu
Annealing
(menit)
(C)
0
25
57
600
117
600
167
1100
287
1100
394
25
Skema Annealing
120 Menit
1100
Suhu ( C)
900
700
60 Menit
500
300
100
0
100
200
300
400
Waktu (h)
Universitas Sumatera Utara
Pada temperatur annealing 1200 oC, t hold = 2 jam
Temperatur
Waktu
Annealing
(menit)
(C)
0
25
57
600
117
600
177
1200
297
1200
414
25
Skema Annealing
1200
Suhu (C)
1000
800
600
400
200
0
0
100
200
300
400
500
Waktu (menit)
Universitas Sumatera Utara
LAMPIRAN 5
PARAMETER KISI
Entry # 96-100-8329
Phase classification
Name
Barium dodecairon(III) oxide
Formula
BaFe12O19
I/Ic
2.880000
Sample
1008328
Name
Quality
C (calculated)
References
Publication
Bibliography
Collomb A, Wolfers P, Obradors X, "Neutron diffraction studies of some
hexagonal ferrites: BaFe~12~O~19~, BaMg~2~-W and BaCo~2~-W", Journal
of Magnetism and Magnetic Materials 62, 57-67 (1986)
Origin of data
Source of
COD (Crystallography Open Database)
entry
Link to orig.
1008328
entry
Crystal structure
Crystallographic data
Space group
P 63/m m c (194)
Crystal
Hexagonal
system
Cell
a= 5.8650 Å c= 23.0990 Å
parameters
Z
2
Element Oxid.
Atom
x
y
coordinates
Ba
2.0 0.667 0.333
Fe
3.0 0.000 0.000
Fe
3.0 0.000 0.000
Fe
3.0 0.333 0.667
Fe
3.0 0.333 0.667
Fe
3.0 0.167 0.333
O
-2.0 0.000 0.000
O
-2.0 0.333 0.667
O
-2.0 0.188 0.376
O
-2.0 0.159 0.318
O
-2.0 0.500 1.000
z
0.250
0.000
0.250
0.028
0.190
-0.108
0.152
-0.056
0.250
0.052
0.149
Bi
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Focc
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Diffraction data
Diffraction lines
d [Å]
11.5495
5.7748
5.0792
4.9607
4.6495
4.2398
3.8498
3.8139
3.4176
3.0681
Int.
h
5.5 0
0.8 0
0.1 1
53.3 1
111.6 0
0.3 0
103.6 0
28.4 0
5.5 0
11.0 0
k
0
0
0
0
1
1
0
1
1
1
l
2
4
0
1
2
3
6
4
5
6
Mult.
2
2
6
12
12
12
2
12
12
12
Universitas Sumatera Utara
2.9325
2.8874
2.8423
2.7672
2.7405
2.6147
2.5396
2.5244
2.5101
2.4804
2.4758
2.4118
2.3328
2.3247
2.3099
2.2907
2.2255
2.1920
2.1199
2.1027
2.0575
2.0126
1.9406
1.9313
1.9249
1.9198
1.9132
1.9069
1.8938
1.8627
1.8217
1.8146
1.8052
1.8000
1.7728
1.7180
1.7088
1.7073
1.6931
1.6885
1.6772
1.6752
1.6594
1.6536
1.6499
1.6247
1.6183
1.6092
1.5987
1.5897
1.5692
1.5498
1.5373
1.5341
1.5064
1.4764
1.4737
1.4662
1.4605
1.4559
1.4546
1.4437
1.4404
1.4380
455.1
150.4
91.5
905.5
0.0
1000.0
94.4
61.7
82.4
12.3
0.0
469.1
25.6
1.8
1.9
17.5
272.5
0.0
170.5
14.5
7.1
4.3
48.3
0.0
1.4
0.0
14.1
4.9
5.1
3.6
3.0
34.8
66.6
7.8
3.3
5.3
31.3
0.0
73.3
0.3
3.2
16.4
360.3
1.3
63.4
192.7
394.4
41.6
48.9
0.0
5.4
5.4
12.8
29.4
0.8
7.5
13.2
389.9
2.3
25.1
0.3
5.8
0.0
16.2
1
0
1
0
1
1
2
2
0
2
1
0
1
0
0
0
0
1
0
0
1
0
0
1
0
2
1
0
1
1
1
1
0
0
1
1
0
1
3
3
0
3
1
3
0
0
0
1
1
0
0
0
1
0
0
1
0
2
0
0
2
0
2
1
1 0
0 8
1 2
1 7
1 3
1 4
0 0
0 1
1 8
0 2
1 5
2 3
1 6
2 4
0 10
1 9
2 5
1 7
2 6
1 10
1 8
2 7
1 11
1 9
0 12
1 0
2 1
2 8
2 2
2 3
2 4
1 10
2 9
1 12
2 5
2 6
2 10
1 11
0 0
0 1
1 13
0 2
2 7
0 3
0 14
3 4
2 11
1 12
2 8
3 5
1 14
3 6
2 9
2 12
3 7
2 10
1 15
2 0
3 8
2 13
2 2
0 16
2 3
1 14
6
2
12
12
12
12
6
12
12
12
12
12
12
12
2
12
12
12
12
12
12
12
12
12
2
12
24
12
24
24
24
12
12
12
24
24
12
12
6
12
12
12
24
12
2
12
12
12
24
12
12
12
24
12
12
24
12
6
12
12
12
2
12
12
Universitas Sumatera Utara
1.4212
1.4169
1.4133
1.4087
1.4061
1.3984
1.3975
1.3887
1.3857
1.3836
1.3702
1.3686
1.3655
1.3634
1.3593
1.3475
1.3399
1.3229
1.3180
1.3168
1.3126
1.3073
1.3040
1.2956
1.2952
1.2833
1.2731
1.2713
1.2698
1.2679
1.2661
1.2622
1.2551
1.2529
1.2513
1.2442
1.2402
1.2379
1.2349
1.2257
1.2244
1.2059
1.2027
1.2022
1.2012
1.1981
1.1851
1.1823
1.1816
1.1756
1.1699
1.1664
1.1653
1.1638
1.1624
1.1594
1.1550
1.1538
1.1521
1.1454
1.1422
1.1392
1.1381
1.1368
0.0
33.4
0.2
0.1
4.9
5.9
0.0
0.7
0.7
94.9
20.3
2.9
11.4
0.0
8.6
1.9
0.0
0.6
0.1
0.1
3.2
54.9
5.0
124.7
27.7
0.0
0.0
16.0
7.6
5.7
11.2
0.4
1.5
42.8
3.2
19.8
0.9
0.0
5.6
0.3
21.7
14.2
4.2
0.0
13.0
17.0
0.2
0.1
7.4
53.4
16.0
1.3
0.0
1.7
0.3
4.7
13.9
0.8
0.1
0.5
1.9
0.0
9.8
1.8
2
1
0
3
1
1
2
0
1
0
2
1
0
1
1
1
2
1
0
0
0
2
1
1
1
0
2
0
4
4
1
4
0
4
1
0
4
2
1
0
0
0
1
2
1
0
0
0
0
1
1
2
3
2
0
2
0
1
2
0
2
0
0
1
2 4
2 11
3 9
1 0
3 1
3 2
2 5
1 16
3 3
2 14
2 6
3 4
3 10
1 15
2 12
3 5
2 7
3 6
3 11
2 15
1 17
2 8
2 13
3 7
1 16
0 18
2 9
3 12
0 0
0 1
3 8
0 2
2 16
0 3
2 14
1 18
0 4
2 10
3 9
3 13
4 5
4 6
3 10
2 11
2 15
2 17
4 7
1 19
3 14
1 18
3 11
2 12
2 0
3 1
4 8
3 2
0 20
2 16
3 3
2 18
3 4
3 15
4 9
3 12
12
24
12
12
24
24
12
12
24
12
12
24
12
12
24
24
12
24
12
12
12
12
24
24
12
2
12
12
6
12
24
12
12
12
24
12
12
12
24
12
12
12
24
12
24
12
12
12
12
12
24
12
12
24
12
24
2
24
24
12
24
12
12
24
Universitas Sumatera Utara
1.1299
1.1262
1.1153
1.1128
1.1091
1.1084
1.1071
1.1039
1.1033
1.0988
1.0985
1.0971
1.0966
1.0960
1.0885
1.0866
1.0806
1.0778
1.0750
1.0746
1.0713
1.0669
1.0651
1.0619
1.0610
1.0600
1.0597
1.0513
1.0507
1.0500
1.0404
1.0394
1.0348
1.0331
1.0299
1.0287
1.0282
1.0271
1.0227
1.0189
1.0175
1.0158
1.0149
1.0119
1.0093
1.0083
1.0071
1.0063
0.8
3.0
0.1
4.9
1.9
29.1
0.1
2.2
8.0
59.8
14.5
0.3
6.3
73.1
81.8
74.8
3.9
0.0
15.1
2.5
2.9
17.6
1.2
0.0
2.6
5.9
0.1
0.1
0.2
6.1
2.5
8.7
2.1
5.5
0.0
9.3
0.4
0.0
33.2
9.0
0.1
0.0
1.0
0.1
0.1
0.2
0.5
26.6
2
0
2
0
1
4
1
1
1
2
0
1
0
2
1
0
2
1
0
1
1
1
1
2
2
0
0
0
1
0
2
1
1
0
1
2
0
1
0
2
1
5
5
5
0
1
5
0
3 5
1 20
3 6
4 10
2 17
1 0
4 1
3 13
4 2
3 7
3 16
4 3
2 19
2 14
4 4
4 11
3 8
4 5
1 21
1 20
3 14
2 18
4 6
2 15
3 9
4 12
3 17
2 20
4 7
0 22
3 10
3 15
4 8
4 13
1 21
2 16
1 22
2 19
3 18
3 11
4 9
0 0
0 1
0 2
2 21
3 16
0 3
4 14
24
12
24
12
24
12
24
24
24
24
12
24
12
12
24
12
24
24
12
12
24
24
24
12
24
12
12
12
24
2
24
24
24
12
12
12
12
24
12
24
24
6
12
12
12
24
12
12
Experimental
Physical Properties
Calc. density 5.36300 g/cm³
Remarks
Remarks
Comments
- Diffraction pattern calculated by Match!.
- I/Ic calculated by Match!.
Universitas Sumatera Utara
Entry # 96-901-5504
Phase classification
Name
Mineral
Hematite
Name
Formula
Fe2O3
I/Ic
4.030000
Sample
9015503
Name
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Finger L. W., Hazen R. M., "Crystal structure and isothermal compression of
Fe2O3, Cr2O3, and V2O3 to 50 kbars Note: P = 52.4 kbar", Journal of Applied
Physics 51, 5362-5367 (1980)
COD (Crystallography Open Database)
9015503
Crystal structure
Crystallographic data
Space group
R -3 c (167)
Crystal
trigonal (hexagonal axes)
system
Cell
a= 5.0020 Å c= 13.6202 Å
parameters
Element Oxid.
Bi
Focc
Atom
x
y
z
coordinates
Fe
0.000 0.000 0.355 0.460000 1.000000
O
0.311 0.000 0.250 0.220000 1.000000
Diffraction data
Diffraction lines
d [Å]
3.6551
2.6770
2.5010
2.2700
2.1906
2.0641
1.8275
1.6809
1.6256
1.5919
1.5845
1.4756
1.4440
1.4033
1.3385
1.2993
1.2948
1.2528
Int.
h
270.4 0
1000.0 1
722.5 1
19.9 0
184.6 1
21.8 2
360.0 0
450.4 1
3.4 2
24.6 1
80.1 0
297.0 2
299.1 3
1.7 1
30.2 2
105.0 1
18.4 1
1.0 2
k l
1 2
0 4
1 0
0 6
1 3
0 2
2 4
1 6
1 1
2 2
1 8
1 4
0 0
2 5
0 8
0 10
1 9
1 7
Mult.
6
6
6
2
12
6
6
12
12
12
6
12
6
12
6
6
12
12
Universitas Sumatera Utara
1.2505
1.2184
1.2056
1.1968
1.1832
1.1801
1.1530
1.1350
1.1330
1.0993
1.0953
1.0695
1.0471
1.0336
1.0320
1.0223
67.2
22.6
11.7
0.5
14.8
41.8
56.4
1.4
87.4
0.3
81.5
7.3
88.9
5.6
28.9
0.3
2
0
2
1
3
1
0
0
1
3
2
0
2
1
4
1
2 0
3 6
2 3
3 1
1 2
2 8
2 10
0 12
3 4
1 5
2 6
4 2
1 10
1 12
0 4
3 7
6
6
12
12
12
12
6
2
12
12
12
6
12
12
6
12
Experimental
Physical Properties
Calc. density 5.39100 g/cm³
Remarks
Remarks
Comments
-
Synthetic
Diffraction pattern calculated by Match!.
I/Ic calculated by Match!.
Space group has been derived from given symmetry operations.
Ambiguous space group information in source file.
Universitas Sumatera Utara
Entry # 96-900-8945
Phase classification
Name
Formula
BFe
I/Ic
2.610000
Sample Name 9008944
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Wyckoff R. W. G., "Second edition. Interscience Publishers, New York, New
York", Crystal Structures 1, 85-237 (1963)
COD (Crystallography Open Database)
9008944
Crystal structure
Crystallographic data
Space group
P b n m (62)
Crystal
orthorhombic
system
Cell
a= 4.0530 Å b= 5.4950 Å c= 2.9460 Å
parameters
Element Oxid.
Bi
Focc
Atom
x
y
z
coordinates
Fe
0.125 0.180 0.250 1.000000 1.000000
B
0.610 0.040 0.250 1.000000 1.000000
Diffraction data
Diffraction lines
d [Å]
3.2617
2.7475
2.3830
2.2742
2.1863
2.0265
2.0093
1.9013
1.8002
1.6691
1.6309
1.5975
1.4730
1.4522
1.4268
1.3737
1.3589
1.3425
1.3119
1.3010
1.2982
1.2450
Int.
h
157.9 1
358.9 0
679.2 1
383.8 1
1000.0 1
0.3 2
680.6 0
707.8 2
354.7 1
279.0 1
0.2 2
239.9 2
185.3 0
31.7 1
0.1 2
1.7 0
6.0 2
18.0 1
10.9 3
100.6 1
49.0 0
112.0 0
k
1
2
0
2
1
0
2
1
2
3
2
1
0
3
2
4
3
1
1
4
2
4
l Mult.
0 4
0 2
1 4
0 4
1 8
0 2
1 4
0 4
1 8
0 4
0 4
1 8
2 2
1 8
1 8
0 2
0 4
2 8
0 4
0 4
2 4
1 4
Universitas Sumatera Utara
1.2363
1.2339
1.2280
1.2124
1.1985
1.1915
1.1902
1.1644
1.1371
1.1211
1.1044
1.0931
1.0872
1.0608
1.0607
1.0200
1.0132
72.3
216.4
49.2
31.5
96.4
0.1
7.3
191.9
0.0
56.8
102.4
0.1
45.1
0.1
22.8
6.7
42.8
1
2
3
3
3
2
1
2
2
3
1
2
3
2
1
3
4
2
3
0
2
1
0
4
1
4
2
3
2
3
4
5
3
0
2
1
1
0
1
2
1
2
0
1
2
2
0
1
0
1
0
8
8
4
4
8
4
8
8
4
8
8
8
4
8
4
8
2
Experimental
Physical Properties
Calc. density
6.74800 g/cm³
Remarks
Remarks
Comments
- Diffraction pattern calculated by Match!.
- I/Ic calculated by Match!.
Universitas Sumatera Utara
Entry # 96-100-8327
Phase classification
Name
Barium dodecairon(III) oxide
Formula
BaFe12O19
I/Ic
2.860000
Sample
1008326
Name
Quality
C (calculated)
References
Publication
Bibliography
Collomb A, Wolfers P, Obradors X, "Neutron diffraction studies of some
hexagonal ferrites: BaFe~12~O~19~, BaMg~2~-W and BaCo~2~-W", Journal
of Magnetism and Magnetic Materials 62, 57-67 (1986)
Origin of data
Source of
COD (Crystallography Open Database)
entry
Link to orig.
1008326
entry
Crystal structure
Crystallographic data
Space group
P 63/m m c (194)
Crystal
hexagonal
system
Cell
a= 5.9290 Å c= 23.4130 Å
parameters
Z
2
Element Oxid.
Atom
x
y
coordinates
Ba
2.0 0.667 0.333
Fe
3.0 0.000 0.000
Fe
3.0 0.000 0.000
Fe
3.0 0.333 0.667
Fe
3.0 0.333 0.667
Fe
3.0 0.167 0.333
O
-2.0 0.000 0.000
O
-2.0 0.333 0.667
O
-2.0 0.183 0.366
O
-2.0 0.157 0.314
O
-2.0 0.503 1.006
z
0.250
0.000
0.261
0.026
0.190
-0.108
0.151
-0.056
0.250
0.052
0.149
Bi
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Focc
1.000000
1.000000
0.500000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Diffraction data
Diffraction lines
d [Å]
11.7065
5.8533
5.1347
5.0155
4.7022
4.2895
3.9022
3.8600
3.4599
3.1068
2.9645
2.9410
2.9266
2.8738
2.8026
Int.
h
3.5 0
0.6 0
0.5 1
65.9 1
112.3 0
0.0 0
94.9 0
30.3 0
7.3 0
11.7 0
455.3 1
0.0 1
151.7 0
87.6 1
904.7 0
k
0
0
0
0
1
1
0
1
1
1
1
1
0
1
1
l
2
4
0
1
2
3
6
4
5
6
0
1
8
2
7
Mult.
2
2
6
12
12
12
2
12
12
12
6
12
2
12
12
Universitas Sumatera Utara
2.7713
2.6446
2.5673
2.5520
2.5426
2.5077
2.5047
2.4388
2.3606
2.3511
2.3413
2.3206
2.2512
2.2185
2.1448
2.1303
2.0827
2.0366
1.9662
1.9553
1.9511
1.9407
1.9341
1.9300
1.9146
1.8834
1.8421
1.8374
1.8273
1.8239
1.7928
1.7377
1.7300
1.7290
1.7116
1.7070
1.6995
1.6935
1.6786
1.6724
1.6718
1.6428
1.6386
1.6298
1.6174
1.6075
1.5901
1.5674
1.5555
1.5534
1.5237
1.4942
1.4934
1.4822
1.4774
1.4744
1.4705
1.4633
1.4566
1.4562
1.4369
1.4341
1.4298
1.4241
0.0
1000.0
95.3
59.4
69.5
12.2
0.0
471.6
33.5
1.1
0.6
18.5
280.7
0.0
177.0
16.6
7.4
4.7
54.2
0.0
1.3
0.0
11.8
3.0
5.5
3.1
4.7
24.5
71.6
3.2
4.3
4.5
29.4
0.0
74.5
0.3
2.4
16.5
362.9
57.5
1.1
196.2
406.2
38.4
42.8
0.1
8.6
7.0
11.0
21.7
0.6
10.4
15.7
399.1
2.6
28.7
0.4
4.4
9.4
0.0
0.0
33.9
0.2
0.0
1
1
2
2
0
2
1
0
1
0
0
0
0
1
0
0
1
0
0
1
0
2
1
0
1
1
1
1
0
0
1
1
0
1
3
3
0
3
1
0
3
0
0
1
1
0
0
0
1
0
0
1
0
2
0
0
2
0
1
2
2
1
0
3
1 3
1 4
0 0
0 1
1 8
0 2
1 5
2 3
1 6
2 4
0 10
1 9
2 5
1 7
2 6
1 10
1 8
2 7
1 11
1 9
0 12
1 0
2 1
2 8
2 2
2 3
2 4
1 10
2 9
1 12
2 5
2 6
2 10
1 11
0 0
0 1
1 13
0 2
2 7
0 14
0 3
3 4
2 11
1 12
2 8
3 5
1 14
3 6
2 9
2 12
3 7
2 10
1 15
2 0
3 8
2 13
2 2
0 16
1 14
2 3
2 4
2 11
3 9
1 0
12
12
6
12
12
12
12
12
12
12
2
12
12
12
12
12
12
12
12
12
2
12
24
12
24
24
24
12
12
12
24
24
12
12
6
12
12
12
24
2
12
12
12
12
24
12
12
12
24
12
12
24
12
6
12
12
12
2
12
12
12
24
12
12
Universitas Sumatera Utara
1.4215
1.4137
1.4131
1.4073
1.4013
1.4010
1.3857
1.3837
1.3817
1.3811
1.3759
1.3625
1.3551
1.3378
1.3338
1.3337
1.3302
1.3223
1.3201
1.3122
1.3103
1.3007
1.2879
1.2867
1.2837
1.2817
1.2805
1.2760
1.2713
1.2669
1.2666
1.2609
1.2539
1.2524
1.2492
1.2407
1.2380
1.2194
1.2167
1.2164
1.2163
1.2136
1.1984
1.1982
1.1962
1.1911
1.1836
1.1803
1.1780
1.1765
1.1756
1.1721
1.1707
1.1684
1.1648
1.1603
1.1548
1.1533
1.1511
1.1503
1.1424
1.1414
1.1277
1.1256
5.1
5.8
0.0
0.0
108.0
0.4
19.5
3.1
8.2
0.0
4.5
2.1
0.0
0.7
0.1
0.0
4.7
57.0
4.2
24.1
123.4
0.1
0.0
15.1
8.0
5.4
9.7
0.4
3.3
5.7
44.0
26.6
0.7
0.3
5.5
0.3
22.7
15.2
4.7
0.0
15.4
15.6
0.2
0.0
4.4
45.4
17.1
1.4
0.0
2.3
0.1
4.8
12.2
0.0
0.0
0.0
1.8
0.0
10.6
0.7
0.8
1.4
0.2
4.4
1
1
2
0
0
1
2
1
0
1
1
1
2
1
0
0
0
2
1
1
1
0
2
0
4
4
1
4
0
1
4
0
4
2
1
0
0
0
1
2
1
0
0
0
0
1
1
2
3
2
0
2
0
1
2
0
2
0
0
1
2
0
2
0
3 1
3 2
2 5
1 16
2 14
3 3
2 6
3 4
3 10
1 15
2 12
3 5
2 7
3 6
3 11
2 15
1 17
2 8
2 13
1 16
3 7
0 18
2 9
3 12
0 0
0 1
3 8
0 2
2 16
2 14
0 3
1 18
0 4
2 10
3 9
3 13
4 5
4 6
3 10
2 11
2 15
2 17
4 7
1 19
3 14
1 18
3 11
2 12
2 0
3 1
4 8
3 2
0 20
2 16
3 3
2 18
3 4
3 15
4 9
3 12
3 5
1 20
3 6
4 10
24
24
12
12
12
24
12
24
12
12
24
24
12
24
12
12
12
12
24
12
24
2
12
12
6
12
24
12
12
24
12
12
12
12
24
12
12
12
24
12
24
12
12
12
12
12
24
12
12
24
12
24
2
24
24
12
24
12
12
24
24
12
24
12
Universitas Sumatera Utara
1.1232
1.1205
1.1192
1.1171
1.1154
1.1122
1.1111
1.1109
1.1093
1.1091
1.1005
1.0992
1.0928
1.0897
1.0895
1.0888
1.0842
1.0805
1.0770
1.0748
1.0731
1.0730
1.0724
1.0651
1.0642
1.0624
1.0523
1.0520
1.0464
1.0453
1.0435
1.0421
1.0413
1.0403
1.0356
1.0307
1.0291
1.0269
1.0259
1.0230
1.0226
1.0206
1.0183
1.0182
1.0115
1.0107
1.0084
3.0
29.3
0.1
1.6
7.6
12.6
59.5
7.6
66.4
0.3
81.9
76.6
3.0
0.0
13.8
0.6
4.3
24.2
1.8
0.0
3.0
0.1
4.1
0.1
4.9
0.2
2.5
9.7
2.0
6.1
0.0
2.1
7.1
0.1
28.0
10.4
0.1
0.0
0.8
0.1
0.3
0.0
29.8
0.6
0.3
6.7
0.1
1
4
1
1
1
0
2
0
2
1
1
0
2
1
0
1
1
1
1
2
2
0
0
0
0
1
2
1
1
0
1
0
2
1
0
2
1
5
5
5
0
1
0
5
5
1
2
2 17
1 0
4 1
3 13
4 2
3 16
3 7
2 19
2 14
4 3
4 4
4 11
3 8
4 5
1 21
1 20
3 14
2 18
4 6
2 15
3 9
3 17
4 12
2 20
0 22
4 7
3 10
3 15
4 8
4 13
1 21
1 22
2 16
2 19
3 18
3 11
4 9
0 0
0 1
0 2
2 21
3 16
4 14
0 3
0 4
4 10
3 12
24
12
24
24
24
12
24
12
12
24
24
12
24
24
12
12
24
24
24
12
24
12
12
12
2
24
24
24
24
12
12
12
12
24
12
24
24
6
12
12
12
24
12
12
12
24
24
Experimental
Physical Properties
Calc. density 5.17900 g/cm³
Remarks
Remarks
Comments
- Diffraction pattern calculated by Match!.
- I/Ic calculated by Match!.
Universitas Sumatera Utara
Entry # 96-101-1337
Phase classification
Name
Iron boride (1/1)
Formula
BFe
I/Ic
3.740000
Sample Name 1011336
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Hendricks S. B., Kosting P. R., "The crystal structure of Fe2P, Fe2N, Fe3N and
FeB", Zeitschrift fur Kristallographie74, 511-533 (1930)
COD (Crystallography Open Database)
1011336
Crystal structure
Crystallographic data
Space group
P n a m (62)
Crystal
orthorhombic
system
Cell
a= 4.0530 Å b= 5.4950 Å c= 2.9460 Å
parameters
Z
4
Element Oxid.
Bi
Focc
Atom
x
y
z
coordinates
Fe
3.0 0.115 0.175 0.250 1.000000 1.000000
B
-3.0 0.700 -0.130 0.250 1.000000 1.000000
Diffraction data
Diffraction lines
d [Å]
3.2617
2.7475
2.5964
2.2742
2.1863
2.0265
1.9013
1.8002
1.6696
1.6691
1.6309
1.5975
1.5555
1.4730
1.4522
1.4268
1.3737
1.3589
1.3425
1.3119
1.3010
1.2982
1.2363
1.2339
1.2124
1.1985
Int.
h
295.3 1
337.1 0
1000.0 0
454.7 1
87.1 1
0.2 2
391.9 2
383.2 1
389.6 2
175.4 1
1.4 2
19.0 2
13.9 0
129.4 0
125.4 1
125.0 2
14.0 0
5.9 2
27.7 1
4.5 3
50.5 1
42.8 0
83.1 1
0.4 2
32.2 3
31.1 3
k
1
2
1
2
1
0
1
2
0
3
2
1
3
0
3
2
4
3
1
1
4
2
2
3
2
1
l Mult.
0 4
0 2
1 4
0 4
1 8
0 2
0 4
1 8
1 4
0 4
0 4
1 8
1 4
2 2
1 8
1 8
0 2
0 4
2 8
0 4
0 4
2 4
2 8
1 8
0 4
1 8
Universitas Sumatera Utara
1.1915
1.1902
1.1644
1.1371
1.1211
1.1044
1.0931
1.0872
1.0608
1.0607
1.0297
1.0200
1.0132
0.1
86.4
105.7
0.3
41.0
63.2
0.5
13.4
15.9
16.7
17.9
74.2
20.4
2
1
2
2
3
1
2
3
2
1
0
3
4
0
4
1
4
2
3
2
3
4
5
5
3
0
2
1
2
0
1
2
2
0
1
0
1
1
0
4
8
8
4
8
8
8
4
8
4
4
8
2
Experimental
Physical Properties
Calc. density
6.74800 g/cm³
Remarks
Remarks
Comments
- Diffraction pattern calculated by Match!.
- I/Ic calculated by Match!.
Universitas Sumatera Utara
Entry # 96-901-5066
Phase classification
Name
Mineral
Hematite
Name
Formula
Fe2O3
I/Ic
4.010000
Sample
9015065
Name
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Finger L. W., Hazen R. M., "Crystal structure and isothermal compression of
Fe2O3, Cr2O3, and V2O3 to 50 kbars Note: P = 15.4 kbar", Journal of Applied
Physics 51, 5362-5367 (1980)
COD (Crystallography Open Database)
9015065
Crystal structure
Crystallographic data
Space group
R -3 c (167)
Crystal
trigonal (hexagonal axes)
system
Cell
a= 5.0249 Å c= 13.7163 Å
parameters
Element Oxid.
Bi
Focc
Atom
x
y
z
coordinates
Fe
0.000 0.000 0.355 0.368000 1.000000
O
0.306 0.000 0.250 0.479000 1.000000
Diffraction data
Diffraction lines
d [Å]
3.6744
2.6934
2.5124
2.2861
2.2019
2.0740
1.8372
1.6909
1.6331
1.5994
1.5952
1.4830
1.4506
1.4107
1.3467
1.3082
1.3030
1.2598
1.2562
1.2248
1.2113
1.2023
1.1887
Int.
h
281.0 0
1000.0 1
736.6 1
20.4 0
177.9 1
19.6 2
374.8 0
448.8 1
4.6 2
23.6 1
86.3 0
309.9 2
297.4 3
2.3 1
31.6 2
109.4 1
17.0 1
1.3 2
71.5 2
26.1 0
10.0 2
0.5 1
15.8 3
k l
1 2
0 4
1 0
0 6
1 3
0 2
2 4
1 6
1 1
2 2
1 8
1 4
0 0
2 5
0 8
0 10
1 9
1 7
2 0
3 6
2 3
3 1
1 2
Mult.
6
6
6
2
12
6
6
12
12
12
6
12
6
12
6
6
12
12
6
6
12
12
12
Universitas Sumatera Utara
1.1869
1.1603
1.1430
1.1385
1.1047
1.1009
1.0745
1.0534
1.0404
1.0370
1.0276
44.2
57.8
1.1
90.0
0.4
81.0
8.0
91.5
5.9
29.3
0.3
1
0
0
1
3
2
0
2
1
4
1
2 8
2 10
0 12
3 4
1 5
2 6
4 2
1 10
1 12
0 4
3 7
12
6
2
12
12
12
6
12
12
6
12
Experimental
Physical Properties
Calc. density 5.30400 g/cm³
Remarks
Remarks
Comments
-
Synthetic
Diffraction pattern calculated by Match!.
I/Ic calculated by Match!.
Space group has been derived from given symmetry operations.
Ambiguous space group information in source file.
Universitas Sumatera Utara
Entry # 96-100-8327
Phase classification
Name
Barium dodecairon(III) oxide
Formula
BaFe12O19
I/Ic
2.860000
Sample
1008326
Name
Quality
C (calculated)
References
Publication
Bibliography
Collomb A, Wolfers P, Obradors X, "Neutron diffraction studies of some
hexagonal ferrites: BaFe~12~O~19~, BaMg~2~-W and BaCo~2~-W", Journal
of Magnetism and Magnetic Materials 62, 57-67 (1986)
Origin of data
Source of
COD (Crystallography Open Database)
entry
Link to orig.
1008326
entry
Crystal structure
Crystallographic data
Space group
P 63/m m c (194)
Crystal
hexagonal
system
Cell
a= 5.9290 Å c= 23.4130 Å
parameters
Z
2
Element Oxid.
Atom
x
y
coordinates
Ba
2.0 0.667 0.333
Fe
3.0 0.000 0.000
Fe
3.0 0.000 0.000
Fe
3.0 0.333 0.667
Fe
3.0 0.333 0.667
Fe
3.0 0.167 0.333
O
-2.0 0.000 0.000
O
-2.0 0.333 0.667
O
-2.0 0.183 0.366
O
-2.0 0.157 0.314
O
-2.0 0.503 1.006
z
0.250
0.000
0.261
0.026
0.190
-0.108
0.151
-0.056
0.250
0.052
0.149
Bi
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Focc
1.000000
1.000000
0.500000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Diffraction data
Diffraction lines
d [Å]
11.7065
5.8533
5.1347
5.0155
4.7022
4.2895
3.9022
3.8600
3.4599
3.1068
2.9645
2.9410
2.9266
2.8738
2.8026
Int.
h
3.5 0
0.6 0
0.5 1
65.9 1
112.3 0
0.0 0
94.9 0
30.3 0
7.3 0
11.7 0
455.3 1
0.0 1
151.7 0
87.6 1
904.7 0
k
0
0
0
0
1
1
0
1
1
1
1
1
0
1
1
l
2
4
0
1
2
3
6
4
5
6
0
1
8
2
7
Mult.
2
2
6
12
12
12
2
12
12
12
6
12
2
12
12
Universitas Sumatera Utara
2.7713
2.6446
2.5673
2.5520
2.5426
2.5077
2.5047
2.4388
2.3606
2.3511
2.3413
2.3206
2.2512
2.2185
2.1448
2.1303
2.0827
2.0366
1.9662
1.9553
1.9511
1.9407
1.9341
1.9300
1.9146
1.8834
1.8421
1.8374
1.8273
1.8239
1.7928
1.7377
1.7300
1.7290
1.7116
1.7070
1.6995
1.6935
1.6786
1.6724
1.6718
1.6428
1.6386
1.6298
1.6174
1.6075
1.5901
1.5674
1.5555
1.5534
1.5237
1.4942
1.4934
1.4822
1.4774
1.4744
1.4705
1.4633
1.4566
1.4562
1.4369
1.4341
1.4298
1.4241
0.0
1000.0
95.3
59.4
69.5
12.2
0.0
471.6
33.5
1.1
0.6
18.5
280.7
0.0
177.0
16.6
7.4
4.7
54.2
0.0
1.3
0.0
11.8
3.0
5.5
3.1
4.7
24.5
71.6
3.2
4.3
4.5
29.4
0.0
74.5
0.3
2.4
16.5
362.9
57.5
1.1
196.2
406.2
38.4
42.8
0.1
8.6
7.0
11.0
21.7
0.6
10.4
15.7
399.1
2.6
28.7
0.4
4.4
9.4
0.0
0.0
33.9
0.2
0.0
1
1
2
2
0
2
1
0
1
0
0
0
0
1
0
0
1
0
0
1
0
2
1
0
1
1
1
1
0
0
1
1
0
1
3
3
0
3
1
0
3
0
0
1
1
0
0
0
1
0
0
1
0
2
0
0
2
0
1
2
2
1
0
3
1 3
1 4
0 0
0 1
1 8
0 2
1 5
2 3
1 6
2 4
0 10
1 9
2 5
1 7
2 6
1 10
1 8
2 7
1 11
1 9
0 12
1 0
2 1
2 8
2 2
2 3
2 4
1 10
2 9
1 12
2 5
2 6
2 10
1 11
0 0
0 1
1 13
0 2
2 7
0 14
0 3
3 4
2 11
1 12
2 8
3 5
1 14
3 6
2 9
2 12
3 7
2 10
1 15
2 0
3 8
2 13
2 2
0 16
1 14
2 3
2 4
2 11
3 9
1 0
12
12
6
12
12
12
12
12
12
12
2
12
12
12
12
12
12
12
12
12
2
12
24
12
24
24
24
12
12
12
24
24
12
12
6
12
12
12
24
2
12
12
12
12
24
12
12
12
24
12
12
24
12
6
12
12
12
2
12
12
12
24
12
12
Universitas Sumatera Utara
1.4215
1.4137
1.4131
1.4073
1.4013
1.4010
1.3857
1.3837
1.3817
1.3811
1.3759
1.3625
1.3551
1.3378
1.3338
1.3337
1.3302
1.3223
1.3201
1.3122
1.3103
1.3007
1.2879
1.2867
1.2837
1.2817
1.2805
1.2760
1.2713
1.2669
1.2666
1.2609
1.2539
1.2524
1.2492
1.2407
1.2380
1.2194
1.2167
1.2164
1.2163
1.2136
1.1984
1.1982
1.1962
1.1911
1.1836
1.1803
1.1780
1.1765
1.1756
1.1721
1.1707
1.1684
1.1648
1.1603
1.1548
1.1533
1.1511
1.1503
1.1424
1.1414
1.1277
1.1256
5.1
5.8
0.0
0.0
108.0
0.4
19.5
3.1
8.2
0.0
4.5
2.1
0.0
0.7
0.1
0.0
4.7
57.0
4.2
24.1
123.4
0.1
0.0
15.1
8.0
5.4
9.7
0.4
3.3
5.7
44.0
26.6
0.7
0.3
5.5
0.3
22.7
15.2
4.7
0.0
15.4
15.6
0.2
0.0
4.4
45.4
17.1
1.4
0.0
2.3
0.1
4.8
12.2
0.0
0.0
0.0
1.8
0.0
10.6
0.7
0.8
1.4
0.2
4.4
1
1
2
0
0
1
2
1
0
1
1
1
2
1
0
0
0
2
1
1
1
0
2
0
4
4
1
4
0
1
4
0
4
2
1
0
0
0
1
2
1
0
0
0
0
1
1
2
3
2
0
2
0
1
2
0
2
0
0
1
2
0
2
0
3 1
3 2
2 5
1 16
2 14
3 3
2 6
3 4
3 10
1 15
2 12
3 5
2 7
3 6
3 11
2 15
1 17
2 8
2 13
1 16
3 7
0 18
2 9
3 12
0 0
0 1
3 8
0 2
2 16
2 14
0 3
1 18
0 4
2 10
3 9
3 13
4 5
4 6
3 10
2 11
2 15
2 17
4 7
1 19
3 14
1 18
3 11
2 12
2 0
3 1
4 8
3 2
0 20
2 16
3 3
2 18
3 4
3 15
4 9
3 12
3 5
1 20
3 6
4 10
24
24
12
12
12
24
12
24
12
12
24
24
12
24
12
12
12
12
24
12
24
2
12
12
6
12
24
12
12
24
12
12
12
12
24
12
12
12
24
12
24
12
12
12
12
12
24
12
12
24
12
24
2
24
24
12
24
12
12
24
24
12
24
12
Universitas Sumatera Utara
1.1232
1.1205
1.1192
1.1171
1.1154
1.1122
1.1111
1.1109
1.1093
1.1091
1.1005
1.0992
1.0928
1.0897
1.0895
1.0888
1.0842
1.0805
1.0770
1.0748
1.0731
1.0730
1.0724
1.0651
1.0642
1.0624
1.0523
1.0520
1.0464
1.0453
1.0435
1.0421
1.0413
1.0403
1.0356
1.0307
1.0291
1.0269
1.0259
1.0230
1.0226
1.0206
1.0183
1.0182
1.0115
1.0107
1.0084
3.0
29.3
0.1
1.6
7.6
12.6
59.5
7.6
66.4
0.3
81.9
76.6
3.0
0.0
13.8
0.6
4.3
24.2
1.8
0.0
3.0
0.1
4.1
0.1
4.9
0.2
2.5
9.7
2.0
6.1
0.0
2.1
7.1
0.1
28.0
10.4
0.1
0.0
0.8
0.1
0.3
0.0
29.8
0.6
0.3
6.7
0.1
1
4
1
1
1
0
2
0
2
1
1
0
2
1
0
1
1
1
1
2
2
0
0
0
0
1
2
1
1
0
1
0
2
1
0
2
1
5
5
5
0
1
0
5
5
1
2
2 17
1 0
4 1
3 13
4 2
3 16
3 7
2 19
2 14
4 3
4 4
4 11
3 8
4 5
1 21
1 20
3 14
2 18
4 6
2 15
3 9
3 17
4 12
2 20
0 22
4 7
3 10
3 15
4 8
4 13
1 21
1 22
2 16
2 19
3 18
3 11
4 9
0 0
0 1
0 2
2 21
3 16
4 14
0 3
0 4
4 10
3 12
24
12
24
24
24
12
24
12
12
24
24
12
24
24
12
12
24
24
24
12
24
12
12
12
2
24
24
24
24
12
12
12
12
24
12
24
24
6
12
12
12
24
12
12
12
24
24
Experimental
Physical Properties
Calc. density 5.17900 g/cm³
Remarks
Remarks
Comments
- Diffraction pattern calculated by Match!.
- I/Ic calculated by Match!.
Universitas Sumatera Utara
Entry # 96-101-1337
Phase classification
Name
Iron boride (1/1)
Formula
BFe
I/Ic
3.740000
Sample Name 1011336
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Hendricks S. B., Kosting P. R., "The crystal structure of Fe2P, Fe2N, Fe3N and
FeB", Zeitschrift fur Kristallographie74, 511-533 (1930)
COD (Crystallography Open Database)
1011336
Crystal structure
Crystallographic data
Space group
P n a m (62)
Crystal
orthorhombic
system
Cell
a= 4.0530 Å b= 5.4950 Å c= 2.9460 Å
parameters
Z
4
Element Oxid.
Bi
Focc
Atom
x
y
z
coordinates
Fe
3.0 0.115 0.175 0.250 1.000000 1.000000
B
-3.0 0.700 -0.130 0.250 1.000000 1.000000
Diffraction data
Diffraction lines
d [Å]
3.2617
2.7475
2.5964
2.2742
2.1863
2.0265
1.9013
1.8002
1.6696
1.6691
1.6309
1.5975
1.5555
1.4730
1.4522
1.4268
1.3737
1.3589
1.3425
1.3119
1.3010
1.2982
1.2363
1.2339
1.2124
1.1985
Int.
h
295.3 1
337.1 0
1000.0 0
454.7 1
87.1 1
0.2 2
391.9 2
383.2 1
389.6 2
175.4 1
1.4 2
19.0 2
13.9 0
129.4 0
125.4 1
125.0 2
14.0 0
5.9 2
27.7 1
4.5 3
50.5 1
42.8 0
83.1 1
0.4 2
32.2 3
31.1 3
k
1
2
1
2
1
0
1
2
0
3
2
1
3
0
3
2
4
3
1
1
4
2
2
3
2
1
l Mult.
0 4
0 2
1 4
0 4
1 8
0 2
0 4
1 8
1 4
0 4
0 4
1 8
1 4
2 2
1 8
1 8
0 2
0 4
2 8
0 4
0 4
2 4
2 8
1 8
0 4
1 8
Universitas Sumatera Utara
1.1915
1.1902
1.1644
1.1371
1.1211
1.1044
1.0931
1.0872
1.0608
1.0607
1.0297
1.0200
1.0132
0.1
86.4
105.7
0.3
41.0
63.2
0.5
13.4
15.9
16.7
17.9
74.2
20.4
2
1
2
2
3
1
2
3
2
1
0
3
4
0
4
1
4
2
3
2
3
4
5
5
3
0
2
1
2
0
1
2
2
0
1
0
1
1
0
4
8
8
4
8
8
8
4
8
4
4
8
2
Experimental
Physical Properties
Calc. density
6.74800 g/cm³
Remarks
Remarks
Comments
- Diffraction pattern calculated by Match!.
- I/Ic calculated by Match!.
Universitas Sumatera Utara
Entry # 96-901-5965
Phase classification
Name
Mineral
Hematite
Name
Formula
Fe2O3
I/Ic
4.010000
Sample
9015964
Name
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Finger L. W., Hazen R. M., "Crystal structure and isothermal compression of
Fe2O3, Cr2O3, and V2O3 to 50 kbars Note: P = 0.001 kbar", Journal of Applied
Physics51, 5362-5367 (1980)
COD (Crystallography Open Database)
9015964
Crystal structure
Crystallographic data
Space group
R -3 c (167)
Crystal
trigonal (hexagonal axes)
system
Cell
a= 5.0346 Å c= 13.7473 Å
parameters
Element Oxid.
Bi
Focc
Atom
x
y
z
coordinates
Fe
0.000 0.000 0.355 0.319000 1.000000
O
0.306 0.000 0.250 0.400000 1.000000
Diffraction data
Diffraction lines
d [Å]
3.6818
2.6991
2.5173
2.2912
2.2063
2.0780
1.8409
1.6944
1.6362
1.6025
1.5987
1.4860
1.4534
1.4135
1.3496
1.3111
1.3059
1.2624
1.2586
1.2273
1.2137
1.2046
1.1910
Int.
h
286.1 0
1000.0 1
740.7 1
20.6 0
179.3 1
19.4 2
379.8 0
455.9 1
5.0 2
23.7 1
87.3 0
315.0 2
301.6 3
2.5 1
31.6 2
112.0 1
17.5 1
1.5 2
72.8 2
26.8 0
10.1 2
0.6 1
16.4 3
k l
1 2
0 4
1 0
0 6
1 3
0 2
2 4
1 6
1 1
2 2
1 8
1 4
0 0
2 5
0 8
0 10
1 9
1 7
2 0
3 6
2 3
3 1
1 2
Mult.
6
6
6
2
12
6
6
12
12
12
6
12
6
12
6
6
12
12
6
6
12
12
12
Universitas Sumatera Utara
1.1894
1.1628
1.1456
1.1407
1.1069
1.1032
1.0766
1.0556
1.0427
1.0390
1.0297
44.5
58.9
1.2
91.3
0.4
83.1
8.5
93.6
5.9
29.5
0.3
1
0
0
1
3
2
0
2
1
4
1
2 8
2 10
0 12
3 4
1 5
2 6
4 2
1 10
1 12
0 4
3 7
12
6
2
12
12
12
6
12
12
6
12
Experimental
Physical Properties
Calc. density 5.27200 g/cm³
Remarks
Remarks
Comments
-
Synthetic
Diffraction pattern calculated by Match!.
I/Ic calculated by Match!.
Space group has been derived from given symmetry operations.
Ambiguous space group information in source file.
Universitas Sumatera Utara
LAMPIRAN 6
KURVA BH MAX
Kurva BH-Max 97 %wt BaFe12O19 + 3 %wt FeB
BH Max
Aditif FeB
(%wt)
bHc
(Oe)
B
(G)
BH Max
(MGOe)
3
-175
450
0,07
Kurva BH-Max 91 %wt BaFe12O19 + 9 %wt FeB
BH Max
Aditif FeB
(%wt)
9
bHc
B
(Oe)
(G)
-279
650
BH Max
(MGOe)
0,18
Universitas Sumatera Utara
GAMBAR ALAT DAN BAHAN
Bahan Barium Heksaferit
Mortar dan Alu
Ayakan 200 Mesh
Bahan FeB
Spatula
Cawan Perahu
Universitas Sumatera Utara
Planetary Ball Mill
High Energy Milling
Bola-bola keramik
Jar mill
Beaker glass
Neraca digital 2 digit
Piknometer
Oven
Universitas Sumatera Utara
Optical Microscope
Fiber Glass Vacuum Desicator
Aquades
Vakum
Toluene
Alat XRD
Universitas Sumatera Utara
LAMPIRAN 2
PENGUKURAN TRUE DENSITY
Perhitugan True Density serbuk sampel uji
Dimana: m1 = massa piknometer kosong
m2 = massa piknometer + aquades
m3 = massa piknometer + serbuk
m4 = massa piknometer + serbuk + aquades
1. TRUE DENSITY BaFe12O19
m1
14.09
14.1
14.1
m2
23.79
23.83
23.82
m1
14.1
14.09
14.09
m2
23.83
23.79
23.78
m1
14.09
14.09
14.1
m2
23.79
23.79
23.82
T Milling = 12 jam
m3
m4
ρ (g/cm3)
15.09
24.59
4.98
15.09
24.61
4.70
15.1
24.61
4.74
3
Rata-rata = 4,81 g/cm
T Milling = 24 jam
m3
m4
ρ (g/cm3)
15.09
24.61
4.70
15.09
24.59
4.98
15.09
24.59
5.24
3
Rata-rata = 4,97 g/cm
T Milling = 36 jam
m3
m4
ρ (g/cm3)
15.09
24.59
4.98
15.09
24.58
4.74
15.1
24.61
4.74
3
Rata-rata = 4,82 g/cm
2. TRUE DENSITY BaFe12O19 – FeB sebelum Annealing
m1
28.756
28.756
28.756
m2
78.415
78.415
78.415
m3
29.757
29.756
29.757
m4
79.218
79.22
79.223
ρ (g/cm3)
5.04
5.11
5.17
Universitas Sumatera Utara
3. TRUE DENSITY BaFe12O19 – FeB setelah Annealing
Aditif FeB
3
6
9
Aditif FeB
3
6
9
Aditif FeB
3
6
9
m1
28.756
28.756
28.756
28.756
28.756
28.756
28.756
28.756
28.756
T annealing = 1000 oC
m2
m3
m4
(g/cm3)
78.415 29.757 79.226
5.25
78.415 29.757 79.225
5.23
78.415 29.757 79.227
5.28
78.415 29.757 79.224
5.20
78.415 29.757 79.225
5.23
78.415 29.757 79.225
5.23
78.415 29.757 79.214
4.94
78.415 29.756 79.212
4.91
78.415 29.757 79.215
4.97
m1
28.756
28.756
28.756
28.756
28.756
28.756
28.756
28.756
28.756
T annealing = 1100 oC
m2
m3
m4
(g/cm3)
78.415 29.757 79.229
5.34
78.415 29.757 79.225
5.23
78.415 29.757 79.233
5.45
78.415 29.757 79.227
5.28
78.415 29.757 79.229
5.34
78.415 29.757 79.23
5.37
78.415 29.757 79.226
5.25
78.415 29.756 79.225
5.25
78.415 29.757 79.226
5.25
m1
28.756
28.756
28.756
28.756
28.756
28.756
28.756
28.756
28.756
T annealing = 1200 oC
m2
m3
m4
(g/cm3)
78.415 29.757 79.234
5.48
78.415 29.757 79.236
5.54
78.415 29.757 79.238
5.61
78.415 29.757 79.226
5.25
78.415 29.757 79.229
5.34
78.415 29.757 79.232
5.42
78.415 29.757 79.226
5.25
78.415 29.756 79.227
5.30
78.415 29.757 79.226
5.25
Rata-rata
5.25 g/cm
3
5.22 g/cm3
4.94 g/cm3
Rata-rata
5.34 g/cm3
5.33 g/cm3
5.25 g/cm3
Rata-rata
5.54 g/cm3
5.34 g/cm3
5.27 g/cm3
Universitas Sumatera Utara
LAMPIRAN 3
HASIL Analisis X-RAY DIFFRACTION
a) Barium Heksaferit
b) FeB
Universitas Sumatera Utara
Hasil XRD 97 % BaFe12O19 – 3 % FeB setelah Annealing 1200 oC
T-Cal 1200_Theta_2-Theta.rawFeB 3%
Sample name : T-Cal 1200
Comment :
IS=RS1=2;RS2=1
Date : 2016/04/27
13:18:02
Operator :
X-Ray : 40 kV , 30 mA
Wavelength :CuKa /
1.541862 A
Goniometer :
Base att. config. :
Attachment :
Detector : SC-70
Memo :
Optics attribute :
Scan mode :
CONTINUOUS
Scan speed / Duration
time : 4.0000 deg./min.
Step width : 0.0200 deg.
Scan axis : 2Theta/Theta
Scan range : 10.0000 90.0000 deg.
2-Theta :
Omega :
Chi :
Phi :
2-ThetaChi :
CBO selection slit :
Incident parallel slit :
Incident slit : 2.000deg
Length limiting slit :
Receiving slit # 1 :
2.000deg
Filter :Cu_K-beta
Receiving optical device :
Receiving parallel slit :
Receiving slit # 2 :
1.000mm
Attenuator :
Diffrected beam mono. :
None Monochromatorslit :
Universitas Sumatera Utara
Hasil XRD 91 % BaFe12O19 – 9 % FeB setelah Annealing 1200 oC
T-Cal 1200_Theta_2-Theta.raw FeB 9%
Sample name : T-Cal 1200
Comment :
IS=RS1=2;RS2=1
Date : 2016/04/27
13:18:02
Operator :
X-Ray : 40 kV , 30 mA
Wavelength :CuKa /
1.541862 A
Goniometer :
Base att. config. :
Attachment :
Detector : SC-70
Memo :
Optics attribute :
Scan mode :
CONTINUOUS
Scan speed / Duration
time : 4.0000 deg./min.
Step width : 0.0200 deg.
Scan axis : 2Theta/Theta
Scan range : 10.0000 90.0000 deg.
2-Theta :
Omega :
Chi :
Phi :
2-ThetaChi :
CBO selection slit :
Incident parallel slit :
Incident slit : 2.000deg
Length limiting slit :
Receiving slit # 1 :
2.000deg
Filter :Cu_K-beta
Receiving optical device :
Receiving parallel slit :
Receiving slit # 2 :
1.000mm
Attenuator :
Diffrected beam mono. :
None
Universitas Sumatera Utara
LAMPIRAN 4
SKEMA ANNEALING
Pada temperatur annealing 1000 oC, t hold = 2 jam
Temperatur
Waktu
(menit)
Annealing
(⁰C)
0
25
57
600
117
600
157
1000
277
1000
374
25
Skema Annealing
120 Menit
1000
Suhu (⁰C)
800
600
400
200
0
0
100
200
Waktu (menit)
300
400
Universitas Sumatera Utara
Pada temperatur annealing 1100 oC, t hold = 2 jam
Temperatur
Waktu
Annealing
(menit)
(C)
0
25
57
600
117
600
167
1100
287
1100
394
25
Skema Annealing
120 Menit
1100
Suhu ( C)
900
700
60 Menit
500
300
100
0
100
200
300
400
Waktu (h)
Universitas Sumatera Utara
Pada temperatur annealing 1200 oC, t hold = 2 jam
Temperatur
Waktu
Annealing
(menit)
(C)
0
25
57
600
117
600
177
1200
297
1200
414
25
Skema Annealing
1200
Suhu (C)
1000
800
600
400
200
0
0
100
200
300
400
500
Waktu (menit)
Universitas Sumatera Utara
LAMPIRAN 5
PARAMETER KISI
Entry # 96-100-8329
Phase classification
Name
Barium dodecairon(III) oxide
Formula
BaFe12O19
I/Ic
2.880000
Sample
1008328
Name
Quality
C (calculated)
References
Publication
Bibliography
Collomb A, Wolfers P, Obradors X, "Neutron diffraction studies of some
hexagonal ferrites: BaFe~12~O~19~, BaMg~2~-W and BaCo~2~-W", Journal
of Magnetism and Magnetic Materials 62, 57-67 (1986)
Origin of data
Source of
COD (Crystallography Open Database)
entry
Link to orig.
1008328
entry
Crystal structure
Crystallographic data
Space group
P 63/m m c (194)
Crystal
Hexagonal
system
Cell
a= 5.8650 Å c= 23.0990 Å
parameters
Z
2
Element Oxid.
Atom
x
y
coordinates
Ba
2.0 0.667 0.333
Fe
3.0 0.000 0.000
Fe
3.0 0.000 0.000
Fe
3.0 0.333 0.667
Fe
3.0 0.333 0.667
Fe
3.0 0.167 0.333
O
-2.0 0.000 0.000
O
-2.0 0.333 0.667
O
-2.0 0.188 0.376
O
-2.0 0.159 0.318
O
-2.0 0.500 1.000
z
0.250
0.000
0.250
0.028
0.190
-0.108
0.152
-0.056
0.250
0.052
0.149
Bi
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Focc
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Diffraction data
Diffraction lines
d [Å]
11.5495
5.7748
5.0792
4.9607
4.6495
4.2398
3.8498
3.8139
3.4176
3.0681
Int.
h
5.5 0
0.8 0
0.1 1
53.3 1
111.6 0
0.3 0
103.6 0
28.4 0
5.5 0
11.0 0
k
0
0
0
0
1
1
0
1
1
1
l
2
4
0
1
2
3
6
4
5
6
Mult.
2
2
6
12
12
12
2
12
12
12
Universitas Sumatera Utara
2.9325
2.8874
2.8423
2.7672
2.7405
2.6147
2.5396
2.5244
2.5101
2.4804
2.4758
2.4118
2.3328
2.3247
2.3099
2.2907
2.2255
2.1920
2.1199
2.1027
2.0575
2.0126
1.9406
1.9313
1.9249
1.9198
1.9132
1.9069
1.8938
1.8627
1.8217
1.8146
1.8052
1.8000
1.7728
1.7180
1.7088
1.7073
1.6931
1.6885
1.6772
1.6752
1.6594
1.6536
1.6499
1.6247
1.6183
1.6092
1.5987
1.5897
1.5692
1.5498
1.5373
1.5341
1.5064
1.4764
1.4737
1.4662
1.4605
1.4559
1.4546
1.4437
1.4404
1.4380
455.1
150.4
91.5
905.5
0.0
1000.0
94.4
61.7
82.4
12.3
0.0
469.1
25.6
1.8
1.9
17.5
272.5
0.0
170.5
14.5
7.1
4.3
48.3
0.0
1.4
0.0
14.1
4.9
5.1
3.6
3.0
34.8
66.6
7.8
3.3
5.3
31.3
0.0
73.3
0.3
3.2
16.4
360.3
1.3
63.4
192.7
394.4
41.6
48.9
0.0
5.4
5.4
12.8
29.4
0.8
7.5
13.2
389.9
2.3
25.1
0.3
5.8
0.0
16.2
1
0
1
0
1
1
2
2
0
2
1
0
1
0
0
0
0
1
0
0
1
0
0
1
0
2
1
0
1
1
1
1
0
0
1
1
0
1
3
3
0
3
1
3
0
0
0
1
1
0
0
0
1
0
0
1
0
2
0
0
2
0
2
1
1 0
0 8
1 2
1 7
1 3
1 4
0 0
0 1
1 8
0 2
1 5
2 3
1 6
2 4
0 10
1 9
2 5
1 7
2 6
1 10
1 8
2 7
1 11
1 9
0 12
1 0
2 1
2 8
2 2
2 3
2 4
1 10
2 9
1 12
2 5
2 6
2 10
1 11
0 0
0 1
1 13
0 2
2 7
0 3
0 14
3 4
2 11
1 12
2 8
3 5
1 14
3 6
2 9
2 12
3 7
2 10
1 15
2 0
3 8
2 13
2 2
0 16
2 3
1 14
6
2
12
12
12
12
6
12
12
12
12
12
12
12
2
12
12
12
12
12
12
12
12
12
2
12
24
12
24
24
24
12
12
12
24
24
12
12
6
12
12
12
24
12
2
12
12
12
24
12
12
12
24
12
12
24
12
6
12
12
12
2
12
12
Universitas Sumatera Utara
1.4212
1.4169
1.4133
1.4087
1.4061
1.3984
1.3975
1.3887
1.3857
1.3836
1.3702
1.3686
1.3655
1.3634
1.3593
1.3475
1.3399
1.3229
1.3180
1.3168
1.3126
1.3073
1.3040
1.2956
1.2952
1.2833
1.2731
1.2713
1.2698
1.2679
1.2661
1.2622
1.2551
1.2529
1.2513
1.2442
1.2402
1.2379
1.2349
1.2257
1.2244
1.2059
1.2027
1.2022
1.2012
1.1981
1.1851
1.1823
1.1816
1.1756
1.1699
1.1664
1.1653
1.1638
1.1624
1.1594
1.1550
1.1538
1.1521
1.1454
1.1422
1.1392
1.1381
1.1368
0.0
33.4
0.2
0.1
4.9
5.9
0.0
0.7
0.7
94.9
20.3
2.9
11.4
0.0
8.6
1.9
0.0
0.6
0.1
0.1
3.2
54.9
5.0
124.7
27.7
0.0
0.0
16.0
7.6
5.7
11.2
0.4
1.5
42.8
3.2
19.8
0.9
0.0
5.6
0.3
21.7
14.2
4.2
0.0
13.0
17.0
0.2
0.1
7.4
53.4
16.0
1.3
0.0
1.7
0.3
4.7
13.9
0.8
0.1
0.5
1.9
0.0
9.8
1.8
2
1
0
3
1
1
2
0
1
0
2
1
0
1
1
1
2
1
0
0
0
2
1
1
1
0
2
0
4
4
1
4
0
4
1
0
4
2
1
0
0
0
1
2
1
0
0
0
0
1
1
2
3
2
0
2
0
1
2
0
2
0
0
1
2 4
2 11
3 9
1 0
3 1
3 2
2 5
1 16
3 3
2 14
2 6
3 4
3 10
1 15
2 12
3 5
2 7
3 6
3 11
2 15
1 17
2 8
2 13
3 7
1 16
0 18
2 9
3 12
0 0
0 1
3 8
0 2
2 16
0 3
2 14
1 18
0 4
2 10
3 9
3 13
4 5
4 6
3 10
2 11
2 15
2 17
4 7
1 19
3 14
1 18
3 11
2 12
2 0
3 1
4 8
3 2
0 20
2 16
3 3
2 18
3 4
3 15
4 9
3 12
12
24
12
12
24
24
12
12
24
12
12
24
12
12
24
24
12
24
12
12
12
12
24
24
12
2
12
12
6
12
24
12
12
12
24
12
12
12
24
12
12
12
24
12
24
12
12
12
12
12
24
12
12
24
12
24
2
24
24
12
24
12
12
24
Universitas Sumatera Utara
1.1299
1.1262
1.1153
1.1128
1.1091
1.1084
1.1071
1.1039
1.1033
1.0988
1.0985
1.0971
1.0966
1.0960
1.0885
1.0866
1.0806
1.0778
1.0750
1.0746
1.0713
1.0669
1.0651
1.0619
1.0610
1.0600
1.0597
1.0513
1.0507
1.0500
1.0404
1.0394
1.0348
1.0331
1.0299
1.0287
1.0282
1.0271
1.0227
1.0189
1.0175
1.0158
1.0149
1.0119
1.0093
1.0083
1.0071
1.0063
0.8
3.0
0.1
4.9
1.9
29.1
0.1
2.2
8.0
59.8
14.5
0.3
6.3
73.1
81.8
74.8
3.9
0.0
15.1
2.5
2.9
17.6
1.2
0.0
2.6
5.9
0.1
0.1
0.2
6.1
2.5
8.7
2.1
5.5
0.0
9.3
0.4
0.0
33.2
9.0
0.1
0.0
1.0
0.1
0.1
0.2
0.5
26.6
2
0
2
0
1
4
1
1
1
2
0
1
0
2
1
0
2
1
0
1
1
1
1
2
2
0
0
0
1
0
2
1
1
0
1
2
0
1
0
2
1
5
5
5
0
1
5
0
3 5
1 20
3 6
4 10
2 17
1 0
4 1
3 13
4 2
3 7
3 16
4 3
2 19
2 14
4 4
4 11
3 8
4 5
1 21
1 20
3 14
2 18
4 6
2 15
3 9
4 12
3 17
2 20
4 7
0 22
3 10
3 15
4 8
4 13
1 21
2 16
1 22
2 19
3 18
3 11
4 9
0 0
0 1
0 2
2 21
3 16
0 3
4 14
24
12
24
12
24
12
24
24
24
24
12
24
12
12
24
12
24
24
12
12
24
24
24
12
24
12
12
12
24
2
24
24
24
12
12
12
12
24
12
24
24
6
12
12
12
24
12
12
Experimental
Physical Properties
Calc. density 5.36300 g/cm³
Remarks
Remarks
Comments
- Diffraction pattern calculated by Match!.
- I/Ic calculated by Match!.
Universitas Sumatera Utara
Entry # 96-901-5504
Phase classification
Name
Mineral
Hematite
Name
Formula
Fe2O3
I/Ic
4.030000
Sample
9015503
Name
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Finger L. W., Hazen R. M., "Crystal structure and isothermal compression of
Fe2O3, Cr2O3, and V2O3 to 50 kbars Note: P = 52.4 kbar", Journal of Applied
Physics 51, 5362-5367 (1980)
COD (Crystallography Open Database)
9015503
Crystal structure
Crystallographic data
Space group
R -3 c (167)
Crystal
trigonal (hexagonal axes)
system
Cell
a= 5.0020 Å c= 13.6202 Å
parameters
Element Oxid.
Bi
Focc
Atom
x
y
z
coordinates
Fe
0.000 0.000 0.355 0.460000 1.000000
O
0.311 0.000 0.250 0.220000 1.000000
Diffraction data
Diffraction lines
d [Å]
3.6551
2.6770
2.5010
2.2700
2.1906
2.0641
1.8275
1.6809
1.6256
1.5919
1.5845
1.4756
1.4440
1.4033
1.3385
1.2993
1.2948
1.2528
Int.
h
270.4 0
1000.0 1
722.5 1
19.9 0
184.6 1
21.8 2
360.0 0
450.4 1
3.4 2
24.6 1
80.1 0
297.0 2
299.1 3
1.7 1
30.2 2
105.0 1
18.4 1
1.0 2
k l
1 2
0 4
1 0
0 6
1 3
0 2
2 4
1 6
1 1
2 2
1 8
1 4
0 0
2 5
0 8
0 10
1 9
1 7
Mult.
6
6
6
2
12
6
6
12
12
12
6
12
6
12
6
6
12
12
Universitas Sumatera Utara
1.2505
1.2184
1.2056
1.1968
1.1832
1.1801
1.1530
1.1350
1.1330
1.0993
1.0953
1.0695
1.0471
1.0336
1.0320
1.0223
67.2
22.6
11.7
0.5
14.8
41.8
56.4
1.4
87.4
0.3
81.5
7.3
88.9
5.6
28.9
0.3
2
0
2
1
3
1
0
0
1
3
2
0
2
1
4
1
2 0
3 6
2 3
3 1
1 2
2 8
2 10
0 12
3 4
1 5
2 6
4 2
1 10
1 12
0 4
3 7
6
6
12
12
12
12
6
2
12
12
12
6
12
12
6
12
Experimental
Physical Properties
Calc. density 5.39100 g/cm³
Remarks
Remarks
Comments
-
Synthetic
Diffraction pattern calculated by Match!.
I/Ic calculated by Match!.
Space group has been derived from given symmetry operations.
Ambiguous space group information in source file.
Universitas Sumatera Utara
Entry # 96-900-8945
Phase classification
Name
Formula
BFe
I/Ic
2.610000
Sample Name 9008944
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Wyckoff R. W. G., "Second edition. Interscience Publishers, New York, New
York", Crystal Structures 1, 85-237 (1963)
COD (Crystallography Open Database)
9008944
Crystal structure
Crystallographic data
Space group
P b n m (62)
Crystal
orthorhombic
system
Cell
a= 4.0530 Å b= 5.4950 Å c= 2.9460 Å
parameters
Element Oxid.
Bi
Focc
Atom
x
y
z
coordinates
Fe
0.125 0.180 0.250 1.000000 1.000000
B
0.610 0.040 0.250 1.000000 1.000000
Diffraction data
Diffraction lines
d [Å]
3.2617
2.7475
2.3830
2.2742
2.1863
2.0265
2.0093
1.9013
1.8002
1.6691
1.6309
1.5975
1.4730
1.4522
1.4268
1.3737
1.3589
1.3425
1.3119
1.3010
1.2982
1.2450
Int.
h
157.9 1
358.9 0
679.2 1
383.8 1
1000.0 1
0.3 2
680.6 0
707.8 2
354.7 1
279.0 1
0.2 2
239.9 2
185.3 0
31.7 1
0.1 2
1.7 0
6.0 2
18.0 1
10.9 3
100.6 1
49.0 0
112.0 0
k
1
2
0
2
1
0
2
1
2
3
2
1
0
3
2
4
3
1
1
4
2
4
l Mult.
0 4
0 2
1 4
0 4
1 8
0 2
1 4
0 4
1 8
0 4
0 4
1 8
2 2
1 8
1 8
0 2
0 4
2 8
0 4
0 4
2 4
1 4
Universitas Sumatera Utara
1.2363
1.2339
1.2280
1.2124
1.1985
1.1915
1.1902
1.1644
1.1371
1.1211
1.1044
1.0931
1.0872
1.0608
1.0607
1.0200
1.0132
72.3
216.4
49.2
31.5
96.4
0.1
7.3
191.9
0.0
56.8
102.4
0.1
45.1
0.1
22.8
6.7
42.8
1
2
3
3
3
2
1
2
2
3
1
2
3
2
1
3
4
2
3
0
2
1
0
4
1
4
2
3
2
3
4
5
3
0
2
1
1
0
1
2
1
2
0
1
2
2
0
1
0
1
0
8
8
4
4
8
4
8
8
4
8
8
8
4
8
4
8
2
Experimental
Physical Properties
Calc. density
6.74800 g/cm³
Remarks
Remarks
Comments
- Diffraction pattern calculated by Match!.
- I/Ic calculated by Match!.
Universitas Sumatera Utara
Entry # 96-100-8327
Phase classification
Name
Barium dodecairon(III) oxide
Formula
BaFe12O19
I/Ic
2.860000
Sample
1008326
Name
Quality
C (calculated)
References
Publication
Bibliography
Collomb A, Wolfers P, Obradors X, "Neutron diffraction studies of some
hexagonal ferrites: BaFe~12~O~19~, BaMg~2~-W and BaCo~2~-W", Journal
of Magnetism and Magnetic Materials 62, 57-67 (1986)
Origin of data
Source of
COD (Crystallography Open Database)
entry
Link to orig.
1008326
entry
Crystal structure
Crystallographic data
Space group
P 63/m m c (194)
Crystal
hexagonal
system
Cell
a= 5.9290 Å c= 23.4130 Å
parameters
Z
2
Element Oxid.
Atom
x
y
coordinates
Ba
2.0 0.667 0.333
Fe
3.0 0.000 0.000
Fe
3.0 0.000 0.000
Fe
3.0 0.333 0.667
Fe
3.0 0.333 0.667
Fe
3.0 0.167 0.333
O
-2.0 0.000 0.000
O
-2.0 0.333 0.667
O
-2.0 0.183 0.366
O
-2.0 0.157 0.314
O
-2.0 0.503 1.006
z
0.250
0.000
0.261
0.026
0.190
-0.108
0.151
-0.056
0.250
0.052
0.149
Bi
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Focc
1.000000
1.000000
0.500000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Diffraction data
Diffraction lines
d [Å]
11.7065
5.8533
5.1347
5.0155
4.7022
4.2895
3.9022
3.8600
3.4599
3.1068
2.9645
2.9410
2.9266
2.8738
2.8026
Int.
h
3.5 0
0.6 0
0.5 1
65.9 1
112.3 0
0.0 0
94.9 0
30.3 0
7.3 0
11.7 0
455.3 1
0.0 1
151.7 0
87.6 1
904.7 0
k
0
0
0
0
1
1
0
1
1
1
1
1
0
1
1
l
2
4
0
1
2
3
6
4
5
6
0
1
8
2
7
Mult.
2
2
6
12
12
12
2
12
12
12
6
12
2
12
12
Universitas Sumatera Utara
2.7713
2.6446
2.5673
2.5520
2.5426
2.5077
2.5047
2.4388
2.3606
2.3511
2.3413
2.3206
2.2512
2.2185
2.1448
2.1303
2.0827
2.0366
1.9662
1.9553
1.9511
1.9407
1.9341
1.9300
1.9146
1.8834
1.8421
1.8374
1.8273
1.8239
1.7928
1.7377
1.7300
1.7290
1.7116
1.7070
1.6995
1.6935
1.6786
1.6724
1.6718
1.6428
1.6386
1.6298
1.6174
1.6075
1.5901
1.5674
1.5555
1.5534
1.5237
1.4942
1.4934
1.4822
1.4774
1.4744
1.4705
1.4633
1.4566
1.4562
1.4369
1.4341
1.4298
1.4241
0.0
1000.0
95.3
59.4
69.5
12.2
0.0
471.6
33.5
1.1
0.6
18.5
280.7
0.0
177.0
16.6
7.4
4.7
54.2
0.0
1.3
0.0
11.8
3.0
5.5
3.1
4.7
24.5
71.6
3.2
4.3
4.5
29.4
0.0
74.5
0.3
2.4
16.5
362.9
57.5
1.1
196.2
406.2
38.4
42.8
0.1
8.6
7.0
11.0
21.7
0.6
10.4
15.7
399.1
2.6
28.7
0.4
4.4
9.4
0.0
0.0
33.9
0.2
0.0
1
1
2
2
0
2
1
0
1
0
0
0
0
1
0
0
1
0
0
1
0
2
1
0
1
1
1
1
0
0
1
1
0
1
3
3
0
3
1
0
3
0
0
1
1
0
0
0
1
0
0
1
0
2
0
0
2
0
1
2
2
1
0
3
1 3
1 4
0 0
0 1
1 8
0 2
1 5
2 3
1 6
2 4
0 10
1 9
2 5
1 7
2 6
1 10
1 8
2 7
1 11
1 9
0 12
1 0
2 1
2 8
2 2
2 3
2 4
1 10
2 9
1 12
2 5
2 6
2 10
1 11
0 0
0 1
1 13
0 2
2 7
0 14
0 3
3 4
2 11
1 12
2 8
3 5
1 14
3 6
2 9
2 12
3 7
2 10
1 15
2 0
3 8
2 13
2 2
0 16
1 14
2 3
2 4
2 11
3 9
1 0
12
12
6
12
12
12
12
12
12
12
2
12
12
12
12
12
12
12
12
12
2
12
24
12
24
24
24
12
12
12
24
24
12
12
6
12
12
12
24
2
12
12
12
12
24
12
12
12
24
12
12
24
12
6
12
12
12
2
12
12
12
24
12
12
Universitas Sumatera Utara
1.4215
1.4137
1.4131
1.4073
1.4013
1.4010
1.3857
1.3837
1.3817
1.3811
1.3759
1.3625
1.3551
1.3378
1.3338
1.3337
1.3302
1.3223
1.3201
1.3122
1.3103
1.3007
1.2879
1.2867
1.2837
1.2817
1.2805
1.2760
1.2713
1.2669
1.2666
1.2609
1.2539
1.2524
1.2492
1.2407
1.2380
1.2194
1.2167
1.2164
1.2163
1.2136
1.1984
1.1982
1.1962
1.1911
1.1836
1.1803
1.1780
1.1765
1.1756
1.1721
1.1707
1.1684
1.1648
1.1603
1.1548
1.1533
1.1511
1.1503
1.1424
1.1414
1.1277
1.1256
5.1
5.8
0.0
0.0
108.0
0.4
19.5
3.1
8.2
0.0
4.5
2.1
0.0
0.7
0.1
0.0
4.7
57.0
4.2
24.1
123.4
0.1
0.0
15.1
8.0
5.4
9.7
0.4
3.3
5.7
44.0
26.6
0.7
0.3
5.5
0.3
22.7
15.2
4.7
0.0
15.4
15.6
0.2
0.0
4.4
45.4
17.1
1.4
0.0
2.3
0.1
4.8
12.2
0.0
0.0
0.0
1.8
0.0
10.6
0.7
0.8
1.4
0.2
4.4
1
1
2
0
0
1
2
1
0
1
1
1
2
1
0
0
0
2
1
1
1
0
2
0
4
4
1
4
0
1
4
0
4
2
1
0
0
0
1
2
1
0
0
0
0
1
1
2
3
2
0
2
0
1
2
0
2
0
0
1
2
0
2
0
3 1
3 2
2 5
1 16
2 14
3 3
2 6
3 4
3 10
1 15
2 12
3 5
2 7
3 6
3 11
2 15
1 17
2 8
2 13
1 16
3 7
0 18
2 9
3 12
0 0
0 1
3 8
0 2
2 16
2 14
0 3
1 18
0 4
2 10
3 9
3 13
4 5
4 6
3 10
2 11
2 15
2 17
4 7
1 19
3 14
1 18
3 11
2 12
2 0
3 1
4 8
3 2
0 20
2 16
3 3
2 18
3 4
3 15
4 9
3 12
3 5
1 20
3 6
4 10
24
24
12
12
12
24
12
24
12
12
24
24
12
24
12
12
12
12
24
12
24
2
12
12
6
12
24
12
12
24
12
12
12
12
24
12
12
12
24
12
24
12
12
12
12
12
24
12
12
24
12
24
2
24
24
12
24
12
12
24
24
12
24
12
Universitas Sumatera Utara
1.1232
1.1205
1.1192
1.1171
1.1154
1.1122
1.1111
1.1109
1.1093
1.1091
1.1005
1.0992
1.0928
1.0897
1.0895
1.0888
1.0842
1.0805
1.0770
1.0748
1.0731
1.0730
1.0724
1.0651
1.0642
1.0624
1.0523
1.0520
1.0464
1.0453
1.0435
1.0421
1.0413
1.0403
1.0356
1.0307
1.0291
1.0269
1.0259
1.0230
1.0226
1.0206
1.0183
1.0182
1.0115
1.0107
1.0084
3.0
29.3
0.1
1.6
7.6
12.6
59.5
7.6
66.4
0.3
81.9
76.6
3.0
0.0
13.8
0.6
4.3
24.2
1.8
0.0
3.0
0.1
4.1
0.1
4.9
0.2
2.5
9.7
2.0
6.1
0.0
2.1
7.1
0.1
28.0
10.4
0.1
0.0
0.8
0.1
0.3
0.0
29.8
0.6
0.3
6.7
0.1
1
4
1
1
1
0
2
0
2
1
1
0
2
1
0
1
1
1
1
2
2
0
0
0
0
1
2
1
1
0
1
0
2
1
0
2
1
5
5
5
0
1
0
5
5
1
2
2 17
1 0
4 1
3 13
4 2
3 16
3 7
2 19
2 14
4 3
4 4
4 11
3 8
4 5
1 21
1 20
3 14
2 18
4 6
2 15
3 9
3 17
4 12
2 20
0 22
4 7
3 10
3 15
4 8
4 13
1 21
1 22
2 16
2 19
3 18
3 11
4 9
0 0
0 1
0 2
2 21
3 16
4 14
0 3
0 4
4 10
3 12
24
12
24
24
24
12
24
12
12
24
24
12
24
24
12
12
24
24
24
12
24
12
12
12
2
24
24
24
24
12
12
12
12
24
12
24
24
6
12
12
12
24
12
12
12
24
24
Experimental
Physical Properties
Calc. density 5.17900 g/cm³
Remarks
Remarks
Comments
- Diffraction pattern calculated by Match!.
- I/Ic calculated by Match!.
Universitas Sumatera Utara
Entry # 96-101-1337
Phase classification
Name
Iron boride (1/1)
Formula
BFe
I/Ic
3.740000
Sample Name 1011336
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Hendricks S. B., Kosting P. R., "The crystal structure of Fe2P, Fe2N, Fe3N and
FeB", Zeitschrift fur Kristallographie74, 511-533 (1930)
COD (Crystallography Open Database)
1011336
Crystal structure
Crystallographic data
Space group
P n a m (62)
Crystal
orthorhombic
system
Cell
a= 4.0530 Å b= 5.4950 Å c= 2.9460 Å
parameters
Z
4
Element Oxid.
Bi
Focc
Atom
x
y
z
coordinates
Fe
3.0 0.115 0.175 0.250 1.000000 1.000000
B
-3.0 0.700 -0.130 0.250 1.000000 1.000000
Diffraction data
Diffraction lines
d [Å]
3.2617
2.7475
2.5964
2.2742
2.1863
2.0265
1.9013
1.8002
1.6696
1.6691
1.6309
1.5975
1.5555
1.4730
1.4522
1.4268
1.3737
1.3589
1.3425
1.3119
1.3010
1.2982
1.2363
1.2339
1.2124
1.1985
Int.
h
295.3 1
337.1 0
1000.0 0
454.7 1
87.1 1
0.2 2
391.9 2
383.2 1
389.6 2
175.4 1
1.4 2
19.0 2
13.9 0
129.4 0
125.4 1
125.0 2
14.0 0
5.9 2
27.7 1
4.5 3
50.5 1
42.8 0
83.1 1
0.4 2
32.2 3
31.1 3
k
1
2
1
2
1
0
1
2
0
3
2
1
3
0
3
2
4
3
1
1
4
2
2
3
2
1
l Mult.
0 4
0 2
1 4
0 4
1 8
0 2
0 4
1 8
1 4
0 4
0 4
1 8
1 4
2 2
1 8
1 8
0 2
0 4
2 8
0 4
0 4
2 4
2 8
1 8
0 4
1 8
Universitas Sumatera Utara
1.1915
1.1902
1.1644
1.1371
1.1211
1.1044
1.0931
1.0872
1.0608
1.0607
1.0297
1.0200
1.0132
0.1
86.4
105.7
0.3
41.0
63.2
0.5
13.4
15.9
16.7
17.9
74.2
20.4
2
1
2
2
3
1
2
3
2
1
0
3
4
0
4
1
4
2
3
2
3
4
5
5
3
0
2
1
2
0
1
2
2
0
1
0
1
1
0
4
8
8
4
8
8
8
4
8
4
4
8
2
Experimental
Physical Properties
Calc. density
6.74800 g/cm³
Remarks
Remarks
Comments
- Diffraction pattern calculated by Match!.
- I/Ic calculated by Match!.
Universitas Sumatera Utara
Entry # 96-901-5066
Phase classification
Name
Mineral
Hematite
Name
Formula
Fe2O3
I/Ic
4.010000
Sample
9015065
Name
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Finger L. W., Hazen R. M., "Crystal structure and isothermal compression of
Fe2O3, Cr2O3, and V2O3 to 50 kbars Note: P = 15.4 kbar", Journal of Applied
Physics 51, 5362-5367 (1980)
COD (Crystallography Open Database)
9015065
Crystal structure
Crystallographic data
Space group
R -3 c (167)
Crystal
trigonal (hexagonal axes)
system
Cell
a= 5.0249 Å c= 13.7163 Å
parameters
Element Oxid.
Bi
Focc
Atom
x
y
z
coordinates
Fe
0.000 0.000 0.355 0.368000 1.000000
O
0.306 0.000 0.250 0.479000 1.000000
Diffraction data
Diffraction lines
d [Å]
3.6744
2.6934
2.5124
2.2861
2.2019
2.0740
1.8372
1.6909
1.6331
1.5994
1.5952
1.4830
1.4506
1.4107
1.3467
1.3082
1.3030
1.2598
1.2562
1.2248
1.2113
1.2023
1.1887
Int.
h
281.0 0
1000.0 1
736.6 1
20.4 0
177.9 1
19.6 2
374.8 0
448.8 1
4.6 2
23.6 1
86.3 0
309.9 2
297.4 3
2.3 1
31.6 2
109.4 1
17.0 1
1.3 2
71.5 2
26.1 0
10.0 2
0.5 1
15.8 3
k l
1 2
0 4
1 0
0 6
1 3
0 2
2 4
1 6
1 1
2 2
1 8
1 4
0 0
2 5
0 8
0 10
1 9
1 7
2 0
3 6
2 3
3 1
1 2
Mult.
6
6
6
2
12
6
6
12
12
12
6
12
6
12
6
6
12
12
6
6
12
12
12
Universitas Sumatera Utara
1.1869
1.1603
1.1430
1.1385
1.1047
1.1009
1.0745
1.0534
1.0404
1.0370
1.0276
44.2
57.8
1.1
90.0
0.4
81.0
8.0
91.5
5.9
29.3
0.3
1
0
0
1
3
2
0
2
1
4
1
2 8
2 10
0 12
3 4
1 5
2 6
4 2
1 10
1 12
0 4
3 7
12
6
2
12
12
12
6
12
12
6
12
Experimental
Physical Properties
Calc. density 5.30400 g/cm³
Remarks
Remarks
Comments
-
Synthetic
Diffraction pattern calculated by Match!.
I/Ic calculated by Match!.
Space group has been derived from given symmetry operations.
Ambiguous space group information in source file.
Universitas Sumatera Utara
Entry # 96-100-8327
Phase classification
Name
Barium dodecairon(III) oxide
Formula
BaFe12O19
I/Ic
2.860000
Sample
1008326
Name
Quality
C (calculated)
References
Publication
Bibliography
Collomb A, Wolfers P, Obradors X, "Neutron diffraction studies of some
hexagonal ferrites: BaFe~12~O~19~, BaMg~2~-W and BaCo~2~-W", Journal
of Magnetism and Magnetic Materials 62, 57-67 (1986)
Origin of data
Source of
COD (Crystallography Open Database)
entry
Link to orig.
1008326
entry
Crystal structure
Crystallographic data
Space group
P 63/m m c (194)
Crystal
hexagonal
system
Cell
a= 5.9290 Å c= 23.4130 Å
parameters
Z
2
Element Oxid.
Atom
x
y
coordinates
Ba
2.0 0.667 0.333
Fe
3.0 0.000 0.000
Fe
3.0 0.000 0.000
Fe
3.0 0.333 0.667
Fe
3.0 0.333 0.667
Fe
3.0 0.167 0.333
O
-2.0 0.000 0.000
O
-2.0 0.333 0.667
O
-2.0 0.183 0.366
O
-2.0 0.157 0.314
O
-2.0 0.503 1.006
z
0.250
0.000
0.261
0.026
0.190
-0.108
0.151
-0.056
0.250
0.052
0.149
Bi
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Focc
1.000000
1.000000
0.500000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Diffraction data
Diffraction lines
d [Å]
11.7065
5.8533
5.1347
5.0155
4.7022
4.2895
3.9022
3.8600
3.4599
3.1068
2.9645
2.9410
2.9266
2.8738
2.8026
Int.
h
3.5 0
0.6 0
0.5 1
65.9 1
112.3 0
0.0 0
94.9 0
30.3 0
7.3 0
11.7 0
455.3 1
0.0 1
151.7 0
87.6 1
904.7 0
k
0
0
0
0
1
1
0
1
1
1
1
1
0
1
1
l
2
4
0
1
2
3
6
4
5
6
0
1
8
2
7
Mult.
2
2
6
12
12
12
2
12
12
12
6
12
2
12
12
Universitas Sumatera Utara
2.7713
2.6446
2.5673
2.5520
2.5426
2.5077
2.5047
2.4388
2.3606
2.3511
2.3413
2.3206
2.2512
2.2185
2.1448
2.1303
2.0827
2.0366
1.9662
1.9553
1.9511
1.9407
1.9341
1.9300
1.9146
1.8834
1.8421
1.8374
1.8273
1.8239
1.7928
1.7377
1.7300
1.7290
1.7116
1.7070
1.6995
1.6935
1.6786
1.6724
1.6718
1.6428
1.6386
1.6298
1.6174
1.6075
1.5901
1.5674
1.5555
1.5534
1.5237
1.4942
1.4934
1.4822
1.4774
1.4744
1.4705
1.4633
1.4566
1.4562
1.4369
1.4341
1.4298
1.4241
0.0
1000.0
95.3
59.4
69.5
12.2
0.0
471.6
33.5
1.1
0.6
18.5
280.7
0.0
177.0
16.6
7.4
4.7
54.2
0.0
1.3
0.0
11.8
3.0
5.5
3.1
4.7
24.5
71.6
3.2
4.3
4.5
29.4
0.0
74.5
0.3
2.4
16.5
362.9
57.5
1.1
196.2
406.2
38.4
42.8
0.1
8.6
7.0
11.0
21.7
0.6
10.4
15.7
399.1
2.6
28.7
0.4
4.4
9.4
0.0
0.0
33.9
0.2
0.0
1
1
2
2
0
2
1
0
1
0
0
0
0
1
0
0
1
0
0
1
0
2
1
0
1
1
1
1
0
0
1
1
0
1
3
3
0
3
1
0
3
0
0
1
1
0
0
0
1
0
0
1
0
2
0
0
2
0
1
2
2
1
0
3
1 3
1 4
0 0
0 1
1 8
0 2
1 5
2 3
1 6
2 4
0 10
1 9
2 5
1 7
2 6
1 10
1 8
2 7
1 11
1 9
0 12
1 0
2 1
2 8
2 2
2 3
2 4
1 10
2 9
1 12
2 5
2 6
2 10
1 11
0 0
0 1
1 13
0 2
2 7
0 14
0 3
3 4
2 11
1 12
2 8
3 5
1 14
3 6
2 9
2 12
3 7
2 10
1 15
2 0
3 8
2 13
2 2
0 16
1 14
2 3
2 4
2 11
3 9
1 0
12
12
6
12
12
12
12
12
12
12
2
12
12
12
12
12
12
12
12
12
2
12
24
12
24
24
24
12
12
12
24
24
12
12
6
12
12
12
24
2
12
12
12
12
24
12
12
12
24
12
12
24
12
6
12
12
12
2
12
12
12
24
12
12
Universitas Sumatera Utara
1.4215
1.4137
1.4131
1.4073
1.4013
1.4010
1.3857
1.3837
1.3817
1.3811
1.3759
1.3625
1.3551
1.3378
1.3338
1.3337
1.3302
1.3223
1.3201
1.3122
1.3103
1.3007
1.2879
1.2867
1.2837
1.2817
1.2805
1.2760
1.2713
1.2669
1.2666
1.2609
1.2539
1.2524
1.2492
1.2407
1.2380
1.2194
1.2167
1.2164
1.2163
1.2136
1.1984
1.1982
1.1962
1.1911
1.1836
1.1803
1.1780
1.1765
1.1756
1.1721
1.1707
1.1684
1.1648
1.1603
1.1548
1.1533
1.1511
1.1503
1.1424
1.1414
1.1277
1.1256
5.1
5.8
0.0
0.0
108.0
0.4
19.5
3.1
8.2
0.0
4.5
2.1
0.0
0.7
0.1
0.0
4.7
57.0
4.2
24.1
123.4
0.1
0.0
15.1
8.0
5.4
9.7
0.4
3.3
5.7
44.0
26.6
0.7
0.3
5.5
0.3
22.7
15.2
4.7
0.0
15.4
15.6
0.2
0.0
4.4
45.4
17.1
1.4
0.0
2.3
0.1
4.8
12.2
0.0
0.0
0.0
1.8
0.0
10.6
0.7
0.8
1.4
0.2
4.4
1
1
2
0
0
1
2
1
0
1
1
1
2
1
0
0
0
2
1
1
1
0
2
0
4
4
1
4
0
1
4
0
4
2
1
0
0
0
1
2
1
0
0
0
0
1
1
2
3
2
0
2
0
1
2
0
2
0
0
1
2
0
2
0
3 1
3 2
2 5
1 16
2 14
3 3
2 6
3 4
3 10
1 15
2 12
3 5
2 7
3 6
3 11
2 15
1 17
2 8
2 13
1 16
3 7
0 18
2 9
3 12
0 0
0 1
3 8
0 2
2 16
2 14
0 3
1 18
0 4
2 10
3 9
3 13
4 5
4 6
3 10
2 11
2 15
2 17
4 7
1 19
3 14
1 18
3 11
2 12
2 0
3 1
4 8
3 2
0 20
2 16
3 3
2 18
3 4
3 15
4 9
3 12
3 5
1 20
3 6
4 10
24
24
12
12
12
24
12
24
12
12
24
24
12
24
12
12
12
12
24
12
24
2
12
12
6
12
24
12
12
24
12
12
12
12
24
12
12
12
24
12
24
12
12
12
12
12
24
12
12
24
12
24
2
24
24
12
24
12
12
24
24
12
24
12
Universitas Sumatera Utara
1.1232
1.1205
1.1192
1.1171
1.1154
1.1122
1.1111
1.1109
1.1093
1.1091
1.1005
1.0992
1.0928
1.0897
1.0895
1.0888
1.0842
1.0805
1.0770
1.0748
1.0731
1.0730
1.0724
1.0651
1.0642
1.0624
1.0523
1.0520
1.0464
1.0453
1.0435
1.0421
1.0413
1.0403
1.0356
1.0307
1.0291
1.0269
1.0259
1.0230
1.0226
1.0206
1.0183
1.0182
1.0115
1.0107
1.0084
3.0
29.3
0.1
1.6
7.6
12.6
59.5
7.6
66.4
0.3
81.9
76.6
3.0
0.0
13.8
0.6
4.3
24.2
1.8
0.0
3.0
0.1
4.1
0.1
4.9
0.2
2.5
9.7
2.0
6.1
0.0
2.1
7.1
0.1
28.0
10.4
0.1
0.0
0.8
0.1
0.3
0.0
29.8
0.6
0.3
6.7
0.1
1
4
1
1
1
0
2
0
2
1
1
0
2
1
0
1
1
1
1
2
2
0
0
0
0
1
2
1
1
0
1
0
2
1
0
2
1
5
5
5
0
1
0
5
5
1
2
2 17
1 0
4 1
3 13
4 2
3 16
3 7
2 19
2 14
4 3
4 4
4 11
3 8
4 5
1 21
1 20
3 14
2 18
4 6
2 15
3 9
3 17
4 12
2 20
0 22
4 7
3 10
3 15
4 8
4 13
1 21
1 22
2 16
2 19
3 18
3 11
4 9
0 0
0 1
0 2
2 21
3 16
4 14
0 3
0 4
4 10
3 12
24
12
24
24
24
12
24
12
12
24
24
12
24
24
12
12
24
24
24
12
24
12
12
12
2
24
24
24
24
12
12
12
12
24
12
24
24
6
12
12
12
24
12
12
12
24
24
Experimental
Physical Properties
Calc. density 5.17900 g/cm³
Remarks
Remarks
Comments
- Diffraction pattern calculated by Match!.
- I/Ic calculated by Match!.
Universitas Sumatera Utara
Entry # 96-101-1337
Phase classification
Name
Iron boride (1/1)
Formula
BFe
I/Ic
3.740000
Sample Name 1011336
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Hendricks S. B., Kosting P. R., "The crystal structure of Fe2P, Fe2N, Fe3N and
FeB", Zeitschrift fur Kristallographie74, 511-533 (1930)
COD (Crystallography Open Database)
1011336
Crystal structure
Crystallographic data
Space group
P n a m (62)
Crystal
orthorhombic
system
Cell
a= 4.0530 Å b= 5.4950 Å c= 2.9460 Å
parameters
Z
4
Element Oxid.
Bi
Focc
Atom
x
y
z
coordinates
Fe
3.0 0.115 0.175 0.250 1.000000 1.000000
B
-3.0 0.700 -0.130 0.250 1.000000 1.000000
Diffraction data
Diffraction lines
d [Å]
3.2617
2.7475
2.5964
2.2742
2.1863
2.0265
1.9013
1.8002
1.6696
1.6691
1.6309
1.5975
1.5555
1.4730
1.4522
1.4268
1.3737
1.3589
1.3425
1.3119
1.3010
1.2982
1.2363
1.2339
1.2124
1.1985
Int.
h
295.3 1
337.1 0
1000.0 0
454.7 1
87.1 1
0.2 2
391.9 2
383.2 1
389.6 2
175.4 1
1.4 2
19.0 2
13.9 0
129.4 0
125.4 1
125.0 2
14.0 0
5.9 2
27.7 1
4.5 3
50.5 1
42.8 0
83.1 1
0.4 2
32.2 3
31.1 3
k
1
2
1
2
1
0
1
2
0
3
2
1
3
0
3
2
4
3
1
1
4
2
2
3
2
1
l Mult.
0 4
0 2
1 4
0 4
1 8
0 2
0 4
1 8
1 4
0 4
0 4
1 8
1 4
2 2
1 8
1 8
0 2
0 4
2 8
0 4
0 4
2 4
2 8
1 8
0 4
1 8
Universitas Sumatera Utara
1.1915
1.1902
1.1644
1.1371
1.1211
1.1044
1.0931
1.0872
1.0608
1.0607
1.0297
1.0200
1.0132
0.1
86.4
105.7
0.3
41.0
63.2
0.5
13.4
15.9
16.7
17.9
74.2
20.4
2
1
2
2
3
1
2
3
2
1
0
3
4
0
4
1
4
2
3
2
3
4
5
5
3
0
2
1
2
0
1
2
2
0
1
0
1
1
0
4
8
8
4
8
8
8
4
8
4
4
8
2
Experimental
Physical Properties
Calc. density
6.74800 g/cm³
Remarks
Remarks
Comments
- Diffraction pattern calculated by Match!.
- I/Ic calculated by Match!.
Universitas Sumatera Utara
Entry # 96-901-5965
Phase classification
Name
Mineral
Hematite
Name
Formula
Fe2O3
I/Ic
4.010000
Sample
9015964
Name
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Finger L. W., Hazen R. M., "Crystal structure and isothermal compression of
Fe2O3, Cr2O3, and V2O3 to 50 kbars Note: P = 0.001 kbar", Journal of Applied
Physics51, 5362-5367 (1980)
COD (Crystallography Open Database)
9015964
Crystal structure
Crystallographic data
Space group
R -3 c (167)
Crystal
trigonal (hexagonal axes)
system
Cell
a= 5.0346 Å c= 13.7473 Å
parameters
Element Oxid.
Bi
Focc
Atom
x
y
z
coordinates
Fe
0.000 0.000 0.355 0.319000 1.000000
O
0.306 0.000 0.250 0.400000 1.000000
Diffraction data
Diffraction lines
d [Å]
3.6818
2.6991
2.5173
2.2912
2.2063
2.0780
1.8409
1.6944
1.6362
1.6025
1.5987
1.4860
1.4534
1.4135
1.3496
1.3111
1.3059
1.2624
1.2586
1.2273
1.2137
1.2046
1.1910
Int.
h
286.1 0
1000.0 1
740.7 1
20.6 0
179.3 1
19.4 2
379.8 0
455.9 1
5.0 2
23.7 1
87.3 0
315.0 2
301.6 3
2.5 1
31.6 2
112.0 1
17.5 1
1.5 2
72.8 2
26.8 0
10.1 2
0.6 1
16.4 3
k l
1 2
0 4
1 0
0 6
1 3
0 2
2 4
1 6
1 1
2 2
1 8
1 4
0 0
2 5
0 8
0 10
1 9
1 7
2 0
3 6
2 3
3 1
1 2
Mult.
6
6
6
2
12
6
6
12
12
12
6
12
6
12
6
6
12
12
6
6
12
12
12
Universitas Sumatera Utara
1.1894
1.1628
1.1456
1.1407
1.1069
1.1032
1.0766
1.0556
1.0427
1.0390
1.0297
44.5
58.9
1.2
91.3
0.4
83.1
8.5
93.6
5.9
29.5
0.3
1
0
0
1
3
2
0
2
1
4
1
2 8
2 10
0 12
3 4
1 5
2 6
4 2
1 10
1 12
0 4
3 7
12
6
2
12
12
12
6
12
12
6
12
Experimental
Physical Properties
Calc. density 5.27200 g/cm³
Remarks
Remarks
Comments
-
Synthetic
Diffraction pattern calculated by Match!.
I/Ic calculated by Match!.
Space group has been derived from given symmetry operations.
Ambiguous space group information in source file.
Universitas Sumatera Utara
LAMPIRAN 6
KURVA BH MAX
Kurva BH-Max 97 %wt BaFe12O19 + 3 %wt FeB
BH Max
Aditif FeB
(%wt)
bHc
(Oe)
B
(G)
BH Max
(MGOe)
3
-175
450
0,07
Kurva BH-Max 91 %wt BaFe12O19 + 9 %wt FeB
BH Max
Aditif FeB
(%wt)
9
bHc
B
(Oe)
(G)
-279
650
BH Max
(MGOe)
0,18
Universitas Sumatera Utara