Identifikasi Senyawa Penyusun Minyak Atsiri Kulit Kayu Manis (Cinnamomum burmannii)Dari Lubuk Pakam, Laguboti Dan Dolok Sanggul Dengan Menggunakan GC-MS

  Lampiran 1. Gambar Tanaman Kayu Manis dari Lubuk Pakam, Laguboti dan DolokSanggul

1.1 Tanaman Kayu Manis dari Lubuk Pakam

  Kulit Kayu Manis Minyak Atsiri Kulit Kayu Manis Hasil Destilasi Alat Stahl

1.2 Tanaman Kayu Manis dari Laguboti

  

Kulit Kayu Manis Minyak Atsiri Kulit Kayu Manis

Hasil Destilasi Alat Sthal

1.3 Tanaman Kayu Manis dari Dolok Sanggul

  

Kulit Kayu Manis Minyak Atsiri Kulit Kayu Manis

Hasil Destilasi Alat Stahl

  1 2 3 4 5 6 8 9 7 10 1 1 12

13

14 C:\GCMSsolution\Data\Project1\patresia Kulit Kayu Manis Medan.qgd

  Lab.Kimia Organik FMIPA - UGM Sample Information

  Analyzed by Sample Name Sample ID Data File Method File Tuning File

  1,640,382 : Admin : Kulit Kayu Manis Medan patresia : : C:\GCMSsolution\Data\Project1\patresia Kulit Kayu Manis Medan.qgd : C:\GCMSsolution\Data\Project1\Atsiri.qgm : C:\GCMSsolution\System\Tune1\Juni 3 2014.qgt

  Chromatogram Kulit Kayu Manis Medan patresiaC:\GCMSsolution\Data\Project1\patresia Kulit Kayu Manis Medan.qgd TIC*1.00

  10.0

  20.0

  30.0

  40.0 min Peak Report TIC

  Peak# R.Time

  I.Time F.Time Area Area% Height Name 1 5.964 5.900 6.083 393919 0.95 95257 2 6.367 6.317 6.475 221654 0.54 55467 3 7.168 7.100 7.300 320104 0.77 72271 4 8.831 8.708 9.042 1732219 4.18 225251 5 13.741 13.675 13.833 223467 0.54 49804 6 14.180 14.117 14.308 380081 0.92 78369 7 17.066 16.667 17.108 25118291

  60.68 1537599 8 17.145 17.108 17.192 2884090 6.97 607283 9 17.259 17.192 17.700 7983437

  19.29 835081 10 19.777 19.700 19.925 910256 2.20 187060 11 20.817 20.750 20.942 180918 0.44 32898 12 21.007 20.942 21.142 353967 0.86 65990 13 23.151 23.075 23.258 241925 0.58 51888 14 23.748 23.642 23.892 448221 1.08 74891 41392549 100.00 3969109 Lampiran 3.1 Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis Dari Lubuk Pakam

  Library << Target >> Line#:1 R.Time:5.967(Scan#:501) MassPeaks:41 RawMode:Averaged 5.958-5.975(500-502) BasePeak:93.05(17284) BG Mode:Calc. from Peak Group 1 - Event 1 100

  93

  77

  41

  53 67 105 121 136

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:19707 Library:WILEY229.LIB SI:94 Formula:C10 H16 CAS:80-56-8 MolWeight:136 RetIndex:0 CompName:.alpha.- PINENE $$ 100

  93 Me Me Me

  77

  39 53 67 105 121 136

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:19683 Library:WILEY229.LIB SI:94 Formula:C10 H16 CAS:80-56-8 MolWeight:136 RetIndex:0 CompName:.ALPHA.-PINENE $$ DIHYDRO-para-CYMENE (OLD NAME) $$ 2,6,6,-TRIMETHYL BICYCLO-(3,1,1)-2-HEPTENE $$ 2-PINENE $$ 100

  93 Me Me Me

  77

  41 53 67 105 121 136

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:19677 Library:WILEY229.LIB SI:94 Formula:C10 H16 CAS:27400-71-1 MolWeight:136 RetIndex:0 CompName:CIS- OCIMENE $$ 100

  93

  79

  41 105 53 67 121 136

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:6623 Library:NIST62.LIB SI:94 Formula:C10H16 CAS:3779-61-1 MolWeight:136 RetIndex:0 CompName:1,3,6-Octatriene, 3,7-dimethyl-, (E)- $$ .beta.-trans-Ocimene $$ trans-.beta.-Ocimene $$ trans-3,7-Dimethyl-1,3,6-Octatriene $$ Ocimene, trans-.beta.- $$ (E)-Ocimene $$ trans-Ocimene 100

  93

  41

  79

  53 67 105 121 136

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:19287 Library:WILEY229.LIB SI:94 Formula:C10 H16 CAS:3779-61-1 MolWeight:136 RetIndex:0 CompName:1,3,6-Octatriene, 3,7-dimethyl-, (E)- (CAS) .BETA. OCIMENE Y $$ trans-.beta.-Ocimene $$ .beta.-trans-Ocimene $$ Ocimene, trans-.beta.- $$ trans-3,7-Dimethyl-1,3,6-octatriene $$ BETA OCIME 100

  93 H CMe CH CH 2C CH 2CH CMe 2

  41

  79

  53 105 121 67 136

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Lampiran 3.2 Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis Dari Lubuk Pakam

  << Target >> Line#:2 R.Time:6.367(Scan#:549) MassPeaks:44 RawMode:Averaged 6.358-6.375(548-550) BasePeak:93.00(7273) BG Mode:Calc. from Peak Group 1 - Event 1 100

  93

  41 121 67 79 53 107

  136 223

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:19503 Library:WILEY229.LIB SI:94 Formula:C10 H16 CAS:79-92-5 MolWeight:136 RetIndex:0 CompName:Camphene $$ Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene- (CAS) 3,3-Dimethyl-2-methylenenorbornane $$ 2,2-Dimethyl-3-methylenenorbornane $$ 3,3-Dimethyl-2-methylenenorcamphane $$ 100

  93 Me 121 Me

  41

  79

  67 107 53 136

  CH 2

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:3531 Library:NIST12.LIB SI:94 Formula:C10H16 CAS:79-92-5 MolWeight:136 RetIndex:0 CompName:Camphene 100

  93 121

  79

  39 67 107 53 136

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:19507 Library:WILEY229.LIB SI:94 Formula:C10 H16 CAS:79-92-5 MolWeight:136 RetIndex:0 CompName:Camphene $$ Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene- (CAS) 3,3-Dimethyl-2-methylenenorbornane $$ 2,2-Dimethyl-3-methylenenorbornane $$ 3,3-Dimethyl-2-methylenenorcamphane $$ 100

93 Me

  Me 121

  41

  79

  67 107 53 136

  CH 2

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:3529 Library:NIST12.LIB SI:94 Formula:C10H16 CAS:79-92-5 MolWeight:136 RetIndex:0 CompName:Camphene 100

  93 121

  41

  79

  67 107 53 136

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:6630 Library:NIST62.LIB SI:94 Formula:C10H16 CAS:79-92-5 MolWeight:136 RetIndex:0 CompName:Camphene $$ Bicyclo 2.2.1 heptane, 2,2-dimethyl-3-methylene- $$ 2,2-Dimethyl-3-methylenebicyclo 2.2.1 heptane $$ 2,2-Dimethyl-3-methylenenorbornane $$ 3,3-Dimethyl-2-methylenenorbornane 100

  93 121 41 67 79

  107

  53 136

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Lampiran 3.3 Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis Dari Lubuk Pakam << Target >> Line#:3 R.Time:7.167(Scan#:645) MassPeaks:41 RawMode:Averaged 7.158-7.175(644-646) BasePeak:93.00(12531) BG Mode:Calc. from Peak Group 1 - Event 1 100

  93

  41

  69

  77

  53 121 105 136

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:6669 Library:NIST62.LIB SI:96 Formula:C10H16 CAS:127-91-3 MolWeight:136 RetIndex:0

CompName:.beta.-Pinene $$ Bicyclo 3.1.1 heptane, 6,6-dimethyl-2-methylene- $$ 2(10)-Pinene $$ Nopinen $$ Nopinene $$ Pseudopinen $$ Pseudopinene $$ Terebenthene $$ 6,6-Dimethyl-2-methylene-bicyclo

100

  93

  41

  69

  77

  53 121 136 107

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:19552 Library:WILEY229.LIB SI:95 Formula:C10 H16 CAS:127-91-3 MolWeight:136 RetIndex:0

CompName:2-.BETA.-PINENE $$ Bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene- (CAS) .beta.-Pinene $$ Nopinen $$ Nopinene $$ Pseudopinen $$ Pseudopinene $$ 2(10)-Pinene $$ Terebenthene $$ BETA-

100

  93

41 Me

  CH 2 Me

  69

  79

  53 121 136 107

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:19684 Library:WILEY229.LIB SI:93 Formula:C10 H16 CAS:127-91-3 MolWeight:136 RetIndex:0 CompName:.beta.- PINENE $$ 2(10)-PINENE $$ 100

  93 Me Me CH 2

  41 69 79 53 121 136

  107

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:3568 Library:NIST12.LIB SI:93 Formula:C10H16 CAS:127-91-3 MolWeight:136 RetIndex:0 CompName:.beta.- Pinene 100

  93

  41

  69

  79

  53 121 136 107

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:19553 Library:WILEY229.LIB SI:93 Formula:C10 H16 CAS:127-91-3 MolWeight:136 RetIndex:0

CompName:2-.BETA.-PINENE $$ Bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene- (CAS) .beta.-Pinene $$ Nopinen $$ Nopinene $$ Pseudopinen $$ Pseudopinene $$ 2(10)-Pinene $$ Terebenthene $$ BETA-

100

  93 Me

  41 Me CH 2

  69

  79

  53 121 136 107 Lampiran 3.4 Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis Dari Lubuk Pakam << Target >> Line#:4 R.Time:8.833(Scan#:845) MassPeaks:57 Line#:5 R.Time:13.742(Scan#:1434) MassPeaks:63 RawMode:Averaged 8.825-8.842(844-846) BasePeak:43.00(27751) RawMode:Averaged 13.733-13.750(1433-1435) BasePeak:71.00(6504) BG Mode:Calc. from Peak Group 1 - Event 1 BG Mode:Calc. from Peak Group 1 - Event 1 100

  43 41 68 81 93 108

  139 154 121

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:4856 Library:NIST12.LIB SI:92 Formula:C10H18O CAS:470-82-6 MolWeight:154 RetIndex:0 CompName:Eucalyptol 100

  43

  41

  69

  84 108 139 154

  O 121

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:31545 Library:WILEY229.LIB SI:92 Formula:C10 H18 O CAS:470-82-6 MolWeight:154 RetIndex:0

CompName:1,8-Cineole $$ 2-Oxabicyclo[2.2.2]octane, 1,3,3-trimethyl- (CAS) Terpan $$ Zineol $$ Eucapur $$ p-Cineole $$ Cajeputol $$ Eucalyptol $$ Cucalyptol $$ Zedoary oil $$ 1,8-Epoxy-p-menthane $$

100

  43 Me

  41 O

  69

  84 Me 108

139 154 Me

121

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:31719 Library:WILEY229.LIB SI:90 Formula:C10 H18 O CAS:470-82-6 MolWeight:154 RetIndex:0 CompName:1,8- CINEOLE $$ EUCALYPTOL $$ 100

  43 Me

  O

  81

  41

  69 84 108

  Me

  139 154

  Me

  125

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:4852 Library:NIST12.LIB SI:90 Formula:C10H18O CAS:470-82-6 MolWeight:154 RetIndex:0 CompName:Eucalyptol 100

  43

  41

  81 69 108 154 139

  O 121

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:31547 Library:WILEY229.LIB SI:89 Formula:C10 H18 O CAS:470-82-6 MolWeight:154 RetIndex:0

CompName:1,8-Cineole $$ 2-Oxabicyclo[2.2.2]octane, 1,3,3-trimethyl- (CAS) Terpan $$ Zineol $$ Eucapur $$ p-Cineole $$ Cajeputol $$ Eucalyptol $$ Cucalyptol $$ Zedoary oil $$ 1,8-Epoxy-p-menthane $$

100

  43 Me

  O

  81

  84

  41

  69 108

  Me

  154 139

  Me

  121 140

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Lampiran 3.6. Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis Dari Lubuk Pakam

  << Target >> Line#:6 R.Time:14.183(Scan#:1487) MassPeaks:47 RawMode:Averaged 14.175-14.192(1486-1488) BasePeak:59.05(13111) BG Mode:Calc. from Peak Group 1 - Event 1 100

  59

  43

  93 121

  81

  41 136 107

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:31714 Library:WILEY229.LIB SI:95 Formula:C10 H18 O CAS:98-55-5 MolWeight:154 RetIndex:0 CompName:.alpha.- TERPINEOL $$ 100

  59 CMe 2OH

  43

  93

  41

  81 121

  Me

  136 107

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:11024 Library:NIST62.LIB SI:94 Formula:C10H18O CAS:98-55-5 MolWeight:154 RetIndex:0 CompName:3-Cyclohexene-1-methanol, .alpha.,.alpha.4-trimethyl- $$ p-Menth-1-en-8-ol $$ .alpha.-Terpineol $$ Terpineol schlechthin $$ Terpineol $$ TERPINEOL, .alpha. $$ Terpenol $$ .alpha.-Terpinol $$ l- 100

  59 OH

  43

  93

  81 121 41 136

  105

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:31354 Library:WILEY229.LIB SI:94 Formula:C10 H18 O CAS:10482-56-1 MolWeight:154 RetIndex:0 CompName:l-.alpha.-Terpineol $$ 3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl-, (S)- (CAS) (-)-.alpha.-Terpineol $$ .alpha.-Terpineol, (-)- $$ p-Menth-1-en-8-ol, (S)-(-)- $$ CYCL(-)-.alpha.-Terpineol 100

  59 CMe 2OH

  93

  43 121 81 136

  Me

  41 107

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:31345 Library:WILEY229.LIB SI:94 Formula:C10 H18 O CAS:98-55-5 MolWeight:154 RetIndex:0 CompName:3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl- (CAS) CYCLOHEXENE, 1-METHYL-4-(2-PROPANOL-2-YL)- $$ 4-(1-HYDROXY-1-METHYLETHYL)-1-METHYLCYCLOHEXENE $ 100

  59 CMe 2OH

  93

  43 121 136

81 Me

  41 107

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:31360 Library:WILEY229.LIB SI:93 Formula:C10 H18 O CAS:10482-56-1 MolWeight:154 RetIndex:0 CompName:l-.alpha.-Terpineol $$ 3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl-, (S)- (CAS) (-)-.alpha.-Terpineol $$ .alpha.-Terpineol, (-)- $$ p-Menth-1-en-8-ol, (S)-(-)- $$ CYCL(-)-.alpha.-Terpineol 100

59 CMe 2OH

  43

93 Me

  81 41 121 136 107

  140

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390

  << Target >> Line#:1 R.Time:17.067(Scan#:1833) MassPeaks:34 RawMode:Averaged 17.058-17.075(1832-1834) BasePeak:130.95(224568) BG Mode:Calc. from Peak Group 1 - Event 1 100

  131 103

  77

  51

  39

  63

  91

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:17191 Library:WILEY229.LIB SI:96 Formula:C9 H8 O CAS:104-55-2 MolWeight:132 RetIndex:0 CompName:cinnamic aldehyde $$ 100

  131 CH CH CHO

  103

  77

  51

  63

  39

  91 115

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:3165 Library:NIST12.LIB SI:95 Formula:C9H8O CAS:104-55-2 MolWeight:132 RetIndex:0 CompName:2- Propenal, 3-phenyl- 100

  131 O 103

  77

  51

  63

  39

  91 115

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:17160 Library:WILEY229.LIB SI:95 Formula:C9 H8 O CAS:104-55-2 MolWeight:132 RetIndex:0 CompName:2-Propenal, 3-phenyl- (CAS) Cinnamaldehyde $$ 3-Phenylpropenal $$ Cinnamic aldehyde $$ Cinnamal $$ Phenylacrolein $$ Cassia aldehyde $$ 3-Phenylacrolein $$ Cinnamyl aldehyde $$ 3-Pheny 100

  131 CH CH CHO

  103

  77

  51

  39

  63

  91 115

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:17157 Library:WILEY229.LIB SI:95 Formula:C9 H8 O CAS:104-55-2 MolWeight:132 RetIndex:0 CompName:2-Propenal, 3-phenyl- (CAS) Cinnamaldehyde $$ 3-Phenylpropenal $$ Cinnamic aldehyde $$ Cinnamal $$ Phenylacrolein $$ Cassia aldehyde $$ 3-Phenylacrolein $$ Cinnamyl aldehyde $$ 3-Pheny 100

  131 CH CH CHO

  103

  77

  51

  63

  91

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:12464 Library:NIST62.LIB SI:94 Formula:C10H8O2 CAS:82700-43-4 MolWeight:160 RetIndex:0 CompName:Benzylidenemalonaldehyde $$ Benzalmalonic dialdehyde 100

  131 O

  103

  77

51 O

  39

  63 115 159

  91

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390

  Lampiran 3.8 Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis

  << Target >> Line#:8 R.Time:17.142(Scan#:1842) MassPeaks:53 RawMode:Averaged 17.133-17.150(1841-1843) BasePeak:43.00(14193) BG Mode:Calc. from Peak Group 1 - Event 1 100

  43

  95

  41 131 121 67 80 108

  154

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:64042 Library:WILEY229.LIB SI:90 Formula:C12 H20 O2 CAS:76-49-3 MolWeight:196 RetIndex:0 CompName:BORNYLACETATE $$ 100

  43 Me

  95 OAc

  41 Me 121 136 67 80 108

  Me

  154

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:63999 Library:WILEY229.LIB SI:88 Formula:C12 H20 O2 CAS:76-49-3 MolWeight:196 RetIndex:0 CompName:bornyl acetate $$ 100

  95

43 Me

  OAc

  41 Me 121 136 108

67 Me

  79 154

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:64043 Library:WILEY229.LIB SI:88 Formula:C12 H20 O2 CAS:125-12-2 MolWeight:196 RetIndex:0 CompName:ISOBORNYLACETATE $$ 100

43 Me

  OAc

  95

  41 Me 121 136 67 108

  Me

  79 154

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:7243 Library:NIST12.LIB SI:87 Formula:C12H20O2 CAS:5655-61-8 MolWeight:196 RetIndex:0 CompName:Bicyclo 2.2.1 heptan-2-ol, 1,7,7-trimethyl-, acetate, (1S-endo)- 100

  95

  43 121 136 41 108

  O 69 80 O 154

  177 196

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:63959 Library:WILEY229.LIB SI:87 Formula:C12 H20 O2 CAS:5655-61-8 MolWeight:196 RetIndex:0 CompName:Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, acetate, (1S-endo)- (CAS) l-Bornyl acetate $$ (-)-Bornyl acetate $$ Levo-bornyl acetate $$ l-.alpha.-Bornyl acetate $$ Borneol, acetate, (1S,2R,4S)-(-)- $ 100

  95 Me

  43 OAc

  Me

  121 136

  41 108 69 80

  Me

  154 177

  19

  6

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390

  Lampiran 3.9 Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis

  << Target >> Line#:9 R.Time:17.258(Scan#:1856) MassPeaks:70 RawMode:Averaged 17.250-17.267(1855-1857) BasePeak:109.00(28358) BG Mode:Calc. from Peak Group 1 - Event 1 100

  109 138 77 121

  94

  43

  41

  65 154

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:20298 Library:WILEY229.LIB SI:89 Formula:C8 H10 O2 CAS:1331-81-3 MolWeight:138 RetIndex:0 CompName:ANISYLALCOHOL $$ PARA-METHOXY BENZYLALCOHOL $$ 100

  109 138

  77 121 94 39 51

  65

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:20344 Library:WILEY229.LIB SI:84 Formula:C8 H10 O2 CAS:105-13-5 MolWeight:138 RetIndex:0 CompName:Benzenemethanol, 4-methoxy- (CAS) Anise alcohol $$ p-Anisyl alcohol $$ ANISYLALCOHOL $$ Anisic alcohol $$ p-Methoxybenzyl alcohol $$ 4-Methoxybenzyl alcohol $$ Benzyl alcohol, p-m 100

  138 109

  OMe

  77 121

  51

  94

41 HO CH 2

  65

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:3663 Library:NIST12.LIB SI:84 Formula:C8H10O2 CAS:105-13-5 MolWeight:138 RetIndex:0 CompName:Benzenemethanol, 4-methoxy- 100 138

  OH 109 77 121

  51

  94

  41

  65 O

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:20342 Library:WILEY229.LIB SI:83 Formula:C8 H10 O2 CAS:105-13-5 MolWeight:138 RetIndex:0 CompName:Benzenemethanol, 4-methoxy- (CAS) Anise alcohol $$ p-Anisyl alcohol $$ ANISYLALCOHOL $$ Anisic alcohol $$ p-Methoxybenzyl alcohol $$ 4-Methoxybenzyl alcohol $$ Benzyl alcohol, p-m 100

  77 109

138 OMe

94 121

  51

  41

  65 HO CH 2

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:20325 Library:WILEY229.LIB SI:83 Formula:C8 H10 O2 CAS:6971-51-3 MolWeight:138 RetIndex:0 CompName:meta-methoxybenzyl alcohol $$ Benzenemethanol, 3-methoxy- $$ Benzyl alcohol, m-methoxy- $$ m-Methoxybenzyl alcohol $$ 3-Methoxybenzyl alcohol $$ 3-Methoxyphenylmethanol $$ 100

  77 138

  10

  9

  94

  67

  51

  41 121 140

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390

  Lampiran 3.10 Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis

  << Target >> Line#:10 R.Time:19.775(Scan#:2158) MassPeaks:72 RawMode:Averaged 19.767-19.783(2157-2159) BasePeak:105.00(18892) BG Mode:Calc. from Peak Group 1 - Event 1 100

  105 119

  41

  91 161

  81

  55 133 69 204

  147 189

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:71082 Library:WILEY229.LIB SI:96 Formula:C15 H24 CAS:3856-25-5 MolWeight:204 RetIndex:0 CompName:.alpha.-Copaene $$ Tricyclo[4.4.0.0(2,7)]dec-3-ene, 1,3-dimethyl-8-(1-methylethyl)-, stereoisomer (CAS) Tricyclo[4.4.0.0(2,7)]dec-3-ene, 1,3-dimethyl-8-(1-methylethyl)-, st (CAS) Copaene $$ Cop 100

  105 119

  41 Me 161 Me

  91

  55

  77 i-Pr 204

  65 133 145 189

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:7690 Library:NIST12.LIB SI:93 Formula:C15H24 CAS:3856-25-5 MolWeight:204 RetIndex:0 CompName:Copaene 100

  105 119 161

  93

  41

  55

  81 204 69 133

  147 189

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:71083 Library:WILEY229.LIB SI:93 Formula:C15 H24 CAS:3856-25-5 MolWeight:204 RetIndex:0 CompName:.alpha.-Copaene $$ Tricyclo[4.4.0.0(2,7)]dec-3-ene, 1,3-dimethyl-8-(1-methylethyl)-, stereoisomer (CAS) Tricyclo[4.4.0.0(2,7)]dec-3-ene, 1,3-dimethyl-8-(1-methylethyl)-, st (CAS) Copaene $$ Cop 100

  105 119 161 Me

93 Me

  41

  81

  55 i-Pr 69 204

  133 147 189

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:71189 Library:WILEY229.LIB SI:93 Formula:C15 H24 CAS:3856-25-5 MolWeight:204 RetIndex:0 CompName:.ALPHA.-COPAENE $$ 100

  105 119 161 Me Me

  91

  41

  77 i-Pr 43 204

  67 133 145

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:7689 Library:NIST12.LIB SI:93 Formula:C15H24 CAS:3856-25-5 MolWeight:204 RetIndex:0 CompName:Copaene 100

  161 105 119

  93

  41

  77 204 43 133

  67 147 189

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390

  Lampiran 3.11 Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis

  << Target >> Line#:1 R.Time:20.817(Scan#:2283) MassPeaks:113 RawMode:Averaged 20.808-20.825(2282-2284) BasePeak:41.00(3182) BG Mode:Calc. from Peak Group 1 - Event 1 100

  41

  93 119 69 79 107

  55 131 149 161 210 246 263 319 381

181 189 228 282 298 347 357

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:71012 Library:WILEY229.LIB SI:89 Formula:C15 H24 CAS:13474-59-4 MolWeight:204 RetIndex:0 CompName:,TRANS-.ALPHA.-BERGAMOTENE $$ Bergamotene $$ trans-.alpha.-Bergamotene $$ Bicyclo[3.1.1]hept-2-ene, 2,6-dimethyl-6-(4-methyl-3-pentenyl)-, [1S-(1.alpha.,5.alpha.,6.alpha.)]- $$ 2-Norp

  93

  100

  41 119 69 107

  77

  55

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:7668 Library:NIST12.LIB SI:86 Formula:C15H24 CAS:502-61-4 MolWeight:204 RetIndex:0 CompName:.alpha.- Farnesene 100

  41

  93

  69

  55 107 79 119

  135 147 161 204

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:70726 Library:WILEY229.LIB SI:86 Formula:C15 H24 CAS:502-61-4 MolWeight:204 RetIndex:0 CompName:Farnesene $$ 1,3,6,10-Dodecatetraene, 3,7,11-trimethyl- (CAS) .alpha.-Farnesene $$ 2,6,10-Trimethyl-2,6,9,11-dodecatetraene $$ 3,7,11-Trimethyl-1,3,6,10-dodecatetraene $$ 1,3,6,10-Dodecatetrae 100

  41

  93

  69

  55 Me Me Me 107 H C CHC CHCH CH CCH CH CH CMe

  79 2 2 2 2 119 135 147 161 204

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:71176 Library:WILEY229.LIB SI:85 Formula:C15 H24 CAS:13474-59-4 MolWeight:204 RetIndex:0 CompName:(Z)- TRANS-.ALPHA.-BERGAMOTENE $$ 100

  41

  93 119

  79

  69 55 105 161 189

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:70840 Library:WILEY229.LIB SI:85 Formula:C15 H24 CAS:87-44-5 MolWeight:204 RetIndex:0 CompName:trans-Caryophyllene $$ Bicyclo[7.2.0]undec-4-ene, 4,11,11-trimethyl-8-methylene-, [1R-(1R*,4E,9S*)]- (CAS) l-Caryophyllene $$ (-)-Caryophyllene $$ Caryophyllene $$ .beta.-Caryophyllen $$ .b 100

  41 CH 2

  69 Me

  93

  79 Me

  55 105 133 120

  Me

  147 161 189

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390

  

Lampiran 3.12 Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis

  << Target >> Line#:12 R.Time:21.008(Scan#:2306) MassPeaks:79 RawMode:Averaged 21.000-21.017(2305-2307) BasePeak:41.00(6714) BG Mode:Calc. from Peak Group 1 - Event 1 100

  41

  79

  69

  93 133 55 105 119

  147 161 175 189 297 311 359

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:70840 Library:WILEY229.LIB SI:93 Formula:C15 H24 CAS:87-44-5 MolWeight:204 RetIndex:0 CompName:trans-Caryophyllene $$ Bicyclo[7.2.0]undec-4-ene, 4,11,11-trimethyl-8-methylene-, [1R-(1R*,4E,9S*)]- (CAS) l-Caryophyllene $$ (-)-Caryophyllene $$ Caryophyllene $$ .beta.-Caryophyllen $$ .b 100

  41 CH

  2

  69 Me

  93

  79 Me

  55 105 133 120

  Me

  147 161 189

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:71237 Library:WILEY229.LIB SI:92 Formula:C15 H24 CAS:87-44-5 MolWeight:204 RetIndex:0 CompName:.beta.- CARYOPHYLLENE $$ 100

  41 CH

  2

  69

  93 Me

  79 133

  Me

  105

  55 120 147 161

  Me

  189 175 204

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:70838 Library:WILEY229.LIB SI:91 Formula:C15 H24 CAS:87-44-5 MolWeight:204 RetIndex:0 CompName:trans-Caryophyllene $$ Bicyclo[7.2.0]undec-4-ene, 4,11,11-trimethyl-8-methylene-, [1R-(1R*,4E,9S*)]- (CAS) l-Caryophyllene $$ (-)-Caryophyllene $$ Caryophyllene $$ .beta.-Caryophyllen $$ .b 100

  41 CH

  2

  69 Me

  93

  79 Me

  55 133 105 120

  Me

  147 161 189 204

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:70849 Library:WILEY229.LIB SI:91 Formula:C15 H24 CAS:118-65-0 MolWeight:204 RetIndex:0 CompName:ISOCARYOPHYLLEN $$ .gamma.-caryophyllene $$ isocaryophyllene $$ Bicyclo[7.2.0]undec-4-ene, 4,11,11-trimethyl-8-methylene-, [1R-(1R*,4Z,9S*)]- $$ Bicyclo[7.2.0]undec-4-ene, 4,11,11-tri 100

  41 CH

  93

  2

  69 Me

  79 133

  Me

  105

  55 161 119

  Me

  147 189 175 204

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:70837 Library:WILEY229.LIB SI:91 Formula:C15 H24 CAS:87-44-5 MolWeight:204 RetIndex:0 CompName:trans-Caryophyllene $$ Bicyclo[7.2.0]undec-4-ene, 4,11,11-trimethyl-8-methylene-, [1R-(1R*,4E,9S*)]- (CAS) l-Caryophyllene $$ (-)-Caryophyllene $$ Caryophyllene $$ .beta.-Caryophyllen $$ .b 100

41 CH

  2 Me Me

  91 69 79 53 105 133

  120 Me 147 161 175 189

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390

  

Lampiran 3.l3 Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis

  << Target >> Line#:1 R.Time:23.150(Scan#:2563) MassPeaks:72 RawMode:Averaged 23.142-23.158(2562-2564) BasePeak:105.05(6743) BG Mode:Calc. from Peak Group 1 - Event 1 100

  105

  41 91 119 77 161

  43 69 133 147 189 204

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:70985 Library:WILEY229.LIB SI:92 Formula:C15 H24 CAS:31983-22-9 MolWeight:204 RetIndex:0 CompName:.alpha.-Muurolene $$ Naphthalene, 1,2,4a,5,6,8a-hexahydro-4,7-dimethyl-1-(1-methylethyl)-, (1.alpha.,4a.alpha.,8a.alpha.)- (CAS) .ALPHA.-MUUROLEN $$ 1.xi.,6.xi.,7.xi.-Cadina-4,9-diene $$ A 100

  105 Me

  93

  41 161 79 119

  Me

  55

  69 204 Pr-i 133

  147 189

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:70986 Library:WILEY229.LIB SI:89 Formula:C15 H24 CAS:31983-22-9 MolWeight:204 RetIndex:0 CompName:.alpha.-Muurolene $$ Naphthalene, 1,2,4a,5,6,8a-hexahydro-4,7-dimethyl-1-(1-methylethyl)-, (1.alpha.,4a.alpha.,8a.alpha.)- (CAS) .ALPHA.-MUUROLEN $$ 1.xi.,6.xi.,7.xi.-Cadina-4,9-diene $$ A 100

  105 Me 161

  94

  41 204

  81 Me 119

  43 Pr-i 133 147 69 189

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:7686 Library:NIST12.LIB SI:89 Formula:C15H24 CAS:31983-22-9 MolWeight:204 RetIndex:0 CompName:Naphthalene, 1,2,4a,5,6,8a-hexahydro-4,7-dimethyl-1-(1-methylethyl)-, (1.alpha.,4a.alpha.,8a.alpha.)- 100

  105 161

  41

  94 204 81 119

  43 69 133 147 189 175

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:70988 Library:WILEY229.LIB SI:89 Formula:C15 H24 CAS:31983-22-9 MolWeight:204 RetIndex:0 CompName:.alpha.-Muurolene $$ Naphthalene, 1,2,4a,5,6,8a-hexahydro-4,7-dimethyl-1-(1-methylethyl)-, (1.alpha.,4a.alpha.,8a.alpha.)- (CAS) .ALPHA.-MUUROLEN $$ 1.xi.,6.xi.,7.xi.-Cadina-4,9-diene $$ A 100

  105 Me 161

  41

  94 204 Me 81 119

  43 Pr-i 133 147 69 189 175

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:70982 Library:WILEY229.LIB SI:87 Formula:C15 H24 CAS:10208-80-7 MolWeight:204 RetIndex:0 CompName:.alpha.-Muurolene-(-) $$ Naphthalene, 1,2,4a,5,6,8a-hexahydro-4,7-dimethyl-1-(1-methylethyl)-, [1S-(1.alpha.,4a.alpha.,8a.alpha.)]- (CAS) .ALPHA.-MUUROLEN $$ 1.xi.,6.xi.,7.xi.-Cadina-4,9-di 100

  105 Me 161

  94 81 204 Me 41 119

  43 Pr-i 69 133 147 189

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390

  

Lampiran 3.14 Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis

  << Target >> Line#:14 R.Time:23.750(Scan#:2635) MassPeaks:91 RawMode:Averaged 23.742-23.758(2634-2636) BasePeak:105.00(5097) BG Mode:Calc. from Peak Group 1 - Event 1 100

  105 119 159

  41

  91 134 81 204

  55

  69 144 189 175

  349 362 394

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:71182 Library:WILEY229.LIB SI:81 Formula:C15 H24 CAS:39029-41-9 MolWeight:204 RetIndex:0 CompName:.DELTA.-CADINENE $$ 100

  161 CH2 119 105

  134

  91 204

  81

  41 Me 189 Pr-i

  55 69 145

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:70926 Library:WILEY229.LIB SI:80 Formula:C15 H24 CAS:483-76-1 MolWeight:204 RetIndex:0 CompName:.delta.-Cadinene $$ Naphthalene, 1,2,3,5,6,8a-hexahydro-4,7-dimethyl-1-(1-methylethyl)-, (1S-cis)- (CAS) (+)-.delta.-Cadinene $$ Cadina-1(10),4-diene $$ .delta.-Cadinene, (+)- $$ DELTA-CADIN 100

  134 Me 204 105 119

  41 81 91 162 189

55 Me

  69 Pr-i 147

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:71082 Library:WILEY229.LIB SI:80 Formula:C15 H24 CAS:3856-25-5 MolWeight:204 RetIndex:0 CompName:.alpha.-Copaene $$ Tricyclo[4.4.0.0(2,7)]dec-3-ene, 1,3-dimethyl-8-(1-methylethyl)-, stereoisomer (CAS) Tricyclo[4.4.0.0(2,7)]dec-3-ene, 1,3-dimethyl-8-(1-methylethyl)-, st (CAS) Copaene $$ Cop 100

  105 119

  41 Me 161 Me

  91

  55

  77 i-Pr 204

  65 133 145 189

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:71188 Library:WILEY229.LIB SI:80 Formula:C15 H24 CAS:23986-74-5 MolWeight:204 RetIndex:0 CompName:GERMACRENE-D $$ 100

  161 91 105 79 119

  41 133 55 67 204

  147

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:7708 Library:NIST12.LIB SI:80 Formula:C15H24 CAS:483-76-1 MolWeight:204 RetIndex:0 CompName:Naphthalene, 1,2,3,5,6,8a-hexahydro-4,7-dimethyl-1-(1-methylethyl)-, (1S-cis)- 100

  161 105 119 134 204

  41

  91

  81

  55 189 69 147

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390

  1

  17 Analyzed by : Admin

  I.Time F.Time Area Area% Height Name 1 11.272 11.167 11.333 5457804 3.84 1381465 2 11.375 11.333 11.442 535653 0.38 165473 3 11.833 11.783 11.900 387566 0.27 123548 4 12.842 12.792 12.908 488725 0.34 153450 5 14.233 14.192 14.367 518996 0.36 98909 6 14.411 14.367 14.467 417393 0.29 130359 7 14.683 14.625 14.708 600881 0.42 174135 8 14.764 14.708 14.833 2908399 2.04 833734 9 15.773 15.717 15.842 371258 0.26 115817 10 18.335 18.267 18.433 1015105 0.71 255272 11 19.955 19.900 20.017 342448 0.24 95650 12 20.218 20.158 20.300 536130 0.38 136830 13 22.079 21.650 22.200 117130074

  Peak# R.Time

  50.0 min Peak Report TIC

  40.0

  30.0

  20.0

  10.0

  TIC*1.00

  6,699,877 Chromatogram Kulit Kayu manis Patresia Lumban Batu C:\GCMSsolution\Data\Project1\Patresia Kayu manis.qgd

  Sample Name : Kulit Kayu manis Patresia Lumban Batu Sample ID : 4.15.16.1 Data File : C:\GCMSsolution\Data\Project1\Patresia Kayu manis.qgd Method File : C:\GCMSsolution\Data\Project1\atsiri.qgm Tuning File : C:\GCMSsolution\System\Tune1\Januari 5 2015.qgt

  16

  2

  15

  14

  13

  1 1 2

  10

  9

  8

  7

  4 5 6

  3

  82.33 6527802 14 22.999 22.917 23.092 4209325 2.96 1123608 15 26.055 25.992 26.142 988192 0.69 264622 16 26.330 26.225 26.442 2889282 2.03 537923 17 26.953 26.858 27.050 3469437 2.44 632327 Lampiran 5.1 Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis Dari Laguboti

  Library << Target >> Line#:1 R.Time:11.275(Scan#:1138) MassPeaks:21 RawMode:Averaged 11.267-11.283(1137-1139) BasePeak:77.00(284752) BG Mode:Calc. from Peak Group 1 - Event 1 100

  77 105

  51

  39

  63

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:1453 Library:NIST12.LIB SI:97 Formula:C7H6O CAS:100-52-7 MolWeight:106 RetIndex:0 CompName:Benzaldehyde 100

  77 106 O

  51

  39

  63

  86

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:6826 Library:WILEY229.LIB SI:96 Formula:C7 H6 O CAS:100-52-7 MolWeight:106 RetIndex:0 CompName:Benzaldehyde (CAS) Phenylmethanal $$ Benzenecarbonal $$ Benzaldehyde FFC $$ Benzoic aldehyde $$ Artificial Almond Oil $$ Benzeneca 100

  77 106 CH O

  51

  39

  63

  84

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:1450 Library:NIST12.LIB SI:96 Formula:C7H6O CAS:100-52-7 MolWeight:106 RetIndex:0 CompName:Benzaldehyde 100

  77 106 O

  51

  39

  63

  84

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:1451 Library:NIST12.LIB SI:96 Formula:C7H6O CAS:100-52-7 MolWeight:106 RetIndex:0 CompName:Benzaldehyde 100

  77 106 O

  51

  63

  84

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:6839 Library:WILEY229.LIB SI:96 Formula:C7 H6 O CAS:100-52-7 MolWeight:106 RetIndex:0 CompName:benzaldehyde $$ 100

  77 106 CH O

  51

  39

  63

  

Lampiran 5.2 Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis

Dari Laguboti

  << Target >> Line#:2 R.Time:11.375(Scan#:1150) MassPeaks:34 RawMode:Averaged 11.367-11.383(1149-1151) BasePeak:93.00(29765) BG Mode:Calc. from Peak Group 1 - Event 1 100

  93

  79

  41

  53 67 121 107 136

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:1 Entry:19707 Library:WILEY229.LIB SI:93 Formula:C10 H16 CAS:80-56-8 MolWeight:136 RetIndex:0 CompName:.alpha.-PINENE $$ 100

  93 Me Me Me

  77

  39 105 121 136

  53

  67

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:2 Entry:19627 Library:WILEY229.LIB SI:93 Formula:C10 H16 CAS:80-56-8 MolWeight:136 RetIndex:0 CompName:.alpha.-pipene $$ .alpha.-pinene $$ 100

  93 Me Me Me

  77

  39 53 105 121 136

  67

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:3 Entry:19537 Library:WILEY229.LIB SI:93 Formula:C10 H16 CAS:80-56-8 MolWeight:136 RetIndex:0 CompName:.ALPHA.-PINENE, (-)- $$ Bicyclo[3.1.1]hept-2-ene, 2,6,6-trimethyl- (CAS) Pinene $$ 2-Pinene $$ .alpha.-Pinene $$ 2,6,6-Trimethylbicyclo[3 100

  93 Me Me Me

  77

  41 121 53 67 105 136

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:4 Entry:3574 Library:NIST12.LIB SI:93 Formula:C10H16 CAS:80-56-8 MolWeight:136 RetIndex:0 CompName:.alpha.-Pinene 100

  93

  39

  77 121

  53

  67 105 136

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 Hit#:5 Entry:19541 Library:WILEY229.LIB SI:92 Formula:C10 H16 CAS:80-56-8 MolWeight:136 RetIndex:0 CompName:.ALPHA.-PINENE, (-)- $$ Bicyclo[3.1.1]hept-2-ene, 2,6,6-trimethyl- (CAS) Pinene $$ 2-Pinene $$ .alpha.-Pinene $$ 2,6,6-Trimethylbicyclo[3 100

  93 Me Me Me

  77

  41

  53

  67 105 121 136

  30

  50

  70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390

  

Lampiran 5.3 Data Hasil Uji Analisa GC-MS Minyak Atsiri Kulit Kayu Manis

Dari Laguboti

  << Target >> Line#:3 R.Time:11.833(Scan#:1205) MassPeaks:41 RawMode:Averaged 11.825-11.842(1204-1206) BasePeak:93.05(18694) BG Mode:Calc. from Peak Group 1 - Event 1 100

  93 121 67 79

  41 107 53 136

  30

  50

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