Electronic Resources
Electronic Resources
Chemical Heritage Foundation 315 Chestnut Street Philadelphia, PA 19106 Phone: 215-925-2222. Fax: 215-925-1954 www.chemheritage.org
Chemical Heritage Foundation (CHF) serves the community of the chemical and molecular sciences. CHF maintains a collection of materials that document the history and heritage of the chemical and molecular sciences, technolo- gies, and industries.
Index
Bayer process, 180 ACS (American Chemical Society),
Abelson, Philip Hauge, 317
Apatite, 213
Becquerel, Antoine Henri, 16, 31, 304, 343, 344, 346, 347, 348,
Apollo I, 228
Aqua Regia, 139, 160, 161, 235
“Beer Drinker’s Syndrome,” 107 Actinide metal series, 29, 37,
Arfwedson, Johan August, 48
Bell Research Laboratories, 196, 305–37
Argentite, 141
199 Adams catalyst, 164
Argonne National Laboratory, Chi-
Benzene ring, 22, 44, 193. See also “Affinitas” concept, 216
cago, IL, 272, 322, 324
Hydrocarbons Agate, 195, 196
Argyria, 143
Berg, Otto Carl, 156 Agricola, Georgius, 221
Argyrodite, 199
Beryl, 66, 68 Alchemy, age of, 4
Aristotle, 3, 6
Berylliosis, 69 ALCOA (Aluminum Company of
Armbruster, Peter, 347, 348, 349,
Berzelius, Jöns Jakob, 5, 123, America), 180, 182
152, 196, 214, 237, 238, 278, Alexander the Great, 4
Arsenolite, 217
280–81, 310 Alkali earth metals, 36, 65–83
Arsenopyrite, 217
Bessemer, Henry, 103 Alkali metals, 36, 39–64
Arsphenamine, 217
Bessemer process, 103 Alkanes, 20–21
Atomic: bomb, 14, 329; clock, 61,
Beta particles, 16, 17 Alkenes, 21
62; energy, 15; mass number, 26,
Beta radiation, 31 Alkynes, 21
31; models, 9, 10, 13–15; num-
“Big Bang” Theory, 2, 41, 263 Allanite, 282, 284, 289, 295
ber, 26, 27, 29, 31; proton num-
Bismuthinite, 221 Allison, Fred, 258
ber, 26; radius, 28; structure,
Black, Joseph, 71, 210 Alpha particles, 9–10, 16, 17, 68,
6–7, 9–23, 191; weight, 6, 28
Blomstrand, Christian Wilhelm, 167. See also Atomic Structure
Atom smasher, 17, 68
126 Alpha radiation, 31
Autunite, 314
Bohr, Niels, 13, 149–50, 346 Altaite, 240
Azurite, 112
Bohr model, 13. See also Atomic Alum, 179, 181
structure Amblygonite, 48
Babbitt metal, 202, 205
Boisbaudran, Paul-Emile Lecoq de, Ammonia, production of, 43
Baddeleyite, 123, 124, 149
182, 288, 291–92, 295 Amu (atomic mass unit), 31, 191
Balard, Antoine-Jerome, 253
“Bologna stones,” 80 Andrews, Thomas, 231
Ballard Power Systems of Canada,
45 Borax, 51, 176 Anglesite, 204
Bormite, 112 Anions, 18, 35–36
Bardeen, John, 199
Boron Group, 175–88 Antidepressants, 49, 50
Barite, 79, 246
Boyle, Robert, 4–5, 41 Antimatter, 17
Bastnasite, 275, 280, 282, 284,
Boyle’s Law, 5, 41 Antiparticle, 18
Brand, Hennig, 213–14 Antiproton, 17
Bauxite, 179, 180, 181, 182, 227
Bayer, Karl Joseph, 180
Brande, W. T., 48
418 | Index
Brandt, George, 106, 109 Brattain, Walter Hauser, 199 Breithauptite, 218 Brimstone, 234–35 Brochanite, 112 Bronze, 3, 216 Bronze Age, 3, 102, 103 “Bucky Balls,” 22–23 Bunsen, Robert W., 58, 59, 61 Bunsen Burner, 58
Calamine, 143, 144 Calaverite, 240 Calcite, 75, 246 Calx, 75 Canfieldite, 199 Carats, 166 Carbon black, 191, 220 Carbon chemistry. See Chemistry,
organic Carbon dating, 193 Carbon dioxide, 193, 194, 232 Carbon Group, 189–206 Carbon monoxide, 194 Carbon-12, 31, 191 Carcinogens, 68, 69, 78, 83, 97,
110, 217, 220, 243, 274 Cardiac stress test, 187–88 Carnallite, 54, 249 Carnotite, 94 Cassiterite, 201 Cations, 18, 35 Cavendish, Henry, 42, 210 Celestite, 77, 235 Cerite, 282, 288, 289 CERN (Conseil Européen pour la
Recherche Nucléaire), 17 Cerussite, 204, 206 Cesium atom, 61 Chadwick, James, 16, 26, 68 Chain reaction. See Fission Chalcedony, 195 Chalcogen Group. See Oxygen
Group Chalcolite, 82, 112 Chalcopyrite, 112 Chalk, 74, 75 Chaoplexity, 232–33 Chemical Analysis through Observa-
tion of the Spectrum, 61 Chemical bonding, 18–20 Chemical reaction, 2–5, 15 Chemistry: age of modern, 4–5;
atomic, 6–7; biochemistry, 20; early uses of, 2–4; electrochem- istry, 71; hydrocarbon, 20, 192– 94; iatrochemistry, 4; nuclear, 16–18; organic, 20–23, 193
Chloanthite, 106 Chlorofluorocarbons, 231–32, 247,
250. See also Ozone Chlorofluorohydrocarbons, 251.
See also Ozone Choppin, Gregory R., 329, 333 Chromite, 96, 102 Chrysocolla, 112 Cinnabar, 169, 235 Claudetite, 217 Clay, 179 Cleve, Per Teodor, 89, 263–64,
296, 300 Cobaltite, 106 Coke, 191, 193, 194 Colemanite, 176 Coloradoite, 240 Columbite, 125, 126, 151,
156 Columbium, 126 Combustion, 5 Compounds, 5–7, 18–20 “Compound 606.” See Arsphena-
mine Corson, Dale Raymond, 258 Corundum, 97, 154, 180 Coryell, Charles DuBois, 286 Coryell, Grace Mary, 286 Coster, Dirk, 149 Cotunnite, 205 Council on Environmental Qual-
ity, 233 Courtois, Bernard, 255 Covalent bond. See Chemical
bonding Covellite, 112 Cranston, John, 312 Crawford, Adair, 77 Cristobalite, 196 Crocoite, 96, 206 Cromer, Alan, 1 Cronstedt, Axel Frederich, 109 Crookes, William, 187, 263 Crooksite, 187 Cruikshank, William, 77 Cryolite, 180, 247 CT (Computerized Tomography
Scans), 80, 106 Cuprite, 112 Curie, Marie Sklodowska, 9, 16,
64, 82, 83, 241, 242–43, 308, 315, 323 Curie, Pierre, 16, 82, 83, 242, 308,
315, 323 Curie Institute, Paris, 63 Curie point, 105–6 Cyanogen, 18–19 Cyclotron, 16, 68
Daimler-Benz, 45 Dalton, John, 6 DaVinci, Leonardo, 226, 230 Davy, Humphry, 48, 51, 55, 71,
74, 77, 80, 176, 196, 250, 255 DDT (DichloroDiphenylTrichloro- ethane), 251 Dead Sea, 253 Debierne, Andre-Louis, 308 Delafontaine, Marc, 296 Del Rio, Andres Manuel, 94 Demarcay, Eugene-Anatole, 290 Democritus, 6, 13 Dephlogisticated air, 226 “Devil’s Copper,” 109 Diamond, 188, 191–93 Diaspore, 182 Dicrasite, 218 Didymium, 282, 284 Döbereiner, Wolfgang, 25 Dolomite, 71, 192 Dorn, Friedrich Ernst, 273 Downs cells, 51. See also Elec-
trolysis Duhamel du Monceau, Henri- Louis, 51 Duralumin, 181 Dysprosium Group. See Lanthanide
Series Ehrlich, Paul, 217
Einstein, Albert, 328 Eka-elements, 26, 64, 89, 131,
156, 182, 199, 258, 360 Ekeberg, Anders Gustav, 152 “Electric Eyes,” 59, 238. See also
Photoelectric cells Electrochemistry, 71 Electrolysis, 42 Electromagnetic spectrum, 11 Electron affinity, 18, 28 “Electron Cloud,” 14 Electronegativity, 18, 85–86 Electrons, 2–4, 14–20, 27, 33 Elements, 2, 5–7; actinide series,
29, 37, 305–37; alkali-earth metals, 36, 65–83; alkali met- als, 36, 39–64; boron group, 175–88; carbon group, 189–206; cataloguing of, 27–30; eka, 26,
64, 89, 131, 156, 182, 199, 258, 360; guide to, 35–37; halogen group, 245–59; heavy metals, 37; lanthanide series, 29, 30,
37, 275–304; light metals, 37; metallics, 173–74, 175–88; metalloids, 37, 189–222; ni- trogen 2 group, 207–22; noble
Index |
metals, 37; non-metal oxidiz- ers, 245–59; origin of, 1–2; other metals, 37; oxidizers and nonmetals, 223–43; oxygen group, 223–43; periodic table, explanation of, 27–30; platinum metals, 37; rare-earth, 30, 37, 119–21; superactinides, 357–65; super heavy elements (SHE), 357–65; transactinides, 339–56; transition, 85–117, 119–46, 147–71; transition metals, 29,
37, 173–74, 175–88, 189–222; transuranic, 30, 305, 316–37 Elhuyar, Don Fausto de, 154 Elhuyar, Don Juan Jose de, 154 Elixir Vitae, 4 Elpidite, 123 Emeralds, 66, 68 Empyreal air, 226 Enargite, 112 Energy level, 11–13. See also
Atomic structure Eniwetok Atoll, 328–29 EPA (Environmental Protection
Agency), 231 Epicurus, 6 Epsom salt, 71, 72 Erythrite, 106 Erythronium, 94 Esmark, Hans Morten Thrane, 310 Esmark, Jens, 310 Ethanol, 43 Eucairite, 237, 238 Eudialyte, 123 Euxenite, 151, 293, 301 Evans, Thomas Wilberger, 142 “Exclusion principle,” 11, 12
Fabry, Charles, 231 Fajans, Kasimir, 312 Faraday, Michael, 21 Feldspar, 179 Fermi, Enrico, 131, 330 Fermi National Laboratory, 17 Fertilizers, 52, 55, 75, 100, 214 Fire, 2–3 Fire air, 226 Fischer-Tropsch method, 42 Fission, 15 “Fixed Air” concept, 210 Fluorapatite, 247 Fluoride, 248 Fluorite, 180, 246 “Fool’s gold,” 104, 235 Fossil fuels. See Hydrocarbons Fractional crystallization, 126 Fractionation, 149
Frasch, Herman, 235 Frasch process, 235 Free electrons, 33 Free radicals. See Radicals Freon, 44 Fuels, 44–45, 53 Fuller, Buckminster, 22 Fullerenes, 22–23, 191 Fusion, 15 “Fuzzy Ball” Atom, 14
Gadolin, Johann, 120, 278, 290, 291 Gadolinite, 120, 288, 293, 296, 298, 301, 302 Gahn, John Gottlieb, 99 Galena, 203, 204, 235, 246 Gallite, 182 Galvanic protection, 114–15 Gamma radiation, 31 Gases: inert, 29; noble, 261–74 Gasoline. See Petroleum Gay-Lussac, Joseph Louis, 18, 176 Geiger counter, 61, 62 Geijer, Bengt Reinhold, 120 Geneva System of 1892, 5 Geoffroy, Claud J., 221 Germanite, 182, 199 Gersdorffite, 216 Ghiorso, Albert, 322–51 passim Giesel, Friedrich Otto, 308 Glauber, Johann Rudolf, 115, 221 Glauber salt, 51, 52, 115 Glendenin, Lawrence E., 286 Global warming, 194, 227, 231 Gohring, O. H., 312 Goiter, 256 Gold standard, 167 Gore, George, 247 Granite, 89 Gran Sasso, Italy, 183 Graphite, 48, 128, 129, 191, 192 “Greenhouse” effect, 233–34 Greenockite, 144 Gregor, William, 91 GSI (German National Labora-
tory), 351 Gypsum, 74, 227
Haber, Fritz, 210 Haber-Bosch process, 43, 56,
210–11 Hahn, Otto, 312, 343 Halides. See Halogen Group Halite, 249 Hall, Charles Martin, 180 Hall-Heroult process, 180 Halogenation, 44
Harvey, Bernard, 329, 333 Hatchett, Charles, 126 Ha¨vy, Abbe René Just, 68 Heavy Ion Research Laboratory. See
Institute for Heavy Ion Research Heavy metals, 37 Heisenberg, Werner Karl, 11 Heisenberg uncertainty principle, 11 Hematite, 102 Heroult, Paul-Louis-Toussaint, 180 Hessite, 240 Hevesy, Georg Karl von, 149 HILAC (Heavy Ion Linear Accel-
erator), 344 Hillebrand, William F., 281 The Hindenburg, 46 Hisinger, Wilhelm, 238, 281 Hittorf, Johann Wilhelm, 214 Hjelm, Peter Jacob, 128 Hoffman, Darleane C., 340–41,
351 Hofman, Sigurd, 352 Hohenheim, Theophrastus Bom-
bastus von. See Paracelsus Hussein, Saddam, 188 Hutchinsonite, 187 Hydrides, 46 Hydrocarbons, 20–23, 44, 191–94 Hydrocracking, 44–45 Hydrogasification, 42 Hydrogenation, 43–44 Hydrozincite, 115 Hypothyroidism, 256
Iatrochemistry, 4 Ilmenite, 91 Impetigo, 100 Implants, medical, 152, 170, 183,
197–98, 256 Indeterminacy, 11 Indigo, 185 Inert gases, 29 Institute for Heavy Ion Research,
Darmstadt, Germany, 347, 349, 351, 352, 354
International Committee of Weights and Measure, 61 Ion accelerator, 336 Ionic bond. See Chemical
bonding Ionization energy, 18, 28 Ions, 18, 34, 35–36. See also
Chemical bonding Iridosmine, 158 Iron Age, 3, 102–3 Island of (nuclear) stability, 357–
58, 364 Isomers, 21
420 | Index
IUPAC (International Union of
Meyer, Julius Lothar, 25–26 Pure and Applied Chemists), 5,
Light metals, 37
Mica, 179 28, 207, 341, 343, 346, 347,
Limestone, 74, 75, 192, 227
Milk of Magnesia, 72 348, 349
Limonite, 102
Linear accelerator, 336
Milky Way, 210
Millikan, Robert Andrews, 9, 10 James, Charles, 304
Linnaeite, 106
Minum, 204 James, Ralph A., 322, 324
Lithopone, 80
Misch metal, 150, 277, 279 Janssen, Pierre-Jules-César, 263
Lockyer, Joseph Norman, 263
Mitscherlich, Eilhardt, 21 Jezebel, Queen, 219
“Lodestone,” 102
Moissan, Ferdinand-Frederic Henri, JINR (Joint Institute for Nuclear
Lorandite, 187
247 Research), Dubna, Russia, 307,
Lowig, Carl, 253
Molecular structure. See Chemical 341, 342, 344, 346, 347, 355,
bonding 359, 360, 361
Mackenzie, K. R., 258
Molina, Mario, 231 Jupiter, 41
Magnesia alba. See Epsom salt
Magnetite, 91, 102
Molybdenite, 128, 156, 192
Moly-steel, 129 Kekule, Fredrich, 21–22
Magnus, Albertus, 216
Monazite, 89, 120, 275, 276, Kelp, 255
Malachite, 112, 113
280–314 passim Kennedy, Joseph W., 317, 320
Manganite, 99
Monel metal, 109, 113 Kernite, 176
Marble, 74, 75, 192
Monetary standard, 167 Kirchhoff, Gustav, 58, 59, 61
Marggraf, Andreas Sigismund, 115
Morgan, Leon O., 322, 324 Klaproth, Martin Heinrich, 91,
Marignac, Jean-Charles-Gallissard
Mosander, Carl Gustaf, 278, 293, 123, 240, 281, 314
de, 126, 152, 288, 291, 302
296, 300, 301, 302 Klaus, Karl Karlovich, 135
Marinsky, Jacob A., 286
Mosely, Henry Gwynn, 26, 27 Kobolds, 106
“Marsh” test, 217
Mozart, Wolfgang Amadeus, 219 Krennerite, 240
Mass, definition of, 5–6
MRI (Magnetic Resonance Imag- Kroll process, 124, 149
Matter, 14
ing), 106 Kupfernickel, 108, 109
McMillan, Edwin Mattison, 317
Muller von Reichenstein, Franz Kurchatov, Ivan, 342
Meitner, Lise, 312, 349
Menachanite, 91
Joseph, 91, 240
Munzenberg, Gottfried, 347, 348, Langewiesche, William, 188
Mendeleev, Dmitri Ivanovich,
349 Langlet, Niles, 264
Muon, 18 Lanthanide metal series, 29, 30, 37,
Muriatic acid, 250 Larsh, Almon E., 336
Metallic bond. See Chemical bond-
Murphy, E. J., 258 Lasers, 121
ing
Murrah Federal Building, Okla- Latimer, Robert M., 336
Metallics, 173–74, 175–88
homa City, Oklahoma, 211 “Laughing gas,” 211
Metalloids, 29, 37, 189–222
Metallurgical Laboratory at the
Lavoisier, Antoine-Laurent, 5, 42,
Nagyagite, 240 192, 226–27, 235
University of Chicago. See Ar-
Nanotechnology, 22–23 Law of Definite Proportions, 5
gonne National Laboratory
Napoleon Bonaparte, 180 Lawrence, Ernest Orlando, 335
Metallurgy, 103, 112
Natural gas, 42 Lawrence Berkeley National Labo-
Metals, 3, 28, 36–37; actinides, 37,
Neutrino, 18, 183 ratory (LBNL), Berkeley, Cali-
305–37; alkali, 36, 39–64; alkali
Neutrons, 16, 17, 26, 27, 28, 33. fornia, 334, 336, 339, 340, 341,
earth, 36, 65–83; heavy, 37;
See also Atomic structure 342, 346, 359, 360, 361, 364
lanthanides, 37, 275–304; light,
Newlands, John Alexander Reina, Lawrence Livermore National
37; metallics, 173–74, 175–85;
26 Laboratory (LLNL), Livermore,
metalloids, 37, 189–222; noble,
New System of Chemical Philoso- California, 40, 307, 351, 355,
29, 37; other, 37; platinum, 37,
phy, 6 361
134; rare-earth, 37, 275–305;
Niccolite, 109, 216 Lead poisoning, 204–6
superactinides, 357–66; super
Nilson, Lars Frederick, 89 Leadville, Colorado, 204
heavy elements (SHE), 357–65;
Ninov, Victor, 364 LeBeau, P., 68
transactinides, 339–56; transi-
Niobic acid, 126 Lemery, Nicolas, 219
tion, 29, 37, 85–117, 119–46,
Nitrogen cycle, 210 Lepidolite, 48, 58, 61
Nitrogen fixation, 210 Leptons, 17–18, 183
transuranic, 305, 316–37
Nitrogen Group, 207–222 Leucippus of Miletus, 6, 13
Meteorologica, 4–5
“Nitrogen Narcosis,” 264 Lewisite, 217
The Methods of Chemical Nomen-
Nitroglycerine, 211 Libavius, Andreas, 235
clature, 5
Metric system, 160, 164
Nobel, Alfred B., 333
Index |
Nobel Institute of Physics, 334
Rare gases. See Noble gases Nobel Prizes, 407–12
Phosgene, 251
Rayleigh, Lord. See John William Noble gases, 261–74
Phosphates, 213
Photoelectric cells, 59
Strutt
Noble metals, 29, 37
Photons, 11, 13
Realgar, 216
Noddack, Ida (nee Tacke), 132,
Reich, Ferdinand, 185 156
Photosynthesis, 72, 225, 227
Relative weights, concept of, 7 Noddack, Walter Karl, 132, 156
Pierce, John Robinson, 199
Rhodichrosite, 99 Non-polar covalent bond. See
Richter, Hieronymous Theodor, Chemical bonding
Pigeon process, 71
Pine Grove Furnace, Pennsylvania,
Norton, T. H., 281
Rock salt, 249
Nuclear power plants, 314, 315
Röentgen, Wilhelm Konrad, 16 Nuclear reaction, 15, 16–18, 192
Pitchblende, 82, 242, 308, 314
Roscoe, Henry Enfield, 94 Nucleus. See Atomic structure
Pittsburgh Reduction Company.
See ALCOA
Roscoelite, 94
Rose, Heinrich, 126 Oak Ridge National Laboratory,
Planck, Max Karl Ernst Ludwig, 11
Rowland, F. Sherwood, 231 Oak Ridge, Tennessee, 331
Planck’s Constant, 11
Rutherford, Daniel, 210, 226 Octet rule, 25
Plaster of Paris, 74
Rutherford, Ernest, 9, 13, 16, 26, Oersted, Hans-Christian, 179
Platinum metals, 37, 134
31, 167, 342, 343 OFPA (Organic Foods Production
Pnictogen group. See Nitrogen
Rutherford model, 11, 13. See also Act), 23
Group
Atomic structure Old Nick’s Copper, 109
Polar covalent bond. See Chemical
bonding
Rutile, 91, 92
Orbital theory, 11–15
Pollucite, 61
Organic chemistry. See Chemistry
SAGE (Soviet American Gallium Orpiment, 216
Polyhalite, 54
Experiment), 183 Osann, Gottfried Wilhelm, 134–35
Polymers, 44
Saint-Claire-Deville, Henri, 180 Ostwald, Wilhelm, 211
Positron, 18
Sal mirabile. See Glauber salt Oxidation, 225
Potash, 253
Saltpeter, 51, 55, 75, 211 Oxygen Group, 223–43
Powellite, 128
Salts, 51–53, 253–54 Ozone, 229–34; greenhouse ef-
Priestley, Joseph, 99, 129, 169,
Samarskite, 288 fect, 233–34; layer, 231–33,
SASSY-2 (Small Angle Separator 247; level, 231; UV radiation,
“Proof” (alcohol), 43
Scheele, Carl Wilhelm, 80, 99,
Scherbenkobalt, 216 Paris green, 217
Paris Commission, 134
Pyrochlore, 125, 126
Schonbein, Christian Friederich, Particle physics. See Atomic struc-
Pyrolusite, 99, 250
Seaborg, Glenn T., 320–65 passim Patronite, 94
ture
Quantum energy, 11, 14–15
Quantum mechanics, 13
Seaweed, 255
Pauli, Wolfgang, 11
Sefstrom, Nils Gabriel, 94 Pauling, Linus, 22, 242
Quantum theory, 13
Segre, Emilio Gino, 132, 258 Pegmatite, 89
Quarks, 17
Semiconductors, 29, 37, 121, Peligo, Eugene-Melchoir, 314
Quartz, 195, 196, 246
Pelopic acid, 126
SHE (Super Heavy Elements). See Pentlandite, 109
Radiation, 31–34; discovery of,
Superactinides Perey, Marguerite, 63, 64
16, 31; experimentation, 16–17;
Shells, 11, 14–15 Periodic Table of the Chemical Ele-
hazards, 33; sources, 107; trans-
SHIP (Separator for Heavy Ion ments, 25, 209
mutation, 31–32; treatments, 62,
Research Products), Darmstadt, Perrier, Carlo, 132
83, 129; types, 31; Ultraviolet,
Germany, 347, 351, 352 PET (Positron Emission Tomogra-
Shockley, William Bradford, 199 phy), 106, 211, 247–48
Petrochemicals. See Hydrocarbons
Sikkeland, Torbjorn, 334, 336 Petroleum, 44–45
Radioisotope, 32
Radon, hazards, 32, 83, 274
Silicosis, 197
Philosopher’s stone, 4, 169
The Skeptical Chymist, 4 Phlogisticated air, 226
Ramsay, William, 263–64, 266,
Smaltite, 106, 216 Phlogiston theory, 5, 41–42
Rare-earth metals, 30, 37, 275–304
Smithsonite, 115
422 | Index
Vermillion, 169 Soddy, Frederick, 312
Sniadecki, Jedrzej, 134
Thompson, Stanley G., 325, 327,
Vitiated air, 226 Solvay process, 52, 56
Thomson, Joseph John, 9, 13, 26