Thick-Film Sacrificial Layer Techniques

39 dielectric material is printed on top of the filler and parts of the substrate, where the part that printed on the substrate will form a rigid base to support the free-standing structure. The dried paste is then co-fired in a nitrogen atmosphere. The nitrogen must be used because the filler must not be burnt out before the glass-ceramic has sintered. The process is repeated to form a multilayer composite film. Finally, the composite film is co-fired in an air environment, where the carbon filler acting as a sacrificial layer is burnt out without residues, releasing a composite thick-film free-standing structure. The fabrication steps are shown in Figure 2-18. Figure 2-18: Fabrication steps for thick-film sacrificial layer technique. Alumina substrate Carbon-like filler Step 1: Carbon-like filler printing Step 2: Electrode and PZT layers print on top of the filler and fired in nitrogen environment Electrode PZT Step 3: Fire in air environment to burn carbon-like filler Free-Standing Structure 40

2.7 Conclusion

Free-standing structures in the form of a cantilever are interesting features which find application in sensing and actuating. Incorporated with high piezoelectric activity materials like PZT, the structures can be operated as micro-generators for powering low power microelectronic devices. The micro-generators can be modelled as a single- degree-of-freedom mass-spring-damper system, where the electrical output power can be estimated and improved with optimised designs. Conventionally, free-standing structures were fabricated with thin-film and silicon micro-engineering technologies. Thick-film technology, however, has not received significant attention compared with its competitor technologies, for fabricating free-standing structures. One of the main reasons for this is because piezoceramics are considered too fragile to form free- standing structures. In this work, studies on the free-standing structures fabricated by thick-film technology will be presented. 41

Chapter 3 Free-Standing

Cantilever Structure Designs

3.1 Introduction

Making the reality of ambient vibration energy harvesting using thick-film free-standing structure is very challenging. Some of the challenges include, fabricating a robust piezoceramic structure, ensuring the structure resonates with the vibration sources, solving the problem of unpredictable ambient vibrations and meeting the minimum electrical energy requirement. First and foremost the characteristics of potential vibration sources from the environment have to be investigated before any energy harvester device can be designed. Once the vibration sources are identified, energy harvesters can be tailored to suit that specific environment. Besides that, the design of the energy harvesters has to be based on the limitation of the fabrication technology in this case, thick-film technology and the physical constrains of the real device e.g. the maximum allowed displacement and stress before the device fails to respond accordingly or is broken in order to fabricate a robust piezoceramic structure. The output voltage and electrical power are the crucial factors in making the device useful. For this reason, the multimorph structure was developed to enhance the electrical performance of the device. Besides improving the electrical energy output, the multimorph can be deployed as either current source or voltage source depending on the