Sintesis Surfaktan Tert-Butil 6-O-Butanoil Galaktosida Melalui Reaksi Setalisasi Antara Galaktosa Dengan Tert-Butanol Yang Diikuti Reaksi Esterifikasi Dengan Asam Butirat

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

_._---
SINTESIS SURFAKTAN tert-BUTIL 6-0-BUTANOIL GALAKTOSIDA MELALUI REAKSI ASETAUSASI ANTARA GALAKTOSA DENGAN tert·BUTANOL YANG DHKUTI REAKSI
ESTERlFIKASI DENGAN ASAM BUTIRAT
TESIS
Ulltuk memper-eleh Geier Magister Scins delcm Program Studi Kimia pada Program Pascasarjalla Universitas Sumatel'Q Utero
HELMINA BR. SEMBIRING 992106007 I KIMIA
PROGRAM PASCASARJANA
UNIVERSITAS SUMATJ3RA UTARA MSDAN 2001
Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Judul Tesis

: SINTESIS SURFAKTAN lerl·BUTll 6-0-BUTANOll GALAKTOSIDA MELALUI REAKSI ASETALlSASI ANTARA GALAKTOSA DENGAN tert-BUTANOl YANG DIIKUTI REAKSI ESTERIFIKASI DENGAN ASAM BUTIRAT

Nama Mahas!swa Helmina Br. Sembiring

Nemer Pokok

992106007


Program Studi

Kimia

Menyelujui Komisi Pembimb' g,
⦅OセA
(Prof. Dr. Hakim erangun, Apt.)
Ketua

(Prof. C . Hemat , . Brahmana, M.Sc.) (Drs. Mimpin Ginting, M.S.)

Anggota

Anggota

Ketua Program S di,
(Prof.
Tilnggal tutus : 08 Desember 2001


Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

ABSTRAK
Surfaktan ester tert-butil-6-0-butanoil galaktosida dapat disintesis dari galaktosa, tert-butanol dan asam butirat melalui satu seri reaksi yakni asetalisasi dan esterifikasi.
Asetalisasi dari D-galaktosa dengan tert-butanol dari dalam pelarut petroleum eter menggunakan katalisasam para toluen sulfonat menghasilkan tert-butil galaktosida. Hasil asetalisasi ini diesterifikasi secara selektif dengan asam butirat menggunakan katalis asam para toluen sulfonat dan dihasilkan ester tert-butil-6-0butanoil galaktosida.
Setiap tahap reaksi dikarakterisasi dengan analisis spektroskopi FT-IR, IH_ NMR, dan pengukuran tegangan permukaan. Senyawa ester tert-butil-6-0-butanoil galaktosida yang diperoleh adalah suatu surfaktan dengan konsentrasi misel kritis (CMC) adalah 0,006% dan nilai HLB 3,50.
Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

ABSTRACT
A surfactant tert-butil-c-Osbutanoyl galactoside ester has been synthesized from galaktose, tert-butanol and butyric acid in a series of reactions, i.e. acetalization and esterification.
Acetalization of D-galaetose with tert-butanol in petroleum eter as a solvent using para toluene sulfonic acid as a catalyst gave tert-butyl galactoside. The product was selectively esterificated with butiric acid using para toluene sulfonic acid as a catalyst to produce tert-butyl-e-Osbutanoyl galactoside ester.
Each step of reaction was characterized by analysis spectroscopy FT-IR, IH_ NMR, and the measurement of surface tesion. The compound tert-butyl-S-Ocbutanoyl galactoside ester produced was a surfactant with critical micelle (CMC) was 0.006% and HLB value 3.50.
II Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008


Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008


Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008


Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008


Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008


Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008


Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008


Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008

Helmina br. Sembiring : Sintesis surfaktan tert-butil 6-O-butanoil galaktosida melalui reaksi setalisasi antara..., 2001 USU e-Repository © 2008