2. 1. BCP I 2. 1. 1. HAp Bidang 2 1 1 2
P3 x, y, z;
-y, x-y, z; -x+y, -x, z;
-y, -x, z+12; -x+y, y, z+12;
x, x-y, z+12; x
= -0,3470 y
= -0,1536 z
= -0,2332 O1
x, y, z; -y, x-y, z;
-x+y, -x, z; -y, -x, z+12;
-x+y, y, z+12; x, x-y, z+12;
x = -0,2744 y = -0,09440
z = -0,09170
O2 x, y, z;
-y, x-y, z; -x+y, -x, z;
-y, -x, z+12; -x+y, y, z+12;
x, x-y, z+12; x
= -0,2326 y
= -0,2167 z
= -0,1452 O3
x, y, z; -y, x-y, z;
-x+y, -x, z; -y, -x, z+12;
-x+y, y, z+12; x, x-y, z+12;
x = -0,2702
y = 0,008800
z = -0,1514
O4 x, y, z;
-y, x-y, z; -x+y, -x, z;
-y, -x, z+12; -x+y, y, z
+12; x, x-y, z+12;
x = -0,4779
y = -0,2392
z = -0,1373
O5 x, y, z;
-y, x-y, z; -x+y, -x, z;
-y, -x, z+12; -x+y, y, z+12;
x, x-y, z+12; x
= -0,4013 y
= -0,04880 z
= -0,2206 O6
x, y, z; -y, x-y, z;
-x+y, -x, z; -y, -x, z+12;
-x+y, y, z+12; x, x-y, z+12;
x = -0,4262
y = -0,3070
z = -0,2150
Tabel 45 Posisi atom CaOH
2
Atom Posisi
Ca x, y, z;
x = 0
y = 0
z = 0
O x, y, z;
-x, -y, -z; x
= 0,3333 y
= 0,6666 z
= 0,2330 H
x, y, z; -x, -y, -z;
x = 0,3333
y = 0,6666
z = 0,4180
7. 2. Menentukan Faktor Struktur
F
hkl
7. 2. 1. BCP I 7. 2. 1. 1. HAp Bidang 2 1 1 2
θ = 31,68
o
Faktor hamburan atomik =
sin θ
=
sin 15,84 1,54056 Å
= 0,1772 f
Ca
2+
= 16,80 f
P
5+
= 9,800 f
O
2 –
= 8,000 f
H
+
= 0,4800 F
hkl
= f
N N
e
2 πihx
N
+ky
N
+lz
N
F
211
= f
Ca
2+
� 2
N = 1
e
2 πi2.x
Ca2+
+1.y
Ca2+
+1.z
Ca2+
+ f
P
5+
N = 1
e
2 πi2.x
P5+
+1.y
P5+
+1.z
P5+
+ f
O
2 –
N 3
N = 1
e
2 πi2.x
O2–
+1.y
O2–
+1.z
O2–
+ f
H
+
N = 1
e
2 πi2.x
H
+1.y
H
+1.z
H
F
211
= f
Ca
2+
1
e
2 πi2.0,3333+1.0,6667+1.0,0011
+ e
2 πi2.-0,3333+1.-0,6667+1.0,5000+0,001100
+ e
2 πi2.-0,3333+1.-0,6667+1.-0,0011
+ e
2 πi2.0,3333+1.0,6667+1.-0,5000-0,001100
+ f
Ca
2+
2
e
2 πi2.0,7513+1.0,7584+1.0,25
+ e
2 πi2.-0,7584+1.0,7513-0,7584+1.0,25
+ e
2 πi2.0,7584-0,7513+1.-0,7513+1.0,25
+ e
2 πi2.-0,7513+1.-0,7584+1.-0,25
+ e
2 πi2.0,7584+1.-0,7513+0,7584+1.-0,25
+ e
2 πi2.-0,7584+0,7513+1.0,7513+1.-0,25
+ f
P
5+
e
2 πi2.0,9707+1.0,6019+1.0,25
+ e
2 πi2.-0,6019+1.0,9707-0,6019+1.0,25
+ e
2 πi2.0,6019-0,9707+1.-0,9707+1.0,25
+ e
2 πi2.-0,9707+1.-0,6019+1.-0,25
+ e
2 πi2.0,6019+1.-0,9707+0,6019+1.-0,25
+ e
2 πi2.-0,6019+0,9707+1.0,9707+1.-0,25
+ f
O
2 –
1
e
2 πi2.0,1581+1.0,6738+1.0,25
+ e
2 πi2.-0,6738+1.0,1581-0,6738+1.0,25
+ e
2 πi2.0,6738-0,1581+1.-0,1581+1.0,25
+ e
2 πi2.-0,1581+1.-0,6738+1.-0,25
+ e
2 πi2.0,6738+1.-0,1581+0,6738+1.-0,25
+ e
2 πi2.-0,6738+0,1581+1.0,1581+1.-0,25
+ f
O
2 –
2
e
2 πi2.0,8788+1.0,4120+1.0,25
+ e
2 πi2.-0,4120+1.0,8788-0,4120+1.0,25
+ e
2 πi2.0,4120-0,8788+1.-0,8788+1.0,25
+ e
2 πi2.-0,8788+1.-0,4120+1.-0,25
+ e
2 πi2.0,4120+1.-0,8788+0,4120+1.-0,25
+ e
2 πi2.-0,4120+0,8788+1.0,8788+1.-0,25
+ f
O
2 –
3
e
2 πi2.0,3416+1.0,2568+1.0,0704
+ e
2 πi2.-0,2568+1.0,3416-0,2568+1.0,0704
+ e
2 πi2.0,2568-0,3416+1.-0,3416+1.0,0704
+ e
2 πi2.-0,3416+1.-0,2568+1.0,5+0,0704
+ e
2 πi2.0,2568+1.0,2568-0,3416+1.0,5+0,0704
+ e
2 πi2.0,3416-0,2568+1.0,3416+1.0,5+0,0704
+ e
2 πi2.-0,3416+1.-0,2568+1.-0,0704
+ e
2 πi2.0,2568+1.-0,3416+0,2568+1.-0,0704
+ e
2 πi2.-0,2568+0,3416+1.0,3416+1.-0,0704
+ e
2 πi2.0,3416+1.0,2568+1.-0,5-0,0704
+ e
2 πi2.-0,2568+1.-0,2568+0,3416+1.-0,5-0,0704
+ e
2 πi2.-0,3416+0,2568+1.-0,3416+1.-0,5-0,0704
+ f
H
+
e
2 πi2.0+1.0+1.0,25
+ e
2 πi2.-0+1.-0+1.-0,25
F
211
= f
Ca
2+
1
– 0,5058 + 0,8626i + 0,4938 + 0,8696i – 0,5058 – 0,8626i + 0,4938 – 0,8696i + f
Ca
2+
2
– 0,9976 – 0,06906i – 0,1496 – 0,9887i – 0,9967 – 0,08096i – 0,9976 + 0,06906i
– 0,1496 + 0,9887i – 0,9967 + 0,08096i + f
P
5+
0,2687 –
0,9632i – 0,8607 + 0,5090i – 0,9659 – 0,2590i + 0,2687 + 0,9632i – 0,8607 –
0,5090i – 0,9659 + 0,2590i + f
O
2 –
1
0,06279 + 0,9980i – 0,7571 + 0,6533i +
0,7146 + 0,6995i + 0,06279 – 0,9980i – 0,7571 – 0,6533i + 0,7146 – 0,6995i +
f
O
2 –
2
– 0,8751 + 0,4840i + 0,7816 – 0,6238i – 0,9241 + 0,3821i – 0,8751 – 0,4840i + 0,7816 + 0,6238i + 0,7816 + 0,6238i + f
O
2 –
3
0,9979 + 0,06530i + 0,9979 + 0,06530i
– 0,9316 – 0,3634i – 0,6827 – 0,7307i + 1,000 – 0,005026i + 0,8714 + 0,4905i + 0,9979
– 0,06530i – 0,6296 + 0,7769i – 0,9316 + 0,3634i – 0,6827 + 0,7307i + 1,000 + 0,005026i + 0,8714
– 0,4905i + f
H
+
1,000i – 1,000i
F
211
= f
Ca
2+
1
– 1,012 + f
Ca
2+
2
– 4,288 + f
P
5+
– 3,116 + f
O
2 –
1
0,04058 + f
O
2 –
2
– 0,3295 + 1,006i + f
O
2 –
3
2,878 + 0,8422i + f
H
+
F
211
= 16,80 – 1,012 + 16,80– 4,288 + 9,800– 3,116 + 8,0000,04058 +
8,000 – 0,3295 + 1,006i + 8,0002,878 + 0,8422i + 0,48000
F
211
= – 17,00 – 72,04 – 30,54 + 0,3246 – 2,636 + 8,048i + 23,02 + 6,738i + 0
F
211
= – 98,86 + 14,79i
|F
211
| = 99,96 7. 2. 1. 2. HAp Bidang 0 0 4 2
θ = 52,88
o
Faktor hamburan atomik =
sin θ
=
sin 26,44 1,54056 Å
= 0,2890 f
Ca
2+
= 14,00 f
P
5+
= 9,250 f
O
2 –
= 5,500 f
H
+
= 0,2500 F
hkl
= f
N N
e
2 πihx
N
+ky
N
+lz
N
F
004
= f
Ca
2+
N 2
N = 1
e
2 πi0.x
Ca2+
+0.y
Ca2+
+4.z
Ca2+
+ f
P
5+
N = 1
e
2 πi0.x
P5+
+0.y
P5+
+4.z
P5+
+ f
O
2 –
N 3
N = 1
e
2 πi0.x
O2–
+0.y
O2–
+4.z
O2–
+ f
H
+
N = 1
e
2 πi0.x
H
+0.y
H
+4.z
H
F
004
= f
Ca
2+
1
e
2 πi4.0,0011
+ e
2 πi4.0,5000+0,001100
+ e
2 πi4.-0,0011
+ e
2 πi4.-0,5000-0,001100
+ f
Ca
2+
2
e
2 πi4.0,25
+ e
2 πi4.0,25
+ e
2 πi4.0,25
+ e
2 πi4.-0,25
+ e
2 πi4.-0,25
+ e
2 πi4.-0,25
+ f
P
5+
e
2 πi4.0,25
+ e
2 πi4.0,25
+ e
2 πi4.0,25
+ e
2 πi4.-0,25
+ e
2 πi4.-0,25
+ e
2 πi4.-0,25
+ f
O
2 –
1
e
2 πi4.0,25
+ e
2 πi4.0,25
+ e
2 πi4.0,25
+ e
2 πi4.-0,25
+ e
2 πi4.-0,25
+ e
2 πi4.-0,25
+ f
O
2 –
2
e
2 πi4.0,25
+ e
2 πi4.0,25
+ e
2 πi4.0,25
+ e
2 πi4.-0,25
+ e
2 πi4.-0,25
+ e
2 πi4.-0,25
+ f
O
2 –
3
e
2 πi4.0,0704
+ e
2 πi4.0,0704
+ e
2 πi4.0,0704
+ e
2 πi4.0,5+0,0704
+ e
2 πi4.0,5+0,0704
+ e
2 πi4.0,5+0,0704
+ e
2 πi4.-0,0704
+ e
2 πi4.-0,0704
+ e
2 πi4.-0,0704
+ e
2 πi4.-0,5-0,0704
+ e
2 πi4.-0,5-0,0704
+ e
2 πi4.-0,5-0,0704
+ f
H
+
e
2 πi4.0,25
+ e
2 πi4.-0,25
F
004
= f
Ca
2+
1
0,9996 + 0,02764i + 0,9996 + 0,02764i + 0,9996 – 0,02764i + 0,9996 –
0,02764i + f
Ca
2+
2
1,000 + 1,000 + 1,000 + 1,000 + 1,000 + 1,000 + f
P
5+
1,000 + 1,000 + 1,000 + 1,000 + 1,000 + 1,000 + f
O
2 –
1
1,000 + 1,000 + 1,000 + 1,000 + 1,000 + 1,000 + f
O
2 –
2
1,000 + 1,000 + 1,000 + 1,000 + 1,000 + 1,000 + f
O
2 –
3
– 0,1972 + 0,9804i – 0,1972 + 0,9804i – 0,1972 + 0,9804i – 0,1972 + 0,9804i
– 0,1972 + 0,9804i – 0,1972 + 0,9804i – 0,1972 – 0,9804i – 0,1972 –
0,9804i – 0,1972 – 0,9804i – 0,1972 – 0,9804i – 0,1972 – 0,9804i – 0,1972 –
0,9804i + f
H
+
1,000 + 1,000 F
004
= f
Ca
2+
1
3,998 + f
Ca
2+
2
6,000 + f
P
5+
6,000 + f
O
2 –
1
6,000 + f
O
2 –
2
6,000 + f
O
2 –
3
– 2,366 + f
H
+
2,000 F
004
= 14,003,998 + 14,006,000 + 9,2506,000 + 5,5006,000 + 5,5006,000 + 5,500
– 2,366 + 0,25002,000 F
004
= 55,97 + 84,00 + 55,50 + 33,00 + 33,00 – 13,01 + 0,5000
F
004
= 249,0 |F
004
| = 249,0 7. 2. 1. 3.
β-TCP Bidang 3 0 0 2θ = 29,54
Faktor hamburan atomik =
sin θ
=
sin 14,77 1,54056 Å
= 0,1655 f
Ca
2+
= 16,80 f
P
5+
= 9,800 f
O
2 –
= 8,000 F
hkl
= Faktor translasiFaktor basis Faktor translasi = e
2 πi3.0+0.0+0.0
+ e
2 πi3.23+0.13+0.13
+ e
2 πi3.13+0.23+0.23
Faktor translasi = e
2 πi0
+ e
2 πi2
+ e
2 πi1
= 1 + 1 + 1 = 3 F
300
= 3 f
Ca
2+
N 5
N = 1
e
2 πi3.x
Ca2+
+0.y
Ca2+
+0.z
Ca2+
+ f
P
5+
N 3
N = 1
e
2 πi3.x
P5+
+0.y
P5+
+0.z
P5+
+ f
O
2 –
N 6
N = 1
e
2 πi3.x
O2–
+0.y
O2–
+0.z
O2–
F
300
= 3f
Ca
2+
1
e
2 πi3.-0,2741
+ e
2 πi3.--0,1382
+ e
2 πi3.--0,1382
+ e
2 πi3.--0,1382
+ e
2 πi3.--0,2741+-0,1382
+ e
2 πi3.-0,2741
+ f
Ca
2+
2
e
2 πi3.-0,3812
+ e
2 πi3.--0,1745
+ e
2 πi3.--0,3812+-0,1745
+ e
2 πi3.--0,1745
+ e
2 πi3.--0,3812+-0,1745
+ e
2 πi3.-0,3812
+ f
Ca
2+
3
e
2 πi3.-0,2734
+ e
2 πi3.--0,1486
+ e
2 πi3.--0,2734+-0,1486
+ e
2 πi3.--0,1486
+ e
2 πi3.--0,2734+-0,1486
+ e
2 πi3.-0,2734
+ f
Ca
2+
4
e
2 πi3.0
+ e
2 πi3.-0
+ f
Ca
2+
5
e
2 πi3.0
+ e
2 πi3.-0
+ f
P
5+
1
e
2 πi3.0
+ e
2 πi3.-0
+ f
P
5+
2
e
2 πi3.-0,3128
+ e
2 πi3.--0,1394
+ e
2 πi3.--0,3128+-0,1394
+ e
2 πi3.--0,1394
+ e
2 πi3.--0,3128+-0,1394
+ e
2 πi3.-0,3128
+ f
P
5+
3
e
2 πi3.-0,3470
+ e
2 πi3.--0,1536
+ e
2 πi3.--0,3470+-0,1536
+ e
2 πi3.--0,1536
+ e
2 πi3.--0,3470+-0,1536
+ e
2 πi3.-0,3470
+ f
O
2 –
1
e
2 πi3.-0,2744
+ e
2 πi3.--0,09440
+ e
2 πi3.--0,2744+-0,09440
+ e
2 πi3.--0,09440
+ e
2 πi3.--0,2744+-0,09440
+ e
2 πi3.-0,2744
+ f
O
2 –
2
e
2 πi3.-0,2326
+ e
2 πi3.--0,2167
+ e
2 πi3.--0,2326+-0,2167
+
e
2 πi3.--0,2167
+ e
2 πi3.--0,2326+-0,2167
+ e
2 πi3.-0,2326
+ f
O
2 –
3
e
2 πi3.-0,2702
+ e
2 πi3.-
0,008800
+ e
2 πi3.--0,2702+0,008800
+ e
2 πi3.-0,008800
+ e
2 πi3.--0,2702+0,008800
+ e
2 πi3.-
0,2702
+ f
O
2 –
4
e
2 πi3.-0,4779
+ e
2 πi3.--0,2392
+ e
2 πi3.--0,4779+-0,2392
+ e
2 πi3.--
0,2392
+ e
2 πi3.--0,4779+-0,2392
+ e
2 πi3.-0,4779
+ f
O
2 –
5
e
2 πi3.-0,4013
+ e
2 πi3.--
0,04880
+ e
2 πi3.--0,4013+-0,04880
+ e
2 πi3.--0,04880
+ e
2 πi3.--0,4013+-0,04880
+ e
2 πi3.-
0,4013
+ f
O
2 –
6
e
2 πi3.-0,4262
+ e
2 πi3.--0,3070
+ e
2 πi3.--0,4262+-0,3070
+ e
2 πi3.--
0,3070
+ e
2 πi3.--0,4262+-0,3070
+ e
2 πi3.-0,4262
F
300
= 3f
Ca
2+
1
0,4388 + 0,8986i – 0,8594 + 0,5112i – 0,8594 + 0,5112i – 0,8594 +
0,5112i – 0,8365 + 0,5480i + 0,4388 + 0,8986i + f
Ca
2+
2
0,6198 – 0,7847i –
0,9891 – 0,1471i – 0,7285 – 0,6850i – 0,9891 – 0,1471i – 0,7285 – 0,6850i +
0,6198 – 0,7847i + f
Ca
2+
3
0,4269 + 0,9043i – 0,9426 + 0,3340i – 0,7044 +
0,7098i – 0,9426 + 0,3340i – 0,7044 + 0,7098i + 0,4269 + 0,9043i + f
Ca
2+
4
1,000 + 1,000 + f
Ca
2+
5
1,000 + 1,000 + f
P
5+
1
1,000 + 1,000 + f
P
5+
2
0,9260 + 0,3774i
– 0,8708 + 0,4916i – 0,9920 – 0,1266i – 0,8708 + 0,4916i – 0,9920 – 0,1266i + 0,9260 + 0,3774i + f
P
5+
3
0,9670 – 0,2548i – 0,9698 + 0,2438i – 0,8757
– 0,4828i – 0,9698 + 0,2438i – 0,8757 – 0,4828i + 0,9670 – 0,2548i + f
O
2 –
1
0,4439 + 0,8961i – 0,2071 + 0,9783i – 0,9686 – 0,2487i – 0,2071 + 0,9783i
– 0,9686 – 0,2487i + 0,4439 + 0,8961i + f
O
2 –
2
– 0,3221 + 0,9467i – 0,5873 – 0,8094i + 0,9554 + 0,2952i
– 0,5873 – 0,8094i + 0,9554 + 0,2952i – 0,3221 + 0,9467i + f
O
2 –
3
0,3716 + 0,9284i + 0,9863 – 0,1651i + 0,5198 – 0,8543i + 0,9863
– 0,1651i + 0,5198 – 0,8543i + 0,3716 + 0,9284i + f
O
2 –
4
– 0,9145 – 0,4046i – 0,2022
– 0,9794i – 0,2114 – 0,9774i – 0,2022 – 0,9794i – 0,2114 – 0,9774i – 0,9145
– 0,4046i + f
O
2 –
5
0,2856 – 0,9583i + 0,6059 + 0,7955i + 0,9354 + 0,3535i
+ 0,6059 + 0,7955i + 0,6059 + 0,7955i + 0,2856 – 0,5834i + f
O
2 –
6
– 0,1787 – 0,9839i + 0,8793
– 0,4762i – 0,6257 + 0,7800i + 0,8793 – 0,4762i – 0,6257 + 0,7800i
– 0,1787 – 0,9839i F
300
= 3f
Ca
2+
1
– 2,537 + 3,879i + f
Ca
2+
2
– 2,196 – 3,234i + f
Ca
2+
3
– 2,440 – 3,896i + f
Ca
2+
4
2,000 + f
Ca
2+
5
2,000 + f
P
5+
1
2,000 + f
P
5+
2
– 1,874 + 1,485i + f
P
5+
3
– 1,757 – 0,9876i + f
O
2 –
1
– 1,464 + 3,251i + f
O
2 –
2
0,09200 + 0,8650i + f
O
2 –
3
3,755 – 0,1820i + f
O
2 –
4
– 2,656 – 4,723i + f
O
2 –
5
3,324 + 1,198i + f
O
2 –
6
0,1498 – 1,360i
F
300
= 316,80 – 2,537 + 3,879i + 16,80– 2,196 – 3,234i + 16,80– 2,440 –
3,896i + 16,802,000 + 16,802,000 + 9,8002,000 + 9,800 – 1,874 +
1,485i + 9,800 – 1,757 – 0,9876i + 8,000– 1,464 + 3,251i +
8,0000,09200 + 0,8650i + 8,0003,755 – 0,1820i + 8,000– 2,656 – 4,723i
+ 8,0003,324 + 1,198i + 8,0000,1498 – 1,360i
F
300
= 3 – 42,62 + 65,17i – 36,89 – 54,33i – 40,99 – 65,45i + 33,60 + 33,60 + 19,60 –
18,36 + 14,55i – 17,22 – 9,678i – 11,71 + 26,01i + 0,7360 + 6,920i + 30,04 –
1,456i – 21,25 – 37,78i + 26,59 + 9,584i + 1,198 – 10,88i
F
300
= 3 – 43,68 – 57,34i
F
300
= – 131,0 – 172,0i
|F
300
| = 216,3 7. 2. 1. 4.
β-TCP Bidang 0 2 10 2θ = 30,98
Faktor hamburan atomik =
sin θ
=
sin 15,49 1,54056 Å
= 0,1734 f
Ca
2+
= 16,80 f
P
5+
= 9,800 f
O
2 –
= 8,000 F
hkl
= Faktor translasiFaktor basis Faktor translasi = e
2 πi3.0+0.0+0.0
+ e
2 πi3.23+0.13+0.13
+ e
2 πi3.13+0.23+0.23
= e
2 πi0
+ e
2 πi2
+ e
2 πi1
= 1 + 1 + 1 = 3 F
0210
= 3 f
Ca
2+
� 5
N = 1
e
2 πi0.x
Ca2+
+2.y
Ca2+
+10.z
Ca2+
+ f
P
5+
N 3
N = 1
e
2 πi0.x
P5+
+2.y
P5+
+10.z
P5+
+ f
O
2 –
N 6
N = 1
e
2 πi0.x
O2–
+2.y
O2–
+10.z
O2–
F
0210
= 3f
Ca
2+
1
e
2 πi2.-0,1382+10.0,1663
+ e
2 πi2.-0,2741--0,1382+10.0,1663
+ e
2 πi2.--0,2741+10.0,1663
+ e
2 πi2.--0,2741+10.0,1663+0,5
+ e
2 πi2.-0,1382+10.0,1663+0,5
+ e
2 πi2.-0,2741--0,1382+10.0,1663+0,5
+ f
Ca
2+
2
e
2 πi2.-0,1745+10.-0,03320
+ e
2 πi2.-0,3812--0,1745+10.-0,03320
+ e
2 πi2.--0,3812+10.-0,03320
+ e
2 πi2.--0,3812+10.-0,03320+0,5
+ e
2 πi2.-0,1745+10.-0,03320+0,5
+ e
2 πi2.-0,3812--0,1745+10.-0,03320+0,5
+ f
Ca
2+
3
e
2 πi2.-0,1486+10.0,06110
+ e
2 πi2.-0,2734--0,1486+10.0,06110
+ e
2 πi2.--0,2734+10.0,06110
+ e
2 πi2.--0,2734+10.0,06110+0,5
+ e
2 πi2.-0,1486+10.0,06110+0,5
+ e
2 πi2.-0,2734--0,1486+10.0,06110+0,5
+ f
Ca
2+
4
e
2 πi2.0+10.0,9149
+ e
2 πi2.-0+10.0,9149+0,5
+ f
Ca
2+
5
e
2 πi2.0+10.0,7336
+ e
2 πi2.-0+10.0,7336+0,5
+ f
P
5+
1
e
2 πi2.0+10.1
+ e
2 πi2.-0+10.1+0,5
+ f
P
5+
2
e
2 πi2.-0,1394+10.-0,1315
+
e
2 πi2.-0,3128--0,1394+10.-0,1315
+ e
2 πi2.--0,3128+10.-0,1315
+ e
2 πi2.--0,3128+10.-0,1315+0,5
+ e
2 πi2.-0,1394+10.-0,1315+0,5
+ e
2 πi2.-0,3128--0,1394+10.-0,1315+0,5
+ f
P
5+
3
e
2 πi2.-0,1536+10.-0,2332
+ e
2 πi2.-0,3470--0,1536+10.-0,2332
+ e
2 πi2.--0,3470+10.-0,2332
+ e
2 πi2.--0,3470+10.-0,2332+0,5
+ e
2 πi2.-0,1536+10.-0,2332+0,5
+ e
2 πi2.-0,3470--0,1536+10.-0,2332+0,5
+ f
O
2 –
1
e
2 πi2.-0,09440+10.-0,09170
+ e
2 πi2.-0,2744--0,09440+10.-0,09170
+ e
2 πi2.--0,2744+10.-0,09170
+ e
2 πi2.--0,2744+10.-0,09170+0,5
+ e
2 πi-0,09440+2.-0,09440+10.-0,09170+0,5
+ e
2 πi2.-0,2744--0,09440+10.-0,09170+0,5
+ f
O
2 –
2
e
2 πi2.-0,2167+10.-0,1452
+ e
2 πi2.-0,2326--0,2167+10.-0,1452
+ e
2 πi2.--0,2326+10.-0,1452
+ e
2 πi2.--0,2326+10.-0,1452+0,5
+ e
2 πi2.-0,2167+10.-0,1452+0,5
+ e
2 πi2.-0,2326--0,2167+10.-0,1452+0,5
+ f
O
2 –
3
e
2 πi2.0,008800+10.-0,1514
+ e
2 πi2.-0,2702-0,008800+10.-0,1514
+ e
2 πi0,008800+2.--0,2702+10.-0,1514
+ e
2 πi2.--0,2702+10.-0,1514+0,5
+ e
2 πi0,008800+2.0,008800+10.-0,1514+0,5
+ e
2 πi2.-0,2702-0,008800+10.-0,1514+0,5
+ f
O
2 –
4
e
2 πi2.-0,2392+10.-0,1373
+ e
2 πi2.-0,4779--0,2392+10.-0,1373
+ e
2 πi-0,2392+2.--0,4779+10.-0,1373
+ e
2 πi2.--0,4779+10.-0,1373+0,5
+ e
2 πi-0,2392+2.-0,2392+10.-0,1373+0,5
+ e
2 πi2.-0,4779--0,2392+10.-0,1373+0,5
+ f
O
2 –
5
e
2 πi2.-0,04880+10.-0,2206
+ e
2 πi2.-0,4013--0,04880+10.-0,2206
+ e
2 πi2.--0,4013+10.-0,2206
+ e
2 πi2.--0,4013+10.-0,2206+0,5
+ e
2 πi-0,04880+2.-0,04880+10.-0,2206+0,5
+ e
2 πi2.-0,4013--0,04880+10.-0,2206+0,5
+ f
O
2 –
6
e
2 πi2.-0,3070+10.-0,2150
+ e
2 πi2.-0,4262--0,3070+10.-0,2150
+ e
2 πi2.--0,4262+10.-0,2150
+ e
2 πi2.--0,4262+10.-0,2150+0,5
+ e
2 πi-0,3070+2.-0,3070+10.-0,2150+0,5
+ e
2 πi2.-0,4262--0,3070+10.-0,2150+0,5
F
0120
= 3 f
Ca
2+
1
– 0,7567 + 0,6537i – 0,7753 + 0,6316i + 0,2414 + 0,9704i + 0,2414 + 0,9704i
– 0,7567 + 0,6537i – 0,7753 + 0,6316i + f
Ca
2+
2
– 0,4201 + 0,9075i – 0,02890 + 0,9996i
– 0,9059 + 0,4235i – 0,9059 + 0,4235i – 0,4201 + 0,9075i – 0,02890 + 0,9996i + f
Ca
2+
3
– 0,3902 + 0,9207i – 0,6442 + 0,7649i – 0,6442 + 0,7649i + 0,5474 + 0,8368i
– 0,3902 + 0,9207i – 0,6442 + 0,7649i + f
Ca
2+
4
0,5928 + 0,8053i + 0,5928 + 0,8053i + f
Ca
2+
5
– 0,5145 + 0,8575i – 0,5145 + 0,8575i + f
P
5+
1
1,000 + 1,000 + f
P
5+
2
– 0,8313 + 0,5558i – 0,5262 + 0,8503i – 0,3716 + 0,9284i – 0,3716 + 0,9284i – 0,8313 + 0,5558i – 0,5262 + 0,8503i +
f
P
5+
3
– 0,6413 + 0,7673i – 0,1948 + 0,9808i – 0,6470 + 0,7624i – 0,6470 + 0,7624i
– 0,6413 + 0,7673i – 0,1948 + 0,9800i + f
O
2 –
1
0,7871 – 0,6169i – 0,1688
– 0,9856i – 0,6762 – 0,7367i – 0,6762 – 0,7367i – 0,6762 – 0,7367i – 0,1688 – 0,9856i + f
O
2 –
2
0,7518 + 0,6594i – 0,9948 – 0,1016i + 0,9966 + 0,08284i +
0,9966 + 0,08284i + 0,7518 + 0,6594i – 0,9948 – 0,1016i + f
O
2 –
3
– 0,9997 – 0,02262i + 0,8994
– 0,4371i + 0,9863 + 0,1652i + 0,9863 + 0,16512i – 0,99974 – 0,2262i + 0,8994
– 0,4371i + f
O
2 –
4
0,5949 + 0,8038i + 0,5898 + 0,8075i – 0,8677
– 0,4971i – 0,8677 – 0,4971i + 0,5949 + 0,8038i + 0,5898 + 0,8075i + f
O
2 –
5
– 0,3304 – 0,9438i + 0,8477 + 0,5305i – 0,8214 – 0,5704i – 0,8214 – 0,5704i
– 0,3304 – 0,9438i + 0,8477 + 0,5305i + f
O
2 –
6
0,08785 + 0,9961i –
0,7641 – 0,6451i – 0,7641 – 0,6451i – 0,2946 – 0,9556i + 0,08785 + 0,9961i –
0,7641 – 0,6451i
F
0210
= 3 f
Ca
2+
1
– 2,581 + 4,511i + f
Ca
2+
2
– 2,710 + 4,661i + f
Ca
2+
3
– 2,166 + 4,973i + f
Ca
2+
4
1,186 + 1,611i + f
Ca
2+
5
– 1,029 + 1,715i + f
P
5+
1
2,000 + f
P
5+
2
– 3,458 + 4,669i + f
P
5+
3
– 2,966 + 5,020i + f
O
2 –
1
– 1,579 – 4,798i + f
O
2 –
2
1,507 + 1,281i + f
O
2 –
3
1,772 – 0,7927i + f
O
2 –
4
0,6340 + 2,228i + f
O
2 –
5
– 0,6082 – 1,967i + f
O
2 –
6
– 2,411 – 0,8987i F
0210
= 316,80 – 2,581 + 4,511i + 16,80– 2,710 + 4,661i + 16,80– 2,166 +
4,973i + 16,801,186 + 1,611i + 16,80 – 1,029 + 1,715i + 9,8002,000 +
9,800 – 3,458 + 4,669i + 9,800– 2,966 + 5,020i + 8,000– 1,579 – 4,798i +
8,0001,507 + 1,281i + 8,0001,772 – 0,7927i + 8,0000,6340 + 2,228i +
8,000 – 0,6082 – 1,967i + 8,000– 2,411 – 0,8987i
F
0210
= 3 – 43,36 + 75,78i – 45,53 + 78,30i – 36,39 + 83,55i + 19,92 + 27,06i – 17,29 +
28,81i + 19,60 – 33,89 + 45,76i – 29,07 + 49,20i – 12,63 – 38,38i + 12,06 + 10,25i
+ 14,18 – 6,342i + 5,072 + 17,82i – 4,866 – 15,74i – 19,29 – 7,190i
F
0210
= 3 – 171,5 + 368,9i
F
0210
= – 514,5 + 1107i
| F
0210
| = 1221