Efek Temperatur Sintering Terhadap Sifat Fisis dan Magnet dari Mill Scale dengan Aditif FeMo
LAMPIRAN 1
GAMBAR ALAT DAN BAHAN
Bahan mill scale
bongkahan FeMo
Mortar dan alu
Ayakan 200 mesh
Planetary Ball Mill
shaker mill
Universitas Sumatera Utara
Bola-bola keramik
Cawan perahu
Serbuk mill scale 200 mesh
jar mill
neraca digital 2 digit
Serbuk FeMo 200 mesh
Universitas Sumatera Utara
Beaker glass
Oven
Under Vacum dryer
piknometer
Vakum
Toluene
Universitas Sumatera Utara
LAMPIRAN 2
PENGUKURAN TRUE DENSITY
Perhitugan True Density serbuk sampel uji
Dimana: m1 = massa piknometer kosong
m2 = massa piknometer + aquades
m3 = massa piknometer + serbuk
m4 = massa piknometer + serbuk + aquades
True density mill scale
ρ toluen
(g/cm3)
True
Density
(g/cm3)
22.36 15.06 23.18
0.86
5.56
14.09
22.36 15.07 23.19
0.86
5.61
14.09
22.36 15.09 23.21
0.86
5.73
ρ toluen
(g/cm3)
True
Density
(g/cm3)
Pengukuran
ke-
m1
(g)
1
14.09
2
3
m2
(g)
m3
(g)
m4
(g)
ratarata
5.63
True density FeMo
m1
(g)
m2
(g)
m3
(g)
m4
(g)
1
14.09
22.36
15
23.19
0.86
9.78
2
14.09
22.36
15
23.2
0.86
11.18
3
14.09
22.36
15
23.19
0.86
9.78
ratarata
10.24
Universitas Sumatera Utara
True density 97 % wt mill scale : 3 %wt FeMo
Pengukuran
ke-
m1
(g)
m2
(g)
m3
(g)
m4
(g)
ρ toluen
(g/cm3)
True
Density
(g/cm3)
1
14.09 22.36 15.08
23.2
0.86
5.67
2
14.09 22.36 15.08
23.2
0.86
5.67
3
14.09 22.36 15.09
23.21
0.86
5.73
ratarata
5.69
True density 95 % wt mill scale : 5 %wt FeMo
Pengukuran
ke-
m1
(g)
m2
(g)
m3
(g)
m4
(g)
ρ toluen
(g/cm3)
True
Density
(g/cm3)
1
14.09 22.36 15.09 23.21
0.86
5.73
2
14.09 22.36 15.08
23.2
0.86
5.67
3
14.09 22.36 15.09 23.21
0.86
5.73
m4
(g)
ρ toluen
(g/cm3)
True
Density
(g/cm3)
ratarata
5.71
True density 93 % wt mill scale : 7 %wt FeMo
Pengukuran
ke-
m1
(g)
m2
(g)
m3
(g)
1
2
14.09 22.36 15.1
14.09 22.36 15.09
23.22
23.22
0.86
0.86
5.79
6.142
3
14.09 22.36 15.08
23.2
0.86
5.676
ratarata
5.86
Universitas Sumatera Utara
LAMPIRAN 3
PENGUKURAN BULK DENSITY
93 %wt mill scale : 7%wt FeMo
T sintering 1100 oC
Pengukuran
ke-
mk
(g)
1.886
mb
(g)
1.466
1.892
1.492
1.786
1.382
ρ aquades
(g/cm3)
Bulk Density
(g/cm3)
4.47
rata-rata
(g/cm3)
1
2
4.71
0.997
4.40
4.53
3
93 %wt mill scale : 7%wt FeMo
T sintering 1150 oC
Pengukuran
ke-
mk
(g)
1.244
mb
(g)
0.971
1.876
1.471
ρ aquades
(g/cm3)
Bulk Density
(g/cm3)
4.54
rata-rata
(g/cm3)
1
2
4.61
0.997
1.19
0.934
4.63
4.59
3
93 %wt mill scale : 7%wt FeMo
T sintering 1200 oC
Pengukuran
ke-
mk
(g)
1.916
mb
(g)
1.487
ρ aquades
(g/cm3)
1.858
1.448
0.997
0.997
0.775
Bulk Density
(g/cm3)
4.45
rata-rata
(g/cm3)
1
2
4.51
4.48
4.47
3
Universitas Sumatera Utara
LAMPIRAN 4
PENGUKURAN POROSITY
93 %wt mill scale : 7%wt FeMo
T sintering 1100 oC
Pengukuran
ke-
mk
(g)
1.858
mb
(g)
1.954
1.915
2.006
0.997
1.046
ρ aquades
(g/cm3)
porosity
(g/cm3)
4.91
rata-rata
(g/cm3)
1
2
4.53
0.997
4.71
4.68
3
93 %wt mill scale : 7%wt FeMo
T sintering 1150 oC
Pengukuran
ke-
mk
(g)
1.844
mb
ρ aquades
(g)
(g/cm3)
1.926
1.786
1.888
1.844
1.926
porosity
(g/cm3)
4.25
rata-rata
(g/cm3)
1
2
5.40
0.997
4.63
4.25
3
93 %wt mill scale : 7%wt FeMo
T sintering 1200 oC
Pengukuran
ke-
mk
(g)
1.244
mb
ρ aquades
(g)
(g/cm3)
1.307
1.876
1.978
1.19
1.252
porosity
(g/cm3)
4.82
rata-rata
(g/cm3)
1
2
0.997
5.15
4.97
4.95
3
Universitas Sumatera Utara
LAMPIRAN 5
HASIL PARAMETER KISI
Entry # 96-900-9771
Phase classification
Name
Mineral Name Wuestite
Formula
FeO
I/Ic
6.030000
Sample Name 9009770
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Fjellvag H., Gronvold F., Stolen S., Hauback B. C., "On the crystallographic
and magnetic structures of nearly stoichiometric iron monoxide Locality:
synthetic Note: low-temperature polymorph Sample: Three-Phase Mixture
FeO, T = 12 K", Journal of Solid State Chemistry 124, 52-57 (1996)
COD (Crystallography Open Database)
9009770
Crystal structure
Crystallographic data
Space group
R -3 (148)
Crystal
trigonal (rhombohedral axes)
system
Cell
a= 6.1320 Å α= 59.340º
parameters
Cell meas.
T= 12.0 K
conditions
Element Oxid.
Atom
x
y
coordinates
Fe
0.000 0.000
Fe
0.500 0.500
Fe
0.500 0.000
Fe
0.000 0.500
O
0.250 0.250
O
0.250 0.250
z
0.000
0.500
0.000
0.500
0.250
0.750
Bi
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Focc
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Diffraction data
Diffraction lines
d [Å]
2.5158
2.4824
2.1570
1.5328
1.5177
1.3090
1.2995
1.2949
1.2579
1.2412
1.0785
Int.
h k l Mult.
176.1 2 2 2 2
508.2 0 2 0 6
1000.0 2 0 2 6
263.5 2 4 2 6
252.4 2 0 -2 6
53.5 4 2 4 6
103.9 2 0 4 6
51.2 2 -2 2 6
36.8 4 4 4 2
104.1 0 4 0 6
59.0 4 0 4 6
Universitas Sumatera Utara
Experimental
Physical Properties
Calc. density
5.94200 g/cm³
Remarks
Remarks
Comments
- Diffraction pattern calculated by Match!.
- I/Ic calculated by Match!.
- Space group has been derived from given symmetry operations.
Entry # 96-900-2027
Phase classification
Name
Mineral Name Fe3O4
Formula
Fe3O4
I/Ic
3.840000
Sample Name 9002026
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Fei Y., Frost D. J., Mao H. K., Prewitt C. T., Hausermann D., "In situ structure
determination of the high-pressure phase of Fe3O4 Sample data recorded at P
= 23.96 GPa, T = = 823 K", American Mineralogist 84, 203-206 (1999)
COD (Crystallography Open Database)
9002026
Crystal structure
Crystallographic data
Space group
P b c m (57)
Crystal
orthorhombic
system
Cell
a= 2.7992 Å b= 9.4097 Å c= 9.4832 Å
parameters
Cell meas.
p= 23960000.0 kPa
conditions
Element Oxid.
Bi
Atom
x
y
z
coordinates
Fe
0.724 0.376 0.250 1.000000
Fe
0.246 0.111 0.088 1.000000
O
0.506 0.250 0.000 1.000000
O
0.180 0.245 0.250 1.000000
O
0.296 0.490 0.098 1.000000
Focc
1.000000
1.000000
1.000000
1.000000
1.000000
Diffraction data
Diffraction lines
d [Å]
4.7416
4.7049
4.2147
3.3397
2.7992
2.6830
2.6238
2.5817
Int.
h
3.2 0
38.8 0
0.0 0
29.3 0
14.3 1
97.8 1
1000.0 0
333.4 1
k
0
2
2
2
0
1
2
1
l Mult.
2 2
0 2
1 4
2 4
0 2
0 4
3 4
1 8
Universitas Sumatera Utara
2.4105
2.4056
2.3708
2.3524
2.3351
2.3318
2.2832
2.1453
2.1172
2.1073
2.0885
2.0455
2.0396
1.9143
1.9113
1.8872
1.8091
1.8009
1.7766
1.7693
1.7591
1.7425
1.6886
1.6836
1.6699
1.5805
1.5683
1.5671
1.5648
1.5618
1.5487
1.5473
1.5410
1.4983
1.4894
1.4890
1.4834
1.4765
1.4341
1.4049
1.4041
1.4002
1.3996
1.3844
1.3763
1.3699
1.3682
1.3618
1.3542
1.3423
1.3415
1.3289
1.3283
1.3209
1.3146
1.3119
1.3080
1.3060
1.3042
1.3018
1.2908
1.2781
1.2681
1.2667
6.5
0.0
0.2
137.8
175.9
7.2
4.3
14.4
80.4
6.6
46.9
12.1
245.7
0.9
263.1
16.0
1.8
1.0
103.4
0.0
2.1
31.3
3.1
17.5
1.4
116.2
11.6
160.0
0.1
2.6
58.5
0.0
135.0
9.3
1.1
1.4
41.4
0.6
0.7
106.0
30.2
62.9
64.5
2.5
0.1
0.0
0.0
14.0
0.4
0.9
6.8
2.5
0.1
3.3
1.3
57.2
0.3
0.0
24.4
0.6
6.9
0.1
4.5
1.6
1
1
0
0
1
1
0
1
0
0
1
1
1
1
1
0
1
1
1
1
0
1
1
1
0
0
0
1
1
1
1
0
1
0
1
0
1
0
1
0
1
1
2
2
1
2
1
1
1
2
2
2
2
1
1
0
0
1
1
0
2
2
2
2
0
2
0
4
1
2
4
2
2
4
3
1
3
2
3
4
0
4
1
4
2
3
2
4
4
0
6
3
4
5
1
6
5
2
2
6
5
4
4
6
3
5
0
1
0
1
6
1
6
0
2
1
2
2
6
4
6
4
5
2
2
3
1
3
2
0
4
0
2
1
1
2
4
2
0
3
1
3
2
3
4
0
4
1
5
3
4
2
4
6
0
4
3
0
5
1
1
6
5
2
2
5
4
3
5
3
0
0
6
1
0
6
1
2
0
2
1
6
2
6
4
5
4
7
2
0
3
1
4
4
2
2
8
8
4
8
4
4
4
8
8
8
8
4
4
4
8
8
4
8
8
8
4
2
2
8
8
4
8
4
8
4
8
4
8
4
8
4
8
8
2
4
4
8
4
8
8
4
4
8
8
8
8
4
4
8
8
4
8
4
8
8
Universitas Sumatera Utara
1.2603
1.2556
1.2349
1.2341
1.2118
1.2093
1.2086
1.2056
1.2052
1.2028
1.2020
1.1955
1.1933
1.1879
1.1854
1.1850
1.1849
1.1804
1.1762
1.1740
1.1740
1.1675
1.1673
1.1659
1.1495
1.1416
1.1366
1.1315
1.1250
1.1242
1.1231
1.1182
1.1153
1.1132
1.1109
1.1096
1.1024
1.0952
1.0928
1.0916
1.0844
1.0843
1.0826
1.0790
1.0774
1.0727
1.0633
1.0599
1.0586
1.0583
1.0571
1.0537
1.0478
1.0442
1.0414
1.0380
1.0344
1.0309
1.0282
1.0257
1.0252
1.0234
1.0228
1.0211
11.8
0.3
116.7
0.0
10.5
23.8
1.0
25.6
2.3
41.7
4.3
1.8
1.0
1.2
2.7
0.6
0.0
0.6
31.8
21.3
0.6
1.8
3.9
0.2
1.0
0.2
30.5
4.5
0.0
4.1
0.1
0.3
1.1
2.3
1.0
0.2
10.1
0.4
0.0
0.5
0.5
6.7
0.0
21.4
0.0
0.2
0.1
0.3
0.0
0.2
0.2
0.2
48.2
1.6
1.3
0.0
1.2
13.8
29.6
0.0
0.2
37.1
0.7
3.8
1
1
2
2
1
1
0
1
2
2
1
2
2
1
0
1
2
1
0
1
0
2
0
2
0
0
1
1
2
2
2
2
2
0
1
1
0
2
2
1
1
1
1
1
1
2
1
2
0
2
1
0
2
2
2
2
1
1
0
1
0
1
2
1
3
6
2
3
7
1
6
5
0
4
7
1
4
4
0
6
3
2
8
7
4
2
8
4
2
8
3
7
3
4
5
1
5
6
5
6
8
2
5
0
8
1
4
7
8
4
2
3
4
5
8
8
0
6
1
6
6
3
2
8
6
5
2
7
6
3
3
2
0
7
5
5
4
0
1
4
1
6
8
4
3
7
0
2
7
4
1
2
8
2
7
3
4
3
0
5
1
6
6
5
3
5
2
8
0
8
7
4
1
4
8
5
8
3
2
4
6
0
6
1
6
8
9
3
7
7
6
5
8
8
8
8
4
8
4
8
4
4
8
8
8
8
2
8
8
8
2
8
4
8
4
8
4
4
8
8
8
8
4
8
8
4
8
8
4
8
8
4
4
8
8
8
8
8
8
8
4
8
8
4
4
4
8
8
8
8
4
8
4
8
8
8
Universitas Sumatera Utara
1.0198
1.0158
1.0149
0.0
0.3
0.0
2 6 2
2 4 5
2 5 4
8
8
8
Experimental
Physical Properties
Calc. density
6.15700 g/cm³
Remarks
Remarks
Comme
Entry # 96-231-0324
Phase classification
Name
Fe Mo
Formula
FeMo
I/Ic
3.910000
Sample Name
2310323
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Wilson C.G., Spooner F.J., "Ordering of atoms in the sigma phase of Fe Mo",
Acta Crystallographica (1,1948-23,1967)16, 230-230 (1963)
COD (Crystallography Open Database)
2310323
Crystal structure
Crystallographic
Space group
Crystal system
Cell
parameters
Z
Atom
coordinates
data
P 42/m n m (136)
tetragonal
a= 9.1280 Å c= 4.8130 Å
15
Element Oxid.
Bi
Focc
x
y
z
Fe
0.182 0.182 0.252 1.000000 0.250000
Fe
0.738 0.065 0.000 1.000000 1.000000
Fe
0.000 0.000 0.000 1.000000 1.000000
Mo
0.398 0.398 0.000 1.000000 0.750000
Mo
0.182 0.182 0.252 1.000000 0.750000
Fe
0.398 0.398 0.000 1.000000 0.250000
Fe
0.463 0.132 0.000 1.000000 0.250000
Mo
0.463 0.132 0.000 1.000000 0.750000
Diffraction data
Diffraction lines
d [Å]
6.4545
4.5640
4.2574
4.0822
3.8584
3.2272
3.1132
Int.
h
5.7 1
2.4 2
21.0 1
27.3 1
6.8 1
6.5 2
10.7 2
k
1
0
0
2
1
2
1
l Mult.
0 4
0 4
1 8
0 8
1 8
0 4
1 16
Universitas Sumatera Utara
2.8865
2.6804
2.5718
2.5317
2.4755
2.4065
2.2820
2.2549
2.2406
2.2139
2.1515
2.1287
2.0731
2.0411
2.0113
1.9642
1.9292
1.8791
1.8484
1.8256
1.7901
1.7442
1.7069
1.6950
1.6778
1.6559
1.6293
1.6136
1.6039
1.5988
1.5801
1.5654
1.5570
1.5566
1.5299
1.5213
1.5006
1.4932
1.4887
1.4544
1.4433
1.4366
1.4363
1.4326
1.4256
1.4191
1.4023
1.3858
1.3824
1.3669
1.3607
1.3551
1.3402
1.3122
1.3094
1.2991
1.2909
1.2861
1.2859
1.2733
1.2658
1.2613
1.2586
1.2538
22.3
3.9
28.0
19.0
147.1
183.8
13.5
50.4
19.4
967.6
464.5
448.7
783.2
2.1
1000.0
438.4
111.1
4.4
126.0
0.3
3.0
14.9
18.5
1.2
7.9
0.1
0.8
0.6
0.1
4.6
0.8
3.2
1.4
13.5
0.4
3.3
0.5
0.7
0.1
53.3
7.8
0.8
41.0
3.3
10.8
5.9
18.7
90.7
22.9
13.4
1.0
2.0
1.0
188.5
7.0
185.5
64.9
84.9
79.1
69.8
0.8
1.9
13.8
156.1
1
2
3
2
3
0
4
1
3
1
3
2
2
2
4
3
2
4
3
3
1
3
4
2
5
4
4
4
3
5
0
3
1
4
4
6
1
2
5
4
2
2
5
6
4
3
3
5
6
5
3
3
4
5
6
4
1
3
6
6
4
4
7
2
3
2
0
3
1
0
0
1
2
4
3
0
1
4
1
3
2
2
1
4
5
2
3
5
1
0
1
4
3
2
1
5
1
2
4
0
6
1
3
3
6
2
1
1
5
0
1
2
2
4
6
2
4
3
3
1
7
3
0
1
6
2
0
7
0
1
1
0
1
2
0
2
1
0
0
2
2
0
1
1
2
1
2
0
0
2
1
0
1
2
2
0
2
1
3
0
3
2
1
0
0
3
1
2
0
3
2
1
0
3
3
2
1
1
0
3
2
2
1
3
0
3
2
2
0
3
1
0
8
8
8
8
16
2
4
8
16
8
4
8
16
8
16
8
8
16
16
8
8
16
16
8
16
8
16
4
8
16
8
8
8
16
8
4
8
16
16
16
8
8
16
16
8
8
16
16
16
16
8
16
8
16
16
16
8
8
8
16
8
16
8
8
Universitas Sumatera Utara
1.2468
1.2377
1.2265
1.2242
1.2133
1.2051
1.2033
1.1986
1.1947
1.1845
1.1829
1.1687
1.1652
1.1635
1.1630
1.1542
1.1410
1.1377
1.1376
1.1357
1.1322
1.1274
1.1204
1.1203
1.1120
1.1106
1.1069
1.1021
1.0959
1.0867
1.0788
1.0757
1.0730
1.0729
1.0684
1.0656
1.0644
1.0611
1.0572
1.0513
1.0502
1.0498
1.0430
1.0377
1.0365
1.0362
1.0310
1.0245
1.0205
1.0119
1.0080
1.0057
1.0056
61.9
40.7
27.3
10.1
65.9
4.3
87.8
0.0
2.3
1.9
0.1
4.7
0.7
0.1
0.1
1.1
1.5
0.5
2.5
0.7
4.2
0.5
0.0
6.5
14.1
1.9
74.9
4.4
1.6
2.3
57.7
28.8
8.3
5.0
0.0
5.7
2.2
0.0
125.6
1.5
66.1
36.8
0.1
4.3
0.7
8.0
50.9
102.5
1.0
6.6
0.0
29.6
8.2
5
6
5
6
7
4
0
3
5
6
1
5
5
0
7
2
8
4
5
6
1
2
5
6
7
3
2
7
6
3
8
6
6
7
3
5
4
5
4
6
3
6
8
6
4
7
8
7
4
7
1
5
8
5
2
4
4
2
3
0
7
1
3
1
6
2
2
3
1
0
4
5
5
8
2
3
4
2
1
8
4
1
2
2
6
2
3
8
4
0
7
1
5
3
6
3
3
2
5
0
4
8
0
9
5
2
1
2
2
1
1
3
4
0
3
2
4
0
3
4
1
4
0
3
2
1
0
4
3
2
2
4
0
1
3
4
1
0
3
2
0
3
4
0
4
2
4
1
1
3
4
1
2
2
0
3
0
3
2
8
16
16
16
16
16
2
8
16
16
8
8
16
8
16
16
4
8
8
16
8
8
16
16
16
16
8
16
16
16
16
4
16
16
8
16
8
8
16
16
8
8
16
16
16
16
8
16
8
8
8
8
16
Experimental
Physical Properties
Calc. density
9.42600 g/cm³
Remarks
Remarks
Comments
Universitas Sumatera Utara
Entry # 96-900-9769
Phase classification
Name
Mineral Name
Formula
I/Ic
Sample Name
Quality
Magnetite
Fe3O4
6.060000
9009768
C (calculated)
References
Publication
Bibliography
Origin of data
Source of entry
Link to orig. entry
Fjellvag H., Gronvold F., Stolen S., Hauback B. C., "On the crystallog
structures of nearly stoichiometric iron monoxide Locality: synthetic
Journal of Solid State Chemistry 124, 52-57 (1996)
COD (Crystallography Open Database)
9009768
Crystal structure
Crystallographic data
Space group
Crystal system
Cell parameters
Cell meas. conditions
Atom coordinates
F d -3 m (227)
cubic
a= 8.4045 Å
T= 298.0 K
Element Oxid.
Bi
Focc
x
y
z
Fe
0.875 0.875 0.875 1.000000 1.000000
Fe
0.500 0.500 0.500 1.000000 1.000000
O
0.254 0.254 0.254 1.000000 1.000000
Diffraction data
Diffraction lines
d [Å]
4.8523
2.9714
2.5341
2.4262
2.1011
1.9281
1.7156
1.6174
1.4857
1.4206
1.4008
1.3289
1.2817
1.2670
1.2131
1.1769
1.1231
1.0942
1.0506
1.0268
1.0192
0.9905
0.9705
0.9641
0.9397
0.9225
0.9170
Int.
h
79.4 1
282.4 2
1000.0 3
80.8 2
201.3 4
7.1 3
90.1 4
292.1 3
389.1 4
9.1 5
0.0 4
31.0 6
77.5 5
33.3 6
24.2 4
4.3 5
31.8 6
119.1 5
44.9 8
0.3 7
0.0 6
16.1 6
70.0 5
14.7 6
30.5 8
2.7 7
0.0 8
k
1
0
1
2
0
1
2
3
0
3
2
0
3
2
4
1
4
3
0
3
4
0
5
2
0
5
4
l
1
2
1
2
0
3
2
3
4
1
4
2
3
2
4
5
2
5
0
3
4
6
5
6
4
3
2
Mult.
8
12
24
8
6
24
24
8
12
48
24
24
24
24
8
24
48
24
6
24
24
12
8
24
24
48
48
Universitas Sumatera Utara
0.8959
0.8810
0.8578
0.8447
0.8241
0.8125
0.8087
0.7837
9.0
59.6
138.1
2.4
33.1
111.5
25.2
6.4
6
9
8
7
8
7
6
9
4
3
4
1
6
3
6
5
6
1
4
7
2
7
6
3
24
48
24
24
48
24
8
48
Experimental
Physical Properties
Calc. density
5.18100 g/cm³
Phase classification
Name
Mineral Name
Formula
I/Ic
Sample Name
Quality
Hematite
Fe2O3
3.580000
9009782
C (calculated)
References
Publication
Bibliography
Origin of data
Source of entry
Link to orig. entry
Pauling L., Hendricks S. B., "Crystal structures of hematite and corun
American Chemical Society47, 781-790 (1925)
COD (Crystallography Open Database)
9009782
Crystal structure
Crystallographic data
Space group
Crystal system
Cell parameters
Atom coordinates
R -3 c (167)
trigonal (rhombohedral axes)
a= 5.4200 Å α= 55.280º
Element Oxid.
Bi
Focc
x
y
z
Fe
0.355 0.355 0.355 1.000000 1.000000
O
0.542 -0.042 0.250 1.000000 1.000000
Diffraction data
Diffraction lines
d [Å]
3.6775
2.6959
2.5144
2.2884
2.2037
2.0756
1.8388
1.6924
1.6344
1.6007
1.5968
1.4842
1.4517
1.4118
1.3479
1.3095
1.3043
1.2609
Int.
h k l Mult.
377.2 1 1 0 6
1000.0 2 1 1 6
803.2 1 0 -1 6
23.0 2 2 2 2
175.7 2 1 0 12
15.3 2 0 0 6
401.9 2 0 2 6
455.9 3 1 2 12
10.8 2 0 -1 12
19.8 2 1 -1 12
87.1 3 3 2 6
312.9 3 1 0 12
273.0 2 -1 -1 6
5.2 2 3 0 12
25.1 4 2 2 6
108.1 4 3 3 6
15.2 4 3 2 12
2.9 4 2 1 12
Universitas Sumatera Utara
1.2572
1.2258
1.2032
1.1896
1.1880
1.1614
1.1442
1.1394
1.1057
1.1019
1.0753
1.0544
1.0414
1.0378
1.0285
67.5
29.0
0.6
17.5
34.4
49.6
1.3
72.7
0.4
70.2
10.0
75.4
3.7
19.7
0.3
2
3
2
3
4
4
4
2
4
4
2
5
5
4
4
0
3
1
-1
3
2
4
3
1
2
-2
3
3
0
3
-2
0
-2
0
1
4
4
-1
0
0
2
2
4
0
0
6
6
12
12
12
6
2
12
12
12
6
12
12
6
12
Experimental
Physical Properties
Calc. density
5.29100 g/cm³
Remarks
Remarks
Commen
Diffraction lines
d [Å]
3.6855
2.7028
2.5190
2.2953
2.2084
2.0797
1.8428
1.6966
1.6374
1.6037
1.6014
1.4873
1.4543
1.4149
1.3514
1.3133
1.3078
1.2638
1.2595
1.2285
1.2146
1.2054
1.1918
1.1909
1.1646
1.1477
1.1416
1.1079
1.1042
1.0773
1.0571
1.0444
1.0398
1.0307
Int.
h
292.1 0
1000.0 1
732.7 1
20.2 0
176.8 1
19.0 2
359.4 0
427.4 1
4.6 2
21.9 1
79.8 0
282.4 2
270.2 3
2.2 1
27.3 2
96.8 1
15.4 1
1.3 2
61.2 2
22.0 0
8.7 2
0.5 1
13.6 3
36.5 1
48.2 0
1.0 0
73.4 1
0.3 3
66.4 2
6.7 0
72.4 2
4.5 1
22.4 4
0.2 1
k l
1 2
0 4
1 0
0 6
1 3
0 2
2 4
1 6
1 1
2 2
1 8
1 4
0 0
2 5
0 8
0 10
1 9
1 7
2 0
3 6
2 3
3 1
1 2
2 8
2 10
0 12
3 4
1 5
2 6
4 2
1 10
1 12
0 4
3 7
Mult.
6
6
6
2
12
6
6
12
12
12
6
12
6
12
6
6
12
12
6
6
12
12
12
12
6
2
12
12
12
6
12
12
6
12
Universitas Sumatera Utara
Phase classification
Name
Mineral Name Magnetite
Formula
Fe3O4
I/Ic
6.020000
Sample Name 9002317
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Haavik C., Stolen S., Fjellvag H., Hanfland M., Hausermann D., "Equation of
state of magnetite and its high-pressure modification: Thermodynamics of
the Fe-O system at high pressure Sample at P = 1.4 GPa", American
Mineralogist85, 514-523 (2000)
COD (Crystallography Open Database)
9002317
Crystal structure
Crystallographic data
Space group
F d -3 m (227)
Crystal
Cubic
system
Cell
a= 8.3837 Å
parameters
Cell meas.
p= 1400000.0 kPa
conditions
Element Oxid.
Bi
Focc
Atom
x
y
z
coordinates
Fe
0.125 0.125 0.125 1.000000 1.000000
Fe
0.500 0.500 0.500 1.000000 1.000000
O
0.255 0.255 0.255 1.000000 1.000000
Diffraction data
Diffraction lines
d [Å]
4.8403
2.9641
2.5278
2.4202
2.0959
1.9234
1.7113
1.6134
1.4820
1.4171
1.3973
1.3256
1.2785
1.2639
1.2101
1.1740
1.1203
1.0915
1.0480
1.0242
1.0167
0.9880
0.9681
0.9617
Int.
h
86.6 1
285.2 2
1000.0 3
81.9 2
201.3 4
6.0 3
90.0 4
297.0 3
388.5 4
9.6 5
0.0 4
30.8 6
77.4 5
33.9 6
24.0 4
4.7 5
32.2 6
118.1 5
44.9 8
0.2 7
0.0 6
16.4 6
70.8 5
15.2 6
k
1
0
1
2
0
1
2
3
0
3
2
0
3
2
4
1
4
3
0
3
4
0
5
2
l
1
2
1
2
0
3
2
3
4
1
4
2
3
2
4
5
2
5
0
3
4
6
5
6
Mult.
8
12
24
8
6
24
24
8
12
48
24
24
24
24
8
24
48
24
6
24
24
12
8
24
Universitas Sumatera Utara
0.9373
0.9202
0.9147
0.8937
0.8789
0.8557
0.8426
0.8221
0.8105
0.8067
30.3
2.8
0.0
8.9
61.8
139.3
2.4
33.9
117.1
26.8
8
7
8
6
9
8
7
8
7
6
0
5
4
4
3
4
1
6
3
6
4
3
2
6
1
4
7
2
7
6
24
48
48
24
48
24
24
48
24
8
Experimental
Physical Properties
Calc. density
5.21900 g/cm³
Remarks
Remarks
Co
Entry # 96-231-0324
Phase classification
Name
Formula
I/Ic
Sample Name
Quality
Fe Mo
FeMo
3.910000
2310323
C (calculated)
References
Publication
Bibliography
Origin of data
Source of entry
Link to orig. entry
Wilson C.G., Spooner F.J., "Ordering of atoms in the sigma phase
of Fe Mo", Acta Crystallographica (1,1948-23,1967)16, 230-230
(1963)
COD (Crystallography Open Database)
2310323
Crystal structure
Crystallographic data
Space group
P 42/m n m (136)
Crystal system
tetragonal
Cell parameters
a= 9.1280 Å c= 4.8130 Å
Z
15
Element Oxid.
Atom coordinates
x
y
Fe
0.182 0.182
Fe
0.738 0.065
Fe
0.000 0.000
Mo
0.398 0.398
Mo
0.182 0.182
Fe
0.398 0.398
Fe
0.463 0.132
Mo
0.463 0.132
z
0.252
0.000
0.000
0.000
0.252
0.000
0.000
0.000
Bi
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Focc
0.250000
1.000000
1.000000
0.750000
0.750000
0.250000
0.250000
0.750000
Diffraction data
Diffraction lines
d [Å]
6.4545
4.5640
Int.
h k l Mult.
5.7 1 1 0 4
2.4 2 0 0 4
Universitas Sumatera Utara
4.2574
4.0822
3.8584
3.2272
3.1132
2.8865
2.6804
2.5718
2.5317
2.4755
2.4065
2.2820
2.2549
2.2406
2.2139
2.1515
2.1287
2.0731
2.0411
2.0113
1.9642
1.9292
1.8791
1.8484
1.8256
1.7901
1.7442
1.7069
1.6950
1.6778
1.6559
1.6293
1.6136
1.6039
1.5988
1.5801
1.5654
1.5570
1.5566
1.5299
1.5213
1.5006
1.4932
1.4887
1.4544
1.4433
1.4366
1.4363
1.4326
1.4256
1.4191
1.4023
1.3858
1.3824
1.3669
1.3607
1.3551
1.3402
1.3122
1.3094
1.2991
1.2909
1.2861
1.2859
21.0
27.3
6.8
6.5
10.7
22.3
3.9
28.0
19.0
147.1
183.8
13.5
50.4
19.4
967.6
464.5
448.7
783.2
2.1
1000.0
438.4
111.1
4.4
126.0
0.3
3.0
14.9
18.5
1.2
7.9
0.1
0.8
0.6
0.1
4.6
0.8
3.2
1.4
13.5
0.4
3.3
0.5
0.7
0.1
53.3
7.8
0.8
41.0
3.3
10.8
5.9
18.7
90.7
22.9
13.4
1.0
2.0
1.0
188.5
7.0
185.5
64.9
84.9
79.1
1
1
1
2
2
1
2
3
2
3
0
4
1
3
1
3
2
2
2
4
3
2
4
3
3
1
3
4
2
5
4
4
4
3
5
0
3
1
4
4
6
1
2
5
4
2
2
5
6
4
3
3
5
6
5
3
3
4
5
6
4
1
3
6
0
2
1
2
1
3
2
0
3
1
0
0
1
2
4
3
0
1
4
1
3
2
2
1
4
5
2
3
5
1
0
1
4
3
2
1
5
1
2
4
0
6
1
3
3
6
2
1
1
5
0
1
2
2
4
6
2
4
3
3
1
7
3
0
1
0
1
0
1
0
1
1
0
1
2
0
2
1
0
0
2
2
0
1
1
2
1
2
0
0
2
1
0
1
2
2
0
2
1
3
0
3
2
1
0
0
3
1
2
0
3
2
1
0
3
3
2
1
1
0
3
2
2
1
3
0
3
2
8
8
8
4
16
8
8
8
8
16
2
4
8
16
8
4
8
16
8
16
8
8
16
16
8
8
16
16
8
16
8
16
4
8
16
8
8
8
16
8
4
8
16
16
16
8
8
16
16
8
8
16
16
16
16
8
16
8
16
16
16
8
8
8
Universitas Sumatera Utara
1.2733
1.2658
1.2613
1.2586
1.2538
1.2468
1.2377
1.2265
1.2242
1.2133
1.2051
1.2033
1.1986
1.1947
1.1845
1.1829
1.1687
1.1652
1.1635
1.1630
1.1542
1.1410
1.1377
1.1376
1.1357
1.1322
1.1274
1.1204
1.1203
1.1120
1.1106
1.1069
1.1021
1.0959
1.0867
1.0788
1.0757
1.0730
1.0729
1.0684
1.0656
1.0644
1.0611
1.0572
1.0513
1.0502
1.0498
1.0430
1.0377
1.0365
1.0362
1.0310
1.0245
1.0205
1.0119
1.0080
1.0057
1.0056
69.8
0.8
1.9
13.8
156.1
61.9
40.7
27.3
10.1
65.9
4.3
87.8
0.0
2.3
1.9
0.1
4.7
0.7
0.1
0.1
1.1
1.5
0.5
2.5
0.7
4.2
0.5
0.0
6.5
14.1
1.9
74.9
4.4
1.6
2.3
57.7
28.8
8.3
5.0
0.0
5.7
2.2
0.0
125.6
1.5
66.1
36.8
0.1
4.3
0.7
8.0
50.9
102.5
1.0
6.6
0.0
29.6
8.2
6
4
4
7
2
5
6
5
6
7
4
0
3
5
6
1
5
5
0
7
2
8
4
5
6
1
2
5
6
7
3
2
7
6
3
8
6
6
7
3
5
4
5
4
6
3
6
8
6
4
7
8
7
4
7
1
5
8
1
6
2
0
7
5
2
4
4
2
3
0
7
1
3
1
6
2
2
3
1
0
4
5
5
8
2
3
4
2
1
8
4
1
2
2
6
2
3
8
4
0
7
1
5
3
6
3
3
2
5
0
4
8
0
9
5
2
2
0
3
1
0
1
2
2
1
1
3
4
0
3
2
4
0
3
4
1
4
0
3
2
1
0
4
3
2
2
4
0
1
3
4
1
0
3
2
0
3
4
0
4
2
4
1
1
3
4
1
2
2
0
3
0
3
2
16
8
16
8
8
8
16
16
16
16
16
2
8
16
16
8
8
16
8
16
16
4
8
8
16
8
8
16
16
16
16
8
16
16
16
16
4
16
16
8
16
8
8
16
16
8
8
16
16
16
16
8
16
8
8
8
8
16
Experimental
Physical Properties
Calc. density
9.42600 g/cm³
Universitas Sumatera Utara
LAMPIRAN 6
HASIL X-RAY DIFRACTION (XRD)
93%MillScale+7%FeMo-Tk 1000_Theta_2-Theta.r
Sample name :
93%MillScale+7%FeMoComment : IS=RS1=2;
RS2=1
Date : 2016/05/09
12:43:39
Operator :
X-Ray : 40 kV , 30 mA
Wavelength : CuKa /
1.541862 A
Goniometer :
Base att. config. :
Attachment :
Detector : SC-70
Memo :
Optics attribute :
Scan mode :
CONTINUOUS
Scan speed / Duration
time : 5.0000 deg./min.
Step width : 0.0100 deg.
Scan axis : 2Theta/Theta
Scan range : 20.0000 90.0000 deg.
2-Theta :
Omega :
Chi :
Phi :
2-ThetaChi :
CBO selection slit :
Incident parallel slit :
Incident slit : 2.000deg
Length limiting slit :
Receiving slit # 1 :
2.000deg
Filter : Cu_K-beta
Receiving optical device :
Receiving parallel slit :
Receiving slit # 2 :
1.000mm
Attenuator :
Diffrected beam mono. :
None
Monochromator slit :
Universitas Sumatera Utara
93%MillScale+7%FeMo-Ts1100_Theta_2-Theta.raw
Comment : IS=RS1=2;
RS2=1
Date : 2016/05/09
13:17:36
Operator :
X-Ray : 40 kV , 30 mA
Wavelength : CuKa /
1.541862 A
Goniometer :
Base att. config. :
Attachment :
Detector : SC-70
Memo :
Optics attribute :
Scan mode :
CONTINUOUS
Scan speed / Duration
time : 5.0000 deg./min.
Step width : 0.0100 deg.
Scan axis : 2Theta/Theta
Scan range : 20.0000 90.0000 deg.
2-Theta :
Omega :
Chi :
Phi :
2-ThetaChi :
CBO selection slit :
Incident parallel slit :
Incident slit : 2.000deg
Length limiting slit :
Receiving slit # 1 :
2.000deg
Filter : Cu_K-beta
Receiving optical device :
Receiving parallel slit :
Receiving slit # 2 :
1.000mm
Attenuator :
Diffrected beam mono. :
None
95
Universitas Sumatera Utara
LAMPIRAN 7
SKEMA SINTERING
Pada temperatur Sintering 1100 oC, t hold = 2 jam
Temperatur
Waktu
sintering
(menit)
(C)
0
25
57
600
117
600
167
1100
287
1100
394
25
Skema sintering
120 Menit
1100
Suhu ( C)
900
700
60 Menit
500
300
100
0
100
200
300
400
Waktu (h)
96
Universitas Sumatera Utara
Pada temperatur sintering 1150 oC, t hold = 2 jam
Temperatur
Waktu
sintering
(menit)
(C)
0
25
57
600
112
600
172
1200
295
1200
409
25
Skema sintering
1400
1200
suhu (°C)
1000
800
600
400
200
0
0
100
200
300
400
500
Waktu (menit)
97
Universitas Sumatera Utara
Pada temperatur sintering 1200 oC, t hold = 2 jam
Waktu
(menit)
Temperatur
sintering
(C)
0
25
57
600
117
600
177
1200
297
1200
414
25
Skema sintering
1200
Suhu (C)
1000
800
600
400
200
0
0
100
200
300
400
500
Waktu (menit)
98
Universitas Sumatera Utara
GAMBAR ALAT DAN BAHAN
Bahan mill scale
bongkahan FeMo
Mortar dan alu
Ayakan 200 mesh
Planetary Ball Mill
shaker mill
Universitas Sumatera Utara
Bola-bola keramik
Cawan perahu
Serbuk mill scale 200 mesh
jar mill
neraca digital 2 digit
Serbuk FeMo 200 mesh
Universitas Sumatera Utara
Beaker glass
Oven
Under Vacum dryer
piknometer
Vakum
Toluene
Universitas Sumatera Utara
LAMPIRAN 2
PENGUKURAN TRUE DENSITY
Perhitugan True Density serbuk sampel uji
Dimana: m1 = massa piknometer kosong
m2 = massa piknometer + aquades
m3 = massa piknometer + serbuk
m4 = massa piknometer + serbuk + aquades
True density mill scale
ρ toluen
(g/cm3)
True
Density
(g/cm3)
22.36 15.06 23.18
0.86
5.56
14.09
22.36 15.07 23.19
0.86
5.61
14.09
22.36 15.09 23.21
0.86
5.73
ρ toluen
(g/cm3)
True
Density
(g/cm3)
Pengukuran
ke-
m1
(g)
1
14.09
2
3
m2
(g)
m3
(g)
m4
(g)
ratarata
5.63
True density FeMo
m1
(g)
m2
(g)
m3
(g)
m4
(g)
1
14.09
22.36
15
23.19
0.86
9.78
2
14.09
22.36
15
23.2
0.86
11.18
3
14.09
22.36
15
23.19
0.86
9.78
ratarata
10.24
Universitas Sumatera Utara
True density 97 % wt mill scale : 3 %wt FeMo
Pengukuran
ke-
m1
(g)
m2
(g)
m3
(g)
m4
(g)
ρ toluen
(g/cm3)
True
Density
(g/cm3)
1
14.09 22.36 15.08
23.2
0.86
5.67
2
14.09 22.36 15.08
23.2
0.86
5.67
3
14.09 22.36 15.09
23.21
0.86
5.73
ratarata
5.69
True density 95 % wt mill scale : 5 %wt FeMo
Pengukuran
ke-
m1
(g)
m2
(g)
m3
(g)
m4
(g)
ρ toluen
(g/cm3)
True
Density
(g/cm3)
1
14.09 22.36 15.09 23.21
0.86
5.73
2
14.09 22.36 15.08
23.2
0.86
5.67
3
14.09 22.36 15.09 23.21
0.86
5.73
m4
(g)
ρ toluen
(g/cm3)
True
Density
(g/cm3)
ratarata
5.71
True density 93 % wt mill scale : 7 %wt FeMo
Pengukuran
ke-
m1
(g)
m2
(g)
m3
(g)
1
2
14.09 22.36 15.1
14.09 22.36 15.09
23.22
23.22
0.86
0.86
5.79
6.142
3
14.09 22.36 15.08
23.2
0.86
5.676
ratarata
5.86
Universitas Sumatera Utara
LAMPIRAN 3
PENGUKURAN BULK DENSITY
93 %wt mill scale : 7%wt FeMo
T sintering 1100 oC
Pengukuran
ke-
mk
(g)
1.886
mb
(g)
1.466
1.892
1.492
1.786
1.382
ρ aquades
(g/cm3)
Bulk Density
(g/cm3)
4.47
rata-rata
(g/cm3)
1
2
4.71
0.997
4.40
4.53
3
93 %wt mill scale : 7%wt FeMo
T sintering 1150 oC
Pengukuran
ke-
mk
(g)
1.244
mb
(g)
0.971
1.876
1.471
ρ aquades
(g/cm3)
Bulk Density
(g/cm3)
4.54
rata-rata
(g/cm3)
1
2
4.61
0.997
1.19
0.934
4.63
4.59
3
93 %wt mill scale : 7%wt FeMo
T sintering 1200 oC
Pengukuran
ke-
mk
(g)
1.916
mb
(g)
1.487
ρ aquades
(g/cm3)
1.858
1.448
0.997
0.997
0.775
Bulk Density
(g/cm3)
4.45
rata-rata
(g/cm3)
1
2
4.51
4.48
4.47
3
Universitas Sumatera Utara
LAMPIRAN 4
PENGUKURAN POROSITY
93 %wt mill scale : 7%wt FeMo
T sintering 1100 oC
Pengukuran
ke-
mk
(g)
1.858
mb
(g)
1.954
1.915
2.006
0.997
1.046
ρ aquades
(g/cm3)
porosity
(g/cm3)
4.91
rata-rata
(g/cm3)
1
2
4.53
0.997
4.71
4.68
3
93 %wt mill scale : 7%wt FeMo
T sintering 1150 oC
Pengukuran
ke-
mk
(g)
1.844
mb
ρ aquades
(g)
(g/cm3)
1.926
1.786
1.888
1.844
1.926
porosity
(g/cm3)
4.25
rata-rata
(g/cm3)
1
2
5.40
0.997
4.63
4.25
3
93 %wt mill scale : 7%wt FeMo
T sintering 1200 oC
Pengukuran
ke-
mk
(g)
1.244
mb
ρ aquades
(g)
(g/cm3)
1.307
1.876
1.978
1.19
1.252
porosity
(g/cm3)
4.82
rata-rata
(g/cm3)
1
2
0.997
5.15
4.97
4.95
3
Universitas Sumatera Utara
LAMPIRAN 5
HASIL PARAMETER KISI
Entry # 96-900-9771
Phase classification
Name
Mineral Name Wuestite
Formula
FeO
I/Ic
6.030000
Sample Name 9009770
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Fjellvag H., Gronvold F., Stolen S., Hauback B. C., "On the crystallographic
and magnetic structures of nearly stoichiometric iron monoxide Locality:
synthetic Note: low-temperature polymorph Sample: Three-Phase Mixture
FeO, T = 12 K", Journal of Solid State Chemistry 124, 52-57 (1996)
COD (Crystallography Open Database)
9009770
Crystal structure
Crystallographic data
Space group
R -3 (148)
Crystal
trigonal (rhombohedral axes)
system
Cell
a= 6.1320 Å α= 59.340º
parameters
Cell meas.
T= 12.0 K
conditions
Element Oxid.
Atom
x
y
coordinates
Fe
0.000 0.000
Fe
0.500 0.500
Fe
0.500 0.000
Fe
0.000 0.500
O
0.250 0.250
O
0.250 0.250
z
0.000
0.500
0.000
0.500
0.250
0.750
Bi
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Focc
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Diffraction data
Diffraction lines
d [Å]
2.5158
2.4824
2.1570
1.5328
1.5177
1.3090
1.2995
1.2949
1.2579
1.2412
1.0785
Int.
h k l Mult.
176.1 2 2 2 2
508.2 0 2 0 6
1000.0 2 0 2 6
263.5 2 4 2 6
252.4 2 0 -2 6
53.5 4 2 4 6
103.9 2 0 4 6
51.2 2 -2 2 6
36.8 4 4 4 2
104.1 0 4 0 6
59.0 4 0 4 6
Universitas Sumatera Utara
Experimental
Physical Properties
Calc. density
5.94200 g/cm³
Remarks
Remarks
Comments
- Diffraction pattern calculated by Match!.
- I/Ic calculated by Match!.
- Space group has been derived from given symmetry operations.
Entry # 96-900-2027
Phase classification
Name
Mineral Name Fe3O4
Formula
Fe3O4
I/Ic
3.840000
Sample Name 9002026
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Fei Y., Frost D. J., Mao H. K., Prewitt C. T., Hausermann D., "In situ structure
determination of the high-pressure phase of Fe3O4 Sample data recorded at P
= 23.96 GPa, T = = 823 K", American Mineralogist 84, 203-206 (1999)
COD (Crystallography Open Database)
9002026
Crystal structure
Crystallographic data
Space group
P b c m (57)
Crystal
orthorhombic
system
Cell
a= 2.7992 Å b= 9.4097 Å c= 9.4832 Å
parameters
Cell meas.
p= 23960000.0 kPa
conditions
Element Oxid.
Bi
Atom
x
y
z
coordinates
Fe
0.724 0.376 0.250 1.000000
Fe
0.246 0.111 0.088 1.000000
O
0.506 0.250 0.000 1.000000
O
0.180 0.245 0.250 1.000000
O
0.296 0.490 0.098 1.000000
Focc
1.000000
1.000000
1.000000
1.000000
1.000000
Diffraction data
Diffraction lines
d [Å]
4.7416
4.7049
4.2147
3.3397
2.7992
2.6830
2.6238
2.5817
Int.
h
3.2 0
38.8 0
0.0 0
29.3 0
14.3 1
97.8 1
1000.0 0
333.4 1
k
0
2
2
2
0
1
2
1
l Mult.
2 2
0 2
1 4
2 4
0 2
0 4
3 4
1 8
Universitas Sumatera Utara
2.4105
2.4056
2.3708
2.3524
2.3351
2.3318
2.2832
2.1453
2.1172
2.1073
2.0885
2.0455
2.0396
1.9143
1.9113
1.8872
1.8091
1.8009
1.7766
1.7693
1.7591
1.7425
1.6886
1.6836
1.6699
1.5805
1.5683
1.5671
1.5648
1.5618
1.5487
1.5473
1.5410
1.4983
1.4894
1.4890
1.4834
1.4765
1.4341
1.4049
1.4041
1.4002
1.3996
1.3844
1.3763
1.3699
1.3682
1.3618
1.3542
1.3423
1.3415
1.3289
1.3283
1.3209
1.3146
1.3119
1.3080
1.3060
1.3042
1.3018
1.2908
1.2781
1.2681
1.2667
6.5
0.0
0.2
137.8
175.9
7.2
4.3
14.4
80.4
6.6
46.9
12.1
245.7
0.9
263.1
16.0
1.8
1.0
103.4
0.0
2.1
31.3
3.1
17.5
1.4
116.2
11.6
160.0
0.1
2.6
58.5
0.0
135.0
9.3
1.1
1.4
41.4
0.6
0.7
106.0
30.2
62.9
64.5
2.5
0.1
0.0
0.0
14.0
0.4
0.9
6.8
2.5
0.1
3.3
1.3
57.2
0.3
0.0
24.4
0.6
6.9
0.1
4.5
1.6
1
1
0
0
1
1
0
1
0
0
1
1
1
1
1
0
1
1
1
1
0
1
1
1
0
0
0
1
1
1
1
0
1
0
1
0
1
0
1
0
1
1
2
2
1
2
1
1
1
2
2
2
2
1
1
0
0
1
1
0
2
2
2
2
0
2
0
4
1
2
4
2
2
4
3
1
3
2
3
4
0
4
1
4
2
3
2
4
4
0
6
3
4
5
1
6
5
2
2
6
5
4
4
6
3
5
0
1
0
1
6
1
6
0
2
1
2
2
6
4
6
4
5
2
2
3
1
3
2
0
4
0
2
1
1
2
4
2
0
3
1
3
2
3
4
0
4
1
5
3
4
2
4
6
0
4
3
0
5
1
1
6
5
2
2
5
4
3
5
3
0
0
6
1
0
6
1
2
0
2
1
6
2
6
4
5
4
7
2
0
3
1
4
4
2
2
8
8
4
8
4
4
4
8
8
8
8
4
4
4
8
8
4
8
8
8
4
2
2
8
8
4
8
4
8
4
8
4
8
4
8
4
8
8
2
4
4
8
4
8
8
4
4
8
8
8
8
4
4
8
8
4
8
4
8
8
Universitas Sumatera Utara
1.2603
1.2556
1.2349
1.2341
1.2118
1.2093
1.2086
1.2056
1.2052
1.2028
1.2020
1.1955
1.1933
1.1879
1.1854
1.1850
1.1849
1.1804
1.1762
1.1740
1.1740
1.1675
1.1673
1.1659
1.1495
1.1416
1.1366
1.1315
1.1250
1.1242
1.1231
1.1182
1.1153
1.1132
1.1109
1.1096
1.1024
1.0952
1.0928
1.0916
1.0844
1.0843
1.0826
1.0790
1.0774
1.0727
1.0633
1.0599
1.0586
1.0583
1.0571
1.0537
1.0478
1.0442
1.0414
1.0380
1.0344
1.0309
1.0282
1.0257
1.0252
1.0234
1.0228
1.0211
11.8
0.3
116.7
0.0
10.5
23.8
1.0
25.6
2.3
41.7
4.3
1.8
1.0
1.2
2.7
0.6
0.0
0.6
31.8
21.3
0.6
1.8
3.9
0.2
1.0
0.2
30.5
4.5
0.0
4.1
0.1
0.3
1.1
2.3
1.0
0.2
10.1
0.4
0.0
0.5
0.5
6.7
0.0
21.4
0.0
0.2
0.1
0.3
0.0
0.2
0.2
0.2
48.2
1.6
1.3
0.0
1.2
13.8
29.6
0.0
0.2
37.1
0.7
3.8
1
1
2
2
1
1
0
1
2
2
1
2
2
1
0
1
2
1
0
1
0
2
0
2
0
0
1
1
2
2
2
2
2
0
1
1
0
2
2
1
1
1
1
1
1
2
1
2
0
2
1
0
2
2
2
2
1
1
0
1
0
1
2
1
3
6
2
3
7
1
6
5
0
4
7
1
4
4
0
6
3
2
8
7
4
2
8
4
2
8
3
7
3
4
5
1
5
6
5
6
8
2
5
0
8
1
4
7
8
4
2
3
4
5
8
8
0
6
1
6
6
3
2
8
6
5
2
7
6
3
3
2
0
7
5
5
4
0
1
4
1
6
8
4
3
7
0
2
7
4
1
2
8
2
7
3
4
3
0
5
1
6
6
5
3
5
2
8
0
8
7
4
1
4
8
5
8
3
2
4
6
0
6
1
6
8
9
3
7
7
6
5
8
8
8
8
4
8
4
8
4
4
8
8
8
8
2
8
8
8
2
8
4
8
4
8
4
4
8
8
8
8
4
8
8
4
8
8
4
8
8
4
4
8
8
8
8
8
8
8
4
8
8
4
4
4
8
8
8
8
4
8
4
8
8
8
Universitas Sumatera Utara
1.0198
1.0158
1.0149
0.0
0.3
0.0
2 6 2
2 4 5
2 5 4
8
8
8
Experimental
Physical Properties
Calc. density
6.15700 g/cm³
Remarks
Remarks
Comme
Entry # 96-231-0324
Phase classification
Name
Fe Mo
Formula
FeMo
I/Ic
3.910000
Sample Name
2310323
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Wilson C.G., Spooner F.J., "Ordering of atoms in the sigma phase of Fe Mo",
Acta Crystallographica (1,1948-23,1967)16, 230-230 (1963)
COD (Crystallography Open Database)
2310323
Crystal structure
Crystallographic
Space group
Crystal system
Cell
parameters
Z
Atom
coordinates
data
P 42/m n m (136)
tetragonal
a= 9.1280 Å c= 4.8130 Å
15
Element Oxid.
Bi
Focc
x
y
z
Fe
0.182 0.182 0.252 1.000000 0.250000
Fe
0.738 0.065 0.000 1.000000 1.000000
Fe
0.000 0.000 0.000 1.000000 1.000000
Mo
0.398 0.398 0.000 1.000000 0.750000
Mo
0.182 0.182 0.252 1.000000 0.750000
Fe
0.398 0.398 0.000 1.000000 0.250000
Fe
0.463 0.132 0.000 1.000000 0.250000
Mo
0.463 0.132 0.000 1.000000 0.750000
Diffraction data
Diffraction lines
d [Å]
6.4545
4.5640
4.2574
4.0822
3.8584
3.2272
3.1132
Int.
h
5.7 1
2.4 2
21.0 1
27.3 1
6.8 1
6.5 2
10.7 2
k
1
0
0
2
1
2
1
l Mult.
0 4
0 4
1 8
0 8
1 8
0 4
1 16
Universitas Sumatera Utara
2.8865
2.6804
2.5718
2.5317
2.4755
2.4065
2.2820
2.2549
2.2406
2.2139
2.1515
2.1287
2.0731
2.0411
2.0113
1.9642
1.9292
1.8791
1.8484
1.8256
1.7901
1.7442
1.7069
1.6950
1.6778
1.6559
1.6293
1.6136
1.6039
1.5988
1.5801
1.5654
1.5570
1.5566
1.5299
1.5213
1.5006
1.4932
1.4887
1.4544
1.4433
1.4366
1.4363
1.4326
1.4256
1.4191
1.4023
1.3858
1.3824
1.3669
1.3607
1.3551
1.3402
1.3122
1.3094
1.2991
1.2909
1.2861
1.2859
1.2733
1.2658
1.2613
1.2586
1.2538
22.3
3.9
28.0
19.0
147.1
183.8
13.5
50.4
19.4
967.6
464.5
448.7
783.2
2.1
1000.0
438.4
111.1
4.4
126.0
0.3
3.0
14.9
18.5
1.2
7.9
0.1
0.8
0.6
0.1
4.6
0.8
3.2
1.4
13.5
0.4
3.3
0.5
0.7
0.1
53.3
7.8
0.8
41.0
3.3
10.8
5.9
18.7
90.7
22.9
13.4
1.0
2.0
1.0
188.5
7.0
185.5
64.9
84.9
79.1
69.8
0.8
1.9
13.8
156.1
1
2
3
2
3
0
4
1
3
1
3
2
2
2
4
3
2
4
3
3
1
3
4
2
5
4
4
4
3
5
0
3
1
4
4
6
1
2
5
4
2
2
5
6
4
3
3
5
6
5
3
3
4
5
6
4
1
3
6
6
4
4
7
2
3
2
0
3
1
0
0
1
2
4
3
0
1
4
1
3
2
2
1
4
5
2
3
5
1
0
1
4
3
2
1
5
1
2
4
0
6
1
3
3
6
2
1
1
5
0
1
2
2
4
6
2
4
3
3
1
7
3
0
1
6
2
0
7
0
1
1
0
1
2
0
2
1
0
0
2
2
0
1
1
2
1
2
0
0
2
1
0
1
2
2
0
2
1
3
0
3
2
1
0
0
3
1
2
0
3
2
1
0
3
3
2
1
1
0
3
2
2
1
3
0
3
2
2
0
3
1
0
8
8
8
8
16
2
4
8
16
8
4
8
16
8
16
8
8
16
16
8
8
16
16
8
16
8
16
4
8
16
8
8
8
16
8
4
8
16
16
16
8
8
16
16
8
8
16
16
16
16
8
16
8
16
16
16
8
8
8
16
8
16
8
8
Universitas Sumatera Utara
1.2468
1.2377
1.2265
1.2242
1.2133
1.2051
1.2033
1.1986
1.1947
1.1845
1.1829
1.1687
1.1652
1.1635
1.1630
1.1542
1.1410
1.1377
1.1376
1.1357
1.1322
1.1274
1.1204
1.1203
1.1120
1.1106
1.1069
1.1021
1.0959
1.0867
1.0788
1.0757
1.0730
1.0729
1.0684
1.0656
1.0644
1.0611
1.0572
1.0513
1.0502
1.0498
1.0430
1.0377
1.0365
1.0362
1.0310
1.0245
1.0205
1.0119
1.0080
1.0057
1.0056
61.9
40.7
27.3
10.1
65.9
4.3
87.8
0.0
2.3
1.9
0.1
4.7
0.7
0.1
0.1
1.1
1.5
0.5
2.5
0.7
4.2
0.5
0.0
6.5
14.1
1.9
74.9
4.4
1.6
2.3
57.7
28.8
8.3
5.0
0.0
5.7
2.2
0.0
125.6
1.5
66.1
36.8
0.1
4.3
0.7
8.0
50.9
102.5
1.0
6.6
0.0
29.6
8.2
5
6
5
6
7
4
0
3
5
6
1
5
5
0
7
2
8
4
5
6
1
2
5
6
7
3
2
7
6
3
8
6
6
7
3
5
4
5
4
6
3
6
8
6
4
7
8
7
4
7
1
5
8
5
2
4
4
2
3
0
7
1
3
1
6
2
2
3
1
0
4
5
5
8
2
3
4
2
1
8
4
1
2
2
6
2
3
8
4
0
7
1
5
3
6
3
3
2
5
0
4
8
0
9
5
2
1
2
2
1
1
3
4
0
3
2
4
0
3
4
1
4
0
3
2
1
0
4
3
2
2
4
0
1
3
4
1
0
3
2
0
3
4
0
4
2
4
1
1
3
4
1
2
2
0
3
0
3
2
8
16
16
16
16
16
2
8
16
16
8
8
16
8
16
16
4
8
8
16
8
8
16
16
16
16
8
16
16
16
16
4
16
16
8
16
8
8
16
16
8
8
16
16
16
16
8
16
8
8
8
8
16
Experimental
Physical Properties
Calc. density
9.42600 g/cm³
Remarks
Remarks
Comments
Universitas Sumatera Utara
Entry # 96-900-9769
Phase classification
Name
Mineral Name
Formula
I/Ic
Sample Name
Quality
Magnetite
Fe3O4
6.060000
9009768
C (calculated)
References
Publication
Bibliography
Origin of data
Source of entry
Link to orig. entry
Fjellvag H., Gronvold F., Stolen S., Hauback B. C., "On the crystallog
structures of nearly stoichiometric iron monoxide Locality: synthetic
Journal of Solid State Chemistry 124, 52-57 (1996)
COD (Crystallography Open Database)
9009768
Crystal structure
Crystallographic data
Space group
Crystal system
Cell parameters
Cell meas. conditions
Atom coordinates
F d -3 m (227)
cubic
a= 8.4045 Å
T= 298.0 K
Element Oxid.
Bi
Focc
x
y
z
Fe
0.875 0.875 0.875 1.000000 1.000000
Fe
0.500 0.500 0.500 1.000000 1.000000
O
0.254 0.254 0.254 1.000000 1.000000
Diffraction data
Diffraction lines
d [Å]
4.8523
2.9714
2.5341
2.4262
2.1011
1.9281
1.7156
1.6174
1.4857
1.4206
1.4008
1.3289
1.2817
1.2670
1.2131
1.1769
1.1231
1.0942
1.0506
1.0268
1.0192
0.9905
0.9705
0.9641
0.9397
0.9225
0.9170
Int.
h
79.4 1
282.4 2
1000.0 3
80.8 2
201.3 4
7.1 3
90.1 4
292.1 3
389.1 4
9.1 5
0.0 4
31.0 6
77.5 5
33.3 6
24.2 4
4.3 5
31.8 6
119.1 5
44.9 8
0.3 7
0.0 6
16.1 6
70.0 5
14.7 6
30.5 8
2.7 7
0.0 8
k
1
0
1
2
0
1
2
3
0
3
2
0
3
2
4
1
4
3
0
3
4
0
5
2
0
5
4
l
1
2
1
2
0
3
2
3
4
1
4
2
3
2
4
5
2
5
0
3
4
6
5
6
4
3
2
Mult.
8
12
24
8
6
24
24
8
12
48
24
24
24
24
8
24
48
24
6
24
24
12
8
24
24
48
48
Universitas Sumatera Utara
0.8959
0.8810
0.8578
0.8447
0.8241
0.8125
0.8087
0.7837
9.0
59.6
138.1
2.4
33.1
111.5
25.2
6.4
6
9
8
7
8
7
6
9
4
3
4
1
6
3
6
5
6
1
4
7
2
7
6
3
24
48
24
24
48
24
8
48
Experimental
Physical Properties
Calc. density
5.18100 g/cm³
Phase classification
Name
Mineral Name
Formula
I/Ic
Sample Name
Quality
Hematite
Fe2O3
3.580000
9009782
C (calculated)
References
Publication
Bibliography
Origin of data
Source of entry
Link to orig. entry
Pauling L., Hendricks S. B., "Crystal structures of hematite and corun
American Chemical Society47, 781-790 (1925)
COD (Crystallography Open Database)
9009782
Crystal structure
Crystallographic data
Space group
Crystal system
Cell parameters
Atom coordinates
R -3 c (167)
trigonal (rhombohedral axes)
a= 5.4200 Å α= 55.280º
Element Oxid.
Bi
Focc
x
y
z
Fe
0.355 0.355 0.355 1.000000 1.000000
O
0.542 -0.042 0.250 1.000000 1.000000
Diffraction data
Diffraction lines
d [Å]
3.6775
2.6959
2.5144
2.2884
2.2037
2.0756
1.8388
1.6924
1.6344
1.6007
1.5968
1.4842
1.4517
1.4118
1.3479
1.3095
1.3043
1.2609
Int.
h k l Mult.
377.2 1 1 0 6
1000.0 2 1 1 6
803.2 1 0 -1 6
23.0 2 2 2 2
175.7 2 1 0 12
15.3 2 0 0 6
401.9 2 0 2 6
455.9 3 1 2 12
10.8 2 0 -1 12
19.8 2 1 -1 12
87.1 3 3 2 6
312.9 3 1 0 12
273.0 2 -1 -1 6
5.2 2 3 0 12
25.1 4 2 2 6
108.1 4 3 3 6
15.2 4 3 2 12
2.9 4 2 1 12
Universitas Sumatera Utara
1.2572
1.2258
1.2032
1.1896
1.1880
1.1614
1.1442
1.1394
1.1057
1.1019
1.0753
1.0544
1.0414
1.0378
1.0285
67.5
29.0
0.6
17.5
34.4
49.6
1.3
72.7
0.4
70.2
10.0
75.4
3.7
19.7
0.3
2
3
2
3
4
4
4
2
4
4
2
5
5
4
4
0
3
1
-1
3
2
4
3
1
2
-2
3
3
0
3
-2
0
-2
0
1
4
4
-1
0
0
2
2
4
0
0
6
6
12
12
12
6
2
12
12
12
6
12
12
6
12
Experimental
Physical Properties
Calc. density
5.29100 g/cm³
Remarks
Remarks
Commen
Diffraction lines
d [Å]
3.6855
2.7028
2.5190
2.2953
2.2084
2.0797
1.8428
1.6966
1.6374
1.6037
1.6014
1.4873
1.4543
1.4149
1.3514
1.3133
1.3078
1.2638
1.2595
1.2285
1.2146
1.2054
1.1918
1.1909
1.1646
1.1477
1.1416
1.1079
1.1042
1.0773
1.0571
1.0444
1.0398
1.0307
Int.
h
292.1 0
1000.0 1
732.7 1
20.2 0
176.8 1
19.0 2
359.4 0
427.4 1
4.6 2
21.9 1
79.8 0
282.4 2
270.2 3
2.2 1
27.3 2
96.8 1
15.4 1
1.3 2
61.2 2
22.0 0
8.7 2
0.5 1
13.6 3
36.5 1
48.2 0
1.0 0
73.4 1
0.3 3
66.4 2
6.7 0
72.4 2
4.5 1
22.4 4
0.2 1
k l
1 2
0 4
1 0
0 6
1 3
0 2
2 4
1 6
1 1
2 2
1 8
1 4
0 0
2 5
0 8
0 10
1 9
1 7
2 0
3 6
2 3
3 1
1 2
2 8
2 10
0 12
3 4
1 5
2 6
4 2
1 10
1 12
0 4
3 7
Mult.
6
6
6
2
12
6
6
12
12
12
6
12
6
12
6
6
12
12
6
6
12
12
12
12
6
2
12
12
12
6
12
12
6
12
Universitas Sumatera Utara
Phase classification
Name
Mineral Name Magnetite
Formula
Fe3O4
I/Ic
6.020000
Sample Name 9002317
Quality
C (calculated)
References
Publication
Bibliography
Origin of data
Source of
entry
Link to orig.
entry
Haavik C., Stolen S., Fjellvag H., Hanfland M., Hausermann D., "Equation of
state of magnetite and its high-pressure modification: Thermodynamics of
the Fe-O system at high pressure Sample at P = 1.4 GPa", American
Mineralogist85, 514-523 (2000)
COD (Crystallography Open Database)
9002317
Crystal structure
Crystallographic data
Space group
F d -3 m (227)
Crystal
Cubic
system
Cell
a= 8.3837 Å
parameters
Cell meas.
p= 1400000.0 kPa
conditions
Element Oxid.
Bi
Focc
Atom
x
y
z
coordinates
Fe
0.125 0.125 0.125 1.000000 1.000000
Fe
0.500 0.500 0.500 1.000000 1.000000
O
0.255 0.255 0.255 1.000000 1.000000
Diffraction data
Diffraction lines
d [Å]
4.8403
2.9641
2.5278
2.4202
2.0959
1.9234
1.7113
1.6134
1.4820
1.4171
1.3973
1.3256
1.2785
1.2639
1.2101
1.1740
1.1203
1.0915
1.0480
1.0242
1.0167
0.9880
0.9681
0.9617
Int.
h
86.6 1
285.2 2
1000.0 3
81.9 2
201.3 4
6.0 3
90.0 4
297.0 3
388.5 4
9.6 5
0.0 4
30.8 6
77.4 5
33.9 6
24.0 4
4.7 5
32.2 6
118.1 5
44.9 8
0.2 7
0.0 6
16.4 6
70.8 5
15.2 6
k
1
0
1
2
0
1
2
3
0
3
2
0
3
2
4
1
4
3
0
3
4
0
5
2
l
1
2
1
2
0
3
2
3
4
1
4
2
3
2
4
5
2
5
0
3
4
6
5
6
Mult.
8
12
24
8
6
24
24
8
12
48
24
24
24
24
8
24
48
24
6
24
24
12
8
24
Universitas Sumatera Utara
0.9373
0.9202
0.9147
0.8937
0.8789
0.8557
0.8426
0.8221
0.8105
0.8067
30.3
2.8
0.0
8.9
61.8
139.3
2.4
33.9
117.1
26.8
8
7
8
6
9
8
7
8
7
6
0
5
4
4
3
4
1
6
3
6
4
3
2
6
1
4
7
2
7
6
24
48
48
24
48
24
24
48
24
8
Experimental
Physical Properties
Calc. density
5.21900 g/cm³
Remarks
Remarks
Co
Entry # 96-231-0324
Phase classification
Name
Formula
I/Ic
Sample Name
Quality
Fe Mo
FeMo
3.910000
2310323
C (calculated)
References
Publication
Bibliography
Origin of data
Source of entry
Link to orig. entry
Wilson C.G., Spooner F.J., "Ordering of atoms in the sigma phase
of Fe Mo", Acta Crystallographica (1,1948-23,1967)16, 230-230
(1963)
COD (Crystallography Open Database)
2310323
Crystal structure
Crystallographic data
Space group
P 42/m n m (136)
Crystal system
tetragonal
Cell parameters
a= 9.1280 Å c= 4.8130 Å
Z
15
Element Oxid.
Atom coordinates
x
y
Fe
0.182 0.182
Fe
0.738 0.065
Fe
0.000 0.000
Mo
0.398 0.398
Mo
0.182 0.182
Fe
0.398 0.398
Fe
0.463 0.132
Mo
0.463 0.132
z
0.252
0.000
0.000
0.000
0.252
0.000
0.000
0.000
Bi
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
1.000000
Focc
0.250000
1.000000
1.000000
0.750000
0.750000
0.250000
0.250000
0.750000
Diffraction data
Diffraction lines
d [Å]
6.4545
4.5640
Int.
h k l Mult.
5.7 1 1 0 4
2.4 2 0 0 4
Universitas Sumatera Utara
4.2574
4.0822
3.8584
3.2272
3.1132
2.8865
2.6804
2.5718
2.5317
2.4755
2.4065
2.2820
2.2549
2.2406
2.2139
2.1515
2.1287
2.0731
2.0411
2.0113
1.9642
1.9292
1.8791
1.8484
1.8256
1.7901
1.7442
1.7069
1.6950
1.6778
1.6559
1.6293
1.6136
1.6039
1.5988
1.5801
1.5654
1.5570
1.5566
1.5299
1.5213
1.5006
1.4932
1.4887
1.4544
1.4433
1.4366
1.4363
1.4326
1.4256
1.4191
1.4023
1.3858
1.3824
1.3669
1.3607
1.3551
1.3402
1.3122
1.3094
1.2991
1.2909
1.2861
1.2859
21.0
27.3
6.8
6.5
10.7
22.3
3.9
28.0
19.0
147.1
183.8
13.5
50.4
19.4
967.6
464.5
448.7
783.2
2.1
1000.0
438.4
111.1
4.4
126.0
0.3
3.0
14.9
18.5
1.2
7.9
0.1
0.8
0.6
0.1
4.6
0.8
3.2
1.4
13.5
0.4
3.3
0.5
0.7
0.1
53.3
7.8
0.8
41.0
3.3
10.8
5.9
18.7
90.7
22.9
13.4
1.0
2.0
1.0
188.5
7.0
185.5
64.9
84.9
79.1
1
1
1
2
2
1
2
3
2
3
0
4
1
3
1
3
2
2
2
4
3
2
4
3
3
1
3
4
2
5
4
4
4
3
5
0
3
1
4
4
6
1
2
5
4
2
2
5
6
4
3
3
5
6
5
3
3
4
5
6
4
1
3
6
0
2
1
2
1
3
2
0
3
1
0
0
1
2
4
3
0
1
4
1
3
2
2
1
4
5
2
3
5
1
0
1
4
3
2
1
5
1
2
4
0
6
1
3
3
6
2
1
1
5
0
1
2
2
4
6
2
4
3
3
1
7
3
0
1
0
1
0
1
0
1
1
0
1
2
0
2
1
0
0
2
2
0
1
1
2
1
2
0
0
2
1
0
1
2
2
0
2
1
3
0
3
2
1
0
0
3
1
2
0
3
2
1
0
3
3
2
1
1
0
3
2
2
1
3
0
3
2
8
8
8
4
16
8
8
8
8
16
2
4
8
16
8
4
8
16
8
16
8
8
16
16
8
8
16
16
8
16
8
16
4
8
16
8
8
8
16
8
4
8
16
16
16
8
8
16
16
8
8
16
16
16
16
8
16
8
16
16
16
8
8
8
Universitas Sumatera Utara
1.2733
1.2658
1.2613
1.2586
1.2538
1.2468
1.2377
1.2265
1.2242
1.2133
1.2051
1.2033
1.1986
1.1947
1.1845
1.1829
1.1687
1.1652
1.1635
1.1630
1.1542
1.1410
1.1377
1.1376
1.1357
1.1322
1.1274
1.1204
1.1203
1.1120
1.1106
1.1069
1.1021
1.0959
1.0867
1.0788
1.0757
1.0730
1.0729
1.0684
1.0656
1.0644
1.0611
1.0572
1.0513
1.0502
1.0498
1.0430
1.0377
1.0365
1.0362
1.0310
1.0245
1.0205
1.0119
1.0080
1.0057
1.0056
69.8
0.8
1.9
13.8
156.1
61.9
40.7
27.3
10.1
65.9
4.3
87.8
0.0
2.3
1.9
0.1
4.7
0.7
0.1
0.1
1.1
1.5
0.5
2.5
0.7
4.2
0.5
0.0
6.5
14.1
1.9
74.9
4.4
1.6
2.3
57.7
28.8
8.3
5.0
0.0
5.7
2.2
0.0
125.6
1.5
66.1
36.8
0.1
4.3
0.7
8.0
50.9
102.5
1.0
6.6
0.0
29.6
8.2
6
4
4
7
2
5
6
5
6
7
4
0
3
5
6
1
5
5
0
7
2
8
4
5
6
1
2
5
6
7
3
2
7
6
3
8
6
6
7
3
5
4
5
4
6
3
6
8
6
4
7
8
7
4
7
1
5
8
1
6
2
0
7
5
2
4
4
2
3
0
7
1
3
1
6
2
2
3
1
0
4
5
5
8
2
3
4
2
1
8
4
1
2
2
6
2
3
8
4
0
7
1
5
3
6
3
3
2
5
0
4
8
0
9
5
2
2
0
3
1
0
1
2
2
1
1
3
4
0
3
2
4
0
3
4
1
4
0
3
2
1
0
4
3
2
2
4
0
1
3
4
1
0
3
2
0
3
4
0
4
2
4
1
1
3
4
1
2
2
0
3
0
3
2
16
8
16
8
8
8
16
16
16
16
16
2
8
16
16
8
8
16
8
16
16
4
8
8
16
8
8
16
16
16
16
8
16
16
16
16
4
16
16
8
16
8
8
16
16
8
8
16
16
16
16
8
16
8
8
8
8
16
Experimental
Physical Properties
Calc. density
9.42600 g/cm³
Universitas Sumatera Utara
LAMPIRAN 6
HASIL X-RAY DIFRACTION (XRD)
93%MillScale+7%FeMo-Tk 1000_Theta_2-Theta.r
Sample name :
93%MillScale+7%FeMoComment : IS=RS1=2;
RS2=1
Date : 2016/05/09
12:43:39
Operator :
X-Ray : 40 kV , 30 mA
Wavelength : CuKa /
1.541862 A
Goniometer :
Base att. config. :
Attachment :
Detector : SC-70
Memo :
Optics attribute :
Scan mode :
CONTINUOUS
Scan speed / Duration
time : 5.0000 deg./min.
Step width : 0.0100 deg.
Scan axis : 2Theta/Theta
Scan range : 20.0000 90.0000 deg.
2-Theta :
Omega :
Chi :
Phi :
2-ThetaChi :
CBO selection slit :
Incident parallel slit :
Incident slit : 2.000deg
Length limiting slit :
Receiving slit # 1 :
2.000deg
Filter : Cu_K-beta
Receiving optical device :
Receiving parallel slit :
Receiving slit # 2 :
1.000mm
Attenuator :
Diffrected beam mono. :
None
Monochromator slit :
Universitas Sumatera Utara
93%MillScale+7%FeMo-Ts1100_Theta_2-Theta.raw
Comment : IS=RS1=2;
RS2=1
Date : 2016/05/09
13:17:36
Operator :
X-Ray : 40 kV , 30 mA
Wavelength : CuKa /
1.541862 A
Goniometer :
Base att. config. :
Attachment :
Detector : SC-70
Memo :
Optics attribute :
Scan mode :
CONTINUOUS
Scan speed / Duration
time : 5.0000 deg./min.
Step width : 0.0100 deg.
Scan axis : 2Theta/Theta
Scan range : 20.0000 90.0000 deg.
2-Theta :
Omega :
Chi :
Phi :
2-ThetaChi :
CBO selection slit :
Incident parallel slit :
Incident slit : 2.000deg
Length limiting slit :
Receiving slit # 1 :
2.000deg
Filter : Cu_K-beta
Receiving optical device :
Receiving parallel slit :
Receiving slit # 2 :
1.000mm
Attenuator :
Diffrected beam mono. :
None
95
Universitas Sumatera Utara
LAMPIRAN 7
SKEMA SINTERING
Pada temperatur Sintering 1100 oC, t hold = 2 jam
Temperatur
Waktu
sintering
(menit)
(C)
0
25
57
600
117
600
167
1100
287
1100
394
25
Skema sintering
120 Menit
1100
Suhu ( C)
900
700
60 Menit
500
300
100
0
100
200
300
400
Waktu (h)
96
Universitas Sumatera Utara
Pada temperatur sintering 1150 oC, t hold = 2 jam
Temperatur
Waktu
sintering
(menit)
(C)
0
25
57
600
112
600
172
1200
295
1200
409
25
Skema sintering
1400
1200
suhu (°C)
1000
800
600
400
200
0
0
100
200
300
400
500
Waktu (menit)
97
Universitas Sumatera Utara
Pada temperatur sintering 1200 oC, t hold = 2 jam
Waktu
(menit)
Temperatur
sintering
(C)
0
25
57
600
117
600
177
1200
297
1200
414
25
Skema sintering
1200
Suhu (C)
1000
800
600
400
200
0
0
100
200
300
400
500
Waktu (menit)
98
Universitas Sumatera Utara