Modifikasi Dan Karakterisasi Karet Alam Siklis (Resiprena 35) Dengan Anhidrida Maleat Sebagai Substituen Bahan Pengikat Cat Sintetis
Lampiran 1. Rancangan penelitian pencangkokan Anhidrida Maleat pada Karet Alam Siklis No KAS
1.0
30
17
8
10.22 80 150
2.0
0.3
1
4.8
16
30
16
8
5.11 80 150
0.3
4.8
1
4.8
16
30
15
8
2.55 80 150
0.5
0.3
1
4.8
16
30
16
1 0.3 - - 60 150
8
4.8
1 0.3 - - 80 150
4.8
16
30
22
8
1 0.3 - - 80 150
4.8
16
30
21
6
1 0.3 - - 80 150
16
8
30
20
8
1 0.3 - - 80 150
4.8
16
30
19
8
1 0.3 - - 70 150
4.8
16
30
18
14
10.22 80 150
(g) Anhidrid Maleat Benzoil
5
8
1 0.3 - - 80 150
0.6
2
30
7
8
16 4.8 - - - - 80 150
30
6
8
8 2.4 - - - - 80 150
30
8
30
4 1.2 - - - - 80 150
30
4
8
2 0.6 - - - - 80 150
30
3
8
2 30 - - - - - - 80 150
1 30 - - - - - - - - -
(mol ratio/MA) (g)
C) T (min) (phr) (g) (phr) (g)
T ( o
Peroksida Styrena Kec. rotor (rpm)
8
4
2.0
30
16 4.8 - -
30
13
8
5.11 80 150
1.0
16 4.8 - -
30
12
8
2.55 80 150
0.5
16 4.8 - -
11
1.2
8
1 0.3 - - 80 150
4.8
16
30
10
8
1 0.3 - - 80 150
2.4
8
30
9
8
1 0.3 - - 80 150
12
2.0
1.8 L
am pi
1.6
ra n 2. S
49
1.4
pe 34. kt
29
rum
1.2 e
F
nc
T
ba
- IR
or
1.0 bs
83 K A 59.
ar
0.8
et A
14
59
la m S
74.
0.6
13
ikl
74
is
.49
s 04.
.20
0.4
49
ega
16
7
26
8
r (
fre
0.2 sh )
0.0 4000 3000 2000 1000 Wavenumbers (cm-1)
L am
1.2
pi ra n 3. S
1.1 P
pe
1.0
enc kt am rum pur
0.9 F
I T nt
49
- I R
0.8
er 34.
K na
29
l ar
e
0.7
et A
nc 83 ba
la m
59. or
0.6 S
14 bs A
ikl
59
is
0.5 74.
ya
13
ng s
0.4
uda
05 .49
99.
h di
.04
91
49
0.3
15
7
29 26.
pr
8
17
os
0.2
es di d
0.1
al am
4000 3000 2000 1000 Wavenumbers (cm-1)
L am pi ra
2.0
n 4. S pe
1.8
kt rum
1.6 F
T
29
- I R 33.
KAS
1.4
29
de
e
1.2 nc
nga
25 ba
57.
n p
or
1.0 14 bs
09
ena
A 72.
m ba
13
0.8
ha n A
02 .62
0.6
nhi
84
00 02.
.94
47
16 7 dr
78.
29 80.
8
17
17
id M
0.4
al ea t 2 phr
0.2
, t
0.0
anpa
3000 2000 1000
B
Wavenumbers (cm-1)
P O
L am
2.8
pi ra n 5. S
2.6 M
2.4
pe al kt eat
2.2
rum 4 phr
29 F
T
2.0 33.
, t
- IR
29
anp K
1.8
a B A S
e
P
1.6
de O
nc
25
nga
ba 57. or
1.4
n p
14 bs A
26
1.2
ena 69. m ba
13
1.0
ha n A
0.8
18
nhi
.46
91 .94 84 99.
50
dr
0.6 26.
29
7
15 80.
8
id
17
17
0.4
0.2
0.0 3000 2000 1000 Wavenumbers (cm-1)
L am
0.60
pi ra n 6. S
0.55 M
pe
0.50
al kt eat rum 8 phr
61
0.45 F 27.
T
29
, t
- IR anp
0.40 K
41
a B A
e 54.
0.35 S
P
nc
de
09 O
14 ba
nga 72.
or
0.30 13 bs
n p
A
02
ena
0.25 .10 02.
m
39 7 ba .94
16
0.20
ha
29
8
n A nhi
0.15
dr id
0.10
0.05
0.00 3000 2000 1000 Wavenumbers (cm-1)
3.6 L
am
3.4
pi ra n 7. S
3.2
3.0 M
pe al kt
2.8
ea rum t 16 phr
2.6 F
T
2.4
- IR
29
, t 33.
K
2.2
anp
29 A e
2.0
S a B
de
nc
P O nga
ba
1.8 or
41
n p
bs
1.6 A 54.
ena
14
1.4
m
18 93 ba
99.
1.2
ha 74.
40
15
n A
13
1.0 18.
nhi
17
68 .67
0.8 .62
dr 83.
69
8
47
17
id
0.6
7
0.4
0.2
0.0 3000 2000 1000 Wavenumbers (cm-1)
L am
1.7
pi
1.6
ra n 8. S
1.5 M
pe
1.4
al kt ea rum t 2 phr
1.3
25 F
T 34.
1.2
, de
- IR
29 K
1.1
ng A S
e
an B
1.0
de
nc
P nga
ba
0.9 O or
71
n p
bs
0.8 A 56.
ena
14
0.7
m
47
ba
0.6
ha 74. n A
13
0.5
nhi
51
0.4
dr
46 .56
85 98. .13
id
50 20.
82.
0.3
15
27
7
8
17
17
0.2
0.1
0.0 3000 2000 1000 Wavenumbers (cm-1)
L am pi
2.0
ra n 9. S
1.8 M
pe al kt ea rum
1.6
t 4 phr F
96 T
,de 38.
- IR
1.4
29
ng K A an ke
e
S
1.2 nc
de h
ba
nga
25
adi
or
1.0 57.
n p
bs
ra n B
A
14
ena
09 P
O m
0.8 72.
ba
13
ha n A
0.6
02
23
68
nhi
.62 .94
21.
02.
83.
47
dr
29
7
16
17
0.4
17
8
id
0.2
0.0 3000 2000 1000 Wavenumbers (cm-1)
3.2 L
am
3.0
pi ra n 10. S
2.8 M
2.6
pe al kt ea
2.4
t 8 phr rum
13
2.2 36.
F T
29
,de
- IR
2.0
ng K
1.8 A
an ke
e
S
nc
25
de ha
1.6 ba 57.
nga di
or
14
ra
bs
n pe
1.4
n B
A
09 P n 72.
1.2 O
am
13
ba
23
1.0
53
ha
84 21.
n A 10.
.62
0.8 17 .77 80.
16 47 nhi
32
17
7
8
0.6
dr id
0.4
0.2
0.0 3000 2000 1000 Wavenumbers (cm-1)
1.9 L
am
1.8
pi
1.7
ra n 11. S
1.6 M
1.5
pe
13
al kt ea
1.4 36.
t 16 phr rum
29
1.3 F
T
1.2
- IR ,de
K ng
1.1 e
A
41
an k
nc
1.0 S
de
ba 54.
eha
or
0.9
nga
14
di
bs A
n pe
0.8 93 ra
n B
18 74.
n
0.7 P 13 am 99.
O
0.6
40
ba
15
ha 18.
52
0.5
n A
17 .62
86.
.94
0.4 47 nhi
17
29
7
8
dr
0.3
id
0.2
0.1
0.0 3000 2000 1000 Wavenumbers (cm-1)
0.65 A
0.40
0.10
0.15
0.20
0.25
0.30
0.35
0.45
29
0.50
0.55
0.60
bs or ba nc e
3000 1000 2000 Wavenumbers (cm-1)
L am pi ra n 12. S pe kt rum F T
M /S t = 2: 1) t anpa B P O
0.05
29 33.
7
14 54.
02 .20
7
50 .46
8
38 .45 13 72.
09
41
- IR K A S de nga n pe n am ba ha n A nhi dr id M al ea t da n kom onom er S tir ena , ra si o m ol A
64
15 99.
18
17 21.
23
17 83.
68
18 54.
1.4 A
0.9
0.2
0.3
0.4
0.5
0.6
0.7
0.8
1.0
0.0
1.1
1.2
1.3
bs or ba nc e
4000 3000 1000 2000 Wavenumbers (cm-1)
L am pi ra n 13. S pe kt rum F T
1) t anpa B P O
0.1
49
- IR K A S de nga n pe n am ba ha n A nhi dr id M al ea t da n kom onom er S tir ena , ra si o m ol A M /S t = 1:
14
98 .34
7
58 .01
8
29 .04 13 74.
59
14 54.
6
29 34.
05
17 21.
23
17 80.
90
18 57.
62
15 99.
1.0 A
29 33.
L am pi ra n 14. S pe kt rum F T
0.9
0.8
0.7
29
- IR K A S de nga n pe n am ba ha n A nhi dr id M al ea t da n kom onom er S tir ena , ra si o m ol A M /S t = 1:
14 57.
0.2
2) t anpa B P O
99 .36
3000 1000 2000 Wavenumbers (cm-1)
bs or ba nc e
7
61 .81
8
0.6
0.5
0.4
0.3
0.1
25
0.0
38 .45 13 72.
09
6
18 54.
68
17 83.
23
17 21.
53
16 10.
64
1.3 A
0.8
0.2
0.3
0.4
0.5
0.6
0.7
0.9
0.0
1.0
1.1
1.2
bs or ba nc e
3000 1000 2000 Wavenumbers (cm-1)
L am pi ra n 15. S pe kt rum F T
1) de nga n B P O
0.1
29
- IR K A S de nga n pe n am ba ha n A nhi dr id M al ea t da n kom onom er S tir ena , ra si o m ol A M /S t = 2:
25
05 .04
7
50 .46
8
41 .29 13 72.
09
14 57.
7
29 33.
53
17 18.
40
17 83.
68
18 57.
48
16 10.
1.4 A
68
L am pi ra n 16. S pe kt rum F T
1.3
1.2
1.1
1.0
0.9
29
29 33.
- IR K A S de nga n pe n am ba ha n A nhi dr id M al ea t da n kom onom er S tir ena , ra si o m ol A M /S t = 1:
02
0.7
1) de nga n B P O
05 .04
3000 1000 2000 Wavenumbers (cm-1)
bs or ba nc e
7
53 .29
9
49 .15 13 74.
93
0.8
0.6
17 83.
0.5
0.4
0.3
0.2
0.1
7
14 60.
09
64
18 54.
16 02.
0.0
2.0 A
29
L am pi ra n 17. S pe kt rum F T
1.8
1.6
1.4
- IR K A S de nga n pe n am ba ha n A nhi dr id M al ea t da n kom onom er S tir ena , ra si o m ol A M /S t = 1:
26
0.6
2) de nga n B P O
05 .04
3000 1000 2000 Wavenumbers (cm-1)
bs or ba nc e
7
53 .29
9
1.2
1.0
0.8
0.4
14 57.
0.2
0.0
29 .28 13 69.
7
64
18 54.
84
17 80.
02
16 02.
25
29 33.
L am
2.8
pi ra
2.6
n 18. S
2.4
rot pe or kt 60 r
2.2
rum
29
pm
2.0 F 33.
T
29
- I R
1.8 KAS e
1.6 nc
25
pr
ba 57.
oduk pe
or
1.4 14 bs
A
26
1.2 69.
n
13
ca
1.0
ngkoka
0.8 18 .46 n A
91 .94 84 99.
50
0.6 26.
M
29
7
15 80.
8
d
17
17
0.4
enga n k
0.2
ec ep
0.0
at
3000 2000 1000 an Wavenumbers (cm-1)
L am pi
0.60
ra n 19. S
0.55
rot pe or kt
0.50
70 r rum pm
61
0.45 F
T 27.
- I
29 R
0.40 KAS
41 e 0.35 54.
pr
nc
09
14 ba
oduk pe 72.
or
0.30 13 bs
A
n
02
0.25 .10
ca 02. ngkoka
39
7 .94
16
0.20
29
8
n A
0.15 M
d enga
0.10
n k
0.05
ec ep
0.00
at an
3000 2000 1000 Wavenumbers (cm-1)
L
1.9
am
1.8
pi ra n 20. S
1.7
1.6
rot pe or
1.5
13
kt 80 r rum
1.4 36.
pm
29 F
1.3 T
- I
1.2 R
KAS
1.1 e
41 nc
1.0
pr
ba 54.
oduk pe
or
0.9 14 bs
A
0.8
93
n
18 74.
0.7
ca
13
ngkoka 99.
0.6
40
15 18.
52
0.5
17
n A
.62 86. .94
0.4
47
17
29 M
7
8
d
0.3
enga
0.2
n k
0.1
ec
0.0
ep at
3000 2000 1000
an
Wavenumbers (cm-1)
L am
1.2
pi ra n 21. S
1.1
w pe
1.0
akt kt u 6 m rum
0.9 F
eni T
49
t
- I
0.8 R 34.
KAS
29 e
0.7 nc
pr
83 ba
oduk pe 59.
or
0.6 14 bs
A
59
n
0.5 74.
ca
13
ngkoka
0.4 05 .49
n A 99.
91 .04
49
0.3
15
7 M
29 26.
8
d
17
enga
0.2
n
0.1 4000 3000 2000 1000 Wavenumbers (cm-1)
1.9 A
29 36.
L am pi ra n 22. S pe kt rum F T
1.8
1.7
1.6
1.5
1.4
1.3
13
- I R KAS pr oduk pe n ca ngkoka n A M d enga n w akt u 8 m eni t
40
1.0
47 .62
3000 1000 2000 Wavenumbers (cm-1)
bs or ba nc e
8
29 .94 13 74.
93
14 54.
41
15 99.
1.2
1.1
0.9
17 86.
0.8
0.7
0.6
0.5
0.4
7
0.2
0.1
0.0
18
17 18.
52
0.3
3.6 A
29
L am pi ra n 23. S pe kt rum F T
3.4
3.2
3.0
2.8
2.6
2.4
- I R KAS pr oduk pe n ca ngkoka n A M d enga n w akt u 12 m eni t
17 18.
1.8
47 .62
3000 1000 2000 Wavenumbers (cm-1)
bs or ba nc e
8
69 .67 13 74.
93
14 54.
41
15 99.
2.2
2.0
1.6
40
1.4
1.2
1.0
0.8
7
0.4
0.2
0.0
18
29 33.
68
17 83.
0.6
Lampiran 24. Tabel luas area puncak serapan dan indeks serapan No Luas puncak serapan Indeks 1370 700 1700 fenil karbonil
1 - - - - - 2 7,328 - 0,807 - 0,110126 3 13,191 - 2,76 - 0,209234 4 20,701 - 5,919 - 0,285928 5 3,33 - 1,564 - 0,46967 6 12,422 - 14,577 - 1,173483 7 8,451 1,843 - 0,218081 8 12,49 - 6,509 - 0,521137 9 16,385 - 16,354 - 0,998108 10 8,508 - 10,478 - 1,231547
11 3,162 0,804 4,049 0,254269 1,280519 12 6,082 1,738 10,512 0,285761 1,728379 13 4,588 2,141 12,169 0,466652 2,652354 14 6,633 2,373 18,331 0,357757 2,763606 15 7,132 3,843 20,949 0,538839 2,937325 16 8,515 7,933 29,835 0,93165 3,503817 17 13,213 - 2,801 - 0,211988 18 3,4 - 0,76 - 0,223529 19 8,508 - 10,478 - 1,231547 20 4,889 - 1,869 - 0,382287 21 12,389 - 14,541 - 1,173702 22 8,508 - 10,478 - 1,231547
L am pi ra n 25 . T he rmogr am T G A K ar et A la m S ikl is s ega r (
fre sh ) Lampiran 26. Thermogram TGA Karet Alam Siklis setelah diproses di Pencampur Internal
Utara Sumatera Universitas
L am pi ra n 27 . T he rmogr am D S C K ar et A la m S ikl is s ega r (
fre sh ) Lampiran 28. Thermogram DSC Karet Alam Siklis setelah diproses di dalam Internal Mixer
Utara Sumatera Universitas
L am pi ra n 29 . T he rmogr am T G A K ar et A la m S ikl is pe na m ba ha n A M 2 phr L am pi ra n 30. T he rm ogr am T G A K ar et A la m S ikl is pe na m ba ha n A M 4 phr
L am pi ra n 31 . T he rm ogr am T G A K ar et A la m S ikl is pe na m ba ha n A M 8 phrL am pi ra n 32 . T he rm ogr am T G A K ar et A la m S ikl is pe na m ba ha n A M 16 phr L am pi ra n 33. T he rm ogr am D S C K ar et A la m S ikl is pe na m ba ha n A M 2 phr
L am pi ra n 34 . T he rm ogr am D S C K ar et A la m S ikl is pe na m ba ha n A M 4 phr
L am pi ra n 35 . T he rm ogr am D S C K ar et A la m S ikl is pe na m ba ha n A M 8 phr
L am pi ra n 36 . T he rmogr am D S C K ar et A la m S ikl is pe na m ba ha n A M 16 phr
L am pi ra n 37. T he rm ogr am T G A K ar et A la m S ikl is pe na m ba ha n A M 2 phr de nga n B P O
L am pi ra n 38. T he rm ogr am T G A K ar et A la m S ikl is pe na m ba ha n A M 4 phr de nga n B P O L am pi ra n 39 . T he rm ogr am T G A K ar et A la m S ikl is pe na m ba ha n A M 8 phr de nga n B P O
L am pi ra n 40. T he rm ogr am T G A K ar et A la m S ikl is pe na m ba ha n A M 16 phr de nga n B P O BP L am O pi ra n 41. T he rm ogr am D S C K ar et A la m S ikl is pe na m ba ha n A M 2 phr de nga n
L am pi ra n 42. T he rm ogr am D S C K ar et A la m S ikl is pe na m ba ha n A M
4 phr de nga n B P O
L am pi ra n 43. T he rm ogr am D S C K ar et A la m S ikl is pe na m ba ha n A M 8 phr de nga n B P O L am pi ra n 44. T he rm ogr am D S C K ar et A la m S ikl is pe na m ba ha n A M 16 phr de nga n B P O
Lampiran 45. Thermogram TGA Karet Alam Siklis penambahan AM 16 phr dengan Stirena (2:1)Utara Sumatera Universitas Lampiran 46. Thermogram TGA Karet Alam Siklis penambahan AM 16 phr dengan Stirena (1:1)
Utara Sumatera Universitas Lampiran 47. Thermogram TGA Karet Alam Siklis penambahan AM 16 phr dengan Stirena (1:2)
Utara Sumatera Universitas Lampiran 48. Thermogram DSC Karet Alam Siklis penambahan AM 16 phr dengan Stirena (2:1)
Utara Sumatera Universitas Lampiran 49. Thermogram DSC Karet Alam Siklis penambahan AM 16 phr dengan Stirena (1:1)
Utara Sumatera Universitas Lampiran 50. Thermogram DSC Karet Alam Siklis penambahan AM 16 phr dengan Stirena (1:2)
Utara Sumatera Universitas Lampiran 51. Thermogram TGA Karet Alam Siklis dengan BPO dan penambahan AM 16 phr dengan Stirena (2:1)
Utara Sumatera Universitas Lampiran 52. Thermogram TGA Karet Alam Siklis dengan BPO dan penambahan AM 16 phr dengan Stirena (1:1)
Utara Sumatera Universitas Lampiran 53. Thermogram TGA Karet Alam Siklis dengan BPO dan penambahan AM 16 phr dengan Stirena (1:2)
Utara Sumatera Universitas Lampiran 54. Thermogram DSC Karet Alam Siklis dengan BPO dan penambahan AM 16 phr dengan Stirena (1:2)
Utara Sumatera Universitas Lampiran 55. Thermogram DSC Karet Alam Siklis dengan BPO dan penambahan AM 16 phr dengan Stirena (1:1)
Utara Sumatera Universitas Lampiran 56. Thermogram DSC Karet Alam Siklis dengan BPO dan penambahan AM 16 phr dengan Stirena (2:1)
Utara Sumatera Universitas