Journal of Life Sciences Volume 10 Numbe (1)

J LS

Journal of Life Sciences

Volume 10, Number 1, January 2016 (Serial Number 92)

Contents

Zoology and Botany

1 Teat Length and Lactation Period as A Predisposition Factor of Subclinical Mastitis in Dairy Cattle in Bandung, Indonesia

Herwin Pisestyani, RP Agus Lelana and Yeti Nevia Septiani

7 The Effects of Calcium Chloride and Ascorbic Acid Treatment on Ready-to-use Carrot Shreds

Mehmet Ufuk Kasim and Rezzan Kasim

16 The Cytochrome b Polymorphism of Meat Lines Rabbits

Vladimir Parkanyi, Lubomir Ondruska and Dusan Vasicek

Ecology

21 Using Magnetic Technique to Increase Efficiency of Organic Pollutants Biodegradation in Wastewater

Khalid Falih Hassan, Suadad Awad Kadhim, Noor Nihad Baqer and Elaaf Safa Al-deen Hassan

33 The Impact of Life Sciences Developments on the UK Urban Environment

Peter Jones, Martin Wynn, David Hillier and Daphne Comfort

Interdisciplinary Researches

39 Serpentine Design on Forest Roads by the Internal Circular Curve Method: A Case Study in Serbia

Bogdan Ž. Stefanovi ć

48 The Role of Homocysteine and Other Clinical Laboratory Markers in Assessing Cardiovascular Risk in Patients on Hemodialysis

Irena Ivanova Gencheva-Angelova, Adelaida Lazarova Ruseva and Pavlina Dimitrova Yordanova-Laleva

54 Epidemiology of ADRs in Internal Medicine, HCC

Alba Delia Campaña S., Anthon Álvarez Arredondo, J. Alfredo Contreras G., S. Saúl Irizar S. and A. Miroslava Flores R.

Journal of Life Sciences 10 (2016) 1-6

doi: 10.17265/1934-7391/2016.01.001

DAVID PUBLISHING

Teat Length and Lactation Period as A Predisposition Factor of Subclinical Mastitis in Dairy Cattle in Bandung, Indonesia

1 2 Herwin Pisestyani 2 , RP Agus Lelana and Yeti Nevia Septiani

1. Veterinary Public Health Division, Department of Animal Health and Veterinary Public Health, Faculty of Veterinary Medicine, Bogor Agricultural University, Bogor 16680, Indonesia

2. Clinic Division, Department of Clinic Reproduction and Pathology, Faculty of Veterinary Medicine, Bogor Agricultural University, Bogor 16680, Indonesia

Abstract: In order to improve the practical approach to clinical diagnosis of subclinical mastitis, 72 dairy cattle from KPSBU Lembang Bandung Regency was used in this research. The purpose of this research was to study the correlation between udder length and lactation period with the profile of subclinical mastitis. Lactation period data was collected from interviews with farmers. Subclinical mastitis testing by IPB-1 Mastitis Test reagent and udder length measured using measuring tape (cm). Data was analyzed using Duncan test and logistic regression. The highest correlation of subclinical mastitis occurred to dairy cattle with average udder length of 7.5 cm and was in the third and forth lactation period. This result shows that udder length and lactation period of dairy cattle is a predisposing factor for subclinical mastitis. This finding is important to improve the milking management as well as a way to diagnose subclinical mastitis.

Key words: Lactation period, subclinical mastitis, udder length.

1. Introduction  the farmers accessibility to obtain a subclinical mastitis diagnosis kit. These conditions are also faced by the

Subclinical mastitis is a disease in dairy cattle that livestock in West Java with business scale of 5.8 heads has not been handled well. Subclinical mastitis is per business unit and production capability of inflammation of the internal tissue of the udder [1]. approximately 11.6 liter/head/day [5]. Therefore a Losses caused by subclinical mastitis are decreased in more practical alternative solution is needed, such as milk production, decreased of milk quality, expensive studying the predisposing factors that can be used as an cost for treatment and medication, early culling of

indicator of subclinical mastitis.

cattle as well as purchasing of new dairy cattle [2]. An attempt to identify subclinical mastitis These threats are faced by 127,211 farmers in predisposing factors among others is to assess udder Indonesia whose cattle population reached 475 health. According to Blakely, J. [6], udder health of thousand heads with 19 million liter of milk production dairy cattle in relation to milk production is affected by [3]. It will be hard for Indonesia to reach the cows’ physical condition, milking habits, body self-sufficiency in milk if it does not pay attention to condition score and udder scoring. Udder scoring these threats are. Indonesia is currently only able to covers teats length, position of the front teat, front fulfill 20-30% of its domestic demand [4]. udder linkage, udder depth, rear udder height, middle One of the problems faced in handling subclinical ligament and position of rear teat [6]. Saragih, B. [7] mastitis lies on the ability to diagnose in the field and stated that other than the anatomical factor of the udder,

cleanliness of the floor, floor surface and hygienic Corresponding author: Herwin Pisestyani, DVM, research

field: veterinary public health. milking of udder also affect udder health. Udder health

2 Teat Length and Lactation Period as A Predisposition Factor of Subclinical Mastitis in Dairy Cattle in Bandung, Indonesia

can be achieved by maintaining personal hygiene, farmer and cow in normal lactation condition. milking hygiene, good shed management, good

Farmers’ information includes: name of farmer, milking management, vaccination program, and village, and number of cow in a shed. Cow administrating antibiotic periodically [8].

information includes: cow number, age and lactation BIF [9] assign a standard that average size teat

period, and amount of milk production per day. length for both front teats of Frisian Holstein (FH) cow

Somatic Cell Count (JSS) testing is done by indirect should be 6 cm in length and 2.9 cm in diameter, while

method. The indirect method used is subclinical the rear has an average size of 5 cm in length and 2.6

mastitis diagnosis using IPB-1 Mastitis Test reagent. cm in diameter. Prihadi, S. [10] stated that Indonesian

Measuring the length of teats is done using tape FH cow is different then it’s origin, it has the ability to

measure expressed in centimeters (cm). produce an average of 10 liter per day with 12-15 month

2.4 Determination of Sample Size and Withdrawal calving interval and lactation period approximately 10

month or an average milk production of 2,500-3,000 Determination of sample size begin with recording liter per lactation. The average age of dairy cows first

the number of dairy cattle in Sukajaya Village based lambing is 2-2.5 years and this is the first lactation

on udder health testing requirements which are; cows period [11]. Lactation period is the period the cow

is in its normal lactation condition. The amounts of produces milk between birth and dry period, therefore

sample size obtained are 72 dairy cows. duration of lactation is between 8-10 months [2].

2.5 Measuring of Teat Length

There have not been many studies of predisposing factors for subclinical mastitis in dairy cattle. Therefore

Teat length is measured using measuring tape (cm). this research is needed to know teat length and lactation

Measuring is performed on each quarter after cow is period as one of the predisposition factor for

bathed.

subclinical mastitis in the livestock in KPSBU

2.6 Subclinical Mastitis Testing

Lembang Bandung Regancy. Subclinical mastitis testing is done by indirect method

2. Material and Methods

using IPB-1 Mastitis Test reagent [12]. Paddle is filled

2.1 Time and Place of Research with 2 mL of milk from a cow that was previously The research is conducted in the month of

bathed, udder cleaned, and then milk is milked from July-December 2012, on the livestock who are

the teat. First and second spray is disposed, and then members of KPBSU Lembang in Sukajaya Village,

the next spray of milk is collected in the paddle. IPB-1 District Lembang, Bandung Regency, West Java.

Mastitis Test reagent is added in the sample with a 1:1 ratio. Sample and reagent is homogenized horizontally

2.2 Tools and Materials for 15-30 s. Test principles of IPB-1 Mastitis Test is Tools used in this research are paddle, measuring

that the reagent will bind with somatic cell nucleus tape (cm), cloth and stationery. Materials used are IPB-1

DNA which will form a think gelatin like mass. A reagent mastitis test and milk sample from each quarter.

thicker mass shows more somatic cell nucleus DNAs that are bind with IPB-1 Mastitis Test reagent.

2.3 Research Method Results interpretation. The reaction is observed

This research is a field study of subclinical mastitis according to Sudarwanto M. [1], if reaction is negative, cases. Data is obtained through research and interview.

milk and reagent stays homogeneous, if positive one it Interview is conducted to obtain information regarding

will form a thin mucous, positive two will form a

Teat Length and Lactation Period as A Predisposition Factor of Subclinical

Mastitis in Dairy Cattle in Bandung, Indonesia

thicker mucous, positive three mucous is very thick

Table 1 Average of teat length in each period of lactation

like a gelatin mass. of dairy cattle in KPSBU Lembang, Bandung Regency.

Teat length (cm) Lactation

2.7 Data Analysis

average min

max 1 4.75 3.75 5.0

Data is analyzed descriptively, Gamma test and 2 5.6 5.0 6.2 logistic regression analysis. Descriptive analysis and

Gamma test is used to see relation or correlation 7.1 7.5 5 7.6 7.2 7.8

between variables in the study and to determine the 6 8 7.5 8.3

association variables that are ordinal [13]. Data is also analyzed by using Microsoft Office Excel 2007 and

Milking with two fingers is milking with the thumb and Duncan test.

forefinger that shifts from the base of the teat down while messaging, loosen and tighten to the top. The

3. Result and Discussion

weakness of milking this way is that the teat and udder

3.1 Influence of Teat Length Towards the Severity of are always wet, this can cause lesion on the udder and Subclinical Mastitis

can slowly change the anatomical shape of the teat to become longer [16]. This method of milking is applied

Udder or cows mammary gland consist of 4 separate on farms in KPSBU Lembang. Udder with weak

parts. The left and right part is separated by a sulcus ligaments will show an udder shape that falls and hangs.

called sulcus intermamaria that runs longitudinally. Weak Ligamentum suspensorium will cause the udder

Aspects that must be observed from the udder are size, to loose shape and loose its fold between quarters.

production capacity, udders’ height from floor surface Weakness of this ligament also causes the cows’ teat to

when cow is standing, and udder symmetry [14].

be prominent and long [15]. This study also shows the Ligamentum suspensorium is the divider from each

influence of teat length towards the degree of severity udder quarter. This ligament functions as a foundation

of subclinical mastitis from KPSBU Lembang dairy for the udder and a divider between quarters. The outer

farm that is presented in Table 2.

ligament is the Ligamentum lateralis [15]. This Data obtain from this study indicates that teat length

ligament functions as a buffer and gives the shape of significantly affects the level of severity of subclinical

the udder. Age can affect the strength of the ligament, mastitis (P < 0.05). Table 2 shows that teat with a 7.5

which separates each quarter of the udder. The higher cm length is more susceptible to subclinical mastitis

the lactation period shows the older the age of the cow. compared to teat with a 4.75 cm length, therefore

Average teat lengths of each lactation period of dairy teat length can be used as a predisposing factor of

cattle in KPSBU Lembang Bandung Regency are

shown in Table 1.

Table 2 Influence of teat length towards the degree of

Results of this study show an increase of teat length severity of subclinical mastitis from KPSBU Lembang

Bandung Regency.

in each lactation period. In the first lactation period teat

Degree of

Teat length (cm)

length is 4.75 cm, second lactation 5.6 cm, third

max lactation 6.5 cm, forth lactation 7.5 cm, fifth lactation

Severity of MSK*

average min

7.6 cm, and sixth lactation 8 cm. Teats that become + 5.75ª 5.5 6 longer is influenced by incorrect ways of milking and

++ 6.5 b 67 +++ 7.5 c 7 8.3

weakness of ligament. Description:*subclinical mastitis; different superscript letter in

Traditional milking by using two fingers (Strip the same column followed by the same letter are not Method) will affect the anatomical shape of the udder.

significantly different at the test level of P < 0.05.

4 Teat Length and Lactation Period as A Predisposition Factor of Subclinical

Mastitis in Dairy Cattle in Bandung, Indonesia

subclinical mastitis. Teat with a 7.5 cm length has a subclinical mastitis in dairy cattle in KPSBU level of subclinical mastitis severity of positive 3 (+++),

Lembang is presented in Figure 1. teat with a 6.5 cm has a level of subclinical mastitis

This study shows that lactation period significantly severity of positive 2 (++), and teat with a 5.75 cm has

affects the degree of severity of subclinical mastitis (P

a level of subclinical mastitis severity of positive 1 (+). < 0.05), meaning that the higher the lactation period Teat condition that does not have subclinical mastitis is

will increase the degree of severity of subclinical shown by teat that has a length of 4.75 cm. According

mastitis. Base on Figure 1 it appears that the incidence to the result of the study, farmers can use teat length as

of subclinical mastitis with different degree of severity

a diagnosis indicator for subclinical mastitis that is has increased on each lactation period. For cows in its dairy cattle with teat length of 6.5-7.5 cm may have

first lactation, age between 2.5-3 years and its first time subclinical mastitis.

giving birth, shows that the presentation of subclinical BIF [9] stated that subclinical mastitis cases occur in

mastitis incidence with a degree of severity ranging teats with a length category of 7-9 cm. Subronto [2] stated

between 0.7%-1.7%. Incidence of subclinical mastitis udders that hangs tremendously or udders that are long

with a positive three degree of severity continues to and have large teat opening is a predispose factor to

increase until its peak that is at the forth lactation udder inflammation in terms of the cattle. Long teats

period as high as 8.3%. This is likely due to cows that will make it easy for microbes to enter the internal

previously experienced subclinical mastitis with a tissue of the udder from the outside of the teat through

degree of severity of 1 and 2 whom later became worse the teat hole (ascendens) and lesions on the udder due

and became a positive 3. In cows that have reached the to friction with the floor [16]. Teat size that are to short

fifth and sixth lactation period with age range of 8-9 is also a predispose factor for subclinical mastitis. This

years, it is seen that the degree of severity of subclinical is because farmers have difficulty in milking therefore

mastitis of positive three experience a decrease. Cows the alveoli cannot secrete milk completely.

that initially experienced subclinical mastitis but because they were not handled well became a clinical

3.2 Influence of Lactation Period towards Severity mastitis case may have caused this. The decrease of Level of Subclinical Mastitis percentage of positive 3 degree of severity of subclinical

Mastitis is an inflammation of the udder, whether it mastitis can also be due to healing process because of is acute, sub acute or chronic, with the increase of

somatic cells in the milk and physical as well as the composition of milk, with or without pathological changes in the gland [2]. 95-98% of mastitis incidence is subclinical mastitis, while 2-3% incidence of clinical mastitis is detected [1]. Losess caused by subclinical mastitis are decreased in milk production, decreased of milk quality, expensive cost for treatment and medication, early culling of cattle as well as purchasing of new dairy cattle [2].

Length of the teat, ligament linkage, feed, weather, lactation period and genetic quality of the cow can

Fig. 1 Influence of lactation period towards the degree of

influence subclinical mastitis [17]. The influence of

severity of subclinical mastitis in KPSBU Lembang

lactation period towards the degree of severity of

Bandung Regency.

Teat Length and Lactation Period as A Predisposition Factor of Subclinical

Mastitis in Dairy Cattle in Bandung, Indonesia

good handling. This study is consistent to [18] study up 70% per head [1]. In the practices of dairy that stated that subclinical mastitis incidence will

farming, it is known that the correlation between increase until cow reaches the age of around eight years

lactation periods, teat length with subclinical and will continue to increase from the first lactation

mastitis cannot be separated from the affects of early until its peak that is in the third and forth lactation

selection [19]. Correlation between teat length and period which will then decrease according to the next

lactation period with subclinical mastitis incidence of lactation period.

dairy farms in KPSBU Lembang is presented in Increase of subclinical mastitis incidence may occur

Figure 2.

because the older the cow becomes the udders main Figure 2 shows a linear correlation between teat supporting tissue that is Ligamentum suspensatorium

length and lactation period towards degree of incidence lateral et medial weakens and nutrition that is given to

of subclinical mastitis in KPSBU Lembang. This the cow lacks guarantee which can lead to clinical

means there is a significant correlation between teat mastitis incidence [15]. The increase of lactation period

length and lactation period towards degree of incidence will cause the time needed for teat cistern to close

of subclinical mastitis. Higher lactation period and longer which will facilitate the entrance of longer teats will increase the percentage of subclinical microorganisms from outside into the udder. Age

mastitis incidence. In the first lactation period, cows factor and degree of milk production of cow also

with teat length of 4.75 cm experience subclinical affects the incidence of mastitis. The older the cow and

mastitis incidence as high as 45%. Percentage of the higher its milk production, the more loose the teat

subclinical mastitis incidence as high as 48% occur in sphincter is. Teat with a loose sphincter will enable the

cows with teat length of 6.5 cm and has entered the cow to be infected with microorganism. The more a

third lactation period. Cows that has entered the fifth cow produces milk; therefore the longer time is needed

and sixth lactation period with teat length of 7.6 cm and for the sphincter to close completely [2].

8 cm has a 60% and 70% chance of being affected by subclinical mastitis. From this study it is obtained that

3.3 Correlation between Teat Length and Lactation teat length and lactation period can be used as Period with Degree of Incidence of Subclinical diagnosis indicator of subclinical mastitis and can also Mastitis

be used as a predisposed factor from subclinical Subclinical mastitis causes loss milk production

mastitis incidence.

Fig. 2 Correlation between lactation period and teat length with subclinical mastitis incidence in KPSBU Lembang Bandung Regency (r = 0.972, P < 0.05).

6 Teat Length and Lactation Period as A Predisposition Factor of Subclinical

Mastitis in Dairy Cattle in Bandung, Indonesia

This study is consistent with [20] that stated higher ke-4. Terjemahan: Srigandono B. Yogyakarta (ID): UGM Pr.

lactation period and longer teat length will cause the [7] Saragih, B. 2000. Kumpulan Pemikiran: Agribisnis

degree of incidence of subclinical mastitis to increase. Berbasis Peternakan. Bogor (ID): Pustaka Wirausaha This is due to weakness of ligament in maintaining the

Muda.

anatomical shape and the closing of the teat sphincter [8] Alluwaimi, A. M. 2004. The Cytokines of Bovine which need longer time. Sudarwanto M. [1] stated that Mammary Gland: Prospect for Diagnosis and Therapy. Research in Veterinary Science (in Pr).

time needed for the teat sphincter to close or restore of [9] BIF (Beef Improvement Federation). 2011. BIF teat width after milking is 10-15 sec. The more time the

Guidelines for Unifrom Beef Improvement Program. 8th sphincter needs to close, causes more amounts of

ed. Beef Improvement Federation. Athens (GR): Georgia microorganisms form the environment to enter the Univ. [10] Prihadi, S. 1997. Dasar Ilmu Ternak Perah. Yogyakarta

udder. One of the preventive measures to suppress the (ID): Fakultas Peternakan Universitas Gajah Mada. incidence of subclinical mastitis is teat dipping. Teat

[11] Sudono, A. 1999. Ilmu Produksi Ternak Perah. Diktat dipping is dipping of teats after milking into a liquid

Kuliah Fakultas Peternakan IPB, Bogor. Jurusan that contains disinfectant. Disinfectant used is Ilmu-ilmu Sosial Ekonomi Pertanian. Bogor (ID):

Fakultas Pertanian IPB.

iodophore with a 1% iodine concentration [15]. [12] Sudarwanto M. 1998. Pereaksi IPB-1 sebagai pereaksi

alternatif untuk mendeteksi mastitis subklinis. Bogor

4. Conclusions

(ID): Fakultas Kedokteran Hewan Institut Pertanian Lactation period and length of udder is a Bogor. [13] Agresti, A., and Finlay, B. 2009. Statistical Methods for

predisposing factor towards the level of incidence of the Social Science. New Jersey (US): Pearson E. subclinical mastitis in dairy cattle. Highest incidence

[14] Farmer, W. S., and Chrestman, G. 2006. Dairy Cattle of clinical mastitis occurred to dairy cattle with

Judging. Mississipi (US): Mississipi State University. average teat length of 7.5 cm and was on the third and [15] Falvey, L., and Chantalakhana, C. 1999. Smallholder Dairying in the Tropics. Bibliography: Milking, chapter

forth lactation period. 16. Nairobi. Kenya (KE): Internasional Livestock

Research Institute.

References

[16] Lukman, D. W., Sudarwanto, S., Sanjaya, A. W., [1] Sudarwanto M. 1999. Usaha peningkatan produksi susu

Purnawarman, T., Latif, H., Soejoedono, R. R., and melalui program mastitis subklinis. Orasi Ilmiah. Bogor,

Pisestyani, H. 2009. Higiene Pangan. Bagian Kesehatan 22 Mei 1999.

Masyarakat Veteriner Departemen Ilmu Penyakit Hewan [2] Subronto. 2003. Ilmu Penyakit Ternak 1. Yogyakarta (ID):

dan Kesmavet. Bogor (ID): Fakultas Kedokteran Hewan UGM Pr.

Institut Pertanian Bogor.

[3] DSSP (Data Sementara Statistik Peternakan). 2009. [17] Ikawati, A. 2011. Analisis kandungan protein dan lemak Produksi Susu Sapi Perah. [Internet]. [diacu 2013 April

susu hasil pemerahan pagi dan sore pada peternakan sapi 17]. Tersedia dari: http://faterna.unand.ac.id/index.php?

perah di Wonocolo Surabaya [skripsi]. Surabaya (ID): tabel=1&id_subyek=36.

Fakultas Kedokteran Hewan Universitas Airlangga. [4] Luthan, F. 2011. Pengembangan Agribisnis Persusuan di

[18] Siregar, S. 1995. Jenis Teknik Pemeliharaan dan Analisa Indonesia. Sumatera Barat (ID): Universitas Andalas.

Usaha Sapi Perah. Jakarta (ID): Penebar Swadaya. [5] DSSP (Data Sementara Statistik Peternakan). 2008.

[19] Lush, S. 1990. “Jenetic Progress trough Selection in a Produksi Susu Sapi Perah. [Internet]. [diacu 2013 April

Closed Herd of Indian Cattle.” J. Dairy Sci. 51: 1059-64. 17]. Tersedia dari: http://faterna.unand.ac.id/index.php?

[20] Sudono, A., Rosdiana, R. F., and Setiawan, B. S. 2003. tabel=1&id_subyek=36.

Beternak Sapi Perah Secara Intensif. Jakarta (ID): [6] Blakely, J., and Bade, D. H. 1991. Ilmu Peternakan. Ed

Agromedia Pustaka.

Journal of Life Sciences 10 (2016) 7-15

doi: 10.17265/1934-7391/2016.01.002

DAVID PUBLISHING

The Effects of Calcium Chloride and Ascorbic Acid Treatment on Ready-to-use Carrot Shreds

Mehmet Ufuk Kasim and Rezzan Kasim Kocaeli University, Graduate School of Natural and Applied Sciences, Vocational School of Arslanbey, Kocaeli 41285,

Kartepe-Kocaeli/Turkey

Abstract: This study aimed to evaluate the effect of calcium and ascorbic acid treatments on the quality of carrot shreds during storage. Towards this aim, carrot shreds were dipped into a 5 L solution of 2 g/L ascorbic acid containing 1%, 3%, or 5% CaCl 2 (Ca + AA) for 3 min at room temperature (~20 °C). In case of the control group (control, C), samples were dipped into distilled water for the same time interval. Subsequent to treatment, carrot shreds were stored in a cold room at 5 ± 1 °C, 85-90% RH for a period of 11 days. Color values (L*, a* b*), whiteness index, saturation index, hue angle values, visual quality, firmness scores, bitterness scores, total soluble solids (TSS) and electrolyte leakage measurements were conducted at various sampling dates. The results from this study demonstrated that brightness of carrot shreds was augmented by calcium and ascorbic acid treatments irrespective of the dosage used. Whiteness index values for the 5% Ca + AA treated samples were observed to be low whereas saturation indices of 5% Ca + AA and 3% Ca + AA treated carrot shreds were higher as compared to other treatments. This study concludes that treatment with calcium at high doses improves the color quality of carrot shreds under storage conditions. Visual quality and firmness of carrot shreds was maintained till day 4 of storage, thereafter it declined as compared to the control group. Bitterness of carrot shreds was also observed to increase upon treatment with calcium and ascorbic acid. However, calcium treatment of the test carrot shreds was seen to decrease weight loss and cause an increase in the TSS under storage conditions.

Key words: Calcium, ascorbic acid, color, bitterness, quality.

1. Introduction  fresh-cut vegetables is minimal processing such that the produce retains fresh-like texture, color, flavor,

Fresh-cut vegetables are vegetables that are and safe-to-use quality. However, injuries that occur available in a ready-to-use format. They are during processes such as peeling, slicing, cutting, minimally-processed plant products that are peeled, shredding, etc. result in stress at the tissue cellular, trimmed and/or cut prior to being packaged in a subcellular and biochemical levels leading to several way that retains freshness whilst being convenient undesirable changes in the vegetables during the to the end user. Lettuce and pre-prepared salads are course of storage and transportation [2]. the most common types of fresh-cut vegetables In the case of fresh-cut carrots, the most significant available commercially, although fresh-cut carrots, problem faced is surface whitening. It is a tomatoes, broccoli, cauliflower, and cabbage can also phenomenon that arises as a result of dehydration and

be found [1]. lignin synthesis. Several treatments, such as In recent years, Turkey has witnessed an increase in application of edible coatings [3], treatment with citric the demand and availability of fresh-cut vegetables as acid [4, 5] or ascorbic acid [6] are available to prevent well as fruits; the examples include pre-washed and

the whitening.

trimmed spinach, sliced carrots, leeks, apples, etc. Results from previous studies have indicated that The basic premise for obtaining high quality treatment of carrot shreds with ascorbic acid is

successful in preventing the appearance of surface Corresponding author: Rezzan Kasim, Dr., associate

whitening. However, as this treatment results in professor, research field: postharvest technology of vegetables.

8 The Effects of Calcium Chloride and Ascorbic Acid Treatment on Ready-to-use Carrot Shreds

softening of the shreds, the application of a firming containing 2 g/L ascorbic acid for 3 min. agent has been suggested for maintaining the crispness

(4) C: The control group samples were dipped in [6]. Calcium treatments that use either calcium

distilled water for 3 min.

chloride (CaCl 2 ) or calcium lactate have been shown All treatments were carried out at room temperature to be effective in maintaining the firmness of several

(~20 °C). Treated carrot shreds were dried by first fresh-cut fruits and vegetables during storage [7]. It is

using a salad spinner (2 min, room temperature) so as also known that treatment with Ca 2+ has the potential

to remove excessive surface solution and then at room to maintain the textural qualities of carrot for as long

temperature (15 min).

as up to 10 days of storage [2]. As softening and other

2.2 Packaging and Storage Condition undesirable textural changes in fresh-cut products are

related to their tissue calcium levels, application of The samples of shredded carrots (100 g) were calcium salts (calcium-chloride, -carbonate, -lactate,

placed in covered plastic boxes 110 × 110 × 50 mm in -propionate, -pectate, etc.) to fruits and vegetables,

size. Triplicates of each treatment were stored for 11 such as pears, strawberries, kiwis, shredded carrot,

days at 5 ± 1 °C with relative humidity of 85-90%. honeydew melon discs, nectarines, peaches and

2.3 Color Measurements

melons, helps in retaining tissue firmness [8]. Calcium, in a 1% CaCl 2 formulation, and ascorbic acid dips

Color measurements (L*, a* and b* values) were have been employed as firming agents that aid in

performed using a chroma meter CR-400 (Konica extending the postharvest shelf life of sliced pears and

Minolta Inc. Osaka, Japan) with an illuminant D65 strawberries that have been stored in a controlled

with 8 mm aperture. The instrument was calibrated atmosphere [9].

with a white reference tile (L* = 97.52, a* = -5.06, b* The objective of this study was to determine the

= 3.57) prior to measurements. The L* (0 = black, 100 effect of calcium chloride and ascorbic acid treatments

= white), a* (+red, green) and b* (+yellow, –blue) on the quality parameters of shredded carrots.

color coordinates were determined as per the CIELAB

2. Materials and Methods

coordinate color space system.

Whiteness index [WI, Eq. (1)], saturation index [SI,

2.1 Plant Material and Sample Preparation Eq. (2)] and hue angle [H, Eq. (3)] were calculated Carrots were obtained from the Kocaeli Wholesale

using L*, a* and b* values that were computed as Distribution Center. They were transported described below; these values were used to compare immediately to the laboratory, thoroughly washed,

the color changes of the test samples with that of the peeled, trimmed of tap root and stem plate prior to

control (fresh-cut carrot shreds) [10]. preparation. A grate was used to prepare carrot shreds

WI 100 100 L a b (1) (about 5 mm wide, 40 long, and 2 mm thick).

(2) Processed carrots (100 g for each replicate) were

(3) dipped into the following calcium and ascorbic acid

arctan

2.4 Visual Quality, Firmness and Bitterness solutions:

Assessments (1) 1% Ca + AA: 5 L solution of 1% CaCl 2

containing 2 g/L ascorbic acid for 3 min. Visual quality was evaluated by grading the freshness, (2) 3% Ca + AA: 5 L solution of 3% CaCl 2 appearance, color, uniformity and brightness of the containing 2 g/L ascorbic acid for 3 min.

test samples on a five-point Likert scale: 5, excellent; (3) 5% Ca + AA: 5 L solution of 5% CaCl 2 4, good quality; 3, fair quality; 2, poor quality; 1,

The Effects of Calcium Chloride and Ascorbic Acid Treatment on Ready-to-use Carrot Shreds

extremely poor quality.

2.8 Statistical Analysis

Firmness of the carrot shreds was scored as a Experiments were conducted in a completely subjective variable; the perceived hardness or softness randomized design with a minimum of three experienced when carrot shreds were taken between replications per treatment per sampling date. The two fingers and pressure was applied and was graded resultant data were analyzed by application of the on a five-point Likert scale: 5, very firm; 4, firm; 3, ANOVA test and differences between mean values partially firm/soft; 2, soft; 1, very soft (not usable). were determined using Duncan’s multiple range test. Bitterness of the carrot shreds was also scored on a The results were regarded as significant when P < five-point Likert scale: 5, no bitterness; 4, slightly

0.05 and P < 0.001.

bitter; 3 bitter; 2, very bitter; 1, extremely bitter (not consumable).

3. Results and Discussions

The judging panel for sensory evaluation was

3.1 L* values and Whiteness Index composed of nine food-science students enrolled at

the university. All the students had prior classroom L* values of treated carrot shreds were observed to training and experience in the sensory evaluation of

have increased irrespective of the type of treatment food items.

applied. The highest value was observed on day 4 for shreds treated with 5% Ca + AA (59.757), which was

2.5 Electrolyte Leakage Measurement followed by those treated with 3% Ca + AA (57.790),

Electrolyte leakage (EL) was measured in the test 1% Ca + AA (57.003) and C (control, 56.287). The carrot shreds. Distilled water was used for washing as

difference between the treatments was statistically well as immersion of test sample shreds and

significant (P < 0.05). Post day 4, L* values of conductivity was measured 2 h after immersion. Total

samples were observed to be changing whilst in electrolyte conductivity of the carrot shreds was

storage: Initially a decrease was observed (day 8) measured after they had been frozen and thawed. EL

subsequent to which L* values started increasing was calculated as percentage of the conductivity after

again (Fig. 1).

2 h [11]. The whiteness index of carrot shreds stored after treatment with 3% Ca + AA and 5% Ca + AA was

2.6 Loss of Weight significantly lower than that of shreds treated with 1%

The weight of the triplicate samples was recorded Ca + AA as well as the control samples (P < 0.05). on the day of harvest and after the designated

Previous studies have determined that treatment with sampling dates. The loss in weight was calculated

ascorbic acid has a positive effect on the brightness of using the following formula:

carrot shreds [6] as well as carrot cubes [10]. weight loss (%) = (W i –W s /W i ) × 100; where W i =

Congruent with these findings, the present study initial weight; W s = weight at sampling period.

observed that during the first four days of storage, treatments that combined ascorbic acid with CaCl 2 (at

2.7 Total Soluble Solids (TSS) all doses) were observed to increase the brightness of

For each of the test replicates, TSS was determined carrot shreds as compared to the control group. for two parallel using an Atago DR-A1 digital

Although, L* values of samples were observed to be refractometer (Atago Co. Ltd., Japan). The experiment

decreasing by day 8, brightness of carrot shreds were was conducted at 20 °C and the results were expressed

maintained when treated with 3% Ca + AA as well as as percent value.

5% Ca + AA. Therefore, it can be concluded that

10 The Effects of Calcium Chloride and Ascorbic Acid Treatment on Ready-to-use Carrot Shreds

Storage Duration (Days)

Fig. 1 L* and whiteness index (WI) values of carrot shreds. 1%: 1% CaCl 2 and 2 ppm ascorbic acid (AA); 3%: 3% CaCl 2

and 2 ppm AA; 5%: 5% CaCl 2 and 2 ppm AA; C: Control.

treating carrot shreds with a combination of calcium day 1 and day 11 of storage. During storage, it was chloride and ascorbic acid was effective in seen that treatment with a combination of ascorbic maintaining their brightness.

acid and calcium, irrespective of dose, resulted in a Previously Rico et al., (2007) have reported that in

reduction in h* values. This conclusion was arrived at instances of a colorimeter being used to analyze color,

because significantly higher values were found in increases in luminosity can be correlated with the

control samples compared to those that were treated development of whiteness in the test samples. In this

with Ca + AA (P < 0.05). Saturation index (SI) values study, however, the whiteness index (WI, Fig. 1)

of samples subjected to 3% Ca + AA and 5% Ca + values of high calcium treated samples (3% and 5%

AA were higher than those treated with 1% Ca + AA Ca + AA) were lower than those of control and 1% Ca

and control (Fig. 2; P < 0.05). On day 4, the highest + AA treatments. Therefore, on account of the

value of SI (53.756) was found in fruits treated with decrease in WI values of the samples, it can be

3% Ca + AA. By contrast, the lowest value was concluded that treatment with a high dose of calcium

observed in carrot shreds treated with 1% Ca + AA prevented the whitening of samples. Similar results

(44.303). However, from 4th day of storage till the were reported for ascorbic acid treatments of carrots

conclusion of the study, carrot shreds in the control [6, 10]. Interestingly, in case of carrot shreds calcium

group had the lowest measures of SI values. treatments alone did not impact white tissue formation

The main physiological effect of fresh-cut

and WI values were observed to increase [2]. processing in the case of carrots is surface whitening However, ascorbic acid alone was effective in

which results from a combination of dehydration and inhibiting white color formation on surface of carrots

lignin formation. This leads to significant loss of [6]. Therefore, as a result of this study, it can be

quality. In this study, the orange color of carrot shreds concluded that the combined use of calcium and

was observed to be maintained by treatment with ascorbic acid enhances the color quality and also

calcium and ascorbic acid. This was especially true prevents whitening of carrot shreds. Similar results

when samples of the control group were compared were found [12] in case of nectarine halves.

with those that received high dose treatments. In the case of minimally processed cabbage, results clearly

3.2 Hue Angle and Saturation Index Values demonstrated that while treatment with ascorbic acid

Fig. 2 shows the hue angle (h*) values measured at did not lead to significant differences between test and

The Effects of Calcium Chloride and Ascorbic Acid Treatment on Ready-to-use Carrot Shreds

tion inde 48 a

hue angle 59

0 4 8 11 0 4 8 11 Storage Duration (Days)

Fig. 2 Hue angle (h*) and saturation index (SI) values of carrot shreds. 1%: 1% CaCl 2 and 2 ppm ascorbic acid (AA); 3%:

3% CaCl 2 and 2 ppm AA; 5%: 5% CaCl 2 and 2 ppm AA; C: Control.

control samples with respect to color or general + AA and 5% Ca + AA (Fig. 3). Also, statistically

significant differences amongst the treatments were resulted in consistent maintenance of high quality with

appearance, treatment with 2% CaCl 2 at 20 °C

observed at day 4 and 11 of storage (P < 0.05 and P < less intense browning and the best general appearance

0.001). Fresh-cut vegetables that maintain a firm, [13]. These results were also confirmed in the present

crunchy texture are highly desirable because study.

consumers associate such textures with freshness and wholesomeness of produce [14]. The development of

3.3 Visual Quality, Firmness and Bitterness Scores of such undesirable textural changes in minimally Carrot Shreds processed products can be reduced by the application

Visual quality scores of test samples, regardless of of calcium salts (calcium-chloride, -carbonate, -lactate, type of treatment, were observed to be decreased by

-propionate, -pectate, etc) because the rate of softening day 4. Subsequently, scores increased until the 8th day

was directly related to the reduction of calcium levels of storage after which they continued decreasing till

in fruit tissues [11]. Studies have shown that application the end of the storage (Fig. 3). However, the

of Ca salts to pears, strawberries, kiwifruits, shredded appearance of samples treated with calcium and

carrots, honeydew discs, nectarines, peaches and melons ascorbic acid was superior as compared to control

helps in retaining tissue firmness [15]. Firmness scores during the first eight days of storage with the

of treated carrot shreds across all Ca + AA doses were difference between treatments assuming statistical

lower than that obtained for control samples during significance at day 4 (P < 0.05). Therefore it can be

storage, and differences amongst the different

said that as compared to the control samples, the treatments were observed to be statistically significant visual quality scores of test carrot shreds were highest

at day 4 (P < 0.05) and day 11 (P < 0.001). Also, during the first 4 days of the storage, but subsequent

results clearly showed that the firmness scores of to that the effectiveness of the treatments decreased

samples treated with 1% CaCl 2 were higher than that such that by the end of the storage period the visual

of other calcium treatments leading to the conclusion quality scores of the Ca + AA treated samples were

that CaCl 2 treatments were not effective in improving much below that of the control group.

the texture of carrot shreds during storage. But, as per According to the firmness scores, the texture of the

the weight loss results obtained in this study (Fig. 4), shredded carrots was retained best in the control group

the recorded weight loss of the 3% Ca + AA and 5% followed by samples treated with 1% Ca + AA, 3% Ca

Ca + AA treatments were lower than those obtained

12 The Effects of Calcium Chloride and Ascorbic Acid Treatment on Ready-to-use Carrot Shreds

Storage Duration (Days)

C ittern 2 K

Storage Duration (Days) Storage Duration (Days)

Fig. 3 Visual quality, firmness and bitterness scores of carrot shreds. 1%: 1% CaCl 2 and 2 ppm ascorbic acid (AA); 3%: 3%

CaCl 2 and 2 ppm AA; 5%: 5% CaCl 2 and 2 ppm AA; C: Control.

for 1% Ca + AA and control. Hence, the high firmness present study corroborate the above mentioned results. values of samples in control and 1% Ca + AA

3.4 Weight Loss

treatments can be potentially explained as a byproduct of water loss.

Weight loss of all the treated samples was observed

Bitterness of carrot shreds increased upon to increase during storage (Fig. 4). The highest weight increasing CaCl

2 dose (Fig.3) with the highest (least

bitter) values being obtained by 1% Ca + AA

C 0.5 1%

treatment (4.33) followed by 3% Ca + AA (2.0) and 5%

Ca + AA as recorded on day 4, and these results

continued during the storage. Differences amongst the

treatments were statistically significant at the level of

P < 0.001 (4 and 8 days of storage) and P < 0.05 (11th

Weight losses

day of storage). Studies [16] determined that 0.1

exogenous administration of CaCl 2 in form of a

0 4 8 solution can reduce browning as well flesh softening 11

Storage Duration (Days)

in case of zucchini squash slices. However, CaCl 2 ,

Fig. 4 Weight losses of carrot shreds. 1%: 1% CaCl 2 and

when used in high concentrations (> 0.5%), has been

2 ppm ascorbic acid (AA); 3%: 3% CaCl 2 and 2 ppm AA;

known to cause a detectable off-flavor. The results of

5%: 5% CaCl 2 and 2 ppm AA; C: Control.

The Effects of Calcium Chloride and Ascorbic Acid Treatment on Ready-to-use Carrot Shreds

loss was observed in the control group (0.18 and 0.29)

and followed by the 1% Ca + AA (0.10 and 0.26), 5%

Ca + AA (0.09 and 0.18) and 3% Ca + AA (0.008 and

0.14) groups as noted on day 4 and 8. Also,

statistically significant differences were observed

between the various treatment groups while in storage.

TSS

Therefore it can be concluded that CaCl 2 —ascorbic

acid treatments have a significant effect on weight loss

especially at higher doses.

Peel or skin is a very important barrier against 0 4 8 11 desiccation and loss of turgor. Several fruits and

Storage Duration (Days)

vegetables have a protective waxy coating that makes

Fig. 5 Total soluble solids (TSS) of carrot shreds. 1%: 1%

them highly resistant to water loss. Mechanical injury

CaCl 2 and 2 ppm ascorbic acid (AA); 3%: 3% CaCl 2 and 2

ppm AA; 5%: 5% CaCl 2 to the skin brought about by peeling, cutting, slicing, and 2 ppm AA; C: Control.

shredding, etc. makes fresh cut products highly ranged from 3% to 7%. Subsequent to day 4, TSS of susceptible to weight loss as the protective peel is no

the control group was observed to steadily decrease longer intact [11, 15]. In the present study, water lost

till the end of the storage period whereas in case of the by carrot shreds was reduced when treated with a

Ca treated carrots it was observed to increase. It was combination of calcium and ascorbic acid. Izumi and

also seen that TSS of samples treated with a Watada [2] have previously reported that Ca has no

combination of Ca and AA was higher than that of observable effect on weight loss in case of carrot

control and that the higher values were observed in slices and sticks but is effective in preventing the

correlation with high doses of CaCl 2 treatment during same in case of carrot shreds. Their results also proved

storage. Differences in TSS values amongst the that carrot shreds have almost two and three times

various treatments were statistically significant (P < more Ca content as compared to sticks and slices

respectively. Additionally, Ca has widely been The edible portion of carrot contains about 10% reported to play an important role in preserving the

carbohydrate with the soluble carbohydrate structural integrity and mechanical strength of cell

composition ranging from 6.6 to 7.7 g per 100 g [14]. walls [9]. The basis for the reduced weight loss

In the present study, the initial TSS content of carrot observed in case of carrots shreds treated with Ca +

shreds was observed to be 8%. This value was seen to AA in the present study, can be accounted for by the

decrease across treatments under storage conditions. Ca absorbed by the samples under test.

Interestingly, the maximum decrease in TSS values was observed in case of the control group where

3.5 Total Soluble Solids values fell from 1% on day 4 to below 1% on days 8

Fig. 5 shows total soluble solid (TSS) values for and 11. In contrast, TSS of calcium treated carrot shreds carrot shreds subjected to different treatments. TSS of

maintained constant high values especially in the case carrot shreds was observed to be decreased on day 4

of shreds treated with 5% calcium where values but this decrease was higher in the control group as

ranged from 7.1% to 7.7%. TSS of samples in 1% Ca compared to the calcium and ascorbic acid treated

+ AA and 3% Ca + AA treatment groups was also samples. In quantitative terms, TSS of the control

found to be high as compared to the control. Therefore group was 1.2%; for the Ca treated carrot shreds it

it can be concluded that calcium and ascorbic acid

The Effects of Calcium Chloride and Ascorbic Acid Treatment on Ready-to-use Carrot Shreds

14

Fig. 6 Electrolyte leakage of carrot shreds. 1%: 1% CaCl 2

and 2 ppm ascorbic acid (AA); 3%: 3% CaCl 2 and 2 ppm

AA; 5%: 5% CaCl 2 and 2 ppm AA; C: Control.

treatments prevent loss of TSS in case of carrot shreds especially when used in high doses.

3.6 Electrolyte Leakage On day 4, it was observed that electrolyte leakage

(EL) from carrot shreds in the control group and 1% Ca + AA treated group decreased, whereas in the 3% Ca + AA and 5% Ca + AA treated samples it was increased (Fig. 6). The EL values of the control samples continued to decline but an increase was noted in the 1% Ca + AA and 3% Ca + AA treated groups. Moreover, it showed variations between decrease and increase in 3% Ca + AA treatments during the storage. Differences in EL values among the treatments were statistically significant (P < 0.001). Leakage of electrolytes or cellular content is commonly used as an index for evaluating changes in membrane integrity arising due to ripening, stress damage or mechanical injury [7]. Electrolyte leakage is considered as an indirect measure of plant cell membrane damage [17]. In the present study, EL values for calcium and ascorbic acid treated samples were observed to be higher than that of the control

group. Therefore, it can be concluded that CaCl 2

treatments have no membrane stabilizing effect conferred by exogenous calcium ions.

4. Conclusions

This study aimed to determine the impact of

calcium and ascorbic acid on the quality of carrot shreds during storage. For this purpose, carrots were grated and treated with solutions containing varying doses of calcium along with 2 g/L ascorbic acid. The carrots were then stored for 11 days in a cold room at

5 ± 1 °C and 85-90% RH. According to the results obtained from this study, calcium was found to improve color quality and brightness while decreasing the development of whiteness on carrot shreds. As a cautionary note, however, it was observed that calcium, especially at higher doses, could cause bitterness of carrot shreds. Weight losses of carrot shreds treated with calcium and ascorbic acid was found to be higher than that of the control group; also firmness values of these test samples were low compared with the control. While calcium treatment was observed to improve the visual quality of the produce during the first eight days of storage, it was found to lose its efficacy after that. In addition, the calcium treatments showed no membrane stabilizing effect.

References

[1] Krasaekoopt, W., and Bhandari, B. 2011. “Fresh Cut

Vegetables.” In: Handbook of Vegetables & Vegetable Processing (Ed: Nirmal K. Sinha), Blackwell Publishing Ltd. pp: 226.

[2] Izumi, H., and Watada, A. E. 1994. “Calcium Treatments

Affect Storage Quality of Shredded Carrots.” Journal of Food Science 59 (1): 106-9.

[3] Sargent, S. A., Brecht, J. K., Zoelner, J. J., Baldwin, E. A.,

and Campbell, C. A. 1994. “Edible Films Reduce Surface Drying of Peeled Carrots.” Proc. Fla. State Hort. Soc. 107: 245-7.

[4] Bolin, H. R., and Huxsoll, C. C. 1991. “Control of