Introduction Directory UMM :Data Elmu:jurnal:P:Precambrian Research:Vol104.Issue3-4.2000:

sedimentary rocks of the central Fennoscandian Shield indicating high amounts of Ba lost from the clastic record during 2.3 – 1.9 Ga and further recycled back to the mantle forming a subduction component and an enriched mantle component. Ba depletion seems to have been especially characteristic of chemical weathering during 2.35 – 2.2 Ga under CO 2 -rich and low-O 2 atmosphere. Whether this strong Ba depletion is characteristic of the Archaean – Protero- zoic transition and quiet supercontinent stages in general remains to be determined. © 2000 Elsevier Science B.V. All rights reserved. Keywords : Archaean; Palaeoproterozoic; Sedimentary rocks; Geochemistry; Provenance; Finland

1. Introduction

The geochemistry of clastic sedimentary rocks can be used as an indicator of crustal evolution e.g. Taylor and McLennan, 1985 or to identify ancient tectonic settings in metamorphic terranes. Sedimentary rocks can be divided into those showing local sources and those having experi- enced effective mixing in large river marine sys- tems before deposition. The latter types sample large areas providing data for crustal-scale pro- cesses. The possibility of different crust-forming mechanisms during Archaean and Proterozoic times emphasizes the importance of the Ar- chaean – Proterozoic boundary where there might be a corresponding compositional change in the sedimentary record e.g. Taylor and McLennan, 1985; McLennan and Taylor, 1991. Selective preservation of sedimentary rocks in the ancient record can on the other hand hamper their use in crustal evolution studies. Along with this limita- tion, other factors discussed below, should also be taken into account when using ancient sedi- ments to give information on the general prove- nance of the studied sedimentary unit. The lithology of the provenance area essen- tially controls the chemical composition of the clastic sediments but other factors such as degree of palaeoweathering, hydraulic sorting grain-size effects, organic and sulphide input, diagenesis and metamorphism especially migmatization may greatly modify or ultimately erase prove- nance memory. Sediment recycling is a common feature e.g. Veizer and Jansen, 1985 and pro- duces a buffering effect where a small amount of new input can go unnoticed. Nevertheless, even though the interpretation of their compositions is more controversial than with igneous rocks, the long ‘memory’ of sedimentary rocks can be quite powerful when modelling the tectonic settings and evolutionary histories of metamorphic ter- ranes. The central part of the Fennoscandian Shield in Finland is composed of the Palaeoproterozoic Svecofennian domain and the Archaean Karelian craton with a Palaeoproterozoic allochthonous and autochthonous cover Fig. 1. The occur- rence of a cryptic ‘suture’ Fig. 1; Koistinen, 1981; Huhma, 1986 between the Karelian and Svecofennian domains is favoured by the obser- vation that no Archaean component is found in the 1.93 – 1.91 Ga gneissic tonalites and related felsic volcanics adjacent to the Archaean craton Lahtinen and Huhma, 1997. Lahtinen 1994 proposed also the occurrence of a tentative ‘su- ture’ Fig. 1 separating the central part of the Svecofennian domain from the southern Sve- cofennian. Studies on the geochemistry of sedi- mentary rocks in the study area are few and include a geochemical and isotopic study from the Archaean Hattu schist belt O’Brien et al., 1993, a major element study from the northern part of the Ho¨ytia¨inen area Kohonen, 1995, a regional correlation diagram study from the Savo province Kontinen and Sorjonen-Ward, 1991 and a research concentrating on black schists Loukola-Ruskeeniemi and Heino, 1996 and ref- erences therein. The study area has been sampled in the course of a regional bedrock geochemical survey under- taken by the Geological Survey of Finland in- cluding the 300 metasedimentary samples discussed here. The samples range from Archaean to Palaeoproterozoic, were formed in a variety of tectonic settings, and are thus suitable for study- ing the Archaean – Proterozoic transition and the evolution of Fennoscandian Shield. The main source components and implications for the tec- tonic evolution of the central Fennoscandian shield are given with emphasis on proposed su- tures. Notes on the crustal evolution and Ar- chaean – Proterozoic transition in general, and on Ba depletion are also given. As all the studied sedimentary rocks are metamorphosed, the prefix ’meta’ has been dropped. The data set is available on request from the author.

2. Sampling and analytical methods