Results Directory UMM :Data Elmu:jurnal:P:Precambrian Research:Vol104.Issue3-4.2000:

Pekkarinen, 1979; Pekkarinen and Lukkarinen, 1991; Kohonen and Marmo, 1992; Karhu, 1993. Otherwise lithostratigraphy and chronostratigra- phy of the Ho¨ytia¨inen area are not resolved Ko- honen, 1995 but depositional ages from 2.1 to about 1.9 Ga are inferred. The Suvasvesi area is characterized by the ‘Up- per Kaleva’ Kontinen and Sorjonen-Ward, 1991 or Western Kaleva Kohonen, 1995 a term adopted in this study greywackes that occur as allochthonous units in thrust complexes charac- terized by associated ophiolites and related rocks Koistinen, 1981 and references therein though evidence for local deposition upon Archaean basement has also been noted Ward, 1987. The increase in metamorphic grade from east to west Fig. 2 is seen as an increase in quartz veins and the onset of segregational banding quartz + feldspar leading finally to migmatites. The boundary zone BZ includes migmatitic sedimentary rocks Korsman et al., 1984 and a 1.93 – 1.91 Ga volcano-plutonic formation Lahti- nen, 1994 and references therein. The Svecofen- nian is divided into the central Svecofennian including the Central Finland Granitoid Complex CFGC and Bothnian Belt BB, and the south- ern Svecofennian including the Rantasalmi – Haukivuori area RH. The tentative sedimentation ages for the central Svecofennian, based on data available from the Tampere Schist Belt Lahtinen, 1996 and references therein, are ] 1.91 and 1.89 – 1.87 Ga for rocks correlated to basement- and arc-related groups in the Tampere Schist Belt, respectively. The southern Svecofen- nian, including the Rantasalmi – Haukivuori area, is characterized by granite migmatites, which is a clear difference to the central Svecofennian, boundary zone and Suvasvesi area, which are characterized by tonalite migmatites Korsman et al., 1999 and references therein.

4. Results

Because lithostratigraphic division of sedimen- tary rocks is rarely available, division of sedimen- tary rocks into different groups within domains is based mainly on lithotype and geochemical char- acteristics. All elements analyzed have been used but the main weight has been put on the REE, Th, Sc, Cr and major elements where the REE, Th and Sc are considered as most reliable ele- ments in monitoring the average source composi- tion Taylor and McLennan, 1985; McLennan et al., 1990. The arc-related upper central Sve- cofennian rocks of this study Fig. 2, not dis- cussed in detail, show CaO, MnO, P 2 O 5 , Sr, Ba and Sb enrichment, which is characteristic of sed- imentary rocks derived from high-K calc-alkaline to shoshonitic volcanics Lahtinen, 1996. Strongly altered or mineralized samples are ex- cluded from discussion as are minor groups of sedimentary rocks either having undefined origins or a large non-clastic component e.g. iron forma- tions and carbonate rocks. The group characteristics were also studied by using normalized diagrams Fig. 3. Archaean sedimentary groups are normalized to Archaean crust AC1, autochthonous and allochthonous groups to average Karelian craton KC1 and boundary zone and Svecofennian groups to West- ern Kaleva WK1 Table 1. The AC1 is a first approximation of the average composition of Ar- chaean crust in Finland at its present erosion level based solely on the data from the study area. The granitoid-dominated nature of the exposed Ar- chaean part of the study area is seen in higher LILE and LREE and lower MgO, Cr and Ni compared to the Late Archaean 3.5 – 2.5 Ga restoration model for average juvenile upper con- tinental crust Table 4 in Condie, 1993. The Karelian craton includes a large contribution from Palaeoproterozoic mafic dykes and volcanics 2.2 – 1.97 Ga; Vuollo, 1994 relative to the Ar- chaean crust average Fig. 3. 4 . 1 . Archaean sedimentary rocks The Archaean metagreywackes and mica schistsgneisses have been divided into two main groups Ar1 – Ar2. The Ar1 rocks have a homo- geneous composition indicating a thorough mix- ing of source components. The elevated CIA Chemical Index of Alteration; Nesbitt and Young, 1982 shows the effects of weathering in the source area and the REE, major and trace R . Lahtinen Precambrian Research 104 2000 147 – 174 Table 1 Average chemical composition of estimated Archaean crust AC1 and Karelian craton KC1, and selected sedimentary rock groups non-migmatized, except groups BZ1–BZ2 a BZ1 Ar1 WK2 H1 WK1frag H2 WK1 H3 BZ2 KC1 AC1 N = 4 N = 8 N = 156 N = 129 N = 5 N = 9 N = 47 N = 5 N = 17 N = 11 N = 6 67.23 69.85 69.58 63.23 65.15 68.60 56.42 SiO 2 60.16 65.15 63.64 65.18 0.51 0.80 0.62 0.68 0.69 0.83 0.72 1.08 0.65 0.76 TiO 2 0.72 12.87 14.86 14.74 13.11 13.27 15.42 15.16 17.68 14.68 Al 2 O 3 15.15 15.19 5.20 4.95 4.93 6.64 6.05 7.90 9.24 6.60 6.27 FeO 4.71 5.73 0.06 0.08 0.07 0.07 0.07 0.08 0.08 0.11 0.10 0.08 0.08 MnO 5.19 2.34 2.52 2.26 2.33 3.23 2.84 4.29 2.81 3.55 2.91 MgO 1.46 2.22 2.42 2.36 2.34 1.68 2.59 CaO 0.87 1.46 4.06 3.39 4.24 1.24 1.98 2.98 2.76 2.84 2.92 2.93 3.89 2.37 Na 2 O 2.18 3.44 2.37 2.41 3.36 3.34 3.87 3.44 2.76 K 2 O 2.71 2.35 2.46 0.15 0.18 0.11 0.16 0.15 0.16 0.14 0.11 0.18 0.12 0.13 P 2 O 5 0.34 0.05 0.13 0.22 0.29 0.07 0.05 0.05 0.05 0.10 0.09 C graf. 0.21 0.067 0.082 0.061 0.21 1.24 0.23 S 0.12 0.41 0.061 0.054 0.070 0.054 0.053 0.085 0.078 0.094 F 0.055 0.051 0.045 0.062 0.094 62.64 54.4 54.7 55.8 55.6 57.8 62.9 62.5 49.3 61.9 CIA 50.0 36.2 31.1 32.0 31.6 30.6 33.2 36.7 44.3 31.8 15.2 La ppm 23.4 71.2 62.2 63.2 62.9 60.9 65.4 73.2 86.5 63.4 32.7 Ce ppm 47.9 7.27 7.43 7.29 8.02 8.60 7.44 10.1 Pr ppm 5.67 4.12 7.42 8.23 21.5 27.9 26.7 27.3 26.6 28.9 31.4 37.1 27.3 Nd ppm 15.3 29.7 5.17 5.13 4.98 5.55 5.72 5.49 6.44 3.10 4.28 Sm ppm 4.90 4.76 1.14 1.02 0.96 1.06 1.03 1.15 1.13 1.44 1.07 0.94 0.91 Eu ppm 4.91 3.86 4.27 4.63 4.47 5.04 5.26 6.13 4.00 2.96 3.88 Gd ppm 0.66 0.68 0.66 0.75 0.73 0.73 0.90 Tb ppm 0.61 0.48 0.55 0.50 3.36 3.68 3.42 4.12 3.75 Dy ppm 5.01 2.40 2.76 2.95 3.36 4.21 0.66 0.73 0.68 0.79 0.71 0.79 1.00 0.58 0.67 Ho ppm 0.45 0.53 2.31 1.26 1.88 2.12 2.04 2.31 2.03 3.06 1.50 1.76 1.94 Er ppm 0.33 0.18 0.27 0.31 0.30 0.32 0.29 0.47 0.21 0.26 0.28 Tm ppm 1.79 2.16 1.95 2.19 1.94 2.23 3.13 Yb ppm 1.84 1.73 1.38 1.17 0.27 0.32 0.30 0.32 0.27 0.46 Lu ppm 0.18 0.21 0.25 0.28 0.35 570 489 508 613 704 348 712 Ba ppm 392 371 742 858 116 58.1 48.8 79.4 100 139 139 172 157 127 Cl ppm 52.2 14.1 30.0 16.8 14.1 14.4 21.3 18.9 30.2 18.8 32.0 Co ppm 21.7 110 106 104 137 120 238 172 Cr ppm 180 294 80.6 77.7 3.50 5.02 5.01 4.46 4.92 Hf ppm 5.10 3.78 3.63 3.53 4.63 3.91 10.2 9.20 9.13 11.2 12.2 9.75 14.6 5.74 b 8.70 Nb ppm 5.54 5.70 149 35.6 52.4 44.9 45.4 65.3 53.6 90.9 41.3 145 111 Ni ppm 138 84.0 138 82.5 89.1 117 122 135 74.0 84.5 104 Rb ppm 15.4 15.3 14.9 20.5 17.9 22.0 29.2 Sc ppm 16.3 21.9 15.0 11.4 R . Lahtinen Precambrian Research 104 2000 147 – 174 153 Table 1 Continued BZ1 H1 KC1 H2 BZ2 H3 AC1 WK1 WK1frag WK2 Ar1 N = 11 N = 5 N = 9 N = 47 N = 4 N = 17 N = 6 N = 156 N = 5 N = 8 N = 129 147 247 250 223 275 326 Sr ppm 495 437 180 111 108 0.80 0.68 0.66 0.76 0.82 0.68 0.74 Ta ppm 0.64 0.42 b 0.41 0.40 8.72 8.51 10.8 8.93 8.54 9.27 10.9 12.5 7.59 4.60 Th ppm 7.59 2.56 1.82 1.98 2.00 1.88 2.76 1.64 1.22 1.91 U ppm 1.49 1.32 196 94.9 120 128 128 164 143 222 127 160 142 V ppm 26.6 15.3 23.2 23.7 22.4 26.5 23.1 30.2 17.2 20.9 24.4 Y ppm 105 83.7 83.5 115 109 154 153 Zn ppm b 108 128 88.1 81.6 144 Zr ppm 217 162 208 203 193 202 155 161 190 150 0.082 0.067 0.044 0.061 0.055 0.053 0.059 Ag ppm b 0.16 0.068 0.052 0.047 b 0.86 12.9 4.52 0.42 0.52 0.63 1.10 1.01 0.80 1.28 As ppm b 6.53 0.52 0.34 0.31 0.40 0.79 Au ppb b 1.00 0.78 1.05 0.47 0.73 0.42 0.31 0.10 0.034 0.12 0.15 0.21 0.080 0.079 Bi ppm 0.20 0.22 0.072 84.0 23.8 41.9 25.6 25.1 31.7 37.3 88.8 42.7 61.3 42.7 Cu ppm b 1.71 3.88 0.79 0.26 0.31 0.39 0.27 1.0 Pd ppb 0.2 0.2 1.80 0.031 0.028 0.021 0.021 0.046 0.095 0.041 0.029 0.035 Sb ppm 0.037 0.036 0.56 0.053 0.22 0.13 0.13 0.15 0.20 0.45 0.075 0.31 0.15 Se ppm 28.2 42.2 25.0 12.7 13.5 16.7 22.6 49.6 9.46 Te ppb 9.56 47.4 a WK1frag is the average of mica gneiss fragments in migmatites. Values in parentheses include many determinations below the detection limit C graf 0.05 and Pd 0.2 ppm and show either the detection limit value or averages excluding values below detection limits. b One to two anomalous analyses have been excluded from some group averages. elements indicate a more mafic source compared to local Archaean bedrock at the present erosion level Figs. 4 and 5, and Table 1. The Ar2 samples show variable REE and have higher CaO, Na 2 O and lower K 2 O, Cr and Rb compared to Ar1 see Fig. 4 for K 2 O and Cr. The lower CIA indicates less weathering relative to Ar1 and low ThSc 0.09 – 0.17 favours a dominant mafic source. 4 . 2 . Cratonic co6er The Jatuli-type quartzites of this study show a strong increase in K 2 O with decreasing SiO 2 Fig. 4, which is mainly due to variations in sericite muscovite content. One subarkose contains fresh K-feldspar also seen in a lower CIA value but otherwise high CIA is a characteristic feature. The sedimentary rocks in the Ho¨ytia¨inen basin are classified into high- and low-Cr groups H1 and H3, respectively Fig. 4, Table 1. A distinct litho- logical unit Huhma, 1975 of high-Cr rocks is classified as group H2 and a suspect group of low-Cr rocks, possibly related to the Western Kaleva Kohonen, 1995, is classified as group H4. Samples outside the Ho¨ytia¨inen area Fig. 2, but that occur in autochthonous position to Ar- chaean dome rocks or are geochemically similar, are included in these groups. The H1 – H3 samples include quartz-rich greywackes and more typically pelites showing thin layering from 1 – 3 mm to 1 – 2 cm with thin psammitic interlayers occurring locally. The variation in element abundances in- side the H1 group is mainly explained by quartz dilution Fig. 4. There is evidence of weathering in at least one component CIA 54 – 70 and a Fig. 3. Major- and trace-element distributions in Karelian craton 1, Western Kaleva psammites WK1, Jatuli-type mafics and Kutsu-type granites normalized to Archaean Crust AC1 in Table 1. The Karelian craton KC1 and WK1 averages are from Table 1 and the averages for Jatuli-type mafics N = 21 and Kutsu granites N = 8 are from Lahtinen unpublished data. R . Lahtinen Precambrian Research 104 2000 147 – 174 155 Table 2 Average chemical composition of selected sedimentary groups non-migmatized, except CF3 average including also mica gneiss fragments in migmatites a CF3 RH2mig CF2 RH3lCr CF1 RH4hCr CF3mig RH1 RH2 N = 4 N = 4 N = 14 N = 5 N = 6 N = 6 N = 14 N = 7 N = 12 72.37 69.70 63.71 63.71 70.75 SiO 2 67.94 61.99 64.95 76.50 0.53 0.69 0.52 0.60 0.73 0.74 0.73 0.79 TiO 2 0.58 13.25 14.20 12.78 13.47 15.24 15.71 16.13 Al 2 O 3 17.84 11.75 3.78 4.56 5.97 6.33 5.25 7.18 4.51 FeO 3.78 5.77 0.07 0.03 0.06 0.07 0.08 0.09 0.05 0.06 0.08 MnO 2.78 1.38 1.56 2.21 3.04 2.92 2.30 3.17 2.05 MgO 1.91 2.13 1.88 1.94 2.44 CaO 2.04 0.89 1.23 0.52 2.91 2.54 2.97 2.94 2.59 2.57 2.18 Na 2 O 1.67 1.67 2.58 2.59 3.41 3.28 2.55 2.71 K 2 O 2.59 3.81 3.97 0.17 0.10 0.15 0.16 0.15 0.12 0.13 0.12 0.15 P 2 O 5 0.05 0.05 0.08 0.15 C graf. 0.05 0.25 0.09 0.05 0.05 0.023 0.033 0.11 0.082 0.23 0.10 S 0.051 0.043 0.41 0.064 0.0488 0.052 0.064 0.075 0.076 0.085 0.12 0.052 F 55.1 56.4 54.6 54.8 58.0 58.8 CIA 64.8 62.3 68.8 47.6 37.9 34.2 37.0 37.9 44.8 30.7 La ppm 31.4 44.1 94.3 74.8 69.1 74.3 Ce ppm 63.2 86.9 88.7 75.8 62.5 10.5 8.69 8.16 8.79 7.34 Pr ppm 8.64 10.4 10.1 7.42 37.9 32.0 Nd ppm 30.3 27.5 32.1 38.0 38.4 32.3 27.3 6.53 5.87 5.61 5.95 5.23 7.29 5.63 Sm ppm 4.98 6.85 1.12 0.94 1.21 1.17 1.10 1.10 1.33 1.19 1.06 Eu ppm 5.59 5.28 5.15 5.46 Gd ppm 4.32 6.08 6.46 5.03 4.44 0.80 0.75 0.75 0.80 0.65 0.63 Tb ppm 0.71 0.96 0.89 3.44 3.30 3.99 3.86 3.97 4.33 4.80 5.05 3.80 Dy ppm 0.67 0.64 0.81 0.77 0.78 0.89 0.94 0.95 0.72 Ho ppm 2.32 2.27 2.19 2.64 1.91 2.64 2.14 Er ppm 1.81 2.83 0.29 0.28 0.32 0.31 0.30 0.40 0.41 0.41 0.31 Tm ppm 1.85 1.78 2.12 2.09 2.22 2.60 2.84 2.52 2.03 Yb ppm 0.33 0.34 0.33 0.39 0.27 0.29 Lu ppm 0.30 0.39 0.40 408 534 640 618 630 595 771 639 Ba ppm 628 39.5 42.0 51.1 79.7 46.7 51.7 Cl ppm 75.0 59.5 91.8 16.3 8.93 9.86 14.2 17.9 19.6 14.1 19.2 13.2 Co ppm 158 107 81.2 92.9 119 126 116 149 97.3 Cr ppm 6.62 5.40 4.45 4.56 4.50 Hf ppm 5.46 4.41 5.01 5.10 9.59 9.48 11.4 12.0 Nb ppm 9.3 13.8 15.0 9.03 10.5 32.2 39.8 59.6 62.8 58.2 77.2 38.1 Ni ppm 42.8 60.2 108 115 104 107 144 145 155 208 101 Rb ppm 16.2 10.4 11.6 15.2 18.2 19.4 17.9 20.4 13.4 Sc ppm 301 294 242 238 282 Sr ppm 240 141 181 96.0 R . Lahtinen Precambrian Research 104 2000 147 – 174 Table 2 Continued CF3mig RH3lCr RH1 RH4hCr CF1 CF2 RH2mig CF3 RH2 N = 6 N = 5 N = 6 N = 14 N = 7 N = 12 N = 4 N = 14 N = 4 0.67 0.66 0.84 0.77 0.83 0.82 0.93 1.03 0.68 Ta ppm 10.4 8.12 15.2 11.2 10.3 11.1 Th ppm 9.6 12.9 13.8 2.39 1.98 2.74 2.56 2.56 2.21 3.18 3.32 U ppm 2.29 87.5 112 144 146 143 160 107 V ppm 88.9 153 22.2 21.3 24.0 23.1 23.9 27.8 30.1 33.1 23.2 Y ppm 100 94.3 64.0 78.1 101 116 157 166 69.9 Zn ppm 267 218 178 181 181 227 Zr ppm 225 175 203 0.067 0.061 0.039 0.044 0.063 0.071 Ag ppm 0.088 0.096 0.059 0.58 1.43 0.92 0.60 2.11 1.38 As ppm b 1.03 0.56 1.12 1.38 0.67 0.46 0.82 0.67 0.38 1.16 0.84 0.88 Au ppb b 0.17 0.14 0.056 0.12 0.18 0.045 0.24 0.23 0.12 Bi ppm 11.3 16.6 33.2 53.2 27.0 Cu ppm 19.0 24.0 32.4 30.8 0.2 0.29 Pd ppb b 0.48 0.25 0.85 0.82 1.02 0.28 0.25 0.042 0.041 0.032 0.037 0.083 0.027 0.059 Sb ppm 0.045 0.089 0.10 0.18 0.053 0.10 0.13 0.18 0.56 0.12 0.053 Se ppm 17.4 10.6 6.6 14.8 23.5 28.2 Te ppb b 36.0 8.7 21.4 a The RH2mig and BB4mig are the averages of migmatites, respectively. Group RH3 have been divided into low-Cr RH3lCr and high-Cr RHhCr populations. Values in parentheses include many determinations below the detection limit C graf 0.05 and Pd 0.2 ppm and show either the detection limit value or averages calculated excluding values below detection limits. b One to two anomalous analyses have been excluded from some group averages. Fig. 4. Harker-type Cr, K 2 O, MgO and CIA Nesbitt and Young, 1982 variation diagrams for Archaean, autochthonous and allochthonous sedimentary rocks in the study area. Ar1 and Ar2-Archaean, Jqzt – Jatuli-type quartzites, H1 – H2-autochthonous high-Cr, H3-autochthonous low-Cr, H4- a low-Cr suspect group of Ho¨ytia¨inen area. WK1 – WK2 main field-allochthonous Western Kaleva. AC1 is the average of Archaean crust Table 1. large mafic component indicated by high contents of HREE, MgO and Pd. The H2 group has many compositional similarities with H1 but the H2 average shows higher levels of most elements e.g. MgO and lower SiO 2 Fig. 4 and Table 1. Some H3 pelites show enrichment of felsic source com- ponents manifested as low MgO contents Fig. 4. The K 2 O, Rb and Bi enrichment not shown favour a source dominated by a late-Archaean granite Kutsu; see Fig. 3. The H4 is a heteroge- neous group that deviates to some extent from the WK1 main group in having higher K 2 O and lower Cr Fig. 4. The allochthonous Western Kaleva WK sedi- mentary rocks have been divided into WK psam- mites and SiO 2 -poor pelitic rocks WK2. The WK1 psammites Table 1 form a geochemically homogeneous group Fig. 4 and most of the variation can be explained by grain size variation. The more pelitic nature of WK2 is seen in enrich- ment of elements e.g. Al 2 O 3 , MgO, FeO, K 2 O that characterize clay minerals Table 1 but the WK2 also seems to be enriched in a mafic source as seen in higher Sc and Cr relative to Th. The WK1 migmatites are mainly psammitic fragments floating in tonalitic often trondjhemitic veined gneisses WK2 migmatites. Both groups of migmatites only show the systematic depletion of Bi compared to non-migmatitic samples Table 1. 4 . 3 . Boundary zone and S6ecofennian sedimentary rocks The sedimentary rocks in the boundary zone BZ; Fig. 2 have been divided into psammitic BZ1 and pelitic BZ2 groups. The BZ1 rocks are heterogeneous in chemical composition show- ing high variation, e.g. in HREE, CaO, K 2 O, Th and Nb and the average Table 1 should be only considered as an areal average. The southern Svecofennian sedimentary rocks in the Rantasalmi – Haukivuori area have been classified into three groups RH1 – RH3. The non-migmatitic RH1 rocks are quartz-rich greywackes and the well-preserved RH2 rocks are more pelitic in character. Both RH1 and RH2 show rather similar patterns in Fig. 6 where the strong effect of weathering is seen in negative peaks of Ba, Sr, CaO, MnO and P 2 O 5 , and high CIA values Table 2. The depletion of HREE, Sc, V, TiO 2 and enrichment of K 2 O, Rb, Th and especially U is the main difference when com- pared to the Western Kaleva source. A relative Fig. 5. Plots of La vs. Yb and EuEu vs. Gd N Yb N for selected sedimentary rocks in this study. Gd N and Yb N are chondrite-normalized values and EuEu has been calculated using Eu = Sm N + Gd N 2. The Archaean average has been calculated from the average in the Table 1 and Jatuli-type mafics from the average N = 21 in Lahtinen unpublished data. Ar – Ar2-Archaean groups, Jqtz – Jatuli-type quartzites, H1 – H2-autochthonous high-Cr, H3-autochthonous low-Cr, RH1 – RH2- southern Svecofennian, RH3-southern Svecofennian. CF1 – CF3-central Svecofennian. Fig. 6. Major- and trace-element distributions in averages of southern Svecofennian sedimentary rock groups RH1 – RH3 Table 2 from the Rantasalmi – Haukivuori area normalized to the average of Western Kaleva psammites WK1 in Table 1. RH3lCr and RH3hCr are averages of low- and high-Cr populations of RH3. enrichment of Zn to Ni and Co is also a charac- teristic feature. The RH2 group shows the relative enrichment of CaO, Ba, Nb, V and Sc and low CrSc ratio favouring a new additional mafic component in the RH2. The lower CIA values Table 2, which are normally higher in more pelitic rocks, indicate that this additional compo- nent was less weathered. Compared to the RH1 and RH2 rocks the RH3 samples show lower CIA and higher CaO and Na 2 O with strong variation in the amount of mafic component Fig. 6 and Table 2. The RH1 – RH2 migmatites vary from gneisses with quartz veins and small melt patches cut by pegmatites to veined gneisses with abundant gran- ite leucosome. The main differences Table 2 can be interpreted to show a more pelitic precursor for migmatites but the slightly lower REE and especially deep negative Eu anomaly in some sam- ples ask for a loss of felsic component. The slight depletion in Ba, K 2 O and KRb can be related to a loss of a K-feldspar component and the enrich- ment of ferromagnesian components to the in- creased amount of restite. So it seems that these migmatites are mainly in situ migmatites that show a complex mixture of restite and a melt fraction in variable proportion in outcrop scale. The sedimentary rocks in the central Svecofen- nian have been divided to three groups CF1 – CF3 where the CF1 includes high-SiO 2 and high ThSc ] 1 psammites, CF2 lower ThSc 5 1 psammites and CF3 silt-pelite rocks. The non- migmatitic CF1 samples show LREE enrichment compared to the Western Kaleva psammites Fig. 5. The depletion of elements characteristic of mafic components and the relative enrichment of LREE, Sr, Th, U and Zr point to a larger felsic component relative to the WK psammites. The chemical composition of the CF2 group shows an enrichment of mafic components relative to CF1. CF3 is a heterogeneous group characterized by migmatites and thus the average Table 2 in- cludes also mica gneiss fragments in migmatites. Mineralogically the CF3 rocks differ from the CF1 – CF2 in the ubiquitous occurrence of garnet. The more clay-rich nature of CF3 is seen in lower SiO 2 and higher MgO and K 2 O Table 2. The CF3 migmatites form an inhomogeneous group ranging from samples with HREE enrichment to samples with HREE depletion and Eu enrichment at low total REE abundances compared with less migmatitic CF3 samples. This is interpreted as different amounts of restite and leucosome in sampled outcrops.

5. Discussion