R. Durig, D. A. C. Compton, and A. Q. McArver, Chem. Phys., 73, 719-724 1980. Sbrana and V. Schettino, J. Molec. Spectrosc., 33, 100-108 1970. This value contributes van den Enden, C. van Alsenoy, and H. J. Geise, J. Mol. Struct., 116, 99-118 1984. Shim

15 . S. Ruschin and S. H. Bauer, J. Phys. Chem., 84, 3061-3064 1980. 16 . J. M. Riveros and E. B. Wilson Jr., J. Chem. Phys., 46, 4605-4612 1967. This quantity is reported to be the energy difference between the lowest vibrational levels, but its calculation from measured microwave intensities at a single temperature suggests that it may be a free- energy difference, presumably corrected for the two-fold statistical factor favoring the C-O-C-C gauche conformer; no later report on this measurement appears to have been made. 17 . J. R. Durig, D. A. C. Compton, and A. Q. McArver, J. Chem. Phys., 73, 719-724 1980. 18 .

G. Sbrana and V. Schettino, J. Molec. Spectrosc., 33, 100-108 1970. This value contributes

to the composite value of 0.95 kcalmol cited in ref. 1. For other references, see: P. van Nuffel,

L. van den Enden, C. van Alsenoy, and H. J. Geise, J. Mol. Struct., 116, 99-118 1984.

19 .

T. Shimanouchi, Y. Abe, and M. Makami, Spectrochim. Acta A, 24A, 1037-1053 1968.

20 .

Y. N. Panchenko, A. V. Abramenkov and C. W. Bock, J. Mol. Struct., 140, 87-92 1985.

21 . J. R. Durig, W. E. Bucy, and A. R. H. Cole, Can. J. Phys., 53, 1832-1837 1975. 22 .

L. Carreira, J. Chem. Phys., 62, 3851-3854 1975.

23 . Y. N. Panchenko, V. I. Pupyshev, A. V. Abramenkov, M. Traetteberg, and S. J. Cyvin, J. Mol. Struct., 130, 355-359 1985. 24 .

C. E. Blom and A. Bauder, Chem. Phys. Lett., 88, 55-58 1982. Note that this value

supersedes the earlier result of 1.6 kcalmol obtained by C. E. Blom, R. P. Müller and Hs. H. Günthard, Chem. Phys. Lett., 73, 483-486 1980. 25 .

E. J. Bair, W. Goetz, and D. A. Ramsay, Can. J. Phys., 49, 2710-2717 1971. A note added

in proof to this paper reports a correction, agreed to by the original authors, to the value of 2.00 ± 0.11 kcalmol published by: A. C. P. Alves, J. Christoffersen, and J. M. Hollas, Mol. Phys., 20, 625-644 1971; 21, 384 1971. 26 .

P. Huber-Wälchi and Hs. H. Günthard, Chem. Phys. Lett., 30, 347-351. This result and the