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51
Lampiran 1 Data metode Joback
Non ring increments Tc
Pc Vc
Tb Tf
∆
H
∆
G
∆a ∆b
∆c ∆d
–CH
3
1.41E-02 -1.20E-03
65.00 23.58
-5.10 -76.45
-43.96 19.50
-8.08E-03 1.53E-04 -9.67E-08
CH
2
1.89E-02 0.00E+00
56.00 22.88
11.27 -20.64
8.42 -0.91
9.50E-02 -5.44E-05 1.19E-08
CH- 1.64E-02
2.00E-03 41.00
21.74 12.64
29.89 58.36
-23.00 2.04E-01 -2.65E-04
1.20E-07 C
6.70E-03 4.30E-03
27.00 18.25
46.43 82.23
116.02 -66.20
4.27E-01 -6.41E-04 3.01E-07
.=CH
2
1.13E-02 -2.80E-03
56.00 18.18
-4.32 -9.63
3.77 23.60
-3.81E-02 1.72E-04 -1.03E-07
=CH- 1.29E-02
-6.00E-04 46.00
24.96 8.73
37.97 48.53
-8.00 1.05E-01 -9.63E-05
3.56E-08 =C
1.17E-02 1.10E-03
38.00 24.14
11.14 83.99
92.36 -28.10
2.08E-01 -3.06E-04 1.46E-07
=C= 2.60E-03
2.80E-03 36.00
26.15 17.78
142.14 136.70
27.40 -5.57E-02
1.01E-04 -5.02E-08 CH
2.70E-03 -8.00E-04
46.00 9.20
-11.18 79.30
77.71 24.50
-2.71E-02 1.11E-04 -6.78E-08
C- 2.00E-03
1.60E-03 37.00
27.38 64.32
115.51 109.82
7.87 2.01E-02 -8.33E-06
1.39E-09
TRIGLISERIDA Tripalmitate
Gugus nj
njH njG
nja njb
njc njd
CH2 44
-908.16 370.48
-40.00 4.18 -2.39E-03
5.24E-07 –CH3
3 -229.35
-131.88 58.50
-0.02 4.59E-04
-2.90E-07 .-COO-Ester
3 -1013.76
-905.85 73.50
0.12 1.21E-04
-1.36E-07 CH-
1 29.89
58.36 -23.00
0.20 -2.65E-04 1.20E-07
Total -2121.38
-608.89 69.00
4.48 -2.08E-03 2.18E-07
Triste arate
Gugus nj
njH njG
nja njb
njc njd
CH2 50
-1032.00 421.00
-45.45 4.75
-2.72E-03 5.95E-07
–CH3 3
-229.35 -131.88
58.50 -0.02
4.59E-04 -2.90E-07
.-COO-Ester 3
-1013.76 -905.85
73.50 0.12
1.21E-04 -1.36E-07
CH- 1
29.89 58.36
-23.00 0.20
-2.65E-04 1.20E-07
Total -2245.22
-558.37 63.55
5.05 -2.41E-03
2.89E-07
Triole at
Gugus nj
njH njG
nja njb
njc njd
CH2 44
-908.16 370.48
-40.00 4.18
-2.39E-03 5.24E-07
=CH- 6
227.82 291.18
-48.00 0.63
-5.78E-04 2.14E-07
–CH3 3
-229.35 -131.88
58.50 -0.02
4.59E-04 -2.90E-07
.-COO-Ester 3
-1013.76 -905.85
73.50 0.12
1.21E-04 -1.36E-07
CH- 1
29.89 58.36
-23.00 0.20
-2.65E-04 1.20E-07
Total
-1893.56 -317.71
21.00 5.11
-2.66E-03 4.32E-07
Trilinole at
Gugus nj
njH njG
nja njb
njc njd
CH2 38
-784.32 319.96
-34.54 3.61
-2.07E-03 4.52E-07
–CH3 3
-229.35 -131.88
58.50 -0.02
4.59E-04 -2.90E-07
=CH- 12
25.08 135.60
-25.68 0.69
-1.97E-05 -1.91E-07
.-COO-Ester 3
-1013.76 -905.85
73.50 0.12
1.21E-04 -1.36E-07
CH- 1
29.89 58.36
-23.00 0.20
-2.65E-04 1.20E-07
Total -1972.46
-523.81 48.78
4.60 -1.77E-03
-4.43E-08
53
METHYL ESTER Me thyl palmitate
Gugus nj
njH njG
nja njb
njc njd
CH2 14
-288.96 117.88
-12.73 1.33
-7.62E-04 1.67E-07
–CH3 2
-152.90 -87.92
39.00 -0.02
3.06E-04 -1.93E-07
.-COO-Ester 1
-337.92 -301.95 24.50
0.04 4.02E-05
-4.52E-08
Total -779.78 -271.99
50.77 1.35
-4.15E-04 -7.20E-08
Me thyl ste arate
Gugus nj
njH njG
nja njb
njc njd
CH2 16
-330.24 134.72
-14.54 1.52
-8.70E-04 1.90E-07
–CH3 2
-152.90 -87.92
39.00 -0.02
3.06E-04 -1.93E-07
.-COO-Ester 1
-337.92 -301.95 24.50
0.04 4.02E-05
-4.52E-08
Total -821.06 -255.15
48.96 1.54
-5.24E-04 -4.82E-08
Me thyl ole ate
Gugus nj
njH njG
nja njb
njc njd
CH2 14
-288.96 117.88
-12.73 1.33
-7.62E-04 1.67E-07
–CH3 2
-152.90 -87.92
39.00 -0.02
3.06E-04 -1.93E-07
=CH- 2
4.18 22.60
-4.28 0.11
-3.28E-06 -3.18E-08
.-COO-Ester 1
-337.92 -301.95 24.50
0.04 4.02E-05
-4.52E-08
Total
-775.60 -249.39 46.49
1.47 -4.19E-04
-1.04E-07
TRIGLISERIDA TOTAL
njH njG
nja njb
njc njd
∆Hf kJmol ∆Gf kJmol Cp Jmol K Tripalmitate
-2121.38 -608.89
69.00 4.48 -2.08E-03
2.18E-07 -2053.09
-555.01 1227.33
Tristearate -2245.22
-558.37 63.55
5.05 -2.41E-03 2.89E-07
-2176.93 -504.49
1365.43 Trioleat
-1893.56 -317.71
21.00 5.11 -2.66E-03
4.32E-07 -1825.27
-263.83 1322.09
Trilinoleat -1972.46
-523.81 48.78
4.60 -1.77E-03 -4.43E-08 -1904.17
-469.93 1263.27
1.47 kJkgK
Me thyl Este r Total
njH njG
nja njb
njc njd
∆Hf kJmol-∆Gf kJmol Cp Jmol K Methyl palmitate
-779.78 -271.99
50.77 1.35 -4.15E-04 -7.20E-08
-711.49 -218.11
413.10 Methyl stearate
-821.06 -255.15
48.96 1.54 -5.24E-04 -4.82E-08
-752.77 -201.27
459.13 Methyl oleate
-775.60 -249.39
46.49 1.47 -4.19E-04 -1.04E-07
-707.31 -195.51
442.10 Methyl linoleate
-730.14 -243.63
44.03 1.39 -3.13E-04 -1.59E-07
-661.85 -189.75
425.08 1.48 kJkgK
Me thyl linole ate
Gugus nj
njH njG
nja njb
njc njd
CH2 12
-247.68 101.04
-10.91 1.14
-6.53E-04 1.43E-07
–CH3 2
-152.90 -87.92
39.00 -0.02
3.06E-04 -1.93E-07
=CH- 4
8.36 45.20
-8.56 0.23
-6.56E-06 -6.36E-08
.-COO-Ester 1
-337.92 -301.95
24.50 0.04
4.02E-05 -4.52E-08
Total -730.14
-243.63 44.03
1.39 -3.13E-04
-1.59E-07
GLISEROL T
300 Gugus
nj njH
njG nja
njb njc
njd ∆Hf kJmol-∆Gf kJmol Cp Jmol K
CH2 2
-41.28 16.84
-1.82 0.19
-1.09E-04 2.38E-08
27.01 70.72
41.47 CH-
1 29.89
58.36 -23.00
0.20 -2.65E-04
1.20E-07 98.18
112.24 13.03
.-OH Alkohol 3
-624.12 -567.60
77.10 -0.21
5.31E-04 -2.96E-07
-555.83 -513.72
50.14
Total -635.51
-492.40 52.28
0.19 1.57E-04
-1.53E-07 -567.22
-438.52 113.76
1.24 kJkgK