Free energy and localization properties

536 Electronic Communications in Probability could be relaxed, allowing them to take the value + ∞ outside some interval −M, M, but we stick for simplicity to the above stated assumptions. The model P ǫ,N is an example of a random polymer model, more precisely a homogeneous pinning model. A lot of attention has been devoted to this class of models in the recent mathematical literature see [ 8 , 7 ] for two beautiful monographs. The main question, for models like ours, is whether the pinning reward ǫ ≥ 0 is strong enough to localize the field at the defect line for large N . The case when the self-interaction of the field is of purely gradient type, i.e., when V 2 ≡ 0 in 1, has been studied in depth [ 1 , 3 , 6 , 2 ], as well as the purely Laplacian case when V 1 ≡ 0, cf. [ 4 , 5 ]. We now consider the mixed case when both V 1 6≡ 0 and V 2 6≡ 0, which is especially interesting from a physical viewpoint, because of its direct relevance in modeling semiflexible polymers, cf. [ 9 ]. Intuitively, the gradient interaction penalizes large elongations of the chain while the Laplacian interaction penalizes curvature and bendings.

1.2 Free energy and localization properties

The standard way to capture the localization properties of models like ours is to look at the ex- ponential rate of growth Laplace asymptotic behavior as N → ∞ of the partition function Z ǫ,N . More precisely, we define the free energy F ǫ of our model as F ǫ := lim N →∞ 1 N log ‚ Z ǫ,N Z 0,N Œ , 4 where the limit is easily shown to exist by a standard super-additivity argument [ 8 ]. The function ǫ 7→ Z ǫ,N is non-decreasing for fixed N cf. 3, hence ǫ 7→ Fǫ is non-decreasing too. Recalling that F 0 = 0, we define the critical value ǫ c as ǫ c := sup {ǫ ≥ 0 : Fǫ = 0} = inf{ǫ ≥ 0 : Fǫ 0} ∈ [0, ∞] , 5 and we say that our model {P ǫ,N } N ∈N is • delocalized if ǫ ǫ c ; • localized if ǫ ǫ c . This seemingly mysterious definition of localization and delocalization does correspond to sharply different behaviors of the typical trajectories of our model. More precisely, denoting by ℓ N := {1 ≤ i ≤ N − 1 : ϕ i = 0} the number of contacts between the linear chain and the defect line, it is easily shown by convexity arguments that • if ǫ ǫ c , for every δ 0 there exists c δ 0 such that P ǫ,N ℓ N N δ ≤ e −c δ N , for all N ∈ N ; 6 • if ǫ ǫ c , there exists δ ǫ 0 and c ǫ 0 such that P ǫ,N ℓ N N δ ǫ ≤ e −c ǫ N , for all N ∈ N . 7 In words: if the model is delocalized then typically ℓ N = oN , while if the model is localized then typically ℓ N ≥ δ ǫ N with δ ǫ 0. We refer, e.g., to [ 4 , Appendix A] for the proof of these facts. We Localization for ∇ + ∆-pinning models 537 point out that the behavior of the model at the critical point is a much more delicate issue, which is linked to the regularity of the free energy. Coming back to the critical value, it is quite easy to show that ǫ c ∞ it is a by-product of our main result, that is, the localized regime is non-empty. However, it is not a priori clear whether ǫ c 0, i.e. whether the delocalized regime is non-empty. For instance, in the purely Laplacian case V 1 ≡ 0, cf. [ 4 ], one has ǫ ∆ c 0. On the other hand, in the purely gradient case V 2 ≡ 0, cf. [ 2 ] one has ǫ ∇ c = 0 and the model is said to undergo a trivial phase transition: an arbitrarily small pinning reward is able to localize the linear chain. The main result of this note is that in the general case of mixed gradient and Laplacian interaction the phase transition is always trivial. Theorem 1. For any choice of the potentials V 1 , V 2 satisfying assumptions C1 and C2 one has ǫ c = 0, i.e., F ǫ 0 for every ǫ 0. Generally speaking, it may be expected that the gradient interaction terms should dominate over the Laplacian ones, at least when V 1 and V 2 are comparable functions. Therefore, having just recalled that ǫ ∇ c = 0, Theorem 1 does not come as a surprise. Nevertheless, our assumptions C1 and C2 are very general and allow for strikingly different asymptotic behavior of the poten- tials: for instance, one could choose V 1 to grow only logarithmically and V 2 exponentially fast or even more. The fact that the gradient interaction dominates even in such extreme cases is quite remarkable. Remark 2. Our proof yields actually an explicit lower bound on the free energy, which is however quite poor. This issue is discussed in detail in Remark 9 in section 3 below. Remark 3. Theorem 1 was first proved in the Ph.D. thesis [ 1 ] in the special case when both interaction potentials are quadratic: V 1 x = α 2 x 2 and V 2 x = β 2 x 2 , for any α, β 0. We point out that, with such a choice for the potentials, the free model P 0,N is a Gaussian law and several explicit computations are possible.

1.3 Organization of the paper

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