4.1.2 Penentuan Kandungan Lemak Padat SFC , MP dan IV.
Untuk mengetahui hasil hidrogenasi telah memenuhi spesifikasi coating fat maka perlu dilakukan analisa kandungan lemak padat SFC, titik leleh MP dan
bilangan yodium IV serta hubungan antara parameter analisa percobaan tersebut untuk reaksi hasil hidrogenasi parsial menggunakan katalis Ni dan gas hidrogen,
interesterifikasi , blending , masing-masing ditunjukkan tabel 4.9 sd 4.16. Tabel 4.9. Hubungan antara SFC, IV dan MP Hasil Hidrogenasi Parsial RBDPKO
, kondisi operasi reaksi 1-4 :
NO SFC
IV MP
20 25
30 35
40 45
1.1 76.30
41.93 8.18
0.15 0.14
0.06 8.89
31.2 1.2
81.37 48.25
14.32 2.51
-0.17 -0.10
6.57 32.8
NO SFC
IV MP
20 25
30 35
40 45
2.1 71.04
33.07 2.65
-0.34 -0.09
-0.28 10.71
29.2 2.2
74.33 37.94
5.12 -0.05
0.00 0.16
9.63 30.6
2.3 76.83
41.15 7.12
0.13 0.01
-0.22 8.69
30.2 2.4
79.49 43.40
8.75 0.28
-0.37 0.04
8.11 31.8
2.5 80.68
45.91 10.88
1.02 0.13
-0.11 7.69
32.6 2.6
81.68 48.27
12.59 1.35
-0.16 0.17
7.01 33.2
2.7 82.18
50.10 14.73
1.89 -0.20
0.03 6.39
33.2 2.8
83.79 51.10
15.64 2.81
0.11 -0.20
5.86 34.0
2.9 84.85
54.6 18.44
3.71 -0.22
0.00 5.09
34.6
NO SFC
IV MP
20 25
30 35
40 45
3.1 70.85
32.48 2.80
-0.20 -0.07
-0.06 10.23
28.8 3.2
73.76 39.61
5.73 0.11
0.07 -0.16
9.07 30.8
3.3 77.62
41.73 7.86
0.53 -0.02
-0.32 8.20
32.0 3.4
79.50 44.89
9.78 0.99
0.11 -0.22
7.50 33.0
3.5 81.37
47.83 11.87
1.21 -0.21
-0.08 6.79
33.4 3.6
82.83 49.96
14.16 2.60
-0.01 0.05
6.00 33.8
NO SFC
IV MP
20 25
30 35
40 45
4.1 70.90
33.14 4.27
0.11 -0.07
-0.07 9.98
30.0 4.2
78.47 44.35
11.77 1.39
0.00 0.24
7.23 32.4
4.3 83.14
50.73 16.37
3.00 -0.06
-0.09 5.79
34.0 Tabel 4.10. Hubungan antara SFC, IV dan MP Hasil Hidrogenasi Parsial
RBDPKO , kondisi operasi reaksi 5-8 :
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NO SFC
IV MP
20 25
30 35
40 5.1
82.74 56.3
16.81 3.33
0.06 6.38
33.4
NO SFC
IV MP
20 25
30 35
40 6.1
70.76 39.89
5.05 -0.05
0.01 10.21
30.2 6.2
76.62 45.59
9.49 0.52
0.02 8.47
32.4 6.3
81.32 52.52
14.56 2.17
-0.07 6.74
33.6
NO SFC
IV MP
20 25
30 35
40
7.1 70.63
37.22 3.95
0.03 -0.2
10.3 29.6
7.2 74.75
43.49 6.71
-0.03 -0.15
9.28 31.6
7.3 76.60
47.50 10.49
1.06 -0.32
8.05 32.4
7.4 81.37
53.4 14.82
2.44 -0.14
6.29 33.6
NO SFC
IV MP
20 25
30 35
40
8.1 81.44
50.48 20.34
4.67 0.86
5.30 34.6
8.2 87.26
60.68 26.99
7.33 2.13
2.91 36.6
8.3 88.85
65.19 31.99
10.46 3.77
1.14 38.8
8.4 89.35
67.53 34.96
12.65 5.44
0.46 40.8
8.5 89.77
68.18 38.88
16.68 8.64
0.41 41.8
Tabel 4.11. Hubungan anatara SFC, IV dan MP Hasil Hidrogenasi Parsial RBDPKOlein , kondisi operasi reaksi O1:
NO SFC
IV MP
20 25
30 35
40 45
O1.1 59.26
28.84 8.36
2.43 -0.29
-0.02 10.43
30.6 O1.2
61.30 31.14
9.60 2.95
-0.15 -0.07
9.77 31.4
O1.3 62.65
33.74 10.94
3.51 0.10
0.01 9.06
31.4 O1.4
64.81 36.74
12.99 4.68
0.12 -0.37
8.31 31.6
64
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Tabel 4.12. Hubungan anatara SFC, IV dan MP Hasil Hidrogenasi Parsial RBDPKOlein , kondisi operasi reaksi O2-O5 :
NO SFC
IV MP
20 25
30 35
40 45
O2.1 58.99
29.63 8.44
2.36 0.09
-0.08 10.67
30.0 O2.2
59.57 32.67
10.02 3.28
0.07 0.09
9.73 30.3
O2.3 61.20
34.16 12.34
3.93 0.07
-0.10 9.24
30.8 O2.4
63.66 36.81
13.83 4.81
0.20 -0.24
8.51 31.6
O2.5 65.73
38.44 14.73
5.70 0.76
0.16 7.77
32.0 O2.6
69.77 44.56
20.51 8.99
2.60 -0.17
5.71 33.0
NO SFC
IV MP
20 25
30 35
40 45
O3.1 57.15
27.33 7.64
2.23 0.06
0.07 10.52
30.2 O3.2
63.22 34.72
12.22 4.56
0.14 -0.07
8.45 31.4
O3.3 66.48
40.94 16.66
6.77 1.11
-0.02 6.99
32.4 O3.4
67.44 44.3
20.44 8.60
2.27 -0.10
5.86 34.0
NO SFC
IV MP
20 25
30 35
40 45
O4.1 60.94
33.56 11.19
3.95 -0.09
-0.11 8.82
30.8 O4.2
68.47 43.69
19.27 8.04
2.18 -0.28
5.72 33.8
NO SFC
IV MP
20 25
30 35
40 45
O5.1 60.34
25.77 7.99
1.65 -0.21
0.00 11.12
34.2 O5.2
63.65 32.98
9.39 2.92
-0.22 0.00
10.32 34.4
O5.3 63.21
29.55 10.87
3.00 -0.12
0.00 10.13
34.6 O5.4
66.21 33.50
12.09 3.28
-0.37 0.00
9.47 34.8
O5.5 67.83
35.80 13.22
4.07 -0.42
0.00 8.77
35.2 O5.6
69.08 37.02
14.66 4.23
0.08 0.00
8.22 35.2
O5.7 70.58
40.09 16.15
5.16 0.94
0.00 7.64
35.4 O5.8
72.86 44.16
18.99 6.78
1.56 0.00
6.66 35.8
O5.9 72.94
44.18 19.26
6.72 1.58
0.00 6.54
36.0 O5.10
73.77 47.65
22.18 7.86
2.05 0.00
5.72 36.6
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Tabel 4.13. Hubungan antara SFC , IV dan MP Blending antara RBDHPKO + RBDPKO , kondisi operasi reaksi blending :
No SFC
IV MP
20 25
30 35
40 B1
89.35 69.82
36.81 14.04
6.25 0.26
39.6 B2
42.89 18.34
0.00 0.00
0.00 17.27
27.6 B3
48.25 20.94
0.27 0.00
0.00 15.56
28.6 B4
54.03 26.12
2.65 0.37
0.00 13.85
30.2 B5
59.64 29.61
5.65 1.05
0.00 12.09
30.6 B6
64.43 35.59
9.25 2.65
0.48 10.36
32.0 B7
68.88 41.26
13.5 3.92
1.14 8.76
33.2 B8
73.32 46.19
17.08 5.24
2.21 7.13
34.2 B9
77.33 52.69
22.23 7.22
2.76 5.38
37.2 B10
81.63 58.63
26.45 9.25
3.99 3.73
37.8 B11
85.33 63.33
30.57 11.07
5.02 2.08
38.2
Tabel 4.14. Hubungan antara SFC , IV dan MP Hasil sebelum dan sesudah Interesterifikasi.
Sampel SFC
IV MP
20 25
30 35
40 45
RBDPKO
43.25 17.5
-0.26 17.36 27.0
IE RBDPKO
27.92 4.37
-0.06 17.30 25.6
RBDHPKO
87.77 66.44 32.66 11.08 4.68
0.27 0.302 39.0
IE RBDHPKO
67.09 39.59 14.52 -0.19 -0.39 -0.17 0.402 32.4
RBDHPO
87.77 66.44 32.66 11.08 4.68
0.27 33.45 39.0
IE RBDHPO
67.09 39.59 14.52 -0.19 -0.39 -0.17 33.45 32.4
RBDHPO
52.03 39.17 26.99 17.54 8.56
1.18 44.09 43.2
IE RBDHPO
44.40 32.87 22.46 14.16 5.80
0.02 43.75 40.8
RBDHPKO:RBDHPO=88:12
81.51 62.51 37.73 9.70
-0.26 0.30
37.2
IE RBDHPKO:RBDHPO=88:12
80.15 61.48 37.52 9.73
-0.09 0.30
37.4
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Tabel 4.15. Hubungan antara SFC , IV dan MP blending antara RBDPST dengan RBDPKL dan dilanjutkan dengan interesterifikasi
Parameter RBDPST : RBDPKL =
70:30 RBDPST : RBDPKL =
60:40 RBDPST : RBDPKL =
50:50 sebelum
sesudah IE sebelum
sesudah IE sebelum
sesudah IE IE
Trial 1 Trial 2 IE
Trial 1 Trial 2
IE Trial 1
Trial 2
IV 22.1
23.1 22.8
SMP 53.6
48.2 48.4
51.8 33.8
33.6 52.6
38.0 38.2
SFC, 10°C
78.3 85.8
86.8 72.7
74.6 74.4
67.3 72.5
75.6 20°C
63.0 70.9
71.0 45.8
47.2 46.9
38.1 54.3
53.4 25°C
55.0 56.9
57.3 38.3
30.0 28.8
31.0 37.9
37.2 30°C
49.8 43.7
44.1 33.4
16.2 15.8
26.7 23.1
23.0 35°C
43.8 29.3
29.8 28.4
5.1 4.8
22.6 11.2
11.0 40°C
37.8 17.8
19.4 23.6
0.3 0.1
18.3 1.7
1.4 Tabel 4.16. Hubungan antara SFC , IV dan MP blending antara RBDHPKO
dengan RBDHPKOlein.
No. RBDHPKO IV 0.79 :
IV MP
SFC, at °C
RBDHPKOLEIN IV 8.87
10 20
25 30
35 40
1 100 : 0
0.79 40.0 94.46 86.84 68.55 32.94 11.55 5.71
2 95 : 5
1.20 39.8 94.40 86.04 66.50 31.70 11.14 5.49
3 90 : 10
1.38 39.6 94.28 84.22 64.46 30.68 10.83 5.40
4 85 : 15
1.56 39.6 94.06 83.98 62.95 29.62 10.38 5.04
5 80 : 20
1.98 39.4 93.75 83.40 61.59 28.60
9.95 5.09
6 75 : 25
2.70 39.2 93.92 82.41 59.11 27.50
9.85 5.26
7 70 : 30
2.93 39.0 93.72 81.80 57.35 26.34
9.53 4.83
8 65 : 35
3.27 38.8 93.02 81.69 56.40 25.18
8.94 4.61
9 60 : 40
3.86 38.6 92.75 80.66 54.12 24.34
8.83 4.29
10 55 : 45
4.06 38.4 92.51 79.16 52.81 23.21
8.56 3.90
11 50 : 50
4.55 38.2 92.31 78.61 51.54 22.35
7.80 3.76
12 45 : 55
4.96 37.8 91.74 76.87 50.27 21.87
7.52 3.50
13 40 : 60
5.24 37.4 91.51 75.20 48.81 20.33
7.43 3.19
14 35 : 65
5.68 37.0 90.38 74.80 47.48 19.81
7.16 2.89
15 30 : 70
5.97 36.8 89.68 73.61 45.72 18.71
6.75 2.78
16 25 : 75
6.46 36.4 88.09 71.21 44.30 18.69
6.27 1.78
17 20 : 80
6.80 36.0 87.85 70.55 42.07 17.41
5.95 1.80
18 15 : 85
7.09 35.2 87.83 69.58 40.90 16.33
5.65 1.32
19 10 : 90
7.47 34.8 87.43 68.81 39.92 15.47
5.21 1.20
20 5 : 95
8.04 34.4 87.71 67.41 38.28 14.24
5.04 0.97
21 0 : 100
8.87 34.0 87.40 67.70 38.09 13.69
4.62 0.90
Grafik : Hubungan antara IV, MP dan TFA hidrogenasi parsial RBDPKO
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Grafik 4.1 Grafik 4.2
Grafik 4.3 Grafik 4.4
Grafik 4.5 Grafik 4.6
Grafik 4.7 Grafik 4.8
Grafik : Hubungan antara IV, MP dan TFA hidrogenasi parsial RBDPKOlein Grafik 4.9
Grafik 4.10
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Grafik 4.11 Grafik 4.12
Grafik 4.13 Grafik 4.14
Grafik 4.15
Grafik : SFC hidrogenasi parsial RBDPKO
Grafik 4.16 Grafik 4.17
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Grafik 4.18 Grafik 4.19
Grafik 4.20 Grafik 4.21
Grafik 4.22 Grafik 4.23
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Grafik : SFC hidrogenasi parsial RBDPKOlein , Blending Grafik 4.24
Grafik 4.25
Grafik 4.26 Grafik 4.27
Grafik 4.28 Grafik 4.29
Grafik 4.30 Grafik 4.31
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4.2 PEMBAHASAN 4.2.1. Asam lemak trans TFA , Trans Fatty Acid
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